CN106436445B - A kind of double-layer antimicrobial is breathed freely the preparation method of cigarette tipping paper - Google Patents
A kind of double-layer antimicrobial is breathed freely the preparation method of cigarette tipping paper Download PDFInfo
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- CN106436445B CN106436445B CN201610919074.4A CN201610919074A CN106436445B CN 106436445 B CN106436445 B CN 106436445B CN 201610919074 A CN201610919074 A CN 201610919074A CN 106436445 B CN106436445 B CN 106436445B
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- paper
- wood pulp
- pulp
- cigarette tipping
- tipping paper
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F13/00—Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Paper (AREA)
Abstract
It breathes freely the invention discloses a kind of double-layer antimicrobial the preparation method of cigarette tipping paper, belongs to cigarette tipping paper preparing technical field.The present invention will be after masson's pine wood pulp, the mashing of birch wood pulp, after being handled with compound sheets such as talcum powder, through squeezing, drying, must to dry paper spare, again banana fiber is taken to be mixed with aqueous slkali, filter to obtain filter residue, after squeezing, aging, it is handled with carbon disulfide mixing yellow, banana viscose solution is mixed to prepare with aqueous slkali again, by it coated on behind spare dry paper surface, repressed, dry cigarette tipping paper.The beneficial effects of the invention are as follows:Preparation process of the present invention is simple, occurs in preparation process without hair and powder dropping phenomenon, efficiently solves the problems, such as into the reduction of paper surface strength;Cigarette tipping paper air permeability of the present invention is high, has a stronger printing quality, and antibiotic rate is up to more than 95.6%.
Description
Technical field
It breathes freely the present invention relates to a kind of double-layer antimicrobial the preparation method of cigarette tipping paper, belongs to cigarette tipping paper technology of preparing
Field.
Background technology
With the continuous improvement of China's national life quality and the level of consumption, the cigarette consumption idea of people is becoming
Change.On the premise of smoking consumption is ensured, people increasingly focus on the low evil and health-care effect of cigarette, this is low harm cigarette
Development with health cigarette creates good condition.Cigarette body paper is used as the cigarette package of filter tipped cigarette mouth stick outer packing
Material because its appearance is similar to pine line also known as tipping base paper, belongs to special industrial paper.Cigarette body paper is by printing(It applies
Cloth)After cutting, become tipping paper, be commonly called as cork paper.Cigarette body paper is produced, on the one hand the water imbibition to paper, smooth
Degree and physical strength have higher requirements, to meet typography and reach printing effect;On the other hand paper must also be ensured
Porosity improves the permeability of paper.Cigarette body paper is generally with masson pine(Generally softwood pulp or
A certain amount of jute pulp of adapted or hardwood pulp)For raw material, control beating degree, weight in wet base, AKD sizings, using titanium dioxide, calcium carbonate
It is filled with, after with slurry long mesh paper making machine is sent to manufacture paper with pulp.But easy hair and powder dropping in preparation process reduces, printability into paper surface strength
It can be deteriorated, air permeability is low, and antibiotic property is poor.
The content of the invention
The technical problems to be solved by the invention:For easy hair and powder dropping in current cigarette tipping paper preparation process, into paper
The drawbacks of surface strength reduces, and printing quality is deteriorated, and air permeability is low, and antibiotic property is poor, provides a kind of by masson's pine wood pulp, birch
After wood pulp mashing, after the processing of the compound sheets such as talcum powder, must to dry paper spare through squeezing, dry, then takes banana fiber and alkali
Solution mixes, and filters to obtain filter residue, after squeezing, aging, is handled with carbon disulfide mixing yellow, then is mixed to prepare perfume (or spice) with aqueous slkali
Any of several broadleaf plants viscose solution, by it coated on behind spare dry paper surface, repressed, dry cigarette tipping paper.Preparation process of the present invention
Simply, occur in preparation process without hair and powder dropping phenomenon;Cigarette tipping paper surface strength of the present invention is high, has preferable printability
Energy and anti-microbial property, while there is higher air permeability, it is worthy to be popularized and uses.
