CN206231839U - A kind of plastics aseptic packaging paper and packing box - Google Patents
A kind of plastics aseptic packaging paper and packing box Download PDFInfo
- Publication number
- CN206231839U CN206231839U CN201621065842.6U CN201621065842U CN206231839U CN 206231839 U CN206231839 U CN 206231839U CN 201621065842 U CN201621065842 U CN 201621065842U CN 206231839 U CN206231839 U CN 206231839U
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- Prior art keywords
- polypropylene
- film
- aseptic packaging
- polypropylene film
- propylene
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- 229920003023 plastic Polymers 0.000 title claims abstract description 63
- 239000004033 plastic Substances 0.000 title claims abstract description 63
- 238000009455 aseptic packaging Methods 0.000 title claims abstract description 61
- 238000012856 packing Methods 0.000 title abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 116
- 238000001125 extrusion Methods 0.000 claims abstract description 45
- 239000000463 material Substances 0.000 claims abstract description 24
- 229920001155 polypropylene Polymers 0.000 claims description 142
- -1 polypropylene Polymers 0.000 claims description 90
- 239000010410 layer Substances 0.000 claims description 89
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 48
- 229920000573 polyethylene Polymers 0.000 claims description 47
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 47
- 239000002952 polymeric resin Substances 0.000 claims description 45
- 239000012790 adhesive layer Substances 0.000 claims description 43
- 239000004814 polyurethane Substances 0.000 claims description 43
- 229920002635 polyurethane Polymers 0.000 claims description 43
- 239000005025 cast polypropylene Substances 0.000 claims description 26
- 230000002457 bidirectional effect Effects 0.000 claims description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims 1
- 150000002632 lipids Chemical class 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 230000001954 sterilising effect Effects 0.000 abstract description 31
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 27
- 235000013305 food Nutrition 0.000 abstract description 26
- 239000000853 adhesive Substances 0.000 abstract description 16
- 230000001070 adhesive effect Effects 0.000 abstract description 16
- 235000013361 beverage Nutrition 0.000 abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 230000002378 acidificating effect Effects 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 9
- 229920006378 biaxially oriented polypropylene Polymers 0.000 abstract description 6
- 239000011127 biaxially oriented polypropylene Substances 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 abstract description 6
- 230000007774 longterm Effects 0.000 abstract description 6
- 230000035515 penetration Effects 0.000 abstract description 6
- 239000007921 spray Substances 0.000 abstract description 6
- 238000003860 storage Methods 0.000 abstract description 6
- 238000012546 transfer Methods 0.000 abstract description 6
- 108010082495 Dietary Plant Proteins Proteins 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 239000004014 plasticizer Substances 0.000 abstract description 3
- 239000010408 film Substances 0.000 description 85
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 9
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000010409 thin film Substances 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 238000007766 curtain coating Methods 0.000 description 5
- 210000004276 hyalin Anatomy 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 239000008267 milk Substances 0.000 description 5
- 210000004080 milk Anatomy 0.000 description 5
- 235000013336 milk Nutrition 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000021393 food security Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000036512 infertility Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The utility model provides a kind of plastics aseptic packaging paper and packing box.The wrapping paper has six kinds of structures, and structure one or two is included successively:High-barrier co-extrusion film, adhesive phase, PP sheet materials, adhesive phase and " BOPP or CPP ";Both are different adhesive phase type;Structure three~six is included successively:High-barrier co-extrusion film, adhesive phase, PP sheet materials, adhesive phase, " BOPP or CPP " and PP films, four kinds of structures are different adhesive phase type.Packing box of the present utility model not only can wet sterilization, can also high-temperature water boil or spray sterilization;Sterilization process is without dead angle, more thorough, it is ensured that the safety of product 100%, makes the food can long term storage;Sterilized heat transfer rate is fast, and the time is short;It is difficult water penetration;Inwall can add plasticiser, heavy metal free element, and during for holding vegetable protein liquid beverage or acidic beverages, tinned fruit or solid-state food, safer, health, environmental protection, cost of transportation are relatively low.
Description
Technical field
The utility model is related to a kind of plastics aseptic packaging paper and packing box.
