CN106460208A - Hydrocarbon-production-apparatus and method for producing hydrocarbons with renewable electric energy - Google Patents
Hydrocarbon-production-apparatus and method for producing hydrocarbons with renewable electric energy Download PDFInfo
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- CN106460208A CN106460208A CN201480079278.0A CN201480079278A CN106460208A CN 106460208 A CN106460208 A CN 106460208A CN 201480079278 A CN201480079278 A CN 201480079278A CN 106460208 A CN106460208 A CN 106460208A
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- carbon dioxide
- vapor
- hydrocarbon production
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/005—Carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0903—Feed preparation
- C10J2300/0909—Drying
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0969—Carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0976—Water as steam
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1284—Heating the gasifier by renewable energy, e.g. solar energy, photovoltaic cells, wind
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
- C10J2300/1618—Modification of synthesis gas composition, e.g. to meet some criteria
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1643—Conversion of synthesis gas to energy
- C10J2300/1653—Conversion of synthesis gas to energy integrated in a gasification combined cycle [IGCC]
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1684—Integration of gasification processes with another plant or parts within the plant with electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
- C10J2300/1815—Recycle loops, e.g. gas, solids, heating medium, water for carbon dioxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention relates to a hydrocarbon-production-apparatus for the production of gaseous and / or liquid hydrocarbons from solid, liquid or gaseous carbonaceous carrier comprising a gasifier for the production of a carbon monoxide sustainable gasification gas, a shift-process to produce hydrogen and carbon dioxide from carbon monoxide and water vapour, and a synthesis process for the production of gaseous and / or liquid hydrocarbons from carbon monoxide and hydrogen. Furthermore the invention relates to a hydrocarbon-production-method with a hydrocarbon-production-apparatus according to the invention.
Description
The present invention relates to produced the hydrocarbon production equipment of gaseous state and/or liquid hydrocarbon, institute by solid, liquid or gaseous state carbon-containing carrier
State hydrocarbon production equipment and include gasifier, described gasifier is used for producing the gasifying gas comprising carbon monoxide；Conversion process, described
Conversion process is used for producing hydrogen and carbon dioxide by carbon monoxide and vapor；And building-up process, described building-up process is used for
By carbon monoxide and hydrogen gas production gaseous state and/or liquid hydrocarbon.In addition the present invention relates to using the hydrocarbon of the hydrocarbon production equipment of the present invention
Production method.
The field of the invention is the whole world, region and local power generation and distribution, for the change using liquid and gaseous hydrocarbon
Learn the whole world, region and the localized supplies of industry and energy sector and the energy using recyclable fuel and traffic department.
In describing the invention, Reproduceable electricity is understood to by solar energy equipment, wind turbine or hydroelectric generation
The Reproduceable electricity of the excess of production such as stand, described Reproduceable electricity is not used in that actual electric power needs or electric power will not wherein
Transport and produce to the region of next possible client.It is important to appreciate that fossil energy is very unfavorable for the present invention,
Electric energy needed for therefore it is not used as the present invention.
Liquid is produced by carbon-containing fuel, waste and residue according to prior art and gaseous hydrocarbon utilizes oxygenous gasification substance
Or material gasification is the synthesis gas being mainly made up of carbon monoxide and hydrogen by reagent.Then will be synthesized using conventional synthetic procedures
Gas is converted into liquid or gaseous hydrocarbon.The use of entrained flow gasifiers, conversion process and the synthetically produced hydrocarbon of methane is existing effective skill
Art.
Quality depending on starting material it might therefore be necessary to these materials are prepared with meet respective enter gentle
The particular requirement of change process.Preparation method be by being pyrolyzed, drying, hydrothermal carbonization etc. is dried, crushes/grind, thermally decomposes carbon containing
Gas and/or the starting material of liquid and solid form.
In hydrocarbon synthesis, mainly hydrocarbon is converted into by the synthesis gas that carbon monoxide and hydrogen form, with the release of energy.
The building-up process of liquid hydrocarbon is also known, such as methanol-fueled CLC (Lurgi low pressure process), Fiscber-Tropscb synthesis, and dimethyl ether closes
Become etc..
Synthesize gaseous hydrocarbon for according to prior art, substantially known and use is by carbon monoxide and hydrogen gas production methane.
Because the natural gas of low price, industrially do not used by carbon monoxide and hydrogen gas production methane before.
Because the composition of raw material, the synthesis gas from carbon raw material gasification generally comprises the excessive oxygen with respect to hydrogen
Change carbon.In order to set the carbon monoxide in the synthesis gas of specific synthetic method and the molar ratio needed for hydrogen, generally according to
Homogeneous water gas shift reaction in conversion process by a part of carbon monoxide with steam transforming to form hydrogen and titanium dioxide
Carbon.The carbon dioxide of gained passes through method such as Rectisol or Selexol washing, monoethanolamine washing or the membrance separation being suitable for
Method removes from synthesis gas, and is emitted into air.The Process Design of gaseous mass fluctuating or the change of raw material composition is led to be led to
Cross control conversion process and balance, therefore there is the obtainable constant gaseous mass for synthesis.