In order to solve the above technical problems, the present invention is using technical solution as described below:
(1)200~300g masson's pine wood pulps and 150~200g birch wood pulps are weighed, is separately added into double-arc spline fiberizer
Be beaten, be beaten to masson's pine wood pulp mass fraction be 80~90%, beating degree be 60~70 ° of SR, birch pulp quality fraction
For 80~90%, beating degree is 60~70 ° of SR, and the masson's pine wood pulp after mashing and birch wood pulp are mixed, and stirs 30~40min,
Wood pulp must be mixed;
(2)Be separately added into above-mentioned mixing wood pulp mixing pulp quality 15~20% talcum powder, mixing pulp quality 1~
3% cationic starch and mixing 5~7% nano-titanium dioxide of pulp quality, after being stirred 20~30min, are placed in handsheet machine
Handsheet processing, obtains l Water Paper page, l Water Paper page is placed in hydraulic press, and 30~50s is squeezed under 5~8MPa, is waited after the completion of squeezing, will
It is placed at 100~105 DEG C dry 20~30min, obtains dry paper, spare;
(3)Weigh 250~300g banana fibers, in mass ratio 1:5 are mixed with dipping with 25% sodium hydroxide solution of mass fraction
60~100min then filters to obtain filter residue, is put into squeezer, 25~35min is squeezed under 4~6MPa, by the filter after squeezing
Slag adds in 28~30% carbon disulfide of filter residue quality into the filter residue after aging in 20~25 DEG C of 3~5h of aging at temperature, at yellow
60~90min is managed, obtains yellow object, by volume 1:10 add in 5% sodium hydroxide solution of mass fraction into yellow object, and stirring is mixed
20~30min is closed, obtains banana viscose solution;
(4)Above-mentioned banana viscose solution is evenly applied to step(2)Spare drying paper surface, coated weight for 120~
150g/m2, it is put into after coating in paper machine, is 0.1~0.3kPa in vacuum degree, under the conditions of pressing pressure is 4~6MPa, compacting 30
~60s is dry complete after compacting, you can to obtain double-layer antimicrobial and breathe freely cigarette tipping paper.
Double-layer antimicrobial produced by the present invention breathes freely cigarette tipping paper machine direction tensile strength as 2.46~2.72kNm-1, breathe freely
It spends for 2.450~2.862 μm(Pa·s)-1, elongation is 1.92~2.08%, and ash content is 11.2~12.3%, and water imbibition is
13.8~15.6g/m2, arsenic content≤0.8mg/kg, lead content≤4.5mg/kg, total plate count≤182cfu/g.
Compared with other methods, advantageous effects are the present invention:
(1)Preparation process of the present invention is simple, occurs in preparation process without hair and powder dropping phenomenon, efficiently solves into paper surface
Strength reduction problem;
(2)Cigarette tipping paper air permeability of the present invention is high, has a stronger printing quality, and antibiotic rate is up to more than 95.6%.
