CN106449825A - Preparation method for solar double-glass component - Google Patents

Preparation method for solar double-glass component Download PDF

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Publication number
CN106449825A
CN106449825A CN201611091092.4A CN201611091092A CN106449825A CN 106449825 A CN106449825 A CN 106449825A CN 201611091092 A CN201611091092 A CN 201611091092A CN 106449825 A CN106449825 A CN 106449825A
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adhesive film
glass
layer
preparation
eva adhesive
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CN201611091092.4A
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CN106449825B (en
Inventor
王健新
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Wuxi Le Feng Solar Power Science And Technology Ltd
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Wuxi Le Feng Solar Power Science And Technology Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0488Double glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

The invention discloses a preparation method for a solar double-glass component. The method comprises the following steps: paving a glass layer, an EVA coating layer and a battery layer; performing EL test for the first time; laminating; performing EL test for the second time. A plurality of scratches are horizontally and longitudinally carved on the upper surface of the EVA coating in contact with a battery piece; a circle of scratch is carved along the edge of the battery piece; a layer of coating is paved at each of the four corners; in a laminating stage, the vacuum pumping is firstly performed, and then the vacuum pumping for a lower chamber is maintained, an upper chamber is aerated, the pressure is maintained and the coating is heated and molten. According to the preparation method, the directionality of EVA contraction can be reduced, the displacement resistance of the battery piece can be increased, and meanwhile, the gaps between the glass and the battery piece and between the battery pieces can be more effectively filled, so that the interior and four corners of the component can be prevented from generating bubbles, the yield of the products is increased, the operation is simple and the method is suitable for volume production.