Such as Fossil fuel, oil, gas and future the demand of coal is also had constantly to increase the energy and raw material, but because
Resource-constrained, serves all demands by Problems.Then, exist for reduction CO2 emission to keep environment green
Increasing need with cleaning.Closure Carbon cycle is task.
Because produced by solar energy and wind-force the expansion of the facility of electric energy, the daily and seasonal change related with weather with
And the room and time over loading in power distribution network, need storage and transport Reproduceable electricity, especially excessive can be again
Raw electric energy, and do not close energy generation facilities.
The system being generally employed to produce electric energy occurs with usual away from client at the position away from the site of energy demand,
Therefore there must be the mode of the long-distance transportation energy, this is also related to the high cost of transport and substantial amounts of loss.
In compensation network, an option of local excess capacity is that have the power distribution network of enough transmission capacities or the expansion of network
?.The expansion of electrical network is to be time-consuming and expensive it is impossible to independent significantly solve problem.
In compensation network, another mode of local excess capacity is to store substantial amounts of electric energy, such as electric, chemical, electrochemical
In or mechanical basin.
Accordingly, it would be desirable to exploitation has the storing technology of high storage capacity and also high efficiency of storage.Also focus on the energy of storage
The electric regenerative in source.By using carbon monoxide and/or carbon dioxide and hydrogen conversion in the form of methane storage renewable
Electric energy is important factor, therefore gas transport net, and natural gas network is substantially the unlimited basin of methane and almost producing
Can obtain at any position.The energy thus storing can easily recycle.
Problem of the prior art
Document WO2005/056737 describes to pass through, by solid carbon carrier, the solid carbon carrier production liquid energy carrier that gasifies
Method and apparatus.The molar ratio that the synthesis of hydrogen and carbon monoxide is required can not be adjusted by carbon monoxide transformation process,
But the hydrogen only passing through supply from water electrolysis is adjusted.Oxygen from electrolysis is used as gasifying agent.
But there is not conversion process and produce the constant energy supply of hydrocarbon requirement process to operate electrolysis and with accurate simultaneously
Demand produce hydrogen and oxygen.Because operating electrolysis using Reproduceable electricity, the method can only be passed through to control fuel supply
Fluctuation in response to Reproduceable electricity and the performance therefore reducing gasifier.
In yet another aspect, depending on raw materials quality, the gasification of prior art and subsequent synthesis, and using conversion
Process produces liquid and gaseous hydrocarbon, leads to lack carbon, and conversion process produces hydrogen and carbon dioxide (referring to R5) simultaneously.By this shape
The carbon dioxide becoming removes from synthesis gas and is emitted into air.Therefore this part carbon no longer can obtain to produce liquid and gaseous hydrocarbon
And also pollute air.
In order to improve the hydrogen by being electrolysed the utilization carbon producing, abandon profit as in document WO2005/056737 completely
Option with conversion process control process.Therefore also use the electric energy producing using Fossil fuel, this leads to be sent out by petrochemical industry source
Electric generally increases.
Therefore, by completely canceling out in the carbon dioxide producing Additional discharges during fossil electric power drives electrolysis
By adding the CO2 emission saved from the hydrogen being electrolysed from conversion process.
When using water electrolysis production 1mol H2When, conversion process is saved 1mol CO2Discharge.In order that using water electrolysis
Produce the H of 1mol2, wherein efficiency is 70%, needs the electric energy of 344.5kJ, and this releases the carbon dioxide (burning more than 2mol
Carbon：2.4mol；Burning coal 2.1mol) it is assumed that generating efficiency is 35%.
Due to producing the daily and seasonal fluctuation related with weather in electric energy from renewable origin, from Reproduceable electricity
The region in electrical network for the relation of the supply of the energy producing and time over loading increases it means that fossil base load electromotor
Operate and therefore out of service generally under their economic restriction.
The purpose of the present invention
The purpose of the present invention is to develop to produce gaseous state and liquid by solid, liquid and gaseous carbonaceous fuels, waste and residue
The method of hydrocarbon or process and hydrocarbon production equipment, this discharge improving carbon utilization ratio and reducing the carbon dioxide that environment is harmful to.This
Outward, the method should be adapted in use to a high proportion of Reproduceable electricity to reduce it in the way of gaseous state and liquid hydrocarbon and store.
Therefore, by the Reproduceable electricity of the excess capacity in compensation network.