Background technology
Tetrapack company of Sweden and Kang Mei companies of Switzerland production for holding neutral liquid plus particle or solid-state tinned food
Paper plastic-aluminum aseptic packaging box, generally include 8 layers, structure composite layer successively using PP layers ply of board PE layers EAA layers aluminium foil
Layer EAA layers PE layers PP layers.But, because containing paper sheet in the packing box structure, it is impossible to carry out high-temperature water boil it is sterilized (for example,
121 DEG C of cooking disinfections of water-bath) or spray sterilization, 121 DEG C of wet sterilizations can only be carried out, and wet sterilization can not be usually reached to food
Product are thoroughly sterilized to commercial sterilization.Meanwhile, due also in wet sterilization, compressed air and the positive and negative pressure-volume of high-temperature steam are easily formed
Dead angle, it is impossible to kill the Bacillus in food, causes food qualification rate to can only achieve 98%.Further, since ply of board have every
Thermal effect and steam heat transfer is slow, so as to cause carton centers temperature during wet sterilization unstable, food security it cannot be guaranteed that.And
And, the tinned food wet sterilization time that general paper plastic-aluminum sterility is contained is long, needs 120~150min (wherein, intensification 30min
Left and right, is incubated 60~70min, 30~50min of cooling down), easily there is water penetration in the paper in paper plastic-aluminum aseptic packaging box.
At present, in the market can 121 DEG C of packagings of the vegetable protein liquid beverage of boiling high temperature sterilization frequently with iron flask or aluminium
Tank, can 121 DEG C of packagings of boiling high temperature sterilization solid-state food can frequently with iron flask and vial, however, iron flask or aluminium pot are rich
Containing heavy metal, easily caused damage to healthy;Vial is broken, and security is low for consumer;And, above-mentioned iron
The packaging such as tank, aluminium pot and vial is heavier, also there is the defects such as cost of transportation is high.Those problems demands are solved.
Additionally, acidic beverages of the acidity in pH value below 4.6, plus the acidic beverages or acid canned food of particle do not contain
Bacillus, comprise only general miscellaneous bacteria, therefore (sterilization temperature is at 85~90 DEG C) by pasteurize are only needed in preparation process.Pasteur kills
The mode of bacterium is divided to two kinds:Plus the acidic beverages or canned pack of particle are sterilized using immersion method, agranular acidic beverages are used
Board-like sterilization machine is sterilized.At present, for above-mentioned acidic products, its packaging generally using vial, plastic bottle, plastics butt-ended bag,
The form such as plastic cup or plastic bowl, but because vial is broken, security is low for consumer;Plastics butt-ended bag, modeling
The packaging such as material cup or plastic bowl exists squashy, is easily deformed, and intercepts the defects such as oxygen permeability difference.Those problems demands are solved.
Utility model content
Technical problem to be solved in the utility model is to overcome in the prior art that paper plastic-aluminum aseptic packaging box can not
Carry out high-temperature water to boil, spray sterilized and Pasteur's water dip sterilization, wet sterilization can only be carried out, thus cause sterilized not thorough, food
Qualification rate can only achieve 98%, heat transfer is slow, long sterilizing time, yield poorly, the easy water penetration of paper of packing box, the shelf-life of food
Short and vial fear of throwing, heavier, spraying high temperature boiling is dangerous to food in iron pipe, plastic products are squashy, be easily deformed and
Intercept the defects such as oxygen permeability difference, there is provided a kind of plastics aseptic packaging paper and packing box.Plastics aseptic packaging of the present utility model
Box can not only carry out wet sterilization, can also carry out high-temperature water and boil, spray sterilized (digestion resistant) or pasteurize;Temperature is equal
Even, sterilization process is without dead angle, more thorough, it is ensured that the safety of product 100%, so that food can long term storage;Sterilization process
Middle heat transfer rate is fast, and sterilizing time is short, and packing box is also less prone to water penetration;Its inwall can add plasticiser, heavy metal free unit
Element, during for the acidic beverages, tinned fruit or the solid-state food that hold vegetable protein liquid beverage or the scope of pH value 3~4.6, modeling
Material aseptic packaging box is transparent, lightweight, it can be seen that food in box, more attractive in appearance, safety, health, environmental protection, cost of transportation compared with
It is low.
The utility model is to solve above-mentioned technical problem by following technical proposals.
