CN106478999A - A kind of diamond rope saw rubber, its preparation method and the diamond rope saw using which - Google Patents
A kind of diamond rope saw rubber, its preparation method and the diamond rope saw using which Download PDFInfo
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- CN106478999A CN106478999A CN201610962184.9A CN201610962184A CN106478999A CN 106478999 A CN106478999 A CN 106478999A CN 201610962184 A CN201610962184 A CN 201610962184A CN 106478999 A CN106478999 A CN 106478999A
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- rubber
- agent
- rope saw
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- diamond rope
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
- B29B7/005—Methods for mixing in batches
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
The invention discloses a kind of diamond rope saw rubber, which is filled a prescription according to parts by weight proportioning, including:58~60 parts of rubber, 0.1~0.2 part of peptizer, 25~30 parts of reinforcing agent, 1~3 part of operation oil, 5~6 parts of activating agent, 1~2 part of age resistor, 1~3 part of adhesion promoter, 0.5~0.8 part of tackifier, 1~3 part of vulcanizing agent, 0.5~1 part of accelerator, 0.1~0.2 part of antiscorching agent;And the preparation method of the rubber.Also disclose the diamond rope saw using the rubber.Adhesive strength of the present invention is big, effect stability, long service life.
Description
Technical field
The present invention relates to field of rubber technology, more particularly to a kind of diamond rope saw rubber, its preparation method and use
Its diamond rope saw.
Background technology
Diamond rope saw can be widely applied to the exploitation cutting of the stone materials such as marble, granite, sandstone, also be widely used in
The realm of building construction, can carry out the cutting of house, bridge, large-scale stub, concrete duct and submerged structure.In diamond rope saw
In, need to be combined with steel wire rope using special (purpose) rubber, beading are fixed.The diamond rope saw rubber that at present a lot of producers use with
Steel wire rope bonding is unstable so that diamond rope saw easily occurs beading in use and pulls or wire cable rupture so that gold
There is potential safety hazard in hard rock rope saw, and service life is short.
Content of the invention
It is an object of the invention to overcome the shortcoming of prior art, provide that a kind of adhesive strength is big, effect stability, use the longevity
The long diamond rope saw rubber of life, its preparation method, and the diamond rope saw using which.
For above-mentioned technical problem is solved, following technical measures are present invention employs:A kind of diamond rope saw rubber, which is joined
Just according to parts by weight proportioning, including:58~60 parts of rubber, 0.1~0.2 part of peptizer, 25~30 parts of reinforcing agent, operation oil 1
~3 parts, 5~6 parts of activating agent, 1~2 part of age resistor, 1~3 part of adhesion promoter, 0.5~0.8 part of tackifier, vulcanizing agent 1~3
Part, 0.5~1 part of accelerator, 0.1~0.2 part of antiscorching agent.
The present invention can also be perfect further by following technical measures:
Used as improving further, RSS1# smoke sheet rubber selected by the rubber, and HDBD selected by the peptizer, the reinforcing agent
Including intermediate super abrasion furnace black and white carbon, the operation grease separation cycloalkane, the activating agent include indirect process zinc oxide and hard
6PPD selected by resin acid, the age resistor, and adhesion promoter includes cobalt salt and resorcinol resin, and tackifier select SP1068, sulphur
Agent selects HDOT20, and accelerator includes DZ and H, and antiscorching agent selects CTP.
Used as improving further, RSS1# smoke sheet rubber is 58.5 parts, and HDBD is 0.18 part, and intermediate super abrasion furnace black is 23.72
Part, white carbon is 3.12 parts, 2.11 parts of cycloalkane, and indirect process zinc oxide is 5.34 parts, and stearic acid is 0.5 part, and 6PPD is 1 part,
Cobalt salt is 1.06 parts, and resorcinol resin is 0.32 part, and SP1068 is 0.54 part, and HDOT20 is 2.12 parts, and DZ is 0.34 part, H
For 0.47 part, CTP is 0.18 part.