Solution
Gaseous state is produced by solid, liquid or gaseous state carbon-containing carrier and/or the hydrocarbon production equipment of liquid hydrocarbon is included for producing
The entrained flow gasifiers of the continuable gasifying gas of carbon monoxide, for producing hydrogen and titanium dioxide by carbon monoxide and vapor
The conversion process of carbon, and for the building-up process by carbon monoxide and hydrogen gas production gaseous state and/or liquid hydrocarbon, described hydrocarbon produces and sets
Standby it is characterised by that gasifying gas bypass the bypass stream of conversion process and only operating for hydrogen gas production using Reproduceable electricity
Water electrolysis.
In this process by Reproduceable electricity be incorporated to hydrogen allow to compensate due to the space in producing in Reproduceable electricity and
Excess capacity in the power distribution network that time change leads to, and using existing infrastructure, this electric energy is converted into conventional hydrocarbon
The energy is used for distributing and uses.
By using the hydrogen that produced using Reproduceable electricity by solid, liquid and gaseous carbonaceous fuels, waste and remnants
Material such as coal, carbon, biomass, tar, oil etc. are converted into liquid and gaseous hydrocarbon can supply raw material such as methane etc. to chemical industry,
The energy friendly with liquid or gaseous form storage condition.
When excessive Reproduceable electricity can not be obtained in electrical network, continue to produce hydrocarbon to produce by using conversion process
Must hydrogen be used for synthesizing.
This equipment includes only heating carbon, oxygen, vapor using at least one electric heater of Reproduceable electricity operation
And/or carbon dioxide.
Especially, this equipment includes only heating carbon, the steaming of oxygen gas and water using four electric heaters of Reproduceable electricity operation
Gas and carbon dioxide.
Water electrolysis is steam electrolyzer.The advantage of steam electrolyzer is, must also be by using electric energy in water electrolysis
The energy for evaporating water applying comprises (cover) by heat energy, and this heat energy is advantageously by for example originating from follow-up building-up process
Untapped used heat make.Therefore, steam electrolyzer is more advantageous in terms of efficiency than traditional water electrolysis.
Gasifier is entrained flow gasifiers, and it expeditiously runs.
Creative further is to use this mistake using compression in the hydrogen of electrolysis production before for this process
When the pressure of Cheng Suoxu is to buffer.Upon compression buffering reduce it may happen that pressure change and allow short in synthesis gas quality
Preferably balance between phase fluctuation.The pressure of synthesis gas and mass change can have to the life-span synthesizing used catalyst and disappear
Pole affect and may result in synthetically produced product quality fluctuation.
This equipment includes gas treatment and gas purification apparatus, for remove gasifying gas undesirable gas component,
Carbon dioxide and vapor.
Building-up process includes the device for removing reaction water, thus reusing the water of the removing in electrolysis or as technique
Use water.
Hydrocarbon production method using the hydrocarbon production equipment of the present invention has step：Process modifications including at least two, wherein
In the first modification, conversion process produces hydrogen and carbon dioxide by carbon monoxide and vapor, and converts in the second modification
Process makes steam-laden gasifying gas bypass conversion process by using bypass stream and closes with water electrolysis using can be again
Raw electrical energy production hydrogen, wherein only can obtain Reproduceable electricity, just carry out the second modification.
Oxygen and carbonaceous material is made to preheat to increase hydrogen absorption property.
Carbon dioxide is used as endothermic gasification agent to increase the hydrogen absorption property of this process and therefore integrated more further
Reproduceable electricity replace steam controlling gasification temperature and to realize complete carbon conversion in carbon dioxide gasification.
Additionally, when obtaining or the only not Reproduceable electricity of too excessive can be obtained, produce in conversion process and
Detached carbon dioxide in gas purification apparatus, can be buffered in relay reservoir.Excessive enough renewable obtaining
When electric energy is used for water or steam electrolyzer, the carbon dioxide thus buffering can be further used as endothermic gasification agent.Therefore, water or steam
Electrolyser only produces hydrogen using excessive Reproduceable electricity and the carbon dioxide of buffering is further used as endothermic gasification agent.
Additionally, extra Reproduceable electricity is used for heating carbon, oxygen, vapor and/or carbon dioxide, therefore with high efficiency
Buffer more Reproduceable electricities with chemical specieses.
It is used for gasifying as gasifying agent using the oxygen that excessive Reproduceable electricity produces in electrolysis, wherein preferably described
Oxygen storage is in intermediate buffer.Because the oxygen using storage, it is possible to decrease air separates the performance of equipment.
In order to adjust stable hydrogen and carbon monoxide mole ratios example before building-up process, can control alone or in combination
With adjustment oxygen and carbonaceous solids and/or liquid charging stock, carbon dioxide, the electric preheating of vapor performance, endothermic gasification agent water
Steam and the ratio of carbon dioxide, to the amount of the gasifying gas of conversion process and/or the vaporization ability of equipment.
The economic advantages of the present invention are using excessive Reproduceable electricity in electrical network, and this is due to producing Reproduceable electricity
In daily, the seasonal fluctuation related with weather.