The utility model provides a kind of plastics aseptic packaging paper, and it is structure one, structure two, structure three, structure four, knot
Structure five or structure six;
The structure one is included successively:Polypropylene high-barrier co-extrusion film, the first polyurethane adhesive layer, crystalline p p sheet,
Second polyurethane adhesive layer and bidirectional stretching polypropylene film (BOPP) or cast polypropylene film (CPP);
The structure two is included successively:Polypropylene high-barrier co-extrusion film, the first propylene and ethylene polymer resin layer, polypropylene foil
Material, the second propylene and ethylene polymer resin layer and bidirectional stretching polypropylene film (BOPP) or cast polypropylene film (CPP);
The structure three is included successively:Polypropylene high-barrier co-extrusion film, the first polyurethane adhesive layer, crystalline p p sheet,
Second polyurethane adhesive layer, bidirectional stretching polypropylene film (BOPP) or cast polypropylene film (CPP) and polypropylene film;
The structure four is included successively:Polypropylene high-barrier co-extrusion film, the first propylene and ethylene polymer resin layer, polypropylene foil
Material, the second propylene and ethylene polymer resin layer, bidirectional stretching polypropylene film (BOPP) or cast polypropylene film (CPP) and poly- third
Alkene film;
The structure five is included successively:Polypropylene high-barrier co-extrusion film, polyurethane adhesive layer, crystalline p p sheet, propylene
Vinyl polymerization resin bed, bidirectional stretching polypropylene film (BOPP) or cast polypropylene film (CPP) and polypropylene film;
The structure six is included successively:Polypropylene high-barrier co-extrusion film, propylene and ethylene polymer resin layer, crystalline p p sheet,
Polyurethane adhesive layer, bidirectional stretching polypropylene film (BOPP) or cast polypropylene film (CPP) and polypropylene film.
The thickness of the plastics aseptic packaging paper of the composition of one~structure of the utility model structure six can be this area routine, preferably
Independently be 240~600 μm.
In one~structure of structure six, the polypropylene high-barrier co-extrusion film can be the polypropylene high resistant of this area conventional commercial
Every co-extrusion film, such as with TIE layers/evoh layer of PP layers/adhesive/the polypropylene high resistant of adhesive TIE layers/PP layers five-layer structure
Every co-extrusion film, or with TIE layers/evoh layer of PP layers/PP layers/adhesive/adhesive TIE layers/PP layers/PP layers seven-layer structure poly- third
Alkene high-barrier co-extrusion film.
In one~structure of structure six, the thickness of the polypropylene high-barrier co-extrusion film can be this area routine, preferably solely
It is on the spot 70~120 μm.
First polyurethane adhesive layer described in structure one and structure three or second polyurethane adhesive layer, structure five
The conventional polyurethane binder in this area is may generally be with the material of polyurethane adhesive layer described in structure six.Structure one and knot
First polyurethane adhesive layer described in structure three or second polyurethane adhesive layer, structure five and poly- ammonia described in structure six
The thickness of ester adhesive layer can be this area routine, preferably independently be 1~2 μm.
In one~structure of structure six, it is white that the crystalline p p sheet can be the conventional three-layer co-extruded curtain coating white milk in this area
Film or hyaline membrane.The thickness of the crystalline p p sheet can be this area routine, preferably independently be 240~500 μm, more preferably
It independently is 280 μm.
In one~structure of structure six, the bidirectional stretching polypropylene film can be the conventional biaxial stretching polypropylene in this area
Alkene film.The thickness of the bidirectional stretching polypropylene film can be this area routine, preferably independently be 15~25 μm.
In one~structure of structure six, the cast polypropylene film is also referred to as un-stretched polypropylene film, can be this
Three conventional laminar flows of field prolong co-extrusion polypropylene film.The material of the cast polypropylene film can be this area routine, one
As intermediate layer be HOPP material, two boundary layers are ternary polymerized polypropylene.The thickness of the cast polypropylene film can be equal
It is this area routine, independently preferably is 30~70 μm.
First propylene and ethylene polymer resin layer described in structure two and structure four or the second propylene and ethylene polymer resin
The raw material components of layer, structure five and propylene and ethylene polymer resin layer described in structure six are general independently by polypropylene and polyethylene
Composition.The polyacrylic content can be this area routine, preferably 65~80%, the content of the polyethylene can be ability
Domain routine, preferably 20~35%, above-mentioned percentage is mass percent of each component relative to propylene and ethylene polymer resin.