The present invention provides a kind of preparation method of diamond rope saw rubber, and the rubber in formula and peptizer are put into by S1
In banbury, knead to 100~150 DEG C;Half intermediate super abrasion furnace black is put into, is kneaded to discharge after 125~175 DEG C;S2 is by S1
In product sizing material turn refining in mill, 10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining after 4~6min, then move to roller
Away from slice on 8~10mm, the mill that 60~80 DEG C of roller temperature;Sizing material passes through interleaving agent groove, and surface adhesion interleaving agent after-blow is air-cooled
But to room temperature, fold 8~24h of standing afterwards, obtain broken-down rubber;The broken-down rubber, activating agent, age resistor, bonding are promoted by S3
Agent and tackifier are put in banbury, knead 20~50s;Put into remaining intermediate super abrasion furnace black and white carbon, mixing 40~
60s;Implant operation oil, kneads and cleans to 120~130 DEG C, knead to discharge after 140~150 DEG C;S4 is by the product sizing material in S3
Turn refining in mill, 10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining after 2~5min, then move to 8~10mm of roll spacing, roller
Slice in the mill of 60~80 DEG C of temperature;Sizing material passes through interleaving agent groove, after surface adhesion interleaving agent quenching to room temperature, afterwards
8~24h of standing is folded, obtains elastomeric compound;S5 will be put in banbury after average for elastomeric compound decile, is kneaded to 140~160
Discharge after DEG C;Product sizing material in S5 is turned refining in mill by S6,10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining 4~
After 6min, 8~10mm of roll spacing, slice in the mill that 60~80 DEG C of roller temperature is then moved to;Sizing material passes through interleaving agent groove, surface adhesion
After interleaving agent, quenching folds 8~24h of standing afterwards to room temperature, obtains again and refines elastomeric compound again;S7 refines mixing described in inciting somebody to action again again
Put in banbury after the average decile of glue, then vulcanizing agent, accelerator is put into, knead to discharge after 95~100 DEG C;S8 is by S7
Product sizing material adds rush glue to turn refining in mill, 10~12mm of its roll spacing, 40~60 DEG C of roller temperature;Turn refining after 5~8 times and then move to roller
Away from slice on 5~6mm, the mill that 40~60 DEG C of roller temperature;Sizing material passes through bosh, and surface is dried after can not adhering to interleaving agent
Room temperature is cooled to, is taken with white PE pad film roll afterwards, the diamond rope saw rubber needed for obtaining.
Used as improving further, in S1, Ram Piston Pressure of Mixer is set to 6.0 ± 0.5kgf/c, rotating speed 40r/min;
In formula, rubber and peptizer are kneaded to 125 DEG C, are kneaded to 150 DEG C of discharges after putting into intermediate super abrasion furnace black;Turn refining described in S2
Time is 5min.
Used as improving further, in S3, Ram Piston Pressure of Mixer is set to 5.0 ± 0.5kgf/c, rotating speed 40r/min;
The mixing time of the broken-down rubber, activating agent, age resistor, adhesion promoter and tackifier be 30s, put into intermediate super abrasion furnace black and
50s is kneaded after white carbon;Implant operation oil is kneaded and is cleaned to 130 DEG C, is kneaded to discharge after 150 DEG C;Turn refining the time described in S4
For 3min.
Used as improving further, in S5, Ram Piston Pressure of Mixer is set to 5.0kgf/c, rotating speed 40r/min;Mixing
The discharge to after 150 DEG C;The time is turned refining described in S6 for 5min.
Used as improving further, in S7, Ram Piston Pressure of Mixer is set to 5.0kgf/c, rotating speed 40r/min;Mixing
The discharge to after 97 DEG C;The number of times that turns refining described in S8 is 6 times.
The present invention also provides a kind of diamond rope saw, including a steel wire rope and wears some diamond beads thereon,
Between the adjacent diamond beading, injection rubber forms complete diamond rope saw, and the rubber is the diamond-wire in the present invention
Saw rubber.
Compared with prior art, the present invention has advantages below:Ratio to each composition of filling a prescription is adjusted, and improves
The elongation percentage of rubber so that diamond rope saw rubber and steel wire rope adhesive strength are high, withdrawal force is big, flex cracking resistance, ageing-resistant
Excellent, good stability;Plasticate, knead using rubber, average segmentation is refined again again, the average preparation method that splits again plus promote, it is ensured that
Per a collection of rubber compounding stable homogeneous;Using the diamond rope saw of the diamond rope saw rubber in the present invention, process is being used
In be less prone to beading and pull or the problems such as wire cable rupture.
Description of the drawings
No
Specific embodiment
A kind of diamond rope saw rubber of the present invention, its formula according to weight fraction is:58~60 parts of rubber, peptizer
0.1~0.2 part, 25~30 parts of reinforcing agent, 1~3 part of operation oil, 5~6 parts of activating agent, 1~2 part of age resistor, adhesion promoter 1
~3 parts, 0.5~0.8 part of tackifier, 1~3 part of vulcanizing agent, 0.5~1 part of accelerator, 0.1~0.2 part of antiscorching agent.