It is very important for excessive Reproduceable electricity being buffered with high efficiency in natural gas grid.Electrical network upgrading can be kept away
The high cost of processing.
Due to higher utilizing carbon in this process, the specific needs of carbon raw material are alap and are highly effective
Rate.It reduce the consumption of carbon raw material, therefore, protect the Fossil fuel of limited capacity.
Carbon dioxide is used as endothermic gasification agent, such as with burning carbonaceous energy carrier with life in producing chemical productss
Obtaining in production capacity source or waste gas, carbon dioxide recycle and be then converted to the carbon using with material and/or form of energy.This reduces
The discharge of carbon dioxide that air is harmful to and lead to the Carbon cycle closing.
At least another advantage of the present invention is that existing system can additionally be equipped with electrolysis system.Therefore, in methane production
In the case of equipment, their performance improves at most 400% without extra coal or carbonizable substance and does not have extra gasification defeated
Go out.
Hereinafter, the present invention is described with reference to appended accompanying drawing in preferred embodiments, wherein
Fig. 1 shows the embodiment of the present invention with the schematic diagram with regard to arrangement and method.
Fig. 1 shows the illustrative embodiments of the invention with the schematic diagram with regard to arrangement and method.This arrangement includes
For gaseous state and/or the hydrocarbon of liquid hydrocarbon 60,61 are produced by solid, liquid or gaseous carbonaceous fuels, waste and waste material or carbon carrier 1
Production equipment:
Entrained flow gasifiers 5, for producing the continuable gasifying gas of carbon monoxide 6,
Conversion process 22, for hydrogen 24 and carbon dioxide are produced by carbon monoxide and vapor,
Gas treatment and gas purification apparatus 27, for removing undesirable gas group of gasifying gas, mixed gas 26
Divide 28 and carbon dioxide 29 and water 30,
With
Building-up process 43, for by carbon monoxide and hydrogen gas production gaseous state and/or liquid hydrocarbon 44, including for vapor
48 form removes the device of heat and the water electrolysis 33 of dereaction, and especially steam electrolyzer, for hydrogen gas production 32.
Crushing and dry coal 1 are used oxygen 2 and vapor 3 and/or carbon dioxide 4 to gasify in entrained flow gasifiers 5
For gasifying gas 6.The fuel ash being included in coal 1 is discharged with unreacted carbon as residual carbon 8 also from gasification as slag 7
Device 5 is discharged.
Coal amount 1 controlled by the quantity controller unit 9 for carbon and in electric heater 10 using excess capacity can
Regenerative electric energy 11 is preheating.
Oxygen 2 Reproduceable electricity 13 using excess capacity can preheat in the electric heater 12 for oxygen.And
And vapor 3 Reproduceable electricity 15 using excess capacity can preheat in the electric heater 14 for oxygen.Titanium dioxide
Carbon 4 can also be preheated using Reproduceable electricity 17 in the electric heater 16 for carbon dioxide.
Whole warm is only operated using Reproduceable electricity.In order that being arranged to whole with excessive Reproduceable electricity
Construction and optimization.Do not use the electric power from Fossil fuel, so that the target of environmental protection is come into force.
In order to cool down gasifying gas 6, chilled water (chw) 19 is injected gasifying gas in the gasifier exit 18 of entrained flow gasifiers 5
6.Because cooling, the vapor of the included substantial amounts of necessary amounts of cooled and steam-laden gasifying gas 20 is used for subsequently
Conversion process 22.
The tributary 21 of the steam-laden gasifying gas of steam-laden gasifying gas 20 to conversion process is supplied
Should be used for carbon monoxide and steam transforming being hydrogen and carbon dioxide 24 to conversion process 22.May the desired amount of additional water
23 can supply to gas stream 21.
The gas 24 of the hydrogen filling after conversion process 22 is mixed with the Part II gas 25 from gasifier exit 18
Supply to gas treatment and purification for gas 27 with the gas 26 as mixing.
In purification for gas 27, needed all contaminants such as sulfur and chlorine compound, heavy metal, toxic element according to synthesis
28 and the water 30 of carbon dioxide 29 and excess remove from mixed gas 26.
Then cleaned gas 31 is mixed to synthesis gas with the added hydrogen 32 from water electrolysis or steam electrolyzer 33
35, water electrolysis or steam electrolyzer 33 are also operated using excessive Reproduceable electricity 34.From water electrolysis 33 hydrogen 32
Hydrogen gas compressor 36 compresses and is stored temporarily in hydrogen relay reservoir 37.Pressure in hydrogen relay reservoir 37 is higher than gas
Pressure in production process.
