CN106473260A - A kind of detachable plate exposure suit - Google Patents
A kind of detachable plate exposure suit Download PDFInfo
- Publication number
- CN106473260A CN106473260A CN201611012283.7A CN201611012283A CN106473260A CN 106473260 A CN106473260 A CN 106473260A CN 201611012283 A CN201611012283 A CN 201611012283A CN 106473260 A CN106473260 A CN 106473260A
- Authority
- CN
- China
- Prior art keywords
- fiber
- radiation
- fabric
- exposure suit
- sulfonated graphene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/0002—Details of protective garments not provided for in groups A41D13/0007 - A41D13/1281
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D1/00—Garments
- A41D1/21—Maternity clothing; Clothing specially adapted for persons caring for infants
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
- C08G73/0266—Polyanilines or derivatives thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/94—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of other polycondensation products
Abstract
The invention discloses a kind of exposure suit, especially a kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket accommodates the pluggable radiation proof plate of masking belly around the belly of whole clothing in the shield pocket；The clothing body is made up of radiation resistant fiber fabric with shield pocket；The radiation proof plate is the sheet-like fiber felt of sulfonated graphene polyaniline fabric parcel.The present invention is simultaneously achieved protection effect good and wear light comfortable requirement by above-mentioned specific structure design.
Description
Technical field
The present invention relates to labour protection technical field, more particularly to a kind of exposure suit of detachable plate.
Background technology
Human body is constantly in certain energy electromagnetic wave radiation environment, when its frequency is more than more than 105Hz just to people
Body is harmful to.The power output of wave electromagnetic radiation source is bigger, and radiation intensity is bigger, and wavelength is shorter, and frequency is higher, and distance is nearer, connects
The tactile time is longer, and environment temperature is higher, and humidity is bigger, and air does not circulate, then environmental pollution degree is bigger, and women and
Children are more serious by harm.Electromagnetic wave can upset the natural physiological law of human body, cause organism balance disorderly, cause headache, head
Dizzy, insomnia, the neurasthenia symptom such as forgetful；Make one weak, poor appetite, irritable；Lose can also Models of Human Thermal Regulation
Adjust, cause increased heart rate, blood pressure are raised and lowered, have difficulty in breathing, Neuroleptic Leukocytopenia；Generation to angiocardiopathy and deteriorate
Impetus.In addition electromagnetic wave can cause visual impairment.When intensity is 100mw/cm2Electromagnetic wave irradiation eyes when, can make
There is oedema in crystal, can develop into cataract, result even in blind.When intensity is 5mw/cm2-10mw/cm2Electromagnetic wave shine
When penetrating human body, though the dermal sensation of people not substantially, may affect fertility and heredity., under Electromagnetic Field, menstruation is all for women
Phase occurs substantially to change, and can cause pregnant woman's miscarriage and gene defect, the children being chronically in the presence of strong electromagnetic wave, its cancer
Children of the incidence of disease ratio under low electromagnetic wave are high 2～5 times, and electromagnetic wave is also one of inducement of leukaemia, lymph cancer, brain tumor.
Exposure suit is exactly the clothes using electromagnetic shielding with ELECTROMAGNETIC REFLECTION principle, and which typically adopts specific fabric
Or coating is realizing.But in its technological means for adopting, there is chemical contamination or metallic pollution in some, some radiation-proof effects
Typically.
For specific workplace, which is higher to radiation proof requirement, and its exposure suit is thick and heavy, and protection effect is good, but
Heavy, dress is extreme uncomfortable.And in routine office work environment, the worn exposure suit of such as pregnant woman, which is light comfortable, but anti-spoke
Penetrate, particularly prevent electromagnetic radiation performance general.Therefore how the two to be combined, is that the technology that those skilled in the art face is difficult
One of topic.
Content of the invention
It is an object of the invention to proposing exposure suit, which is comfortable and easy to wear, and radiation-proof effect is excellent.
For reaching this purpose, the present invention is employed the following technical solutions：
A kind of exposure suit, especially a kind of exposure suit of detachable plate, in front of clothing body and clothing
Shield pocket, the shield pocket around whole clothing belly, in the shield pocket accommodate masking belly pluggable radiation proof plate；Institute
State clothing body to be made up of radiation resistant fiber fabric with shield pocket；The radiation proof plate is sulfonated graphene-polyaniline fabric bag
The sheet-like fiber felt that wraps up in, the fibrofelt composition include by weight：
Epoxy resin-base 20-40
Polypyrrole 10-20
Curing agent 2-10
Carbon fiber bundle 10-30
Glass fiber bundle 10-20,
Ni0.8Co0.2Powder microwave absorption 5-15
Manganese dioxide powder 10-20
Quartz/carbon black composite granule 5-10；Wherein,
The carbon fiber is fiber bundle structure with glass fibre, and the carbon fiber is interlocked with glass fiber bundle perpendicular separation
It is dispersed in resin matrix, equidistant array is formed, the spacing is less than 10mm, the Ni0.8Co0.2Powder microwave absorption
Agent is dispersed on the carbon fiber and glass fiber bundle, and the graphite and manganese dioxide powder are dispersed in the epoxy resin
In.