In a preferred embodiment, the formula is:Rubber:RSS1# smoke sheet rubber, 58.5 parts;Peptizer:HDBD,
0.18 part;Reinforcement:Intermediate super abrasion furnace black, 23.72 parts;White carbon, 3.12 parts;Operation oil:Cycloalkane, 2.11 parts;Activating agent:
Indirect process zinc oxide, 5.34 parts;Stearic acid, 0.50 part;Age resistor:6PPD, 1.00 parts;RD, 0.50 part;Adhesion promoter:Cobalt
Salt, 1.06 parts;Resorcinol resin, 0.32 part;Tackifier:SP1068,0.54 part of vulcanizing agent:HDOT20,2.12 parts of accelerator:
DZ, 0.34 part:H, 0.47 part;Antiscorching agent:CTP, 0.18 part.
By the adjustment to rubber compounding ratio, the elongation percentage of rubber is improve, optimize rubber performance so that rubber and steel
Adhesive strength height, flex cracking resistance between cord, ageing-resistant excellent, good stability.
A kind of preparation method of diamond rope saw rubber of the present invention, its step is:S1 banbury leads to cooling water, will be close
Mill ram piston pressure is set to 6.0 ± 0.5kgf/c, rotating speed 40r/min;Rubber in formula and peptizer are put into close
Knead in mill to 125 DEG C;Half intermediate super abrasion furnace black is put into, is kneaded to discharge after 150 DEG C;
Product sizing material in S1 is turned refining in mill by S2,10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining 5min
Afterwards, 8~10mm of roll spacing, slice in the mill that 60~80 DEG C of roller temperature are then moved to;Sizing material passes through interleaving agent groove, and surface adhesion is isolated
After agent, quenching is folded 8~24h of standing afterwards, obtains broken-down rubber to room temperature;
S3 banbury leads to cooling water, and Ram Piston Pressure of Mixer is set to 5.0 ± 0.5kgf/c, rotating speed 40r/min;
The broken-down rubber, activating agent, age resistor, adhesion promoter and tackifier are put in banbury, after mixing 30s;Put into remaining
Intermediate super abrasion furnace black and white carbon, knead 50s;Implant operation oil, kneads and cleans to 130 DEG C, knead to discharge after 150 DEG C;
Product sizing material in S3 is turned refining in mill by S4,10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining 3min
Afterwards, 8~10mm of roll spacing, slice in the mill that 60~80 DEG C of roller temperature are then moved to;Sizing material passes through interleaving agent groove, and surface adhesion is isolated
After agent, quenching is folded 8~24h of standing afterwards, obtains elastomeric compound to room temperature;
S5 banbury leads to cooling water, and Ram Piston Pressure of Mixer is set to 5.0kgf/c, rotating speed 40r/min;By institute
Put in banbury after stating the average decile of elastomeric compound, knead to discharge after 150 DEG C;
Product sizing material in S5 is turned refining in mill by S6,10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining 5min
Afterwards, 8~10mm of roll spacing, slice in the mill that 60~80 DEG C of roller temperature are then moved to;Sizing material passes through interleaving agent groove, and surface adhesion is isolated
After agent, quenching folds 8~24h of standing afterwards to room temperature, obtains again and refines elastomeric compound again;
S7 banbury leads to cooling water, and Ram Piston Pressure of Mixer is set to 5.0kgf/c, rotating speed 40r/min;By institute
State and put in banbury after refining the average decile of elastomeric compound again again, then vulcanizing agent, accelerator is put into, knead to discharge after 97 DEG C;
Product sizing material in S7 is added rush glue to turn refining in mill by S8,10~12mm of its roll spacing, 40~60 DEG C of roller temperature;Turn over
5~6mm of roll spacing, slice in the mill that 40~60 DEG C of roller temperature are then moved to after refining 6 times;Sizing material passes through bosh, and surface can not
After adhesion interleaving agent, quenching is taken with white PE pad film roll afterwards to room temperature, the diamond rope saw rubber needed for obtaining.
Plasticate, knead using rubber, average segmentation is refined again again, the average preparation method that splits again plus promote, it is ensured that every a collection of
Rubber compounding stable homogeneous;Mill machine operation all adopts automatic turning glue, reduces the labour intensity of workman, and turns over glue uniformly, protects
The stability of card rubber.
A kind of diamond rope saw of the present invention, including a steel wire rope and wears some diamond beads thereon, described
Between adjacent diamond beading, injection rubber forms complete diamond rope saw, and the rubber is that the diamond rope saw in the present invention is used
Rubber.