First propylene and ethylene polymer resin layer described in structure two and structure four or the second propylene and ethylene polymer resin
The thickness of layer, structure five and propylene and ethylene polymer resin layer described in structure six can be this area routine, preferably independently
It is 10~15nm.
In three~structure of structure six, the thickness of the polypropylene film can be this area routine, preferably independently be 10
~15 μm.
The utility model additionally provides a kind of plastics aseptic packaging box, and its box body uses foregoing plastics aseptic packaging
Paper.
It can be seen from common sense in the field, the packing box of all shapes can be using described plastics aseptic packaging paper system
It is standby.
Positive effect of the present utility model is:
Plastics aseptic packaging box of the present utility model can not only carry out steam sterilization, can also carry out high-temperature water and boil, spray and kill
Bacterium (121 DEG C of boilings of high temperature resistant) or pasteurize;Temperature is uniform, and sterilization process is without dead angle, more thorough, it is ensured that product
100% safety, so that food can long term storage;Heat transfer rate is fast in sterilization process, short (the 121 DEG C of sterilization process of sterilizing time
In, intensification, insulation and temperature fall time can be only 50~75min), packing box is also less prone to water penetration;Its inwall can be moulded without addition
Agent, heavy metal free element, acidic beverages, tinned fruit for holding vegetable protein liquid beverage or the scope of pH value 3~4.6
Or during solid-state food, plastics aseptic packaging box is transparent, lightweight, it can be seen that food in box, safer, health, environmental protection,
Cost of transportation is relatively low;The printing of its outward appearance is beautiful, attractive in appearance, can improve desire to purchase;Its is easy to use;Its good seal, with low
Oxygen design science, can effectively prevent the oxidation of food in box, be easy to food long term storage, in not doping and the feelings of preservative
Under condition, beverage or solid-state food normal temperature can be made to preserve 24 months;Its opening or tearing notch more facilitate, with low cost, appearance looks elegant
It is generous.
Brief description of the drawings
Fig. 1 for embodiment 1 plastics aseptic packaging paper structural representation, wherein, 11 be polypropylene high-barrier co-extrusion film,
12 it is the first polyurethane adhesive layer, 13 be crystalline p p sheet, 14 is the second polyurethane adhesive layer and 15 for biaxial tension is poly-
Polypropylene film.
Fig. 2 for embodiment 2 plastics aseptic packaging paper structural representation, wherein, 21 be polypropylene high-barrier co-extrusion film,
22 is the first propylene and ethylene polymer resin layer, 23 is crystalline p p sheet, 24 is that the second propylene and ethylene polymer resin layer and 25 is stream
Prolong polypropylene film.
Fig. 3 for embodiment 3 plastics aseptic packaging paper structural representation, wherein, 31 be polypropylene high-barrier co-extrusion film,
32 is the first polyurethane adhesive layer, 33 is crystalline p p sheet, 34 is the second polyurethane adhesive layer, 35 is that cast polypropylene is thin
Film and 36 is polypropylene film.
Fig. 4 for embodiment 4 plastics aseptic packaging paper structural representation, wherein, 41 be polypropylene high-barrier co-extrusion film,
42 is the first propylene and ethylene polymer resin layer, 43 is crystalline p p sheet, 44 is the second propylene and ethylene polymer resin layer, 45 is two-way
Stretched polypropene film and 46 is polypropylene film.
Fig. 5 for embodiment 5 plastics aseptic packaging paper structural representation, wherein, 51 be polypropylene high-barrier co-extrusion film,
52 is polyurethane adhesive layer, 53 is crystalline p p sheet, 54 is propylene and ethylene polymer resin layer, 55 is that Biaxially oriented polypropylene is thin
Film and 56 is polypropylene film.
Fig. 6 for embodiment 6 plastics aseptic packaging paper structural representation, wherein, 61 be polypropylene high-barrier co-extrusion film,
62 is propylene and ethylene polymer resin layer, 63 is crystalline p p sheet, 64 is polyurethane adhesive layer, 65 is that Biaxially oriented polypropylene is thin
Film and 66 is polypropylene film.
Specific embodiment
Name preferred embodiment, and become apparent from intactly illustrating the utility model with reference to accompanying drawing.
