CN106478901A - A kind of chemical products are packed for aluminizer - Google Patents

A kind of chemical products are packed for aluminizer Download PDF

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Publication number
CN106478901A
CN106478901A CN201610895426.7A CN201610895426A CN106478901A CN 106478901 A CN106478901 A CN 106478901A CN 201610895426 A CN201610895426 A CN 201610895426A CN 106478901 A CN106478901 A CN 106478901A
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CN
China
Prior art keywords
parts
diester
aluminizer
packed
chemical products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610895426.7A
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Chinese (zh)
Inventor
李建萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUXI SANDI SPECIAL MACROMOLECULE MATERIALS Co Ltd
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WUXI SANDI SPECIAL MACROMOLECULE MATERIALS Co Ltd
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Priority to CN201610895426.7A priority Critical patent/CN106478901A/en
Publication of CN106478901A publication Critical patent/CN106478901A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/02Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonates or saturated polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/02Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of acids, salts or anhydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/08Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/06Coating with compositions not containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/12Esters; Ether-esters of cyclic polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/08Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of chemical products are packed for aluminizer, including:Film base layer and aluminium coated, described film base layer are made up of following components:Methacrylic acid hexafluoro isopropyl ester, butyl benzyl phthalate, 1 octadecane epoxide, 2 DHA, 3 oleic acid AKGs diester, dihexyl maleate, poly- naphthalenedicarboxylic acid fourth diester and Polymethacrylimide, the weight content of its each component is:45 ~ 62 parts of methacrylic acid hexafluoro isopropyl ester, 12 ~ 29 parts of butyl benzyl phthalate, 1 octadecane epoxide, 2 DHA, 38 ~ 23 parts of oleic acid AKGs diester, 9 ~ 25 parts of dihexyl maleate, 3 ~ 16 parts of poly- naphthalenedicarboxylic acid fourth diester and 2 ~ 11 parts of Polymethacrylimide.By the way, tensile strength of the present invention is good, and pliability is good, is not likely to produce electrostatic, it is to avoid absorption powder shape product.