Diamond rope saw is manufactured using the rubber in the present invention, the adhesive property between diamond bead and steel wire rope is high,
Bonding is stable, is prevented effectively from diamond drop-off or wire cable rupture during use.
Presently preferred embodiments of the present invention is the foregoing is only, not in order to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement that is done etc., should be included within the scope of protection of the invention.
Claims (9)
1. a kind of diamond rope saw rubber, its formula according to parts by weight proportioning, including:58~60 parts of rubber, peptizer 0.1
~0.2 part, 25~30 parts of reinforcing agent, 1~3 part of operation oil, 5~6 parts of activating agent, 1~2 part of age resistor, adhesion promoter 1~3
Part, 0.5~0.8 part of tackifier, 1~3 part of vulcanizing agent, 0.5~1 part of accelerator, 0.1~0.2 part of antiscorching agent.
2. diamond rope saw rubber according to claim 1, it is characterised in that:RSS1# smoke sheet rubber selected by the rubber,
HDBD selected by the peptizer, and the reinforcing agent includes intermediate super abrasion furnace black and white carbon, the operation grease separation cycloalkane, institute
Stating activating agent includes indirect process zinc oxide and stearic acid, and 6PPD selected by the age resistor, and adhesion promoter includes cobalt salt and isophthalic
Two phenol resin, tackifier select SP1068, and HDOT20 selected by vulcanizing agent, and accelerator includes DZ and H, and antiscorching agent selects CTP.
3. diamond rope saw rubber according to claim 2, it is characterised in that:RSS1# smoke sheet rubber is 58.5 parts, HDBD
For 0.18 part, intermediate super abrasion furnace black is 23.72 parts, and white carbon is 3.12 parts, 2.11 parts of cycloalkane, and indirect process zinc oxide is 5.34
Part, stearic acid is 0.5 part, and 6PPD is 1 part, and cobalt salt is 1.06 parts, and resorcinol resin is 0.32 part, and SP1068 is 0.54 part,
HDOT20 is 2.12 parts, and DZ is 0.34 part, and H is 0.47 part, and CTP is 0.18 part.
4., according to the preparation method of the diamond rope saw rubber described in Claims 2 or 3, its step includes:
S1 puts into the rubber in formula and peptizer in banbury, kneads to 100~150 DEG C;Put into super abrasive charcoal in half
Black, knead to discharge after 125~175 DEG C;
Product sizing material in S1 is turned refining in mill by S2,10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining 4~6min
Afterwards, 8~10mm of roll spacing, slice in the mill that 60~80 DEG C of roller temperature are then moved to;Sizing material passes through interleaving agent groove, and surface adhesion is isolated
After agent, quenching is folded 8~24h of standing afterwards, obtains broken-down rubber to room temperature;
S3 puts into the broken-down rubber, activating agent, age resistor, adhesion promoter and tackifier in banbury, kneads 20~50s;
Remaining intermediate super abrasion furnace black and white carbon is put into, kneads 40~60s;Implant operation oil, kneads and cleans to 120~130 DEG C, mixes
Refine to discharge after 140~150 DEG C;
Product sizing material in S3 is turned refining in mill by S4,10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining 2~5min
Afterwards, 8~10mm of roll spacing, slice in the mill that 60~80 DEG C of roller temperature are then moved to;Sizing material passes through interleaving agent groove, and surface adhesion is isolated
After agent, quenching is folded 8~24h of standing afterwards, obtains elastomeric compound to room temperature;
S5 will be put in banbury after average for elastomeric compound decile, is kneaded to discharge after 140~160 DEG C;
Product sizing material in S5 is turned refining in mill by S6,10~12mm of its roll spacing, 60~80 DEG C of roller temperature;Turn refining 4~6min
Afterwards, 8~10mm of roll spacing, slice in the mill that 60~80 DEG C of roller temperature are then moved to;Sizing material passes through interleaving agent groove, and surface adhesion is isolated
After agent, quenching folds 8~24h of standing afterwards to room temperature, obtains again and refines elastomeric compound again;
S7 will be described again again after the average decile of refining elastomeric compound in input banbury, then put into vulcanizing agent, accelerator, knead to 95~
Discharge after 100 DEG C;
Product sizing material in S7 is added rush glue to turn refining in mill by S8,10~12mm of its roll spacing, 40~60 DEG C of roller temperature;Turn refining 5
5~6mm of roll spacing, slice in the mill that 40~60 DEG C of roller temperature is then moved to after~8 times;Sizing material passes through bosh, and surface can not
After adhesion interleaving agent, quenching is taken with white PE pad film roll afterwards to room temperature, the diamond rope saw rubber needed for obtaining.
