CN106435615A - Wax solvent used for soaking and cleaning aluminum cosmetic cap - Google Patents
Wax solvent used for soaking and cleaning aluminum cosmetic cap Download PDFInfo
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- CN106435615A CN106435615A CN201610771740.4A CN201610771740A CN106435615A CN 106435615 A CN106435615 A CN 106435615A CN 201610771740 A CN201610771740 A CN 201610771740A CN 106435615 A CN106435615 A CN 106435615A
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- wax
- cosmetic cap
- soaking
- fatty acid
- aluminum cosmetic
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a wax solvent used for soaking and cleaning an aluminum cosmetic cap. The wax solvent comprises triethanolamine oleic soap, a wetting agent, a non-ionic surface active agent, ethyl alcohol, mildew preventive, an organic silicon defoamer and water. 1/3 pure water is added into a reaction still, then the triethanolamine oleic soap is added and automatically stirred for 10 min, the wetting agent and the non-ionic surface active agent are added and automatically stirred for 20 min, finally the ethyl alcohol, the mildew preventive and the organic silicon defoamer are added, and water is added for constant-capacity even mixing, so that the wax solvent is prepared. The wax solvent is used for wax removing treatment of the aluminum cosmetic cap, hardly corrodes the aluminum cosmetic cap and does not influence the glossiness of the aluminum cosmetic cap. The wax removing treatment speed is high, the cost is low, environmental friendliness is achieved, the wax residual amount is smaller than 1%, the brightness change is within 10 gld, and the problems that the wax residual amount is large, energy consumption is large, time is long, the temperature is high, environmental friendliness is not achieved, aluminum cosmetic cap substrates are corroded, and the glossiness of aluminum cosmetic caps is influenced when traditional wax solvents are used for wax removing treatment of the aluminum cosmetic caps are solved.
Description
Technical field
The present invention relates to aluminum cosmetic cap paraffin removal processing technology field, be specifically related to a kind of for soaking and washing aluminum
The Wax removal water of cosmetic lid.
Background technology
As people's quality of the life generally improves, growing with each passing day cosmetics demand, cosmetics have almost become that people's is every
Its requirement;The packaging material of cosmetics occur in that huge demand.In toiletry bag package material, the especially material with aluminum
Account for the largest percentage.Finish aluminum cosmetic cap, comparative maturity is machinery fiber crops wheel, buffing agent technique, during finish, fiber crops
The buffing wax that on wheel, cloth wheel or aluminum lid, last layer to be applied is special, this buffing wax complicated, it after polishing, is attached to aluminium
In lid processed, outside upper suitable difficulty is removed.
The wax dirt of buffing wax is main by paraffin, aliphatic acid, rosin soap, metal oxide and little of some inoganic solids rubbing down
Grain such as corundum, carborundum, alumina porcelain etc. forms.The solid particle such as polishing residual fragment of cloth rumble, the powder of polishing metallic matrix out
End thing and oxide thereof are mainly uniformly distributed in buffing wax system with powder.Wax dirt with workpiece mainly with mechanical adhesion, point
The adherent fashion such as power adhesion, electrostatic force adhesion between Zi, the just more difficult removal when the wax dirt particle of mechanical adhesion is less than 0.11 μm.
Paraffin removal processing method traditional at present has:Organic solvent method, chemical method, electrochemical process etc..Organic solvent is general all
Poisonous, the wax layer of metal material can not be cleaned completely, to some oxides inside wax layer, abrasive dust etc. remains almost without effect
Really;And electrochemical process, energy consumption is big, also has certain corrosiveness to metal material, and paraffin removal effect is not good yet;Some are general on the market
Logical Wax removal water, although also can meet common metal material such as stainless steel, ironware, aluminium alloy, kirsite, copper material etc. and substantially want
Ask, but the cosmetic cap of aluminum is follow-up generally to be electroplated or to aoxidize, glossiness and residual wax content are controlled and is desirable that
High;Tradition Wax removal water simultaneously, belongs to strong acid and strong base type, easily corrodes workpiece, affect material gloss;The paraffin removal time is longer, processes
Not even environmental protection that is temperature required also high, that have, has pollution to water body.