Gas analyses 38 are arranged in gas stream.Gas analyses 38 determine rubbing of hydrogen and carbon monoxide in synthesis gas 35
That ratio.This molar ratio can be adjusted by changing variable：
- change flow velocity to change from hydrogen relay reservoir 37 by using hydrogen supply-regulation and control instrument 39 such as valve
The amount of the hydrogen 32 of entrained gas.By changing the performance of water electrolysis 34, the hydrogen taking from hydrogen relay reservoir 37 will be compensated
Amount；
- bypass the bypass stream 25 of conversion process 22 and change vapor by adjusting bypass stream controller 40 and adjust
The flow velocity of the gasifying gas 25 of saturation；
- change heat absorption by adjusting vapor supply-regulation and control instrument 41 and/or carbon dioxide supply-regulation and control instrument 42
Gasifying agent vapor 3 and/or the quantitative proportion of carbon dioxide 4；
- heat absorption gas is changed by the heating power (Reproduceable electricity) 15 of regulation to the electric heater 14 for vapor
The heating-up temperature of agent vapor 3；
- heat absorption is changed by the heating power (Reproduceable electricity) 17 of regulation to the electric heater 16 for carbon dioxide
The heating-up temperature of gasifying agent carbon dioxide 4；
- oxygen 2 is changed by the heating power (Reproduceable electricity) 13 of regulation to the electric heater 12 for oxygen
Heating-up temperature；
- by adjust to the electric heater 10 for carbon heating power (Reproduceable electricity) 11 change solid, liquid/
Gaseous carbon or the heating-up temperature of carbon carrier 1；
- adjust carbon/coal feed stream to change gasification performance by using the quantity controller unit 9 for carbon；
Feed synthesis gas 35 in methane synthesis 43, wherein synthesis gas 35 is converted into methane 44 and vapor/reaction water 45.
Vapor 45 is cooled down by using gas cooler 46 and is removed in the form of water vapor condensation thing 47.Vapor from methane 44
Condensate 47 can serve as process water (additional water 23 for example as chilled water (chw) 19 or for conversion process).
The heat of the release of building-up process 43 in the form of steam/vapor 48 from this during dissipate and be used as gas
Agent vapor 3, with acting on the vapor 49 of steam electrolyzer and/or being used for other as excessive vapor/steam 50
Purpose.
The oxygen 51 producing together with hydrogen 32 in water or steam electrolyzer 33 by oxygen compressor 52 compression and
After optionally condensing in oxygen liquefier 66, it is stored in oxygen relay reservoir 53.The oxygen 51 of storage is used subsequently to compensate
(bridge) the indivisible oxygen 51 being derived from steam electrolyzer 33 is used for gasification.The excess producing in steam electrolyzer
Oxygen 54 must be emitted into air or must store or otherwise use.If the oxygen 51 producing in steam electrolyzer 33
Not enough and store insufficient oxygen in oxygen relay reservoir 53, extra oxygen 55 for example must separate equipment (not from air
Display) etc. in produce.
Conversion process 22 produces and detached carbon dioxide 29 passes through carbon-dioxide gas compressor in purification for gas 27
57 compress and are stored in carbon dioxide relay reservoir 56 according to storage volume.Excessive carbon dioxide 58 must be emitted into air
Or otherwise use.Renewable electricity from the main excess in electrical network of carbon dioxide of carbon dioxide relay reservoir 56
It is used as endothermic gasification agent 4 to improve the hydrogen absorption property of the gas producing in entrained flow gasifiers 5 during energy.The dioxy lacking
Change carbon 59 to supply to this process from outside.
Additionally, the carbon dioxide 29 of excess from purification for gas 27 and/or the more carbon dioxide from external source can
To be added to the vapor 49 of steam electrolyzer 33, steam electrolyzer 33 is suitable for use with Reproduceable electricity by carbon dioxide decomposition
For carbon monoxide and oxygen.For improve production efficiency, before building-up process 43, using from electrolysis 33 carbon monoxide as
Component adds synthesis gas 35.
Another embodiment that the present invention is used for producing carbon monoxide, hydrogen and oxygen is straight in steam electrolyzer 33
Connect using gasifying gas 6 or steam-laden gasifying gas 20, simultaneously only using excessive Reproduceable electricity.In this program
In, the carbon dioxide, the vapor from gasifier 5 and the chilled water (chw) 19 that produce in gasifier 5 are used for electrolysis 33 to form an oxygen
Change carbon, hydrogen and oxygen.
A certain amount of methane 61, in addition it produce with respect to a certain amount of methane 60, by Reproduceable electricity 11,13,15,17
(and/or) 34 integrated generation and only being produced by regenerative resource, store preferably in natural gas grid 62 and convey.It
Afterwards, convert can in instrument 63 electric regenerative and produce and feed to electrical network 64 in suitable power generator or again.Additionally, different energy
Source form is possible, such as fuel, or as the related methane purposes 65 of alternative material or the energy.