Description

A kind of chemical products are packed for aluminizer
Technical field
The present invention relates to aluminizer field, more particularly to a kind of chemical products are packed for aluminizer.
Background technology
Aluminizer is that the one kind formed in the very thin metallic aluminium of Plastic film surface plating last layer using special process is multiple Flexible packing material is closed, the processing method of most common of which, when number vacuum evaporated aluminium method, is exactly to pass through high temperature under high vacuum state By metallic aluminium fusing evaporation, the steam precipitation of aluminium is made to be stacked in Plastic film surface, so that Plastic film surface has gold Category gloss.As it had both had the characteristic of plastic sheeting, and the characteristic with metal, it is a kind of inexpensive attractive in appearance, function admirable, reality With the strong packaging material of property, therefore, aluminizer has been widely used in the packaging of the products such as food, medicine, chemical industry, such as The packaging of fast food, tealeaves, coffee and cosmetics.
The application of aluminizer is more and more extensive, has had become as the very universal a kind of packing timber of application in Flexible-Packaging Industry Material.The species of aluminizer is a lot, applies most aluminizers to be mainly polyester aluminizer at present(VMPET)With CPP aluminizer (VMCPP), polyester aluminizer(VMPET)The intermediate layer of composite packaging is typically used as, as its outward appearance is beautiful, in high-grade packaging Application is most, the such as packaging bag such as milk powder, tealeaves.CPP aluminizer(VMCPP)The hot sealing layer of composite packaging is typically used as, is usually used in Common pot foods(Such as biscuit)Packaging.
However, the poor tensile strength of the aluminizer for using at present, pliability is poor, easily produces electrostatic, and absorption powder shape is eaten Product.
Content of the invention
The present invention solves the technical problem of providing a kind of chemical products to be packed for aluminizer, tensile strength is good, soft Toughness is good, is not likely to produce electrostatic, it is to avoid absorption powder shape product.
For solving above-mentioned technical problem, one aspect of the present invention is:There is provided a kind of chemical products to be packed for Aluminizer, including:Film base layer and aluminium coated, described film base layer are made up of following components:Methacrylic acid hexafluoro isopropyl Ester, butyl benzyl phthalate, 1- octadecane epoxide -2-DHA-3- oleic acid AKGs diester, dihexyl maleate, poly- Naphthalenedicarboxylic acid fourth diester and Polymethacrylimide, the weight content of its each component is:Methacrylic acid hexafluoro isopropyl ester 45 ~ 62 parts, 12 ~ 29 parts of butyl benzyl phthalate, 8 ~ 23 parts of 1- octadecane epoxide -2-DHA-3- oleic acid AKGs diester, 9 ~ 25 parts of dihexyl maleate, 3 ~ 16 parts of poly- naphthalenedicarboxylic acid fourth diester and 2 ~ 11 parts of Polymethacrylimide.
In a preferred embodiment of the present invention, the weight content of described methacrylic acid hexafluoro isopropyl ester is 49 ~ 62 Part.
In a preferred embodiment of the present invention, the weight content of described butyl benzyl phthalate is 14 ~ 26 parts.
In a preferred embodiment of the present invention, described 1- octadecane epoxide -2-DHA-3- oleic acid AKGs two The weight content of ester is 11 ~ 23 parts.
The invention has the beneficial effects as follows:Tensile strength of the present invention is good, and pliability is good, is not likely to produce electrostatic, it is to avoid absorption powder Last shape product.
Specific embodiment
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection Enclose.
Embodiment 1
A kind of chemical products are packed for aluminizer, including:Film base layer and aluminium coated, described film base layer is by following components system Become:Methacrylic acid hexafluoro isopropyl ester, butyl benzyl phthalate, 1- octadecane epoxide -2-DHA-3- oleic acid alkoxyl are sweet Oily diester, dihexyl maleate, poly- naphthalenedicarboxylic acid fourth diester and Polymethacrylimide, the weight content of its each component is: 55 parts of methacrylic acid hexafluoro isopropyl ester, 20 parts of butyl benzyl phthalate, 1- octadecane epoxide -2-DHA-3- oleic acid alcoxyl 17 parts of base glycerol diester, 17 parts of dihexyl maleate, 10 parts of poly- naphthalenedicarboxylic acid fourth diester and 7 parts of Polymethacrylimide.
Embodiment 2
A kind of chemical products are packed for aluminizer, including:Film base layer and aluminium coated, described film base layer is by following components system Become:Methacrylic acid hexafluoro isopropyl ester, butyl benzyl phthalate, 1- octadecane epoxide -2-DHA-3- oleic acid alkoxyl are sweet Oily diester, dihexyl maleate, poly- naphthalenedicarboxylic acid fourth diester and Polymethacrylimide, the weight content of its each component is: 62 parts of methacrylic acid hexafluoro isopropyl ester, 26 parts of butyl benzyl phthalate, 1- octadecane epoxide -2-DHA-3- oleic acid alcoxyl 23 parts of base glycerol diester, 25 parts of dihexyl maleate, 16 parts of poly- naphthalenedicarboxylic acid fourth diester and 11 parts of Polymethacrylimide.
Embodiment 3
A kind of chemical products are packed for aluminizer, including:Film base layer and aluminium coated, described film base layer is by following components system Become:Methacrylic acid hexafluoro isopropyl ester, butyl benzyl phthalate, 1- octadecane epoxide -2-DHA-3- oleic acid alkoxyl are sweet Oily diester, dihexyl maleate, poly- naphthalenedicarboxylic acid fourth diester and Polymethacrylimide, the weight content of its each component is: 49 parts of methacrylic acid hexafluoro isopropyl ester, 14 parts of butyl benzyl phthalate, 1- octadecane epoxide -2-DHA-3- oleic acid alcoxyl 11 parts of base glycerol diester, 9 parts of dihexyl maleate, 3 parts of poly- naphthalenedicarboxylic acid fourth diester and 2 parts of Polymethacrylimide.
Chemical products of the present invention are packed for the beneficial effect of aluminizer:Tensile strength of the present invention is good, and pliability is good, is difficult Produce electrostatic, it is to avoid absorption powder shape product.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, every using this Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (4)