The preparation method of described sulfonated graphene-polyaniline fabric, including：
(1) graphite oxide is dissolved in deionized water, adds lauryl sodium sulfate, ultrasonic agitation 1-4 hour, graphite oxide
Alkene:The mass ratio of neopelex is 1:20-1:100；
(2) 90-100 DEG C is warming up to, is added one hydrazine reaction 12-36 hour is hydrated, obtains black deposit；
(3) filter and be vacuum dried at 70-90 DEG C, obtain sulfonated graphene；
(4) by sulfonated graphene with ammonium persulfate with mass ratio 1:3-1:5 are dissolved in the hydrochloric acid solution of 0.5-2mol/L,
As water phase；
(5) aniline is dissolved in chloroform, as oil phase；
(6) by water phase and oil phase with sulfonated graphene:Aniline mass ratio is 1:1-1:10 are mixed, anti-at 0-5 DEG C
12-36 hour is answered, obtains green product；
(7) washing green product obtains the sulfonated graphene-polyaniline fiber to colourless, vacuum drying.
The radiation proof plate adopts fibrofelt, and is wrapped up by fabric, and therefore which can bend, to adapt to the human body that does not allow
Shape, and deform under sitting posture and crouching appearance so that comfortable and easy to wear.
Preferably, the radiation proof shield pocket is 4, and which surrounds belly, sidepiece and low back respectively.Therefore, user is permissible
According to working environment, unrestricted choice inserts 1 block protection belly, or only protects sidepiece, or protection low back, and user can root
Insertion position and quantity are voluntarily selected according to position of the applied environment with pre- protection.
Preferably, the polyaniline of the radiation resistant fiber stainless steel fibre containing 15-35% and 5-10% by volume
Fiber, the stainless steel fibre, polyaniline fiber and string or chemical fibre twill blending obtain the radiation-proof fabric
Fiber.
Preferably, in the radiation resistant fiber fabric, the content of stainless steel fibre is 20-30%.When stainless steel fibre contains
When amount is within the scope of this, its snugness of fit and shielding property are balanced the most.
The superposition of radiation proof plate can be used, such as 2 according to radiation event by the exposure suit of the present invention when using
Even 3 pieces of block and above superposition are used, to realize the superposition of protection effect.
Through verification experimental verification, the microwave absorption fiber is unordered in a jumble to be disperseed in the epoxy the present invention, or laterally
In the epoxy, its wave-absorbing effect is all inferior to the vertical distribution of the present invention for dispersion.
Preferably, the epoxy resin-base raw material constitutes as follows by weight：
Brominated bisphenol A glycidyl ether resin 30-70,
Tetrabromobisphenol A 2-glycidyl ether resin 20-40
Four glycidol ether 5-20 of 1,1,2,2- tetra- (p-hydroxybenzene) ethane.
Preferably, the curing agent is dicyandiamide or DADPS.The present invention adopts above-mentioned amine based curative, wherein
Contained amido, can effectively prevent the reunion of graphene fiber, increase its dispersive property, be conducive to the raising of absorbing property.
The exposure suit of the present invention, which is made using fabric, therefore its similar daily fabric comfortable and easy to wear, while gently
Just breathe freely.Which adopts radiation proof plate in abdominal region, and the radiation proof plate is using the radio-opaque substance system of special environment's rank
For forming, more thick and heavy, radiation-proof effect is good, reaches professional protection to the fetus protected effect in belly, particularly pregnant woman's abdomen
Rank.Meanwhile, the radiation proof plate can be plugged, and therefore, pregnant woman can be when office faces the radiation sources such as computer, will be described
Radiation proof plate insertion shield pocket, plays a protective role.After radiation source is left, radiation proof plate is taken out, which is common
Fabric radiation takes, and wears light comfortable.
In the detachable plate that the present invention is adopted, it is to strengthen wave-absorbing effect, using the strong sulfonated graphene of wave-absorbing effect-poly-
Parcel fabric made by aniline fiber, is used in conjunction with ad hoc structure and containing the specific fibrofelt for inhaling ripple material, substantially increases slotting
The absorbing property of plate.