Embodiment 1
1st, the plastics aseptic packaging paper of structure one:
Fig. 1 for embodiment 1 plastics aseptic packaging paper structural representation, wherein, 11 be polypropylene high-barrier co-extrusion film,
12 it is the first polyurethane adhesive layer, 13 be crystalline p p sheet, 14 is the second polyurethane adhesive layer and 15 for biaxial tension is poly-
Polypropylene film.
Wherein, polypropylene high-barrier co-extrusion film is with TIE layers/evoh layer of PP layers/adhesive/adhesive TIE layers/PP layers
The polypropylene high-barrier co-extrusion film of five-layer structure, its thickness is 70 μm;
The material of the first polyurethane adhesive layer or the second polyurethane adhesive layer is polyurethane binder;First polyurethane
The thickness of adhesive phase is 1 μm, and the thickness of the second polyurethane adhesive layer is 2 μm;
For the conventional three-layer co-extruded curtain coating white milk in this area is white or hyaline membrane, its thickness is 240 μm to crystalline p p sheet;
The thickness of bidirectional stretching polypropylene film is 15 μm.
2nd, a kind of plastics aseptic packaging box, its box body uses the plastics aseptic packaging paper of embodiment 1.
Embodiment 2
1st, the plastics aseptic packaging paper of structure two:
Fig. 2 for embodiment 2 plastics aseptic packaging paper structural representation, wherein, 21 be polypropylene high-barrier co-extrusion film,
22 is the first propylene and ethylene polymer resin layer, 23 is crystalline p p sheet, 24 is that the second propylene and ethylene polymer resin layer and 25 is stream
Prolong polypropylene film.
Wherein, polypropylene high-barrier co-extrusion film is with TIE layers/evoh layer of PP layers/PP layers/adhesive/adhesive TIE
Layer/PP layers/PP layers polypropylene high-barrier co-extrusion film of seven-layer structure, its thickness is 120 μm;
The raw material components of the first propylene and ethylene polymer resin layer or the second propylene and ethylene polymer resin layer are by polypropylene and gather
Ethene is constituted;Polyacrylic content is 65%, and the content of polyethylene is 35%, and above-mentioned percentage is each component relative to propylene second
The mass percent of alkene polymer resin;The thickness of the first propylene and ethylene polymer resin layer or the second propylene and ethylene polymer resin layer is
10nm;
For the conventional three-layer co-extruded curtain coating white milk in this area is white or hyaline membrane, its thickness is 280 μm to crystalline p p sheet;
Cast polypropylene film prolongs co-extrusion polypropylene film for three laminar flows, and intermediate layer is HOPP material, two boundary layers
It is ternary polymerized polypropylene;30 μm of its thickness.
2nd, a kind of plastics aseptic packaging box, its box body uses the plastics aseptic packaging paper of embodiment 2.
Embodiment 3
1st, the plastics aseptic packaging paper of structure three:
Fig. 3 for embodiment 3 plastics aseptic packaging paper structural representation, wherein, 31 be polypropylene high-barrier co-extrusion film,
32 is the first polyurethane adhesive layer, 33 is crystalline p p sheet, 34 is the second polyurethane adhesive layer, 35 is that cast polypropylene is thin
Film and 36 is polypropylene film.
Wherein, the material and thickness of polypropylene high-barrier co-extrusion film are identical with the polypropylene high-barrier co-extrusion film of embodiment 1;
The material and thickness of the first polyurethane adhesive layer or the second polyurethane adhesive layer are gathered with the first of embodiment 1
Urethane adhesive phase or the second polyurethane adhesive layer are identical;
For the white milk of three-layer co-extruded curtain coating is white or hyaline membrane, its thickness is 280 μm to crystalline p p sheet;
Cast polypropylene film prolongs co-extrusion polypropylene film for three laminar flows, and intermediate layer is HOPP material, two boundary layers
It is ternary polymerized polypropylene;70 μm of its thickness;
The thickness of polypropylene film is 10 μm.
2nd, a kind of plastics aseptic packaging box, its box body uses the plastics aseptic packaging paper of embodiment 3.
Embodiment 4
1st, the plastics aseptic packaging paper of structure four:
Fig. 4 for embodiment 4 plastics aseptic packaging paper structural representation, wherein, 41 be polypropylene high-barrier co-extrusion film,
42 is the first propylene and ethylene polymer resin layer, 43 is crystalline p p sheet, 44 is the second propylene and ethylene polymer resin layer, 45 is two-way
Stretched polypropene film and 46 is polypropylene film.