Specific embodiment
200~300g masson's pine wood pulps and 150~200g birch wood pulps are weighed first, are separately added into double-arc spline fiberizer
Be beaten, be beaten to masson's pine wood pulp mass fraction be 80~90%, beating degree be 60~70 ° of SR, birch pulp quality fraction
For 80~90%, beating degree is 60~70 ° of SR, and the masson's pine wood pulp after mashing and birch wood pulp are mixed, and stirs 30~40min,
Wood pulp must be mixed;It states then up and 15~20% talcum powder of mixing pulp quality, mixing pulp quality is separately added into mixing wood pulp
1~3% cationic starch and mixing 5~7% nano-titanium dioxide of pulp quality, after being stirred 20~30min, are placed in handsheet machine
Middle handsheet processing, obtains l Water Paper page, l Water Paper page is placed in hydraulic press, 30~50s is squeezed under 5~8MPa, is waited after the completion of squeezing,
Dry 20~30min at 100~105 DEG C is placed it in, obtains dry paper, it is spare;250~300g banana fibers are weighed again, by matter
Measure ratio 1:5 are mixed with dipping 60~100min with 25% sodium hydroxide solution of mass fraction, then filter to obtain filter residue, are put into squeezer
In, 25~35min is squeezed under 4~6kPa, by the filter residue after squeezing in 20~25 DEG C of 3~5h of aging at temperature, after aging
28~30% carbon disulfide of filter residue quality is added in filter residue, yellow handles 60~90min, obtains yellow object, and by volume 1:10 to Huang
5% sodium hydroxide solution of mass fraction is added in compound, 20~30min is stirred, obtains banana viscose solution;It finally will be above-mentioned
Banana viscose solution is evenly applied to spare drying paper surface, and coated weight is 120~150g/m2, it is put into after coating in paper machine,
It is 0.1~0.3MPa in vacuum degree, under the conditions of pressing pressure is 4~6MPa, suppresses 30~60s, it is dry complete after compacting, you can
Double-layer antimicrobial is obtained to breathe freely cigarette tipping paper.
Example 1
200g masson's pine wood pulps and 150g birch wood pulps are weighed first, are separately added into double-arc spline fiberizer and are beaten,
Mashing to masson's pine wood pulp mass fraction is 80%, and beating degree is 60 ° of SR, and birch pulp quality fraction is 80%, and beating degree is 60 °
SR mixes the masson's pine wood pulp after mashing and birch wood pulp, stirs 30min, obtains mixing wood pulp;Mixing wood pulp is stated then up
In be separately added into mixing pulp quality 15% talcum powder, mixing 1% cationic starch of pulp quality and 5% nanometer of pulp quality of mixing
Titanium dioxide after being stirred 20min, is placed in handsheet in handsheet machine and handles, obtain l Water Paper page, l Water Paper page is placed in hydraulic press,
30s is squeezed under 5MPa, is waited after the completion of squeezing, dry 20min at 100 DEG C is placed it in, obtains dry paper, it is spare;It weighs again
250g banana fibers, in mass ratio 1:5 are mixed with dipping 60min with 25% sodium hydroxide solution of mass fraction, and then filtering must filter
Slag is put into squeezer, and 25min is squeezed under 4MPa, by the filter residue after squeezing in 20 DEG C of aging at temperature 3h, the filter after aging
28% carbon disulfide of filter residue quality is added in slag, yellow processing 60min obtains yellow object, and by volume 1:10 add in into yellow object
5% sodium hydroxide solution of mass fraction, is stirred 20min, obtains banana viscose solution;It is finally that above-mentioned banana viscose solution is equal
It is even to be coated on spare drying paper surface, coated weight 120g/m2, it is put into after coating in paper machine, is 0.1MPa in vacuum degree, presses
Under the conditions of pressing pressure is 4kPa, 30s is suppressed, it is dry complete after compacting, you can to obtain double-layer antimicrobial and breathe freely cigarette tipping paper.This hair
Bright preparation process is simple, occurs in preparation process without hair and powder dropping phenomenon, efficiently solves the problems, such as into the reduction of paper surface strength;Cigarette
It is high with tipping paper air permeability, there is stronger printing quality, antibiotic rate is up to 95.69%;Double-layer antimicrobial obtained is breathed freely cigarette
Paper machine direction tensile strength is 2.46kNm-1, air permeability is 2.450 μm(Pa·s)-1, elongation 1.92%, ash content is
11.2%, water imbibition 13.8g/m2, arsenic content is 0.8mg/kg, lead content 4.5mg/kg, total plate count 182cfu/g.
