CN106011864B - Aerial fog type metal decontamination polisher and preparation method thereof - Google Patents
Aerial fog type metal decontamination polisher and preparation method thereof Download PDFInfo
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- CN106011864B CN106011864B CN201610429355.1A CN201610429355A CN106011864B CN 106011864 B CN106011864 B CN 106011864B CN 201610429355 A CN201610429355 A CN 201610429355A CN 106011864 B CN106011864 B CN 106011864B
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- polisher
- type metal
- aerial fog
- fog type
- metal decontamination
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F3/00—Brightening metals by chemical means
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/024—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing hydrocarbons
Abstract
The present invention provides a kind of aerial fog type metal decontamination polisher and preparation method thereof.Aerial fog type metal decontamination polisher of the invention includes component and its weight percent are as follows: aliphatic solvent 25.0-35.0%；Limonene 1.0-3.0%；Oleic acid 0.5-1.0%；Triethanolamine 0.5-1.5%；Nonionic emulsifier 3-6%；Aluminium oxide 5-10%；Diatomite 5-10%；Silica flour 5-10%；Modified manometer silicon dioxide 0.5-1.5%；Deionized water 30-40%；Isopropanol 5-15%；Propellant 5-10%.The preparation method of aerial fog type metal decontamination polisher of the invention, a kind of composition of aerial fog type metal decontamination polisher is made of emulsifying process first, and it is the composition is canned to inhalator jar, appropriate propellant is filled with after sealing, obtain aerial fog type metal decontamination polisher, technological operation is simple, prepared metal decontamination polisher safety and environmental protection, easy to use.
Description
Technical field
The present invention relates to intermetallic composite coating auxiliary agent field more particularly to a kind of aerial fog type metal decontamination polisher and its preparation sides
Method.
Background technique
Metal product in use, due to oxidation, humidity in air or contacts chemical substance and corrosive gas etc.
Reason causes surface of metal product to corrode, and adheres to foul greasy dirt situation, bright and clean in order to increase surface of metal product, usually uses
The metal detergent of chemistry is handled.With the increasingly modernization of communal facility and daily necessity, the use of metal product
Rate is higher and higher, and people are increasingly urgent to the use demand of metal polish.Metal polish is suitable for stainless steel, copper, silver, aluminium
And the clean wiping of the products such as plating is bright.
The country mainly uses medal polish cream as polish product at present, but since traditional antiscuffing paste is by abrasive material, grease
And the raw materials such as solvent composition, due to the difference of abrasive material used, the difference of fat type forms antiscuffing paste a variety of different
Product, using in a variety of different occasions.Therefore the application range of such product is relatively narrow, and there are poor fluidity, construction are inconvenient,
And to the pollution of environment it is more serious the problems such as.And liquid metals polisher product typically contains strong acid or phosphate, pollution
Environment, cleaning efficiency are relatively low.With the raising of environmental requirement, both at home and abroad to volatile organic matter (Volatile Organic
Compounds, VOC) use of solvent limited, therefore, develop not only environmental and price but also cheap metal decontamination
Polisher becomes an urgent demand in market.
Summary of the invention
The purpose of the present invention is to provide a kind of aerial fog type metal decontamination polishers, and VOC solvent content is low, and product is stablized
Property and mobility are preferable, and using aerosol packaging, product is easy to use.
Another object of the present invention is to provide a kind of preparation method of aerial fog type metal decontamination polisher, technological operation letters
Single, prepared metal decontamination polisher safety and environmental protection, it is easy to use.
To achieve the above object, the present invention provides a kind of aerial fog type metal decontamination polisher, includes component and its weight hundred
Divide ratio as follows:
Aliphatic solvent 25.0-35.0%；Limonene 1.0-3.0%；Oleic acid 0.5-1.0%；Triethanolamine 0.5-
1.5%；Nonionic emulsifier 3-6%；Aluminium oxide 5-10%；Diatomite 5-10%；Silica flour 5-10%；Modified nano-silica
Silicon 0.5-1.5%；Deionized water 30-40%；Isopropanol 5-15%；Propellant 5-10%.
The aliphatic solvent is Isopars, and boiling range is 190-230 DEG C.