Wherein, the material and thickness of polypropylene high-barrier co-extrusion film are identical with the polypropylene high-barrier co-extrusion film of embodiment 1;
The raw material components of the first propylene and ethylene polymer resin layer or the second propylene and ethylene polymer resin layer are by polypropylene and gather
Ethene is constituted;Polyacrylic content is 80%, and the content of polyethylene is 20%, and above-mentioned percentage is each component relative to propylene second
The mass percent of alkene polymer resin;The thickness of the first propylene and ethylene polymer resin layer or the second propylene and ethylene polymer resin layer is
15nm;
For the white milk of three-layer co-extruded curtain coating is white or hyaline membrane, its thickness is 500 μm to crystalline p p sheet;
The thickness of bidirectional stretching polypropylene film is 25 μm;
The thickness of polypropylene film is 15 μm.
2nd, a kind of plastics aseptic packaging box, its box body uses the plastics aseptic packaging paper of embodiment 4.
Embodiment 5
1st, the plastics aseptic packaging paper of structure five:
Fig. 5 for embodiment 5 plastics aseptic packaging paper structural representation, wherein, 51 be polypropylene high-barrier co-extrusion film,
52 is polyurethane adhesive layer, 53 is crystalline p p sheet, 54 is propylene and ethylene polymer resin layer, 55 is that Biaxially oriented polypropylene is thin
Film and 56 is polypropylene film.
Wherein, the material and thickness of polypropylene high-barrier co-extrusion film, the material of crystalline p p sheet and thickness, biaxial tension gathers
The thickness of Polypropylene film is same as Example 1;
The material and thickness of polyurethane adhesive layer are identical with the first polyurethane adhesive layer of embodiment 1;
The material and thickness of propylene and ethylene polymer resin layer are identical with the first propylene and ethylene polymer resin layer of embodiment 2;
The thickness of polypropylene film is 15 μm.
2nd, a kind of plastics aseptic packaging box, its box body uses the plastics aseptic packaging paper of embodiment 5.
Embodiment 6
1st, the plastics aseptic packaging paper of structure six:
Fig. 6 for embodiment 6 plastics aseptic packaging paper structural representation, wherein, 61 be polypropylene high-barrier co-extrusion film,
62 is propylene and ethylene polymer resin layer, 63 is crystalline p p sheet, 64 is polyurethane adhesive layer, 65 is that Biaxially oriented polypropylene is thin
Film and 66 is polypropylene film.
Wherein, the material and thickness of polypropylene high-barrier co-extrusion film, the material of crystalline p p sheet and thickness, biaxial tension gathers
The thickness of Polypropylene film is same as Example 1;
The material and thickness of polyurethane adhesive layer are identical with the first polyurethane adhesive layer of embodiment 1;
The material and thickness of propylene and ethylene polymer resin layer are identical with the first propylene and ethylene polymer resin layer of embodiment 2;
The thickness of polypropylene film is 10 μm.
2nd, a kind of plastics aseptic packaging box, its box body uses the plastics aseptic packaging paper of embodiment 6.
Effect example 1
The plastics aseptic packaging box of the utility model embodiment 1~6 is killed with paper plastic-aluminum aseptic packaging box in the prior art
The bacterium time is compared, as a result as shown in table 1.It follows that sterilizing time of the present utility model is substantially than paper in the prior art
The sterilizing time of plastic-aluminum aseptic packaging box is few.
The plastics aseptic packaging box of the utility model embodiment 1~6 can not only carry out steam sterilization, can also carry out high-temperature water
Boil, spray sterilized (121 DEG C of boilings of high temperature resistant) or pasteurize;Temperature is uniform, sterilization process without dead angle, more thoroughly, can protect
The safety of card product 100%, so that food can long term storage;Heat transfer rate is fast in sterilization process, and packing box is also less prone to water penetration;
Its inwall can add plasticiser, heavy metal free element, for holding vegetable protein liquid beverage or the scope of pH value 3~4.6
Acidic beverages, tinned fruit or during solid-state food, plastics aseptic packaging box be it is transparent, it is lightweight, it can be seen that food in box,
Safer, health, environmental protection, cost of transportation are relatively low, and safer, health, environmental protection, cost of transportation are relatively low;The printing of its outward appearance is beautiful
It is beautiful, attractive in appearance, desire to purchase can be improved;Its is easy to use;Its good seal, with low oxygen flow design science, effectively can prevent in box
The oxidation of food, is easy to food long term storage, in the case of not doping and preservative, beverage or solid-state food can be made normal
Temperature is preserved 24 months;Its opening or tearing notch more facilitate, and with low cost, appearance looks elegant is generous.