1. a kind of chemical products are packed for aluminizer, it is characterised in that include:Film base layer and aluminium coated, described film matrix Layer is made up of following components:Methacrylic acid hexafluoro isopropyl ester, butyl benzyl phthalate, 1- octadecane epoxide -2-DHA- 3- oleic acid AKGs diester, dihexyl maleate, poly- naphthalenedicarboxylic acid fourth diester and Polymethacrylimide, its each component Weight content be:45 ~ 62 parts of methacrylic acid hexafluoro isopropyl ester, 12 ~ 29 parts of butyl benzyl phthalate, 1- octadecane oxygen 8 ~ 23 parts of base -2-DHA-3- oleic acid AKGs diester, 9 ~ 25 parts of dihexyl maleate, 3 ~ 16 parts of poly- naphthalenedicarboxylic acid fourth diester With 2 ~ 11 parts of Polymethacrylimide.
2. chemical products according to claim 1 are packed for aluminizer, it is characterised in that described methacrylic acid hexafluoro The weight content of isopropyl ester is 49 ~ 62 parts.
3. chemical products according to claim 1 are packed for aluminizer, it is characterised in that described O-phthalic acid butyl The weight content of benzyl ester is 14 ~ 26 parts.
4. chemical products according to claim 1 are packed for aluminizer, it is characterised in that and described 1- octadecane epoxide- The weight content of 2-DHA-3- oleic acid AKGs diester is 11 ~ 23 parts.
CN201610895426.7A 2016-10-14 2016-10-14 A kind of chemical products are packed for aluminizer Pending CN106478901A (en)

Priority Applications (1)

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Publications (1)

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CN106478901A true CN106478901A (en) 2017-03-08

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02194031A (en) * 1989-01-24 1990-07-31 Toray Ind Inc Film for membrane switch and transparent conductive film
CN1535203A (en) * 2001-07-24 2004-10-06 凸版印刷株式会社 Depositon film
CN101402817A (en) * 2008-11-14 2009-04-08 上海维凯化学品有限公司 Environment-friendly holography aluminising transfer paint, preparation and uses thereof
CN104428353A (en) * 2012-07-26 2015-03-18 钟渊化学工业株式会社 Thermoplastic resin foam film and method for producing same
CN105601797A (en) * 2015-12-31 2016-05-25 徐宪 Environment-friendly fluorine-containing nanometer positive ion acrylic ester polymer emulsion and preparation method thereof
CN105705579A (en) * 2013-11-12 2016-06-22 Sk化学株式会社 Polycyclohexylenedimethylene terephthalate resin composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02194031A (en) * 1989-01-24 1990-07-31 Toray Ind Inc Film for membrane switch and transparent conductive film
CN1535203A (en) * 2001-07-24 2004-10-06 凸版印刷株式会社 Depositon film
CN101402817A (en) * 2008-11-14 2009-04-08 上海维凯化学品有限公司 Environment-friendly holography aluminising transfer paint, preparation and uses thereof
CN104428353A (en) * 2012-07-26 2015-03-18 钟渊化学工业株式会社 Thermoplastic resin foam film and method for producing same
CN105705579A (en) * 2013-11-12 2016-06-22 Sk化学株式会社 Polycyclohexylenedimethylene terephthalate resin composition
CN105601797A (en) * 2015-12-31 2016-05-25 徐宪 Environment-friendly fluorine-containing nanometer positive ion acrylic ester polymer emulsion and preparation method thereof

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Application publication date: 20170308