Description

A kind of preparation method of solar energy solar double-glass assemblies
Technical field
The present invention relates to a kind of solar photovoltaic assembly preparation field, especially relate to a kind of system of solar energy solar double-glass assemblies Preparation Method.
Background technology
With the progress of solar battery technology, the reduction of material cost, photovoltaic power generation technology has stepped into maturation, the sun Can photovoltaic products also gradually develop to market-oriented consumer product from special specialization purposes, its range of application expands to each Field.Conventional solar energy solar double-glass assemblies encapsulating material mainly has PVB film and EVA film.
Carry out solar double-glass assemblies encapsulation using PVB glued membrane, typically on laminating machine, cell piece must be fixed with glass, now Assembly sample is difficult to cool down transparent, needs post bake to cool down again, therefore is encapsulated again using autoclave High Temperature High Pressure, cools down after taking-up Speed is slow.Whole encapsulation flow process is complicated, complex operation, and packaging time, typically more than a hour, largely effects on encapsulation effect Rate, in addition, the price of PVB resin is higher than EVA resin, therefore is existed relatively costly using PVB glued membrane encapsulation double-glass solar energy assembly And the low problem of packaging efficiency.
Being encapsulated in the common problem running into when lamination using EVA adhesive film is cell-slice displacement, and small gas in assembly Easily this problem of bubble and lead to assembly yields in the fabrication process to reduce in bubble, the especially corner of assembly.Occur The main cause of this problem is that the pressure that glass is subject to when being laminated is uneven, and traditional method is outside assembly Portion adds the fixing tool making using conventional epoxies.But due to traditional fixing tool size larger it has not been convenient to raw The bulk production of producing line, so typically should not use.
Accordingly, it would be desirable to one kind not only can stop cell-slice displacement but also can eliminate solar double-glass assemblies micro-bubble phenomenon may be used simultaneously To be applied to the preparation method of bulk production, improve the yields of product.
Content of the invention
The purpose of the present invention is for the cell-slice displacement of the easy appearance of conventional EVA solar double-glass assemblies and asking of glued membrane bubble Topic, provides a kind of preparation method of new solar energy solar double-glass assemblies, can be with bubble in effectively solving cell-slice displacement and assembly Problem, improves the yields of product.
The technical scheme is that:
A kind of preparation method of solar energy solar double-glass assemblies, comprises the following steps:
(1)Ground floor EVA adhesive film layer is laid on bottom safety glass, EVA adhesive film layer upper surface icking tool anyhow side To Ge Keji road cut, the cell piece connecting is placed on EVA adhesive film layer, and at cell piece edge with icking tool in its lower section One week cut is carved on EVA adhesive film layer, then respectively lays one layer of glue film in corner, on solaode string, re-lay second Layer EVA adhesive film layer, is carved and ground floor EVA adhesive film layer identical cut with the one side that icking tool contacts cell piece in this EVA adhesive film layer, Then put a layer safety glass again, form solar energy solar double-glass assemblies, wherein after the completion of solaode string lays, use busbar Described solaode string is connected as an entirety;
(2)EL test, is imaged by infrared camera, checking step(1)Whether the solar battery sheet in solar double-glass assemblies has Hidden sliver, and reject hidden sliver;
(3)To be placed in laminating machine by the solar double-glass assemblies of an EL test, first evacuation, then keep lower room evacuation, on Room is inflated, then pressurize heat and make EVA adhesive film hot melt, so that glass plate is bonded together with cell piece;
(4)Secondary EL test, is imaged by infrared camera, checks in the solar double-glass assemblies after lamination whether solar battery sheet has hidden Sliver, and reject hidden sliver.
Above-mentioned steps(1)On middle adhesive film horizontal and vertical cut respectively at cell piece edge to glass sheet edges distance 1/3 at, and parallel with sideline, scratch depth degree is the 1/2 of adhesive film thickness, and the scratch depth along cell piece edge is glued membrane The 1/2 of thickness degree.
The lamination step of the present invention:In setting laminating machine, pressure is -1MPa, maintains 35-45 minute, then by laminating machine Lower room evacuation, the inflation of upper room, make chamber pressure on laminating machine be -0.8MPa, lower chamber pressure is -1MPa, maintains 10-15 minute, Chamber pressure -0.6MPa on laminating machine, lower chamber pressure -1MPa, maintain 15-20 minute, chamber pressure -0.2MPa on laminating machine, lower room Pressure -1MPa, maintains 15-20 minute;Then pressurize hot melt, keeps the intrinsic pressure power of laminating machine in -0.7 ~ -0.8MPa, is warming up to Set hot melting temperature, maintain 35-40 minute, so that glued membrane is softened and battery strings and bottom, surface layer safety glass bond together.
The hot melting temperature of lamination step of the present invention is 145 ± 5 DEG C.
EVA adhesive film layer of the present invention is the special EVA adhesive film of solar double-glass assemblies, and thickness is 0.45~0.55 mm, each layer Adhesive film lays two-layer EVA adhesive film.
Glue film of the present invention is consistent with EVA adhesive film layer in material, but its thickness is 0.4mm, the length of glue film With the wide cell piece edge that is respectively to the distance at sheet glass edge.
Beneficial effects of the present invention:
By Ke Ji road cut on glued membrane, it is possible to reduce the directivity that EVA shrinks, reduce the battery displacement after encapsulation existing As carving one week cut on cell piece side can increase cell-slice displacement resistance, reduce displacement further;Before EVA is not contracted, Laminating machine is carried out with lower room evacuation, the inflation of upper room, such layer glass is pressed EVA adhesive film and cell piece, can be solved further Cell piece shifts problem;In the pressurize hot melt stage of lamination, by adjusting lamination pressure, temperature and retention time, EVA glue for several times Film can more effectively the space between filling glass and cell piece, cell piece and cell piece and avoid assembly to produce starved or gas Bubble.Observing through many experiments proves, EVA adhesive film thickness degree can effectively reduce the generation of bubble for two-layer 0.45~0.55 mm, Respectively lay the glue film of one layer of 0.4mm in corner, can fill up EVA can not be full of between glass and glass in molten condition Space, eliminates solar double-glass assemblies corner and micro-bubble phenomenon.
Specific embodiment
By the following examples the present invention is further described:
Embodiment 1
A kind of preparation method of solar energy solar double-glass assemblies, comprises the following steps:
(1)Ground floor EVA adhesive film layer is laid on bottom safety glass, EVA adhesive film layer upper surface icking tool anyhow side To Ge Keji road cut, respectively at the 1/3 of cell piece edge to glass sheet edges distance, and, scratch depth parallel with sideline Spend 1/2 for adhesive film thickness.The cell piece connecting is placed on EVA adhesive film layer, and in cell piece edge icking tool at it One week cut is carved on following EVA adhesive film layer, scratch depth is the 1/2 of adhesive film thickness.Then respectively lay one layer of glue in corner Diaphragm, re-lays second layer EVA adhesive film layer on solaode string, contacts cell piece with icking tool in this EVA adhesive film layer Simultaneously carve and ground floor EVA adhesive film layer identical cut, then put a layer safety glass again, form solar energy solar double-glass assemblies, its In after the completion of solaode string lays, with busbar, described solaode string is connected as an entirety;
(2)EL test, is imaged by infrared camera, checking step(1)Whether the solar battery sheet in solar double-glass assemblies has Hidden sliver, and reject hidden sliver;
(3)To be placed in laminating machine by the solar double-glass assemblies of an EL test, first evacuation, then keep lower room evacuation, on Room is inflated, then pressurize heat and make EVA adhesive film hot melt, so that glass plate is bonded together with cell piece;
(4)Secondary EL test, is imaged by infrared camera, checks in the solar double-glass assemblies after lamination whether solar battery sheet has hidden Sliver, and reject hidden sliver.
The lamination step of the present invention:In setting laminating machine, pressure is -1MPa, maintains 45 minutes, then by under laminating machine Room evacuation, the inflation of upper room, make room on laminating machine be in -0.8MPa, lower room is in -1MPa, maintain 10 minutes, room on laminating machine Pressure -0.6MPa, lower chamber pressure -1MPa, maintain 15 minutes, chamber pressure -0.2MPa on laminating machine, lower chamber pressure -1MPa, maintain 15 minutes;Then pressurize hot melt, keeps the intrinsic pressure power of laminating machine in -0.8MPa, is warming up to 150 DEG C, maintain 35 minutes, make glued membrane soft Change and battery strings and bottom, surface layer safety glass bond together.
Above-mentioned EVA adhesive film layer is the special EVA adhesive film of solar double-glass assemblies, and thickness is 0.5 mm, and each layer of adhesive film lays two-layer EVA adhesive film.
Above-mentioned glue film is consistent with EVA adhesive film layer in material, but its thickness is 0.4mm, and the length of glue film and width are respectively Distance for cell piece edge to sheet glass edge.
Comparative example 1
Lamination step directly heats up lamination, and other preparation processes and preparation condition are identical with the embodiment of the present invention 1.
Comparative example 2
The non-cut of glue film, other preparation processes and preparation condition are identical with the embodiment of the present invention 1.
Comparative example 3
Not in corner plus glue film, other preparation processes and preparation condition are identical with the embodiment of the present invention 1.
Comparative example 4
The film thickness of EVA adhesive film layer is 0.4mm, and other preparation processes and preparation condition are identical with the embodiment of the present invention 1.
Above-mentioned comparative example and embodiment quality measurements are as follows:
Table 1
Sample Displacement Bubble in assembly Corner bubble
Comparative example 1 There is obvious displacement There is bubble There is bubble
Comparative example 2 There is micro-displacement Bubble-free Bubble-free
Comparative example 3 Non-displacement Bubble-free There is micro-bubble
Comparative example 4 Non-displacement There is a small amount of micro-bubble There is a small amount of micro-bubble
Embodiment 1 Non-displacement Bubble-free Bubble-free
Attached:The observation procedure of bubble is:Under light intensity 800-1000LUX, apart from eyes 80-100cm, observation assembly.