Example 2
250g masson's pine wood pulps and 175g birch wood pulps are weighed first, are separately added into double-arc spline fiberizer and are beaten,
Mashing to masson's pine wood pulp mass fraction is 85%, and beating degree is 65 ° of SR, and birch pulp quality fraction is 85%, and beating degree is 65 °
SR mixes the masson's pine wood pulp after mashing and birch wood pulp, stirs 35min, obtains mixing wood pulp;Mixing wood pulp is stated then up
In be separately added into mixing pulp quality 18% talcum powder, mixing 2% cationic starch of pulp quality and 6% nanometer of pulp quality of mixing
Titanium dioxide after being stirred 25min, is placed in handsheet in handsheet machine and handles, obtain l Water Paper page, l Water Paper page is placed in hydraulic press,
40s is squeezed under 7MPa, is waited after the completion of squeezing, dry 25min at 103 DEG C is placed it in, obtains dry paper, it is spare;It weighs again
275g banana fibers, in mass ratio 1:5 are mixed with dipping 80min with 25% sodium hydroxide solution of mass fraction, and then filtering must filter
Slag is put into squeezer, and 30min is squeezed under 5MPa, by the filter residue after squeezing in 23 DEG C of aging at temperature 4h, the filter after aging
29% carbon disulfide of filter residue quality is added in slag, yellow processing 75min obtains yellow object, and by volume 1:10 add in into yellow object
5% sodium hydroxide solution of mass fraction, is stirred 25min, obtains banana viscose solution;It is finally that above-mentioned banana viscose solution is equal
It is even to be coated on spare drying paper surface, coated weight 135g/m2, it is put into after coating in paper machine, is 0.2MPa in vacuum degree, presses
Under the conditions of pressing pressure is 5kPa, 45s is suppressed, it is dry complete after compacting, you can to obtain double-layer antimicrobial and breathe freely cigarette tipping paper.This hair
Bright preparation process is simple, occurs in preparation process without hair and powder dropping phenomenon, efficiently solves the problems, such as into the reduction of paper surface strength;Cigarette
It is high with tipping paper air permeability, there is stronger printing quality, antibiotic rate is up to 95.75%;Double-layer antimicrobial obtained is breathed freely cigarette
Paper machine direction tensile strength is 2.59kNm-1, air permeability is 2.648 μm(Pa·s)-1, elongation 2.01%, ash content is
11.7%, water imbibition 14.7g/m2, arsenic content is 0.7mg/kg, lead content 4.1mg/kg, total plate count 179cfu/g.
Example 3
300g masson's pine wood pulps and 200g birch wood pulps are weighed first, are separately added into double-arc spline fiberizer and are beaten,
Mashing to masson's pine wood pulp mass fraction is 90%, and beating degree is 70 ° of SR, and birch pulp quality fraction is 90%, and beating degree is 70 °
SR mixes the masson's pine wood pulp after mashing and birch wood pulp, stirs 40min, obtains mixing wood pulp;Mixing wood pulp is stated then up
In be separately added into mixing pulp quality 20% talcum powder, mixing 3% cationic starch of pulp quality and 7% nanometer of pulp quality of mixing
Titanium dioxide after being stirred 30min, is placed in handsheet in handsheet machine and handles, obtain l Water Paper page, l Water Paper page is placed in hydraulic press,
50s is squeezed under 8MPa, is waited after the completion of squeezing, dry 30min at 105 DEG C is placed it in, obtains dry paper, it is spare;It weighs again
300g banana fibers, in mass ratio 1:5 are mixed with dipping 100min with 25% sodium hydroxide solution of mass fraction, and then filtering must filter
Slag is put into squeezer, and 35min is squeezed under 6MPa, by the filter residue after squeezing in 25 DEG C of aging at temperature 5h, the filter after aging
30% carbon disulfide of filter residue quality is added in slag, yellow processing 90min obtains yellow object, and by volume 1:10 add in into yellow object
5% sodium hydroxide solution of mass fraction, is stirred 30min, obtains banana viscose solution;It is finally that above-mentioned banana viscose solution is equal
It is even to be coated on spare drying paper surface, coated weight 150g/m2, it is put into after coating in paper machine, is 0.3MPa in vacuum degree, presses
Under the conditions of pressing pressure is 6kPa, 60s is suppressed, it is dry complete after compacting, you can to obtain double-layer antimicrobial and breathe freely cigarette tipping paper.This hair
Bright preparation process is simple, occurs in preparation process without hair and powder dropping phenomenon, efficiently solves the problems, such as into the reduction of paper surface strength;Cigarette
It is high with tipping paper air permeability, there is stronger printing quality, antibiotic rate is up to 96.05%;Double-layer antimicrobial obtained is breathed freely cigarette
Paper machine direction tensile strength is 2.72kNm-1, air permeability is 2.862 μm(Pa·s)-1, elongation 2.08%, ash content is
12.3%, water imbibition 15.6g/m2, arsenic content is 0.6mg/kg, lead content 3.9mg/kg, total plate count 175cfu/g.