Using following examples and embodiment, different operator schemes (modification 1-6) and different effects will be by reasons
Explain by consideration:
Modification 1 (prior art):
Prior art is gasified as gasifying agent by using oxygen 2 and vapor 3 methane 60 is produced by carbon 1,
Effectively pass through conversion process 22 in the steam-laden gasifying gas to conversion process using bypass stream controller 40
The reformate stream in tributary 25 in set and control required hydrogen-carbon monoxide-rub by hydrogen is produced by carbon monoxide
That ratio (referring to reaction R4-R7).The prior art methane production process does not have integrated regenerative electric energy (11,13,15,17,34).
For the methane production by coal/carbon, H2：Molar ratio=3 of CO.If Reproduceable electricity can not be obtained, this will be possible
Operator scheme.
Following modification 2-6 (B) produces new arrangement and the new method of integrated Reproduceable electricity:
Modification 2:
Bypass conversion process 22 as bypass stream 25 and conversion process is reduced to 0mol by making total gas stream 20
CO converts；Temperature vapor 3 for 298K is used as endothermic gasification agent (material) and the integrated institute from vapor electrolysis 33
The hydrogen 32 of requirement, vapor electrolysis 33 is only operated using excessive Reproduceable electricity 34.
It is not in operation using the possible option of other of Reproduceable electricity (11,13,15,17).
Modification 3：
Bypass conversion process 22 as bypass stream 25 and conversion process is reduced to 0mol by making total gas stream 20
CO converts；Vapor 3 (steam) is used as endothermic gasification material (reagent), vapor 3 only passes through excessive Reproduceable electricity
15 are preheated to 1300K and the integrated the desired amount of hydrogen being produced by steam electrolyzer 33 in the electric heater 14 for vapor
32, steam electrolyzer 33 is also only operated using excessive Reproduceable electricity 34.Other using Reproduceable electricity (11,13,17)
Possible option is not in operation.
Modification 4：
Bypass conversion process 22 as bypass stream 25 and conversion process is reduced to 0mol by making total gas stream 20
CO converts；Be used the carbon dioxide 4 for 298K for the temperature replace vapor 3 as endothermic gasification agent and integrated from steam electrolyzer
33 required amounts of hydrogen 32, steam electrolyzer 33 is only operated using excessive Reproduceable electricity 34.Using Reproduceable electricity
The option that the other of (11,13,15,17) is possible is not in operation.
Modification 5：
Bypass conversion process 22 as bypass stream 25 and conversion process is reduced to 0mol by making total gas stream 20
CO converts；It is used carbon dioxide 4 to replace vapor 3 as endothermic gasification agent, carbon dioxide 4 is in the heater for carbon dioxide
Only it is preheated to 1300K using excessive Reproduceable electricity 17 in 16, and the integrated the desired amount of hydrogen from steam electrolyzer 33
32, steam electrolyzer 33 is only operated using excessive Reproduceable electricity 34.Other using Reproduceable electricity (11,13,15) can
The option of energy is not in operation.
Modification 6：
Bypass conversion process 22 as bypass stream 25 and conversion process is reduced to 0mol by making total gas stream 20
CO converts；It is used carbon dioxide 4 to replace vapor 3 as endothermic gasification agent, carbon dioxide 4 is in the electrical heating for carbon dioxide
Only it is preheated to 1300K using excessive Reproduceable electricity 17 in device 16.
Additionally, oxygen 2 is preheated to the temperature of 800K and coal/carbon 1 in the electricity for carbon in the heater 12 for oxygen
It is preheated to the temperature of 800K in heater 10, only operated using excessive Reproduceable electricity 13 and 11 respectively.
The desired amount of hydrogen 32 is produced by steam electrolyzer 33, and steam electrolyzer 33 is also only using excessive renewable electricity
Can 34 operations.
It is not in operation using the possible option of other of Reproduceable electricity 15.
In modification 2-6 (B), conversion process 22 makes steam-laden gasifying gas bypass by using bypass stream 25
Conversion process 22 and close.The performance of water electrolysis (33) and/or the heating of carbon and/or the heating of oxygen and/or vapor plus
The heating of heat and/or carbon dioxide each controls in the range of 0-100%.Preferred embodiment is by with respect to excess
The amount of Reproduceable electricity each control performance carrys out combination and forming.