Table 1
Claims (8)
1. a kind of plastics aseptic packaging paper, it is characterised in that its be structure one, structure two, structure three, structure four, structure five or
Structure six;
The structure one is included successively:Polypropylene high-barrier co-extrusion film, the first polyurethane adhesive layer, crystalline p p sheet, second
Polyurethane adhesive layer and bidirectional stretching polypropylene film or cast polypropylene film;
The structure two is included successively:Polypropylene high-barrier co-extrusion film, the first propylene and ethylene polymer resin layer, crystalline p p sheet,
Second propylene and ethylene polymer resin layer and bidirectional stretching polypropylene film or cast polypropylene film;
The structure three is included successively:Polypropylene high-barrier co-extrusion film, the first polyurethane adhesive layer, crystalline p p sheet, second
Polyurethane adhesive layer, bidirectional stretching polypropylene film or cast polypropylene film and polypropylene film;
The structure four is included successively:Polypropylene high-barrier co-extrusion film, the first propylene and ethylene polymer resin layer, crystalline p p sheet,
Second propylene and ethylene polymer resin layer, bidirectional stretching polypropylene film or cast polypropylene film and polypropylene film;
The structure five is included successively:Polypropylene high-barrier co-extrusion film, polyurethane adhesive layer, crystalline p p sheet, propylene and ethylene
Polymer resin layer, bidirectional stretching polypropylene film or cast polypropylene film and polypropylene film;
The structure six is included successively:Polypropylene high-barrier co-extrusion film, propylene and ethylene polymer resin layer, crystalline p p sheet, poly- ammonia
Ester adhesive layer, bidirectional stretching polypropylene film or cast polypropylene film and polypropylene film.
2. plastics aseptic packaging paper as claimed in claim 1, it is characterised in that the plastics of the composition of one~structure of structure six are aseptic
The thickness of wrapping paper independently is 240~600 μm;
And/or, in one~structure of structure six, the thickness of the polypropylene high-barrier co-extrusion film independently is 70~120 μm.
3. plastics aseptic packaging paper as claimed in claim 1, it is characterised in that the first poly- ammonia described in structure one and structure three
The thickness of ester adhesive layer or second polyurethane adhesive layer, structure five and polyurethane adhesive layer described in structure six is only
It is on the spot 1~2 μm.
4. plastics aseptic packaging paper as claimed in claim 1, it is characterised in that in one~structure of structure six, the polypropylene
The thickness of sheet material independently is 240~500 μm.
5. plastics aseptic packaging paper as claimed in claim 4, it is characterised in that the thickness of the crystalline p p sheet independently is
280μm。
6. plastics aseptic packaging paper as claimed in claim 1, it is characterised in that in one~structure of structure six, the two-way drawing
The thickness of polypropylene stretched film independently is 15~25 μm;
And/or, in one~structure of structure six, the thickness of the cast polypropylene film independently is 30~70 μm.
7. plastics aseptic packaging paper as claimed in claim 1, it is characterised in that the first propylene described in structure two and structure four
Vinyl polymerization resin bed or the second propylene and ethylene polymer resin layer, structure five and propylene and ethylene described in structure six polymerization tree
The thickness of lipid layer independently is 10~15nm;
And/or, in three~structure of structure six, the thickness of the polypropylene film independently is 10~15 μm.
8. a kind of plastics aseptic packaging box, it is characterised in that its box body is using the plastics as described in any one of claim 1~7
Aseptic packaging paper.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107010316A (en) * | 2016-09-19 | 2017-08-04 | 常州斯开龙包装机械有限公司 | Plastics aseptic packaging material, packing box and preparation method, application |
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Cited By (1)
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CN107010316A (en) * | 2016-09-19 | 2017-08-04 | 常州斯开龙包装机械有限公司 | Plastics aseptic packaging material, packing box and preparation method, application |
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