CN106751846A - A kind of detachable plate exposure suit - Google Patents

A kind of detachable plate exposure suit Download PDF

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Publication number
CN106751846A
CN106751846A CN201611011922.8A CN201611011922A CN106751846A CN 106751846 A CN106751846 A CN 106751846A CN 201611011922 A CN201611011922 A CN 201611011922A CN 106751846 A CN106751846 A CN 106751846A
Authority
CN
China
Prior art keywords
graphene
radiation
shield
clothing
silicon rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611011922.8A
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Chinese (zh)
Inventor
缪建良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Changan Shuguang Glove Factory
Original Assignee
Wuxi Changan Shuguang Glove Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Changan Shuguang Glove Factory filed Critical Wuxi Changan Shuguang Glove Factory
Priority to CN201611011922.8A priority Critical patent/CN106751846A/en
Publication of CN106751846A publication Critical patent/CN106751846A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D1/00Garments
    • A41D1/21Maternity clothing; Clothing specially adapted for persons caring for infants
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F3/00Shielding characterised by its physical form, e.g. granules, or shape of the material
    • G21F3/02Clothing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/20Metallic fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments

Abstract

The invention discloses a kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket accommodates the pluggable radiation proof plate of masking belly around the belly of whole clothing in the shield pocket;The clothing body is made up of with shield pocket radiation resistant fiber fabric;The radiation proof plate is the electromagnetic shield rubber of fabric parcel.The present invention is by above-mentioned specific structure design, while it is good and wear light comfortable requirement to realize protection effect.