Content of the invention
For the deficiencies in the prior art, it is desirable to provide one to aluminum cosmetic cap base material almost without burn into
Not affecting aluminum cosmetic cap base material glossiness, paraffin removal processing speed is fast, low cost, environmental protection, wax residual quantity are little is used for soaking
Clean the Wax removal water of aluminum cosmetic cap.
For achieving the above object, the present invention adopts the following technical scheme that:
For the Wax removal water of soaking and washing aluminum cosmetic cap, proportionately divide and include trihydroxy ethylamine oleate soap, wetting agent, nonionic table
Face activating agent, ethanol, mould inhibitor, organic silicon defoamer and water, by adding the pure water of 1/3 in a kettle., then add three
Monoethanolamine oleate soap automatic stirring 10min, then add wetting agent, nonionic surfactant automatic stirring 20min, finally add again
Add ethanol, mould inhibitor, the organic silicon defoamer constant volume that adds water mixes and makes.
Further, described by weight trihydroxy ethylamine oleate soap is 70-120 part, and the purity of trihydroxy ethylamine oleate soap is not
Less than 90%.
Further, described wetting agent be AEO, at least one in NPE, press
AEO described in weight portion is 24-35 part, and NPE is 25-50 part.
Further, described nonionic surfactant is cocoanut fatty acid diethanolamide, includes 48-by weight
75 parts.
Further, described by weight ethanol is 15-20 part.
Further, described mould inhibitor is Sodium Benzoate, sodium Diacetate or Nepal's gold ester, includes 1-10 by weight
Part.
Further, described organic silicon defoamer is organic silicon defoamer #422, includes 0.5-2 part by weight.
Preferably, described AEO is AEO AE0-3, AEO
AEO-7 or AEO AEO-9, NPE be NPE TX-3, nonyl phenol gather
Oxygen vinethene TX-4, NPE TX-6, NPE TX-7, NPE TX-10
Or NPE TX-15.
Preferably, described cocoanut fatty acid diethanolamide is cocoanut fatty acid diethanolamide the 6501st, coconut oil
Fatty diglycollic amide the 6502nd, cocoanut fatty acid diethanolamide the 6503rd, cocoanut fatty acid diethanolamide the 6504th, coconut palm
Seed oil fatty diglycollic amide the 6505th, cocoanut fatty acid diethanolamide the 6506th, cocoanut fatty acid diethanolamide
6507 or cocoanut fatty acid diethanolamide 6508.
The present invention has the advantages that:
The present invention is for the Wax removal water of soaking and washing aluminum cosmetic cap, for the paraffin removal process of aluminum cosmetic cap, to aluminum
Cosmetic cap base material does not affect aluminum cosmetic cap base material glossiness almost without burn into, paraffin removal processing speed is fast, low cost,
Environmental protection, wax residual quantity change in the range of 10gld less than the 1%th, brightness, solve tradition Wax removal water to aluminum cosmetic cap
Carry out paraffin removal when processing, the wax residual quantity existing is big, energy consumption is big, time length, temperature are high, not environmentally, to aluminum cosmetic cap base
Material has the problem that burn into affects aluminum cosmetic cap base material glossiness.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described, in order to clearer understand the present invention want
Seek the technological thought of protection.
For the Wax removal water of soaking and washing aluminum cosmetic cap, proportionately divide include trihydroxy ethylamine oleate soap, wetting agent, non-from
Sub-surface activating agent, ethanol, mould inhibitor, organic silicon defoamer and water, by adding the pure water of 1/3 in a kettle., then add
Add trihydroxy ethylamine oleate soap automatic stirring 10min, then add wetting agent, nonionic surfactant automatic stirring 20min, finally
Add ethanol again, mould inhibitor, the organic silicon defoamer constant volume that adds water mixes and makes.