The nonionic emulsifier is sorbitan fatty ester, hydroxyl value 190-220mgKOH/g, saponification number
For 140-160mgKOH/g, hydrophilic lipophilic balance is between 4-6.
The partial size of the modified manometer silicon dioxide is 0.2-0.3 μm, specific surface area 150-250m2/g。
The propellant is dimethyl ether.
The present invention also provides a kind of preparation methods of aerial fog type metal decontamination polisher, include the following steps:
Step 1, on the basis of the total weight of estimated obtained aerial fog type metal decontamination polisher, ratio claims by weight respectively
Take aliphatic solvent 25.0-35.0%, limonene 1.0-3.0%, oleic acid 0.5-1.0%, triethanolamine 0.5-1.5%, it is non-from
Sub- emulsifier 3-6%, aluminium oxide 5-10%, diatomite 5-10%, silica flour 5-10%, modified manometer silicon dioxide 0.5-
1.5%, deionized water 30-40%, isopropanol 5-15% prepare propellant by the weight ratio of 5-10%；
The aliphatic solvent weighed up, limonene, oleic acid, triethanolamine and nonionic emulsifier are mixed step 2
It is even, obtain preliminary mixed solution；
Weighed aluminium oxide, diatomite and silica flour are added in the preliminary mixed liquor step 3, in 2000-
Under the effect of 2500r/min high-speed stirred, weighed isopropanol and a part of weighed deionized water are pressed to the volume of 1-2:1
Than being slowly added to after being mixed, the deionized water for being slowly added to surplus, dispersion and emulsion 10-20min are then proceeded to；
Step 4 provides inhalator jar, will be fitted into the inhalator jar after material filtering that step 3 obtains, loads onto valve bundle
Lid, is filled with propellant according to the weight ratio of the 5-10% in pre- aerial fog type metal decontamination polisher obtained.
The aliphatic solvent is Isopars, and boiling range is 190-230 DEG C.
The nonionic emulsifier is sorbitan fatty ester, hydroxyl value 190-220mgKOH/g, saponification number
For 140-160mgKOH/g, hydrophilic lipophilic balance is between 4-6.
The partial size of the modified manometer silicon dioxide is 0.2-0.3 μm, specific surface area 150-250m2/g。
The propellant is dimethyl ether.
Beneficial effects of the present invention: aerial fog type metal decontamination polisher of the invention is oil-in-water (O/W) type emulsion,
Volatile solvent is replaced using a large amount of water, greatly reduces cost, smell is smaller, reduces VOC release, improves environmental protection
Performance, and product stability and mobility are preferable, use aerosol packaging, so that product is more convenient to use, stable storing, no
It is easy to gag somebody, the corrosion substance and greasy dirt of metal surface can be rapidly removed, can quickly improve the brightness of metal surface, simultaneously
The corrosion and oxidation that protective film alleviates metal surface are formed in metal surface, is suitable for stainless steel, copper, silver, aluminium and plating etc.
The clean wiping of product is bright, improves product service performance.The preparation method of aerial fog type metal decontamination polisher of the invention,
A kind of composition of aerial fog type metal decontamination polisher is made of emulsifying process first, and the composition is canned to aerosol
Tank is filled with appropriate propellant after sealing, obtain aerial fog type metal decontamination polisher, technological operation is simple, and prepared metal is gone
Dirty polisher safety and environmental protection, it is easy to use.
Detailed description of the invention
For further understanding of the features and technical contents of the present invention, it please refers to below in connection with of the invention detailed
Illustrate and attached drawing, however, the drawings only provide reference and explanation, is not intended to limit the present invention.
In attached drawing,
Fig. 1 is the process flow chart of the production method of aerial fog type ceramic tile non-skid coating of the invention.
Specific embodiment
Further to illustrate technological means and its effect adopted by the present invention, below in conjunction with preferred implementation of the invention
Example and its attached drawing are described in detail.
Present invention firstly provides a kind of aerial fog type metal decontamination polishers, as follows comprising component and its weight percent:
Aliphatic solvent 25.0-35.0%；Limonene 1.0-3.0%；Oleic acid 0.5-1.0%；Triethanolamine 0.5-
1.5%；Nonionic emulsifier 3-6%；Aluminium oxide 5-10%；Diatomite 5-10%；Silica flour 5-10%；Modified nano-silica
Silicon 0.5-1.5%；Deionized water 30-40%；Isopropanol 5-15%；Propellant 5-10%.