Description

A kind of detachable plate exposure suit
Technical field
The present invention relates to labour protection technical field, more particularly to a kind of exposure suit of detachable plate.
Background technology
Human body is constantly in certain energy electromagnetic wave radiation environment, when its frequency is more than more than 105Hz just to people Body is harmful to.The power output of wave electromagnetic radiation source is bigger, and radiation intensity is bigger, and wavelength is shorter, and frequency is higher, and distance is nearer, connects The tactile time is more long, and environment temperature is higher, and humidity is bigger, and air does not circulate, then environmental pollution degree is bigger, and women and Children are more serious by harm.Electromagnetic wave can upset the natural physiological law of human body, cause organism balance disorderly, cause headache, head The neurasthenia symptom such as dizzy, insomnia, forgetful;Make one it is weak, poor appetite, irritable;Can also lose Models of Human Thermal Regulation Adjust, cause increased heart rate, blood pressure are raised and lowered, have difficulty in breathing, Neuroleptic Leukocytopenia;Generation to angiocardiopathy and deteriorate Impetus.In addition electromagnetic wave can cause visual impairment.When intensity is 100mw/cm2Electromagnetic wave irradiation eyes when, can make There is oedema in crystal, can develop into cataract, result even in blindness.When intensity is 5mw/cm2-10mw/cm2Electromagnetic wave shine When penetrating human body, though the dermal sensation of people is not obvious, fertility and heredity may be influenceed.Women is under Electromagnetic Field, and menstruation is all Phase occurs substantially to change, and pregnant woman can be caused to miscarry and gene defect, is chronically at the children in the presence of strong electromagnetic wave, its cancer The incidence of disease is higher 2~5 times than the children under low electromagnetic wave, and electromagnetic wave is also one of inducement of leukaemia, lymph cancer, brain tumor.
Exposure suit is exactly the clothes with ELECTROMAGNETIC REFLECTION principle using electromagnetic shielding, and it typically uses specific fabric Or coating is realized.But in its technological means for using, there is chemical contamination or metallic pollution in some, some radiation-proof effects Typically.
For specific workplace, it is higher to radiation proof requirement, and its exposure suit is thick and heavy, and protection effect is good, but Heavy, dress is extreme uncomfortable.And in routine office work environment, such as pregnant woman wears exposure suit, its is light comfortable, but anti-spoke Penetrate, particularly prevent electromagnetic radiation performance general.Therefore how the two to be combined, is that the technology that those skilled in the art face is difficult One of topic.
The content of the invention
It is an object of the invention to propose exposure suit, its is comfortable and easy to wear, and radiation-proof effect is excellent.
It is that, up to this purpose, the present invention uses following technical scheme:
A kind of exposure suit, especially a kind of exposure suit of detachable plate, including clothing body and clothing front Shield pocket, the shield pocket around whole clothing belly, in the shield pocket accommodate masking belly pluggable radiation proof plate;Institute Clothing body is stated to be made up of radiation resistant fiber fabric with shield pocket;The radiation proof plate is the electromagnetic shield rubber of fabric parcel, It is graphene/carbon nano-tube/silicon rubber composite material, in the composite, the weight of graphene/carbon nano-tube/silicon rubber Amount is than being (0.5-2):(2-3):100, preferably 1:2.5:100.
The preparation method of graphene/carbon nano-tube/silicon rubber composite material of the present invention, including:
(1) silicon rubber is scattered in tetrahydrofuran, forms uniform solution;
(2) CNT is scattered in tetrahydrofuran, ultrasonically treated 2-5 hours, ultrasonic power 130-200w;
(3) Graphene is added in the tetrahydrofuran suspension of the CNT, continues ultrasonically treated 0.5-3 hours, Ultrasonic power 130-200w, obtains mixed liquor;
(4) mixed liquor that will be obtained mixes with finely dispersed silicone rubber solution, the lower ultrasound 20-50min of stirring, surpasses Acoustical power 80-100w;
(5) under agitation, tetrahydrofuran is boiled off at 40-60 DEG C, vacuumize drying;
(6) add vulcanizing agent to be vulcanized by Mechanical Method on a mill, obtain the graphene/carbon nano-tube/silicon Rubber composite.
In composite prepared by the present invention, there is synergy between Graphene and CNT.
The radiation proof plate uses fibrofelt, and is wrapped up by fabric, therefore it can bend, to adapt to the human body do not allowed Shape, and deform under sitting posture and crouching appearance so that it is comfortable and easy to wear.
Preferably, the radiation proof shield pocket is 4, and it is respectively around belly, sidepiece and low back.Therefore, user can be with According to working environment, unrestricted choice inserts 1 block protection belly, or only protects sidepiece, or protection low back, and user can be with root According to applied environment insertion position and quantity are voluntarily selected with the position of pre- protection.
Preferably, the polyaniline of the radiation resistant fiber stainless steel fibre containing 15-35% and 5-10% by volume Fiber, the stainless steel fibre, polyaniline fiber and string or chemical fibre twill blending obtain the radiation-proof fabric Fiber.
Preferably, in the radiation resistant fiber fabric, the content of stainless steel fibre is 20-30%.When stainless steel fibre contains When amount is within the scope of this, its snugness of fit and shielding property are balanced the most.
Exposure suit of the invention when in use, can use the superposition of radiation proof plate, such as 2 according to radiation event Even 3 pieces of block and above superposition are used, to realize the superposition of protection effect.
Exposure suit of the invention, it uses fabric to be made, therefore its similar daily fabric comfortable and easy to wear, while gently Just breathe freely.It uses radiation proof plate, the radiation proof plate to use the radio-opaque substance system of special environment's rank in abdominal region Standby to form, more thick and heavy, radiation-proof effect is good, and professional protection is reached to the fetus protecting effect in belly, particularly pregnant woman's abdomen Rank.Meanwhile, the radiation proof plate can be plugged, therefore, pregnant woman can be when office faces the radiation sources such as computer, will be described Radiation proof plate insertion shield pocket, plays a protective role.After radiation source is left, radiation proof plate is taken out, it is common Fabric radiation takes, and wears light comfortable.
The cooperation mechanism of Graphene and CNT has as follows:Because the specific surface area of Graphene is far longer than carbon nanometer Pipe, so Graphene and CNT are in the dispersion process of silicon rubber, CNT will height with graphene sheet layer contact probability In the contact of CNT itself, CNT forms hydrogen bond with Graphene first, therefore weakens CNT itself Agglomeration, further, since there is the presence of CNT around graphene sheet layer, they can be with the distant Graphene of UNICOM Space between lamella, while also causing that graphene sheet layer is difficult to stack again.Graphene and CNT serve mutually system Effect about, has finally obtained preferable dispersion in silicon rubber.
The decomposition temperature of the graphene/carbon nano-tube/silicon rubber composite material is more than 515 DEG C, higher than dividing for pure silicon glue 461.1 DEG C of temperature of solution;Its Tg is more than 107 DEG C, and 7.4 DEG C are improve relative to pure silicon glue.
Graphene is set to 1 part (mass fraction), carries out cooperateing with mixing with CNT, when the consumption of CNT is 2 During part, the specific insulation of silicon rubber is 4.91x109Ω cm, 4 orders of magnitude, stone are have dropped compared to pure silicone rubber matrix Black alkene and CNT gross mass part are 3 parts, but specific insulation is than low 2 orders of magnitude individually plus during 3 parts of CNTs; When the consumption of CNT is 2.5 parts, the specific insulation of silicon rubber is 8.0 × 104Ω cm, compared to pure silicone rubber base Body have dropped 9 orders of magnitude, show that the conductive path of Graphene and CNT in silicone rubber matrix has been formed, Graphene It it is 3.5 parts with CNT gross mass part, the resistivity than independent plus 7 parts of CNTs is also low, only than individually adding 10 parts of carbon Resistivity 1 order of magnitude high of nanotube.Can be drawn by contrast, can be with by the synergy of Graphene and CNT The specific insulation of silicon rubber is significantly reduced, so as to silicon rubber can also be made to obtain good electric conductivity under low loading.
The tensile strength of the graphene/carbon nano-tube/silicon rubber composite material is more than 1, and under the same terms, carbon nanometer When pipe or Graphene are used alone, its tensile strength is only 0.22-0.50.Because Graphene can be good in silicon rubber Dispersion, the associativity with silicon rubber is good.After CNT and Graphene coordinated, Graphene possesses very big surface area, CNT, and good dispersion of the Graphene in silicone rubber matrix are better than with the adhesion of silicon rubber, can effectively be held The effect of power is carried, therefore causes the mechanical properties such as its tensile strength and hardness to greatly improve.
The present invention is by above-mentioned specific structure design, while it is good and wear light comfortable want to realize protection effect Ask.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket around The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body with shield pocket by Radiation resistant fiber fabric is constituted;The radiation proof plate is the electromagnetic shield rubber of fabric parcel, and it is graphene/carbon nanometer Pipe/silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is 0.5:2:100.
Embodiment 2
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket around The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body with shield pocket by Radiation resistant fiber fabric is constituted;The radiation proof plate is the electromagnetic shield rubber of fabric parcel, and it is graphene/carbon nanometer Pipe/silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is 2:3:100.
Embodiment 3
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket around The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body with shield pocket by Radiation resistant fiber fabric is constituted;The radiation proof plate is the electromagnetic shield rubber of fabric parcel, and it is graphene/carbon nanometer Pipe/silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is 1:2.5:100.
Embodiment 1-3 is by above-mentioned specific structure design, while it is good and wear light comfortable to realize protection effect It is required that.

