CN106751846A - A kind of detachable plate exposure suit - Google Patents
A kind of detachable plate exposure suit Download PDFInfo
- Publication number
- CN106751846A CN106751846A CN201611011922.8A CN201611011922A CN106751846A CN 106751846 A CN106751846 A CN 106751846A CN 201611011922 A CN201611011922 A CN 201611011922A CN 106751846 A CN106751846 A CN 106751846A
- Authority
- CN
- China
- Prior art keywords
- graphene
- radiation
- shield
- clothing
- silicon rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D1/00—Garments
- A41D1/21—Maternity clothing; Clothing specially adapted for persons caring for infants
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F3/00—Shielding characterised by its physical form, e.g. granules, or shape of the material
- G21F3/02—Clothing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/20—Metallic fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
Abstract
The invention discloses a kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket accommodates the pluggable radiation proof plate of masking belly around the belly of whole clothing in the shield pocket;The clothing body is made up of with shield pocket radiation resistant fiber fabric;The radiation proof plate is the electromagnetic shield rubber of fabric parcel.The present invention is by above-mentioned specific structure design, while it is good and wear light comfortable requirement to realize protection effect.
Description
Technical field
The present invention relates to labour protection technical field, more particularly to a kind of exposure suit of detachable plate.
Background technology
Human body is constantly in certain energy electromagnetic wave radiation environment, when its frequency is more than more than 105Hz just to people
Body is harmful to.The power output of wave electromagnetic radiation source is bigger, and radiation intensity is bigger, and wavelength is shorter, and frequency is higher, and distance is nearer, connects
The tactile time is more long, and environment temperature is higher, and humidity is bigger, and air does not circulate, then environmental pollution degree is bigger, and women and
Children are more serious by harm.Electromagnetic wave can upset the natural physiological law of human body, cause organism balance disorderly, cause headache, head
The neurasthenia symptom such as dizzy, insomnia, forgetful;Make one it is weak, poor appetite, irritable;Can also lose Models of Human Thermal Regulation
Adjust, cause increased heart rate, blood pressure are raised and lowered, have difficulty in breathing, Neuroleptic Leukocytopenia;Generation to angiocardiopathy and deteriorate
Impetus.In addition electromagnetic wave can cause visual impairment.When intensity is 100mw/cm2Electromagnetic wave irradiation eyes when, can make
There is oedema in crystal, can develop into cataract, result even in blindness.When intensity is 5mw/cm2-10mw/cm2Electromagnetic wave shine
When penetrating human body, though the dermal sensation of people is not obvious, fertility and heredity may be influenceed.Women is under Electromagnetic Field, and menstruation is all
Phase occurs substantially to change, and pregnant woman can be caused to miscarry and gene defect, is chronically at the children in the presence of strong electromagnetic wave, its cancer
The incidence of disease is higher 2~5 times than the children under low electromagnetic wave, and electromagnetic wave is also one of inducement of leukaemia, lymph cancer, brain tumor.
Exposure suit is exactly the clothes with ELECTROMAGNETIC REFLECTION principle using electromagnetic shielding, and it typically uses specific fabric
Or coating is realized.But in its technological means for using, there is chemical contamination or metallic pollution in some, some radiation-proof effects
Typically.
For specific workplace, it is higher to radiation proof requirement, and its exposure suit is thick and heavy, and protection effect is good, but
Heavy, dress is extreme uncomfortable.And in routine office work environment, such as pregnant woman wears exposure suit, its is light comfortable, but anti-spoke
Penetrate, particularly prevent electromagnetic radiation performance general.Therefore how the two to be combined, is that the technology that those skilled in the art face is difficult
One of topic.
The content of the invention
It is an object of the invention to propose exposure suit, its is comfortable and easy to wear, and radiation-proof effect is excellent.
It is that, up to this purpose, the present invention uses following technical scheme:
A kind of exposure suit, especially a kind of exposure suit of detachable plate, including clothing body and clothing front
Shield pocket, the shield pocket around whole clothing belly, in the shield pocket accommodate masking belly pluggable radiation proof plate;Institute
Clothing body is stated to be made up of radiation resistant fiber fabric with shield pocket;The radiation proof plate is the electromagnetic shield rubber of fabric parcel,
It is graphene/carbon nano-tube/silicon rubber composite material, in the composite, the weight of graphene/carbon nano-tube/silicon rubber
Amount is than being (0.5-2):(2-3):100, preferably 1:2.5:100.