Concrete, trihydroxy ethylamine oleate soap by weight is 70-120 part, and the purity of trihydroxy ethylamine oleate soap is not less than
90%.Wetting agent is AEO, at least one in NPE, described by weight fatty alcohol
APEO is 24-35 part, and NPE is 25-50 part.Nonionic surfactant is coco-nut oil fatty acid
Diglycollic amide, includes 48-75 part by weight.Ethanol by weight is 15-20 part.Mould inhibitor is Sodium Benzoate, diacetic acid
Sodium or Nepal's gold ester, include 1-10 part by weight.Organic silicon defoamer is organic silicon defoamer #422, includes by weight
0.5-2 part.AEO is AEO AE0-3, AEO AEO-7 or fatty alcohol
APEO AEO-9, NPE be NPE TX-3, NPE TX-4,
NPE TX-6, NPE TX-7, NPE TX-10 or polyoxyethylene nonyl phenyl second
Alkene ether TX-15.Cocoanut fatty acid diethanolamide is cocoanut fatty acid diethanolamide the 6501st, coco-nut oil fatty acid diethyl
Alkylolamides the 6502nd, cocoanut fatty acid diethanolamide the 6503rd, cocoanut fatty acid diethanolamide the 6504th, coco-nut oil fatty acid
Diglycollic amide the 6505th, cocoanut fatty acid diethanolamide the 6506th, cocoanut fatty acid diethanolamide 6507 or coconut oil
Fatty diglycollic amide 6508.
In embodiment, mould inhibitor is illustrated as a example by Sodium Benzoate.
Embodiment 1:
For the Wax removal water of soaking and washing aluminum cosmetic cap, include by weight 70 parts trihydroxy ethylamine oleate soap, 24 parts
AEO AEO-9, cocoanut fatty acid diethanolamide the 6501st, the NPE of 25 parts of 48 parts
TX-10,15 parts ethanol, 1 part Sodium Benzoate, 0.5 part organic silicon defoamer, excess water be settled to total deal 1000 parts.
Add the pure water of 1/3 during production in a kettle., be subsequently adding the trihydroxy ethylamine oleate soap automatic stirring of 70 parts
10min, adds the AEO AEO-9 of 24 parts, the cocoanut fatty acid diethanolamide the 6501st, 25 parts of 48 parts
NPE TX-10 automatic stirring 20min, then add 15 parts ethanol, 1 part Sodium Benzoate, 0.5 part
Organic silicon defoamer, adding water is settled to the 1000 parts of mixings of total deal and makes required Wax removal water.
Embodiment 2 removes trihydroxy ethylamine oleate soap, embodiment 2 on the basis of embodiment 1:
For the Wax removal water of soaking and washing aluminum cosmetic cap, include by weight 24 parts AEO AEO-9,
The cocoanut fatty acid diethanolamide of 48 parts the 6501st, 25 parts NPE TX-10,15 parts ethanol, 1 part
Sodium Benzoate, 0.5 part organic silicon defoamer, excess water be settled to total deal 1000 parts, also according to the method in embodiment 1
Produce.
Embodiment 3:
For the Wax removal water of soaking and washing aluminum cosmetic cap, include by weight 70 parts trihydroxy ethylamine oleate soap, 30 parts
AEO AEO-3, cocoanut fatty acid diethanolamide the 6508th, the NPE of 30 parts of 50 parts
TX-3,20 parts ethanol, 5 parts Sodium Benzoate, 1 part organic silicon defoamer, excess water be settled to total deal 1000 parts, equally
Produce according to the method in embodiment 1.
Embodiment 4:
For the Wax removal water of soaking and washing aluminum cosmetic cap, include by weight 100 parts trihydroxy ethylamine oleate soap, 35 parts
AEO AEO-7, cocoanut fatty acid diethanolamide the 6502nd, the NPE of 50 parts of 75 parts
TX-7,20 parts ethanol, 10 parts Sodium Benzoate, 2 parts organic silicon defoamer, excess water be settled to total deal 1000 parts, with
Sample produces according to the method in embodiment 1.