The present invention by above-mentioned specific structure design, be simultaneously achieved protection effect good and wear light comfortable will
Ask.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket is surrounded
The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket；The clothing body with shield pocket by
Radiation resistant fiber fabric is constituted；The radiation proof plate is the sheet-like fiber felt of sulfonated graphene-polyaniline fabric parcel, described
Fibrofelt composition includes by weight：
Epoxy resin-base 20
Polypyrrole 10
Curing agent 2
Carbon fiber bundle 10
Glass fiber bundle 10,
Ni0.8Co0.2Powder microwave absorption 5
Manganese dioxide powder 10
Quartz/carbon black composite granule 5；Wherein,
The carbon fiber is fiber bundle structure with glass fibre, and the carbon fiber is interlocked with glass fiber bundle perpendicular separation
It is dispersed in resin matrix, equidistant array is formed, the spacing is less than 10mm, the Ni0.8Co0.2Powder microwave absorption
Agent is dispersed on the carbon fiber and glass fiber bundle, and the graphite and manganese dioxide powder are dispersed in the epoxy resin
In..
Embodiment 2
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket is surrounded
The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket；The clothing body with shield pocket by
Radiation resistant fiber fabric is constituted；The radiation proof plate is the sheet-like fiber felt of sulfonated graphene-polyaniline fabric parcel, described
Fibrofelt composition includes by weight：
Epoxy resin-base 40
Polypyrrole 20
Curing agent 10
Carbon fiber bundle 30
Glass fiber bundle 20,
Ni0.8Co0.2Powder microwave absorption 15
Manganese dioxide powder 20
Quartz/carbon black composite granule 10；Wherein,
The carbon fiber is fiber bundle structure with glass fibre, and the carbon fiber is interlocked with glass fiber bundle perpendicular separation
It is dispersed in resin matrix, equidistant array is formed, the spacing is less than 10mm, the Ni0.8Co0.2Powder microwave absorption
Agent is dispersed on the carbon fiber and glass fiber bundle, and the graphite and manganese dioxide powder are dispersed in the epoxy resin
In..
Embodiment 3
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket is surrounded
The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket；The clothing body with shield pocket by
Radiation resistant fiber fabric is constituted；The radiation proof plate is the sheet-like fiber felt of sulfonated graphene-polyaniline fabric parcel, described
Fibrofelt composition includes by weight：
Epoxy resin-base 30
Polypyrrole 15
Curing agent 5
Carbon fiber bundle 20
Glass fiber bundle 15,
Ni0.8Co0.2Powder microwave absorption 10
Manganese dioxide powder 15
Quartz/carbon black composite granule 70；Wherein,
The carbon fiber is fiber bundle structure with glass fibre, and the carbon fiber is interlocked with glass fiber bundle perpendicular separation
It is dispersed in resin matrix, equidistant array is formed, the spacing is less than 10mm, the Ni0.8Co0.2Powder microwave absorption
Agent is dispersed on the carbon fiber and glass fiber bundle, and the graphite and manganese dioxide powder are dispersed in the epoxy resin
In..
The epoxy resin-base raw material constitutes as follows by weight：
Brominated bisphenol A glycidyl ether resin 30-70,
Tetrabromobisphenol A 2-glycidyl ether resin 20-40
Four glycidol ether 5-20 of 1,1,2,2- tetra- (p-hydroxybenzene) ethane.
The curing agent is dicyandiamide or DADPS.The present invention adopts above-mentioned amine based curative, contained therein
Amido, can effectively prevent the reunion of graphene fiber, increase its dispersive property, be conducive to the raising of absorbing property.
Embodiment 1-3 is simultaneously achieved protection effect good and wear light comfortable by above-mentioned specific structure design
Require.
Claims (4)
1. a kind of exposure suit, especially a kind of exposure suit of detachable plate, in front of clothing body and clothing
Shield pocket, the shield pocket accommodate the pluggable radiation proof plate of masking belly around the belly of whole clothing in the shield pocket；Described
Clothing body is made up of radiation resistant fiber fabric with shield pocket；The radiation proof plate is sulfonated graphene-polyaniline fabric parcel
Sheet-like fiber felt, fibrofelt composition includes by weight：
Epoxy resin-base 20-40
Polypyrrole 10-20
Curing agent 2-10
Carbon fiber bundle 10-30
Glass fiber bundle 10-20,
Ni0.8Co0.2Powder microwave absorption 5-15
Manganese dioxide powder 10-20
Quartz/carbon black composite granule 5-10；Wherein,
The carbon fiber is fiber bundle structure with glass fibre, and the carbon fiber is staggered with glass fiber bundle perpendicular separation to be disperseed
In resin matrix, equidistant array is formed, the spacing is less than 10mm, the Ni0.8Co0.2Powder microwave absorption divides
It is dispersed on the carbon fiber and glass fiber bundle, the graphite and manganese dioxide powder are dispersed in the epoxy resin.
2. exposure suit according to claim 1, it is characterised in that the radiation resistant fiber contains 15- by volume
35% stainless steel fibre and the polyaniline fiber of 5-10%, the stainless steel fibre, polyaniline fiber and string or change
Learn fiber twill blending and obtain the radiation-proof fabric fiber.