Result is found in the following table (table 1) of the relevant parameter value preset with each modification:
Reference numerals list
1 solid, liquid/gaseous carbon or carbon carrier
2 oxygen
3 vapor
4 carbon dioxide
5 entrained flow gasifiers
6 gasifying gas
7 slags
8 residual carbons
The 9 quantity controller units being used for carbon
10 electric heaters being used for carbon
11 Reproduceable electricities
12 electric heaters being used for oxygen
13 Reproduceable electricities
14 electric heaters being used for vapor
15 Reproduceable electricities
16 electric heaters being used for carbon dioxide
17 Reproduceable electricities
18 gasifier exit
19 chilled water (chw)s
20 steam-laden gasifying gas
The tributary of the steam-laden gasifying gas of 21 to conversion process
22 conversion processes
23 additional water being used for conversion process
The gas of the hydrogen filling after 24 conversion processes
The bypass stream of the 25 steam-laden gasifying gas bypassing conversion process
26 mixed gas
27 gas treatment and purification for gas
28 toxic element
29 carbon dioxide
The water of 30 excess
31 cleaned gases
32 added hydrogen being derived from water electrolysis
33 water electrolysis/steam electrolyzer
34 Reproduceable electricities
35 synthesis gas
36 hydrogen gas compressors
37 hydrogen relay reservoirs
38 gas analyses
39 hydrogen supplies-regulation and control instrument
40 bypass stream controllers
41 vapor supplies-regulation and control instrument
42 carbon dioxide supplies-regulation and control instrument
43 synthesis
44 methane
45 reaction water
46 gas coolers
47 water vapor condensation things
48 vapor, the heat of reaction
49 vapor being used for vapor electrolysis
The vapor of 50 excess
The oxygen producing in 51 electrolysis
52 oxygen compressors
53 oxygen relay reservoirs
The oxygen of the excess producing in 54 electrolysis
55 oxygen being added by extraneous air separate apparatus
56 carbon dioxide relay reservoirs
57 carbon-dioxide gas compressors
The carbon dioxide of 58 excess
The carbon dioxide of 59 interpolations
60 methane producing while operation in modification 1 in the case of not using Reproduceable electricity
61 use the extra methane producing of Reproduceable electricity
62 natural gas grid
63 convert instrument again
64 electrical networks
65 alternative materials or the methane purposes of energy correlation
66 oxygen liquefier
Claims (15)
1. the hydrocarbon production equipment of gaseous state and/or liquid hydrocarbon (44,60,61) is produced by solid, liquid or gaseous state carbon-containing carrier (1),
It includes:
- gasifier (5), described gasifier (5) is used for producing the gasifying gas (6) comprising carbon monoxide,
- conversion process (22), described conversion process (22) is used for producing hydrogen and carbon dioxide by carbon monoxide and vapor,
With
- building-up process (43), described building-up process (43) is used for by carbon monoxide and hydrogen gas production gaseous state and/or liquid hydrocarbon
(44),
It is characterised by
- gasifying gas (6,20) bypass the bypass stream (25) of conversion process (22)
With
- for hydrogen gas production the water electrolysis (33) only being operated using Reproduceable electricity (34).
2. hydrocarbon production equipment according to claim 1, wherein said equipment include only using Reproduceable electricity (11,13,
15,17) at least one electric heater (10,12,14,16) operating is to heat carbon, oxygen, vapor and/or carbon dioxide.
3. hydrocarbon production equipment according to claim 2, wherein said equipment include only using Reproduceable electricity (11,13,
15,17) four electric heaters (10,12,14,16) operating are to heat carbon (10), oxygen (12), vapor (14) and titanium dioxide
Carbon (16).
4. the hydrocarbon production equipment according to claim 1,2 or 3, wherein water electrolysis (33) are steam electrolyzer (33).
5. the hydrocarbon production equipment according to claim 1,2,3 or 4, wherein gasifier (5) are entrained flow gasifiers (5).
6. the hydrocarbon production equipment according to claim 1,2,3,4 or 5, wherein said equipment includes gas treatment and gas is pure
Gasifying device (27), for removing undesirable gas component (28), carbon dioxide (29) and water (30) from gasifying gas (6).
7. the hydrocarbon production equipment according to claim 1,2,3,4,5 or 6, wherein building-up process (43) include such dress
Put, described device is used for removing the heat of dereaction in the form of vapor (48) to reuse water steaming in steam electrolyzer (33)
Gas (48) and/or as excessive vapor for other purposes and/or as endothermic gasification agent (3).
8., using the hydrocarbon production method of the hydrocarbon production equipment according to any one of claim 1-7, it includes thering is step
At least two process modifications:
Wherein
- in the first modification (A):
Conversion process (22) produces hydrogen and carbon dioxide by carbon monoxide and vapor
With
- in the second modification (B):
- conversion process (22) make steam-laden gasifying gas bypass conversion process (22) by using bypass stream (25) and
Close, and
- water electrolysis (33) uses Reproduceable electricity (34) to produce hydrogen,
Wherein only can obtain excessive Reproduceable electricity (34), just carry out the second modification (B).
9. hydrocarbon production method according to claim 8, if wherein carrying out the second modification (B), operation simultaneously first change
Type (A) and the second modification (B).
10. hydrocarbon production method according to claim 8 or claim 9, wherein extra Reproduceable electricity (11,13,15,17) is in addition
For the second modification (B) to heat carbon, oxygen, vapor and/or carbon dioxide.