The Wax removal water that comparative example 5 is traditional common type, includes oleic acid 150 parts, diethanol amine 150 according to weight portion
Part, coconut oil diethanol amide 50 parts, alkylolamides phosphate 50 parts, disodium hydrogen phosphate 20 parts, sodium pyrophosphate 200 parts, silicon
50 parts of sodium of acid, 50 parts of sodium carbonate, NPE 20 parts, water surplus.
Take the Wax removal water that the various embodiments described above make respectively to carry out paraffin removal to aluminum cosmetic cap and process test, be specially:
Take standard sample aluminum cosmetic cap several(Size:D=1.8cm, L=2cm), the test method of weighing, use absolute alcohol
By cleaning careful for aluminum cosmetic cap ultrasonic wave, electricity consumption dries up, and being weighed by assay balance obtains M0, makes up aluminum
Inside and outside product lid, uniform wiping buffing wax, is dried by baking box, is weighed to obtain M1 by ten thousand/balance, by Wax removal water with 5% weight
Ratio opens cylinder, and temperature is heated up to about 70 DEG C, is then immersed in aluminum cosmetic cap in working solution, processes 5 minutes, then by aluminium
Cosmetic cap processed takes out, and after repeatedly cleaning with clear water, electricity consumption dries up, and is weighed M2 by assay balance, and cleaning rate=(M1-
M2)/(M1-M0)× 100%, repeatedly survey 10 times, draw mean value.Residual rate=1-cleaning rate.
Result of the test such as following table:
Embodiment | Cleaning rate(10 cell means) | Residual rate |
Embodiment 1 | 99.3% | 0.7% |
Embodiment 2 | 50.4% | 49.6% |
Embodiment 3 | 99.1% | 0.9% |
Embodiment 4 | 99.5% | 0.5% |
Embodiment 5 | 75.4% | 24.6% |
It can be seen that the 3rd, embodiment the 1st, the embodiment including trihydroxy ethylamine oleate soap composition is implemented from above-mentioned result of the test table
The paraffin removal effect of example 4 is good, and wax residual rate is below 1%;And each constituent content is higher, such as embodiment 4, its wax residual rate is lower.
Not including embodiment 2 and the traditional common type Wax removal water embodiment 5 of trihydroxy ethylamine oleate soap composition, its wax residual rate is suitable
High.
The present invention substitutes traditional common type for the Wax removal water of soaking and washing aluminum cosmetic cap with trihydroxy ethylamine oleate soap
The oleic acid of Wax removal water, diethanol amine, when carrying out paraffin removal process to aluminum cosmetic cap, wax residual rate is very low, and wax residual rate is low
In 1%, relative to traditional common type Wax removal water, its wax residual rate decreases about 20%;Have to aluminum cosmetic cap base material several
Not having burn into not affect aluminum cosmetic cap base material glossiness, paraffin removal processing speed is fast, low cost, environmental protection, wax residual quantity are little
In feature in the range of 10gld for the 1%th, the brightness change.
For a person skilled in the art, can technical scheme as described above and design, make other each
Plant corresponding change and deformation, and all these changes and deforms the protection model that all should belong to the claims in the present invention
Within enclosing.
Claims (9)
1. the Wax removal water for soaking and washing aluminum cosmetic cap, it is characterised in that:Proportionately divide and include trihydroxy ethylamine oleate soap, wet
Profit agent, nonionic surfactant, ethanol, mould inhibitor, organic silicon defoamer and water, by add in a kettle. 1/3 pure
Water, then adds trihydroxy ethylamine oleate soap automatic stirring 10min, then adds wetting agent, nonionic surfactant automatic stirring
20min, finally adds ethanol, mould inhibitor, the organic silicon defoamer constant volume that adds water mixes and makes again.
2. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 1, it is characterised in that:Institute by weight
Stating trihydroxy ethylamine oleate soap is 70-120 part, and the purity of trihydroxy ethylamine oleate soap is not less than 90%.
3. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 1, it is characterised in that:Described wetting agent
AEO, at least one in NPE, described by weight AEO
For 24-35 part, NPE is 25-50 part.
4. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 1, it is characterised in that:Described nonionic
Surfactant is cocoanut fatty acid diethanolamide, includes 48-75 part by weight.
5. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 1, it is characterised in that:Institute by weight
Stating ethanol is 15-20 part.
6. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 1, it is characterised in that:Described mould inhibitor
It is Sodium Benzoate, sodium Diacetate or Nepal's gold ester, include 1-10 part by weight.
7. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 1, it is characterised in that:Described organosilicon
Defoamer is organic silicon defoamer #422, includes 0.5-2 part by weight.
8. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 3, it is characterised in that:Described fatty alcohol
APEO is AEO AE0-3, AEO AEO-7 or AEO AEO-
9, NPE is NPE TX-3, NPE TX-4, Nonyl pheno
Ether TX-6, NPE TX-7, NPE TX-10 or NPE TX-15.
9. the Wax removal water for soaking and washing aluminum cosmetic cap as claimed in claim 4, it is characterised in that:Described coconut oil
Fatty diglycollic amide is cocoanut fatty acid diethanolamide the 6501st, cocoanut fatty acid diethanolamide the 6502nd, coconut
Fatty acid oil diglycollic amide the 6503rd, cocoanut fatty acid diethanolamide the 6504th, cocoanut fatty acid diethanolamide is the 6505th,
Cocoanut fatty acid diethanolamide the 6506th, cocoanut fatty acid diethanolamide 6507 or cocoanut fatty acid diethanolamide
6508.
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CN201610771740.4A CN106435615A (en) | 2016-08-31 | 2016-08-31 | Wax solvent used for soaking and cleaning aluminum cosmetic cap |
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CN201610771740.4A CN106435615A (en) | 2016-08-31 | 2016-08-31 | Wax solvent used for soaking and cleaning aluminum cosmetic cap |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107937919A (en) * | 2017-11-24 | 2018-04-20 | 广东埃德伟控汽车部件有限公司 | One kind extends salt fog period protection agent |
CN108660461A (en) * | 2018-06-27 | 2018-10-16 | 东莞盛翔精密金属有限公司 | Preparation method of the efficient paraffin removal of polished part of copper except the integrated cleaning agent of oxidation |
CN113136272A (en) * | 2021-03-03 | 2021-07-20 | 广州市睿承科技有限公司 | Paraffin removal tank liquid synergist |
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---|---|---|---|---|
CN102010806A (en) * | 2010-11-11 | 2011-04-13 | 彭美东 | Rapid wax removing agent |
CN103061120A (en) * | 2012-12-17 | 2013-04-24 | 吴江市金平华纺织有限公司 | Refining agent |
DE102013001084A1 (en) * | 2013-01-23 | 2014-07-24 | Wolfgang Knöchlein | Cleaning and maintaining metallic, preferably steel wall and building surfaces, steel wall surface, comprises e.g. detaching a wax layer, which is present on the metallic wall surface, from the metallic wall surface |
-
2016
- 2016-08-31 CN CN201610771740.4A patent/CN106435615A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102010806A (en) * | 2010-11-11 | 2011-04-13 | 彭美东 | Rapid wax removing agent |
CN103061120A (en) * | 2012-12-17 | 2013-04-24 | 吴江市金平华纺织有限公司 | Refining agent |
DE102013001084A1 (en) * | 2013-01-23 | 2014-07-24 | Wolfgang Knöchlein | Cleaning and maintaining metallic, preferably steel wall and building surfaces, steel wall surface, comprises e.g. detaching a wax layer, which is present on the metallic wall surface, from the metallic wall surface |
Non-Patent Citations (1)
Title |
---|
张允诚等: "《电镀手册》", 31 December 2011 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107937919A (en) * | 2017-11-24 | 2018-04-20 | 广东埃德伟控汽车部件有限公司 | One kind extends salt fog period protection agent |
CN108660461A (en) * | 2018-06-27 | 2018-10-16 | 东莞盛翔精密金属有限公司 | Preparation method of the efficient paraffin removal of polished part of copper except the integrated cleaning agent of oxidation |
CN113136272A (en) * | 2021-03-03 | 2021-07-20 | 广州市睿承科技有限公司 | Paraffin removal tank liquid synergist |
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