Claims (4)

1. a kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket is around whole The belly of individual clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body is with shield pocket by preventing Bergmann's fiber fabric is constituted;The radiation proof plate be fabric parcel electromagnetic shield rubber, its be graphene/carbon nano-tube/ Silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is (0.5-2):(2-3): 100, preferably 1:2.5:100.
2. exposure suit according to claim 1, it is characterised in that the radiation resistant fiber contains 15- by volume 35% stainless steel fibre and the polyaniline fiber of 5-10%, the stainless steel fibre, polyaniline fiber and string or change Learn fiber twill blending and obtain the radiation-proof fabric fiber.
3. exposure suit according to claim 2, it is characterised in that in the radiation resistant fiber fabric, stainless steel fibre Content be 20-30%.
4. according to the exposure suit that one of claims 1 to 3 is described, it is characterised in that described graphene/carbon nano-tube/silicon The preparation method of rubber composite, including:
(1) silicon rubber is scattered in tetrahydrofuran, forms uniform solution;
(2) CNT is scattered in tetrahydrofuran, ultrasonically treated 2-5 hours, ultrasonic power 130-200w;
(3) Graphene is added in the tetrahydrofuran suspension of the CNT, continues ultrasonically treated 0.5-3 hours, ultrasound Power 130-200w, obtains mixed liquor;
(4) mixed liquor that will be obtained mixes with finely dispersed silicone rubber solution, stirring lower ultrasound 20-50min, ultrasonic work( Rate 80-100w;
(5) under agitation, tetrahydrofuran is boiled off at 40-60 DEG C, vacuumize drying;
(6) add vulcanizing agent to be vulcanized by Mechanical Method on a mill, obtain the graphene/carbon nano-tube/silicon rubber Composite.
CN201611011922.8A 2016-11-17 2016-11-17 A kind of detachable plate exposure suit Pending CN106751846A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611011922.8A CN106751846A (en) 2016-11-17 2016-11-17 A kind of detachable plate exposure suit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611011922.8A CN106751846A (en) 2016-11-17 2016-11-17 A kind of detachable plate exposure suit

Publications (1)

Publication Number Publication Date
CN106751846A true CN106751846A (en) 2017-05-31

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611011922.8A Pending CN106751846A (en) 2016-11-17 2016-11-17 A kind of detachable plate exposure suit

Country Status (1)

Country Link
CN (1) CN106751846A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103722843A (en) * 2013-11-28 2014-04-16 苏州威尔德工贸有限公司 Anti-static electromagnetic radiation-resistant fabric
CN204032419U (en) * 2014-02-17 2014-12-24 嘉兴新诚达时装有限公司 Pregnant woman's jacket that a kind of size is adjustable

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103722843A (en) * 2013-11-28 2014-04-16 苏州威尔德工贸有限公司 Anti-static electromagnetic radiation-resistant fabric
CN204032419U (en) * 2014-02-17 2014-12-24 嘉兴新诚达时装有限公司 Pregnant woman's jacket that a kind of size is adjustable

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘寅: "石墨烯/碳纳米管/硅橡胶导电复合材料的研究", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》 *

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Application publication date: 20170531