5. the preparation method of diamond rope saw rubber according to claim 4, it is characterised in that:Push up on banbury in S1
Bolt pressure is set to 6.0 ± 0.5kgf/c, rotating speed 40r/min;In formula, rubber and peptizer are kneaded to 125 DEG C, in input
Knead after super abrasive carbon black to 150 DEG C of discharges;The time is turned refining described in S2 for 5min.
6. the preparation method of diamond rope saw rubber according to claim 4, it is characterised in that:Push up on banbury in S3
Bolt pressure is set to 5.0 ± 0.5kgf/c, rotating speed 40r/min;The broken-down rubber, activating agent, age resistor, adhesion promoter and
The mixing time of tackifier is 30s, kneads 50s after putting into intermediate super abrasion furnace black and white carbon;Implant operation oil is kneaded to 130 DEG C
Clean, knead to discharge after 150 DEG C;The time is turned refining described in S4 for 3min.
7. the preparation method of diamond rope saw rubber according to claim 4, it is characterised in that:Push up on banbury in S5
Bolt pressure is set to 5.0kgf/c, rotating speed 40r/min;Knead to discharge after 150 DEG C;The time is turned refining described in S6 for 5min.
8. the preparation method of diamond rope saw rubber according to claim 4, it is characterised in that:Push up on banbury in S7
Bolt pressure is set to 5.0kgf/c, rotating speed 40r/min;Knead to discharge after 97 DEG C;The number of times that turns refining described in S8 is 6 times.
9. a kind of diamond rope saw, it is characterised in that:Including a steel wire rope and some diamond beads thereon are worn, described
Between adjacent diamond beading, injection rubber forms complete diamond rope saw, and the rubber is arbitrary described in claims 1 to 3
Diamond rope saw rubber.
Priority Applications (1)
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CN201610962184.9A CN106478999B (en) | 2016-10-28 | 2016-10-28 | A kind of diamond rope saw rubber, its preparation method and use its diamond rope saw |
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CN201610962184.9A CN106478999B (en) | 2016-10-28 | 2016-10-28 | A kind of diamond rope saw rubber, its preparation method and use its diamond rope saw |
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CN106478999A true CN106478999A (en) | 2017-03-08 |
CN106478999B CN106478999B (en) | 2018-04-17 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107501639A (en) * | 2017-08-14 | 2017-12-22 | 泉州众志新材料科技有限公司 | A kind of colored injecting glue rope saws special rubber and preparation method thereof |
CN110527125A (en) * | 2019-08-22 | 2019-12-03 | 三力士股份有限公司 | A method of delay natural rubber to plasticate cohesion of film |
CN110643085A (en) * | 2019-10-30 | 2020-01-03 | 中国化工集团曙光橡胶工业研究设计院有限公司 | Rubber material for diamond rope saw |
CN112679810A (en) * | 2020-12-15 | 2021-04-20 | 泉州市华实橡塑科技有限公司 | Rubber compound for diamond wire saw, preparation method and diamond wire saw |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0778102A1 (en) * | 1995-06-28 | 1997-06-11 | Osaka Diamond Industrial Co. | Wire saw |
CN101905491A (en) * | 2010-07-19 | 2010-12-08 | 厦门致力金刚石工具有限公司 | Diamond wire saw and manufacturing method thereof |
-
2016
- 2016-10-28 CN CN201610962184.9A patent/CN106478999B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0778102A1 (en) * | 1995-06-28 | 1997-06-11 | Osaka Diamond Industrial Co. | Wire saw |
CN101905491A (en) * | 2010-07-19 | 2010-12-08 | 厦门致力金刚石工具有限公司 | Diamond wire saw and manufacturing method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107501639A (en) * | 2017-08-14 | 2017-12-22 | 泉州众志新材料科技有限公司 | A kind of colored injecting glue rope saws special rubber and preparation method thereof |
CN110527125A (en) * | 2019-08-22 | 2019-12-03 | 三力士股份有限公司 | A method of delay natural rubber to plasticate cohesion of film |
CN110643085A (en) * | 2019-10-30 | 2020-01-03 | 中国化工集团曙光橡胶工业研究设计院有限公司 | Rubber material for diamond rope saw |
CN112679810A (en) * | 2020-12-15 | 2021-04-20 | 泉州市华实橡塑科技有限公司 | Rubber compound for diamond wire saw, preparation method and diamond wire saw |
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CN106478999B (en) | 2018-04-17 |
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