Claims (8)

1. a kind of preparation method of solar energy solar double-glass assemblies is it is characterised in that comprise the following steps:
(1)Ground floor EVA adhesive film layer is laid on bottom safety glass, EVA adhesive film layer upper surface icking tool laterally and Longitudinal Ge Keji road cut, the cell piece connecting is placed on EVA adhesive film layer, and along cell piece edge with icking tool in its lower section EVA adhesive film layer on carve one week cut, then in one layer of glue film of each laying in corner, re-lay the on solaode string Two layers of EVA adhesive film layer, are carved with the one side that icking tool contacts cell piece in this EVA adhesive film layer and are drawn with ground floor EVA adhesive film layer identical Trace, then puts a layer safety glass again, forms solar energy solar double-glass assemblies, wherein after the completion of solaode string lays, uses foreign currency Stream bar connects described solaode string for an entirety;
(2)EL test, is imaged by infrared camera, checking step(1)Whether the solar battery sheet in solar double-glass assemblies has Hidden sliver, and reject hidden sliver;
(3)To be placed in laminating machine by the solar double-glass assemblies of an EL test, first evacuation, then keep lower room evacuation, on Room is inflated, then pressurize heat and make EVA adhesive film hot melt, so that glass plate is bonded together with cell piece;
(4)Secondary EL test, is imaged by infrared camera, checks in the solar double-glass assemblies after lamination whether solar battery sheet has hidden Sliver, and reject hidden sliver.
2. the preparation method of solar energy solar double-glass assemblies according to claim 1 is it is characterised in that step(1)On middle adhesive film Horizontal and vertical cut is respectively at the 1/3 of cell piece edge to glass sheet edges distance, and, scratch depth parallel with sideline Spend 1/2 for adhesive film thickness.
3. the preparation method of solar energy solar double-glass assemblies according to claim 1 is it is characterised in that step(1)Middle along cell piece The scratch depth at edge is the 1/2 of adhesive film thickness.
4. solar energy solar double-glass assemblies according to claim 1 preparation method it is characterised in that:In step(3)Described in Lamination step:In setting laminating machine, pressure is -1MPa, maintains 35-45 minute, then by the lower room evacuation of laminating machine, on Room is inflated, and makes chamber pressure on laminating machine be -0.8MPa, lower chamber pressure is -1MPa, maintains 10-15 minute, chamber pressure on laminating machine Power -0.6MPa, lower chamber pressure -1MPa, maintain 15-20 minute, chamber pressure -0.2MPa on laminating machine, lower chamber pressure -1MPa, dimension Hold 15-20 minute;Then pressurize hot melt, keeps the intrinsic pressure power of laminating machine in -0.7 ~ -0.8MPa, is warming up to setting hot melting temperature, Maintain 35-40 minute, so that glued membrane is softened and battery strings and bottom, surface layer safety glass bond together.
5. solar energy solar double-glass assemblies according to claim 4 preparation method it is characterised in that:Described hot melting temperature is 145℃±5℃.
6. solar energy solar double-glass assemblies according to claim 1 preparation method it is characterised in that:Described EVA adhesive film layer is The special EVA adhesive film of solar double-glass assemblies, thickness is 0.45 ~ 0.55 mm, and each layer of adhesive film lays two-layer EVA adhesive film.
7. solar energy solar double-glass assemblies according to claim 1 preparation method it is characterised in that:Described glue film is in material Consistent with EVA adhesive film layer in matter, thickness is 0.4mm.
8. solar energy solar double-glass assemblies according to claim 1 preparation method it is characterised in that:The length of described glue film With the wide cell piece edge that is respectively to the distance at sheet glass edge.
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107394005A (en) * 2017-07-07 2017-11-24 东方环晟光伏(江苏)有限公司 Reduce the method and laminar structure of solar double-glass assemblies air bubble problem
CN107579017A (en) * 2017-09-13 2018-01-12 江苏银环新能源科技有限公司 The preparation method of solar energy solar double-glass assemblies
CN109728131A (en) * 2018-12-06 2019-05-07 中建材浚鑫科技有限公司 A kind of preparation process of high density imbrication component
CN109768106A (en) * 2018-12-06 2019-05-17 中建材浚鑫科技有限公司 A kind of preparation process of the lightweight with frame solar double-glass assemblies
CN109786479A (en) * 2018-12-06 2019-05-21 中建材浚鑫科技有限公司 A kind of preparation process of high power half component
CN109786500A (en) * 2018-12-06 2019-05-21 中建材浚鑫科技有限公司 A kind of preparation process of the more main grid components of high efficiency
CN111653639A (en) * 2020-04-29 2020-09-11 南昌理工学院 Method for reducing bubbles in photovoltaic dual-glass assembly
US12094990B1 (en) 2023-03-09 2024-09-17 Jinko Solar (Haining) Co., Ltd. Photovoltaic curtain wall and method for manufacturing photovoltaic curtain wall