The preparation method of graphene/carbon nano-tube/silicon rubber composite material of the present invention, including:
(1) silicon rubber is scattered in tetrahydrofuran, forms uniform solution;
(2) CNT is scattered in tetrahydrofuran, ultrasonically treated 2-5 hours, ultrasonic power 130-200w;
(3) Graphene is added in the tetrahydrofuran suspension of the CNT, continues ultrasonically treated 0.5-3 hours,
Ultrasonic power 130-200w, obtains mixed liquor;
(4) mixed liquor that will be obtained mixes with finely dispersed silicone rubber solution, the lower ultrasound 20-50min of stirring, surpasses
Acoustical power 80-100w;
(5) under agitation, tetrahydrofuran is boiled off at 40-60 DEG C, vacuumize drying;
(6) add vulcanizing agent to be vulcanized by Mechanical Method on a mill, obtain the graphene/carbon nano-tube/silicon
Rubber composite.
In composite prepared by the present invention, there is synergy between Graphene and CNT.
The radiation proof plate uses fibrofelt, and is wrapped up by fabric, therefore it can bend, to adapt to the human body do not allowed
Shape, and deform under sitting posture and crouching appearance so that it is comfortable and easy to wear.
Preferably, the radiation proof shield pocket is 4, and it is respectively around belly, sidepiece and low back.Therefore, user can be with
According to working environment, unrestricted choice inserts 1 block protection belly, or only protects sidepiece, or protection low back, and user can be with root
According to applied environment insertion position and quantity are voluntarily selected with the position of pre- protection.
Preferably, the polyaniline of the radiation resistant fiber stainless steel fibre containing 15-35% and 5-10% by volume
Fiber, the stainless steel fibre, polyaniline fiber and string or chemical fibre twill blending obtain the radiation-proof fabric
Fiber.
Preferably, in the radiation resistant fiber fabric, the content of stainless steel fibre is 20-30%.When stainless steel fibre contains
When amount is within the scope of this, its snugness of fit and shielding property are balanced the most.
Exposure suit of the invention when in use, can use the superposition of radiation proof plate, such as 2 according to radiation event
Even 3 pieces of block and above superposition are used, to realize the superposition of protection effect.
Exposure suit of the invention, it uses fabric to be made, therefore its similar daily fabric comfortable and easy to wear, while gently
Just breathe freely.It uses radiation proof plate, the radiation proof plate to use the radio-opaque substance system of special environment's rank in abdominal region
Standby to form, more thick and heavy, radiation-proof effect is good, and professional protection is reached to the fetus protecting effect in belly, particularly pregnant woman's abdomen
Rank.Meanwhile, the radiation proof plate can be plugged, therefore, pregnant woman can be when office faces the radiation sources such as computer, will be described
Radiation proof plate insertion shield pocket, plays a protective role.After radiation source is left, radiation proof plate is taken out, it is common
Fabric radiation takes, and wears light comfortable.
The cooperation mechanism of Graphene and CNT has as follows:Because the specific surface area of Graphene is far longer than carbon nanometer
Pipe, so Graphene and CNT are in the dispersion process of silicon rubber, CNT will height with graphene sheet layer contact probability
In the contact of CNT itself, CNT forms hydrogen bond with Graphene first, therefore weakens CNT itself
Agglomeration, further, since there is the presence of CNT around graphene sheet layer, they can be with the distant Graphene of UNICOM
Space between lamella, while also causing that graphene sheet layer is difficult to stack again.Graphene and CNT serve mutually system
Effect about, has finally obtained preferable dispersion in silicon rubber.
The decomposition temperature of the graphene/carbon nano-tube/silicon rubber composite material is more than 515 DEG C, higher than dividing for pure silicon glue
461.1 DEG C of temperature of solution;Its Tg is more than 107 DEG C, and 7.4 DEG C are improve relative to pure silicon glue.
Graphene is set to 1 part (mass fraction), carries out cooperateing with mixing with CNT, when the consumption of CNT is 2
During part, the specific insulation of silicon rubber is 4.91x109Ω cm, 4 orders of magnitude, stone are have dropped compared to pure silicone rubber matrix
Black alkene and CNT gross mass part are 3 parts, but specific insulation is than low 2 orders of magnitude individually plus during 3 parts of CNTs;
When the consumption of CNT is 2.5 parts, the specific insulation of silicon rubber is 8.0 × 104Ω cm, compared to pure silicone rubber base
Body have dropped 9 orders of magnitude, show that the conductive path of Graphene and CNT in silicone rubber matrix has been formed, Graphene
It it is 3.5 parts with CNT gross mass part, the resistivity than independent plus 7 parts of CNTs is also low, only than individually adding 10 parts of carbon
Resistivity 1 order of magnitude high of nanotube.Can be drawn by contrast, can be with by the synergy of Graphene and CNT
The specific insulation of silicon rubber is significantly reduced, so as to silicon rubber can also be made to obtain good electric conductivity under low loading.
The tensile strength of the graphene/carbon nano-tube/silicon rubber composite material is more than 1, and under the same terms, carbon nanometer
When pipe or Graphene are used alone, its tensile strength is only 0.22-0.50.Because Graphene can be good in silicon rubber
Dispersion, the associativity with silicon rubber is good.After CNT and Graphene coordinated, Graphene possesses very big surface area,
CNT, and good dispersion of the Graphene in silicone rubber matrix are better than with the adhesion of silicon rubber, can effectively be held
The effect of power is carried, therefore causes the mechanical properties such as its tensile strength and hardness to greatly improve.