3. exposure suit according to claim 2, it is characterised in that in the radiation resistant fiber fabric, stainless steel fibre
Content be 20-30%.
4. exposure suit according to claim 1 and 2, it is characterised in that described sulfonated graphene-polyaniline fabric
Preparation method, including：
(1) graphite oxide is dissolved in deionized water, adds lauryl sodium sulfate, ultrasonic agitation 1-4 hour, graphene oxide:
The mass ratio of neopelex is 1:20-1:100；
(2) 90-100 DEG C is warming up to, is added one hydrazine reaction 12-36 hour is hydrated, obtains black deposit；
(3) filter and be vacuum dried at 70-90 DEG C, obtain sulfonated graphene；
(4) by sulfonated graphene with ammonium persulfate with mass ratio 1:3-1:5 are dissolved in the hydrochloric acid solution of 0.5-2mol/L, as
Water phase；
(5) aniline is dissolved in chloroform, as oil phase；
(6) by water phase and oil phase with sulfonated graphene:Aniline mass ratio is 1:1-1:10 are mixed, and react 12- at 0-5 DEG C
36 hours, obtain green product；
(7) washing green product obtains the sulfonated graphene-polyaniline fiber to colourless, vacuum drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611012283.7A CN106473260A (en) | 2016-11-17 | 2016-11-17 | A kind of detachable plate exposure suit |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611012283.7A CN106473260A (en) | 2016-11-17 | 2016-11-17 | A kind of detachable plate exposure suit |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106473260A true CN106473260A (en) | 2017-03-08 |
Family
ID=58272512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611012283.7A Pending CN106473260A (en) | 2016-11-17 | 2016-11-17 | A kind of detachable plate exposure suit |
Country Status (1)
| Country | Link |
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| CN (1) | CN106473260A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201821986U (en) * | 2010-10-13 | 2011-05-11 | 湖南省忘不了服饰有限公司 | Multifunctional radiation-prevention lining for western-style clothes |
| CN202034068U (en) * | 2011-04-26 | 2011-11-09 | 上海有喜实业有限公司 | Radiation protection garment |
| CN102702517A (en) * | 2012-06-08 | 2012-10-03 | 武汉工程大学 | Preparation method of sulfonated grapheme/polyaniline composite |
| WO2013131300A1 (en) * | 2012-03-07 | 2013-09-12 | 福建赛特新材股份有限公司 | Fiber mat, preparation method therefor and core material for vacuum heat-insulated plate |
| CN103722843A (en) * | 2013-11-28 | 2014-04-16 | 苏州威尔德工贸有限公司 | Anti-static electromagnetic radiation-resistant fabric |
| CN204032419U (en) * | 2014-02-17 | 2014-12-24 | 嘉兴新诚达时装有限公司 | Pregnant woman's jacket that a kind of size is adjustable |
| CN104241616A (en) * | 2014-09-05 | 2014-12-24 | 南京中储新能源有限公司 | Carbon-sulphur composite material based on nano polyaniline array as well as preparation and application of composite material |
| CN105555112A (en) * | 2016-01-22 | 2016-05-04 | 武汉理工大学 | Electromagnetic shielding composite material |
-
2016
- 2016-11-17 CN CN201611012283.7A patent/CN106473260A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201821986U (en) * | 2010-10-13 | 2011-05-11 | 湖南省忘不了服饰有限公司 | Multifunctional radiation-prevention lining for western-style clothes |
| CN202034068U (en) * | 2011-04-26 | 2011-11-09 | 上海有喜实业有限公司 | Radiation protection garment |
| WO2013131300A1 (en) * | 2012-03-07 | 2013-09-12 | 福建赛特新材股份有限公司 | Fiber mat, preparation method therefor and core material for vacuum heat-insulated plate |
| CN102702517A (en) * | 2012-06-08 | 2012-10-03 | 武汉工程大学 | Preparation method of sulfonated grapheme/polyaniline composite |
| CN103722843A (en) * | 2013-11-28 | 2014-04-16 | 苏州威尔德工贸有限公司 | Anti-static electromagnetic radiation-resistant fabric |
| CN204032419U (en) * | 2014-02-17 | 2014-12-24 | 嘉兴新诚达时装有限公司 | Pregnant woman's jacket that a kind of size is adjustable |
| CN104241616A (en) * | 2014-09-05 | 2014-12-24 | 南京中储新能源有限公司 | Carbon-sulphur composite material based on nano polyaniline array as well as preparation and application of composite material |
| CN105555112A (en) * | 2016-01-22 | 2016-05-04 | 武汉理工大学 | Electromagnetic shielding composite material |
Non-Patent Citations (1)
| Title |
|---|
| 田俊莹等: "《纺织品功能整理》", 31 August 2015 * |
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Application publication date: 20170308 |