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CN101060146A (en) * 2007-05-11 2007-10-24 华南理工大学 A package method for double-side silicon-glass solar cell assembly
CN105633183A (en) * 2016-02-18 2016-06-01 安徽旭能光伏电力有限公司 Double-sided glass crystalline silicon solar cell component packaging technology
CN105895739A (en) * 2016-04-28 2016-08-24 江苏林洋光伏科技有限公司 Double-glass assembly manufacturing method
CN106098822A (en) * 2016-06-21 2016-11-09 南通久立安全玻璃有限公司 A kind of double glass photovoltaic module and the equipment of manufacture thereof and manufacture method

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Publication number Priority date Publication date Assignee Title
CN101060146A (en) * 2007-05-11 2007-10-24 华南理工大学 A package method for double-side silicon-glass solar cell assembly
CN105633183A (en) * 2016-02-18 2016-06-01 安徽旭能光伏电力有限公司 Double-sided glass crystalline silicon solar cell component packaging technology
CN105895739A (en) * 2016-04-28 2016-08-24 江苏林洋光伏科技有限公司 Double-glass assembly manufacturing method
CN106098822A (en) * 2016-06-21 2016-11-09 南通久立安全玻璃有限公司 A kind of double glass photovoltaic module and the equipment of manufacture thereof and manufacture method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107394005A (en) * 2017-07-07 2017-11-24 东方环晟光伏(江苏)有限公司 Reduce the method and laminar structure of solar double-glass assemblies air bubble problem
CN107579017A (en) * 2017-09-13 2018-01-12 江苏银环新能源科技有限公司 The preparation method of solar energy solar double-glass assemblies
CN109728131A (en) * 2018-12-06 2019-05-07 中建材浚鑫科技有限公司 A kind of preparation process of high density imbrication component
CN109768106A (en) * 2018-12-06 2019-05-17 中建材浚鑫科技有限公司 A kind of preparation process of the lightweight with frame solar double-glass assemblies
CN109786479A (en) * 2018-12-06 2019-05-21 中建材浚鑫科技有限公司 A kind of preparation process of high power half component
CN109786500A (en) * 2018-12-06 2019-05-21 中建材浚鑫科技有限公司 A kind of preparation process of the more main grid components of high efficiency
CN111653639A (en) * 2020-04-29 2020-09-11 南昌理工学院 Method for reducing bubbles in photovoltaic dual-glass assembly
US12094990B1 (en) 2023-03-09 2024-09-17 Jinko Solar (Haining) Co., Ltd. Photovoltaic curtain wall and method for manufacturing photovoltaic curtain wall

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