The present invention is by above-mentioned specific structure design, while it is good and wear light comfortable want to realize protection effect
Ask.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket around
The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body with shield pocket by
Radiation resistant fiber fabric is constituted;The radiation proof plate is the electromagnetic shield rubber of fabric parcel, and it is graphene/carbon nanometer
Pipe/silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is 0.5:2:100.
Embodiment 2
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket around
The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body with shield pocket by
Radiation resistant fiber fabric is constituted;The radiation proof plate is the electromagnetic shield rubber of fabric parcel, and it is graphene/carbon nanometer
Pipe/silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is 2:3:100.
Embodiment 3
A kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket around
The belly of whole clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body with shield pocket by
Radiation resistant fiber fabric is constituted;The radiation proof plate is the electromagnetic shield rubber of fabric parcel, and it is graphene/carbon nanometer
Pipe/silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is 1:2.5:100.
Embodiment 1-3 is by above-mentioned specific structure design, while it is good and wear light comfortable to realize protection effect
It is required that.
Claims (4)
1. a kind of exposure suit of detachable plate, including the shield pocket in front of clothing body and clothing, the shield pocket is around whole
The belly of individual clothing, accommodates the pluggable radiation proof plate of masking belly in the shield pocket;The clothing body is with shield pocket by preventing
Bergmann's fiber fabric is constituted;The radiation proof plate be fabric parcel electromagnetic shield rubber, its be graphene/carbon nano-tube/
Silicon rubber composite material, in the composite, the weight ratio of graphene/carbon nano-tube/silicon rubber is (0.5-2):(2-3):
100, preferably 1:2.5:100.
2. exposure suit according to claim 1, it is characterised in that the radiation resistant fiber contains 15- by volume
35% stainless steel fibre and the polyaniline fiber of 5-10%, the stainless steel fibre, polyaniline fiber and string or change
Learn fiber twill blending and obtain the radiation-proof fabric fiber.
3. exposure suit according to claim 2, it is characterised in that in the radiation resistant fiber fabric, stainless steel fibre
Content be 20-30%.
4. according to the exposure suit that one of claims 1 to 3 is described, it is characterised in that described graphene/carbon nano-tube/silicon
The preparation method of rubber composite, including:
(1) silicon rubber is scattered in tetrahydrofuran, forms uniform solution;
(2) CNT is scattered in tetrahydrofuran, ultrasonically treated 2-5 hours, ultrasonic power 130-200w;
(3) Graphene is added in the tetrahydrofuran suspension of the CNT, continues ultrasonically treated 0.5-3 hours, ultrasound
Power 130-200w, obtains mixed liquor;
(4) mixed liquor that will be obtained mixes with finely dispersed silicone rubber solution, stirring lower ultrasound 20-50min, ultrasonic work(
Rate 80-100w;
(5) under agitation, tetrahydrofuran is boiled off at 40-60 DEG C, vacuumize drying;
(6) add vulcanizing agent to be vulcanized by Mechanical Method on a mill, obtain the graphene/carbon nano-tube/silicon rubber
Composite.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611011922.8A CN106751846A (en) | 2016-11-17 | 2016-11-17 | A kind of detachable plate exposure suit |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611011922.8A CN106751846A (en) | 2016-11-17 | 2016-11-17 | A kind of detachable plate exposure suit |
Publications (1)
Publication Number | Publication Date |
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CN106751846A true CN106751846A (en) | 2017-05-31 |
Family
ID=58968668
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611011922.8A Pending CN106751846A (en) | 2016-11-17 | 2016-11-17 | A kind of detachable plate exposure suit |
Country Status (1)
Country | Link |
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CN (1) | CN106751846A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103722843A (en) * | 2013-11-28 | 2014-04-16 | 苏州威尔德工贸有限公司 | Anti-static electromagnetic radiation-resistant fabric |
CN204032419U (en) * | 2014-02-17 | 2014-12-24 | 嘉兴新诚达时装有限公司 | Pregnant woman's jacket that a kind of size is adjustable |
-
2016
- 2016-11-17 CN CN201611011922.8A patent/CN106751846A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103722843A (en) * | 2013-11-28 | 2014-04-16 | 苏州威尔德工贸有限公司 | Anti-static electromagnetic radiation-resistant fabric |
CN204032419U (en) * | 2014-02-17 | 2014-12-24 | 嘉兴新诚达时装有限公司 | Pregnant woman's jacket that a kind of size is adjustable |
Non-Patent Citations (1)
Title |
---|
刘寅: "石墨烯/碳纳米管/硅橡胶导电复合材料的研究", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》 * |
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Application publication date: 20170531 |