Claims (1)
- The preparation method of cigarette tipping paper 1. a kind of double-layer antimicrobial is breathed freely, it is characterised in that specifically preparation process is:(1)200~300g masson's pine wood pulps and 150~200g birch wood pulps are weighed, is separately added into double-arc spline fiberizer and carries out Mashing, it is 80~90% to be beaten to masson's pine wood pulp mass fraction, and beating degree is 60~70 ° of SR, and birch pulp quality fraction is 80 ~90%, beating degree is 60~70 ° of SR, and the masson's pine wood pulp after mashing and birch wood pulp are mixed, and stirs 30~40min, obtains mixed Close wood pulp;(2)15~20% talcum powder of mixing pulp quality, 1~3% sun of mixing pulp quality are separately added into above-mentioned mixing wood pulp Ionic starch and mixing 5~7% nano-titanium dioxide of pulp quality, after being stirred 20~30min, are placed in handsheet in handsheet machine Processing, obtains l Water Paper page, l Water Paper page is placed in hydraulic press, and 30~50s is squeezed under 5~8MPa, waits after the completion of squeezing, is put Dry 20~30min, obtains dry paper at 100~105 DEG C, spare;(3)Weigh 250~300g banana fibers, in mass ratio 1:5 with 25% sodium hydroxide solution of mass fraction be mixed with dipping 60~ 100min then filters to obtain filter residue, is put into squeezer, and 25~35min is squeezed under 4~6MPa, the filter residue after squeezing is existed 20~25 DEG C of 3~5h of aging at temperature add in 28~30% carbon disulfide of filter residue quality, yellow processing 60 into the filter residue after aging ~90min obtains yellow object, and by volume 1:10 add in 5% sodium hydroxide solution of mass fraction into yellow object, are stirred 20 ~30min obtains banana viscose solution;(4)Above-mentioned banana viscose solution is evenly applied to step(2)Spare drying paper surface, coated weight are 120~150g/ m2, it is put into after coating in paper machine, is 0.1~0.3kPa in vacuum degree, under the conditions of pressing pressure is 4~6MPa, compacting 30~ 60s is dry complete after compacting, you can to obtain double-layer antimicrobial and breathe freely cigarette tipping paper.
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CN108193547A (en) * | 2017-12-01 | 2018-06-22 | 蒋春霞 | A kind of preparation method of antibacterial hydrophobic type cork paper |
CN108193559A (en) * | 2017-12-11 | 2018-06-22 | 常州市宇科不绣钢有限公司 | A kind of preparation method of cigarette tipping paper |
CN108951269A (en) * | 2018-07-05 | 2018-12-07 | 常州思宇知识产权运营有限公司 | A kind of preparation method of cigarette tipping paper |
CN109364580A (en) * | 2018-11-06 | 2019-02-22 | 江苏三元环保科技有限公司 | A kind of filter cloth and preparation method thereof with antibacterial functions |
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CN105019292A (en) * | 2015-06-26 | 2015-11-04 | 安徽省三环纸业(集团)有限公司 | Production technology for tipping base paper for cigarette |
CN105768214A (en) * | 2016-04-13 | 2016-07-20 | 云南中烟工业有限责任公司 | Cigarette filter enabling users to freely select ventilation rate |
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