Hydrocarbon production method described in 11. according to Claim 8,9 or 10, wherein carbon dioxide be used as endothermic gasification agent, for
Gasification in second modification (B), wherein said carbon dioxide preferably produces and excessive enough not existing in conversion process (22)
Obtainable Reproduceable electricity when be buffered in relay reservoir (56).
12. according to Claim 8, the hydrocarbon production method described in 9,10 or 11, wherein can be again using excessive in electrolysis (33)
The oxygen that raw electric energy produces is used for gasifying as gasifying agent.
13. according to Claim 8, the hydrocarbon production method described in 9,10,11 or 12, is wherein controlled respectively with the scope of 0-100%
The heating of the performance of water electrolysis or steam electrolyzer (33) and/or the heating of carbon and/or the heating of oxygen and/or vapor and/
Or the heating of carbon dioxide.
14. according to Claim 8, the hydrocarbon production method described in 9,10,11,12 or 13, wherein will be from purification for gas (27)
In addition excessive carbon dioxide (29) and/or the more carbon dioxide from external source are added to and steam to the water of steam electrolyzer (33)
Gas (49), described steam electrolyzer (33) apply also for by using excessive Reproduceable electricity by carbon dioxide decomposition be an oxygen
Change carbon and oxygen.
15. according to Claim 8, the hydrocarbon production method described in 9,10,11,12,13 or 14, wherein by gasifying gas (6) or water
The gasifying gas (20) of saturated with vapor are directly used in steam electrolyzer (33) to produce carbon monoxide, hydrogen and oxygen, only simultaneously
Using excessive Reproduceable electricity.
Applications Claiming Priority (1)
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|---|---|---|---|
| PCT/EP2014/060831 WO2015180752A1 (en) | 2014-05-26 | 2014-05-26 | Hydrocarbon-production-apparatus and method for producing hydrocarbons with renewable electric energy |
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| AU2017383560B2 (en) | 2016-12-23 | 2023-05-25 | Carbon Engineering Ltd. | Method and system for synthesizing fuel from dilute carbon dioxide source |
| WO2019157507A1 (en) * | 2018-02-12 | 2019-08-15 | Lanzatech, Inc. | A process for improving carbon conversion efficiency |
| EP3581636A1 (en) * | 2018-06-11 | 2019-12-18 | Glock Technology GmbH | Device and method for storing energy of cogeneration plants |
| EP3872233A1 (en) * | 2020-02-26 | 2021-09-01 | Doosan Lentjes GmbH | Method for storing energy and energy storing system |
| JP7098675B2 (en) * | 2020-03-19 | 2022-07-11 | 本田技研工業株式会社 | Fuel manufacturing system |
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| AU2006257650A1 (en) * | 2005-06-14 | 2006-12-21 | Haldor Topsoe A/S | Process for the preparation and conversion of synthesis gas |
| WO2008067221A1 (en) * | 2006-11-27 | 2008-06-05 | Battelle Energy Alliance, Llc. | Improved synthetic fuel production methods and apparatuses |
| CN101432393A (en) * | 2006-03-30 | 2009-05-13 | 新日铁工程技术株式会社 | Method for start-up of liquid fuel synthesis system, and liquid fuel synthesis system |
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| CN102482584A (en) * | 2009-07-09 | 2012-05-30 | 阿海珐 | Facility for producing synthetic hydrocarbons, and associated method |
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| US7456226B2 (en) | 2003-12-13 | 2008-11-25 | Sascha Schroeder | Method and installation for producing liquid energy carriers from a solid carbon carrier |
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- 2014-05-26 AU AU2014395432A patent/AU2014395432B2/en active Active
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Patent Citations (7)
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| AU2006257650A1 (en) * | 2005-06-14 | 2006-12-21 | Haldor Topsoe A/S | Process for the preparation and conversion of synthesis gas |
| CN101273112A (en) * | 2005-06-14 | 2008-09-24 | 南非煤油气科技（私人）有限公司 | Process for the preparation and conversion of synthesis gas |
| CN101432393A (en) * | 2006-03-30 | 2009-05-13 | 新日铁工程技术株式会社 | Method for start-up of liquid fuel synthesis system, and liquid fuel synthesis system |
| WO2008067221A1 (en) * | 2006-11-27 | 2008-06-05 | Battelle Energy Alliance, Llc. | Improved synthetic fuel production methods and apparatuses |
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| CN102482584A (en) * | 2009-07-09 | 2012-05-30 | 阿海珐 | Facility for producing synthetic hydrocarbons, and associated method |
| WO2011134705A1 (en) * | 2010-04-26 | 2011-11-03 | Siemens Aktiengesellschaft | Production plant for chemical raw materials or fuels and method for operating such a production plant |
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| AU2014395432A1 (en) | 2016-11-17 |
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| AU2014395432B2 (en) | 2018-07-05 |
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