Specifically, the aliphatic solvent is Isopars, and boiling range is 190-230 DEG C, and the aliphatic solvent is excellent
It is selected as isomery hexadecane hydrocarbon solvent.
Specifically, the nonionic emulsifier be sorbitan fatty ester, hydroxyl value 190-220mgKOH/g,
Saponification number is 140-160mgKOH/g, and hydrophilic lipophilic balance is between 4-6.
Specifically, the partial size of the modified manometer silicon dioxide is 0.2-0.3 μm, specific surface area 150-250m2/ g, it is excellent
Selecting specific surface area is 200m2/g。
Specifically, the propellant is dimethyl ether (DME).
Aerial fog type metal decontamination polisher of the invention is oil-in-water emulsion, uses a large amount of water and replaces volatilization
Property solvent, greatly reduce cost, smell is smaller, reduce VOC release, improve environmental-protecting performance, and product stability and stream
Dynamic property is preferable, uses aerosol packaging, so that product is more convenient to use, stable storing, it is not easy to gag somebody, gold can be rapidly removed
The corrosion substance and greasy dirt of metal surface can quickly improve the brightness of metal surface, while form protective film in metal surface
The corrosion and oxidation for alleviating metal surface, the clean wiping suitable for products such as stainless steel, copper, silver, aluminium and plating is bright, mentions
High product service performance.
Referring to Fig. 1, the present invention also provides a kind of preparation methods of aerial fog type metal decontamination polisher, including walk as follows
It is rapid:
Step 1, on the basis of the total weight of estimated obtained aerial fog type metal decontamination polisher, ratio claims by weight respectively
Take aliphatic solvent 25.0-35.0%, limonene 1.0-3.0%, oleic acid 0.5-1.0%, triethanolamine 0.5-1.5%, it is non-from
Sub- emulsifier 3-6%, aluminium oxide 5-10%, diatomite 5-10%, silica flour 5-10%, modified manometer silicon dioxide 0.5-
1.5%, deionized water 30-40%, isopropanol 5-15% prepare propellant by the weight ratio of 5-10%.
Specifically, the aliphatic solvent is Isopars, and boiling range is 190-230 DEG C, and the aliphatic solvent is excellent
It is selected as isomery hexadecane hydrocarbon solvent.
Specifically, the nonionic emulsifier be sorbitan fatty ester, hydroxyl value 190-220mgKOH/g,
Saponification number is 140-160mgKOH/g, and hydrophilic lipophilic balance is between 4-6.
Specifically, the partial size of the modified manometer silicon dioxide is 0.2-0.3 μm, specific surface area 150-250m2/ g, it is excellent
Selecting specific surface area is 200m2/g。
The aliphatic solvent weighed up, limonene, oleic acid, triethanolamine and nonionic emulsifier are mixed step 2
It is even, obtain preliminary mixed solution.
Weighed aluminium oxide, diatomite and silica flour are added in the preliminary mixed liquor step 3, in 2000-
Under the effect of 2500r/min high-speed stirred, weighed isopropanol and a part of weighed deionized water are pressed to the volume of 1-2:1
Than being slowly added to after being mixed, the deionized water for being slowly added to surplus, dispersion and emulsion 10-20min are then proceeded to.
Step 4 provides inhalator jar, will be fitted into the inhalator jar after material filtering that step 3 obtains, loads onto valve bundle
Lid, is filled with propellant according to the weight ratio of the 5-10% in pre- aerial fog type metal decontamination polisher obtained.
Specifically, the propellant is dimethyl ether.
In conclusion aerial fog type metal decontamination polisher of the invention, is oil-in-water (O/W) type emulsion, use big
The water of amount replaces volatile solvent, greatly reduces cost, and smell is smaller, reduces VOC release, improves environmental-protecting performance, and
Product stability and mobility are preferable, use aerosol packaging, so that product is more convenient to use, stable storing, it is not easy to stifled
Mouth can rapidly remove the corrosion substance and greasy dirt of metal surface, can quickly improve the brightness of metal surface, while in metal
Surface forms the corrosion and oxidation that protective film alleviates metal surface, suitable for products such as stainless steel, copper, silver, aluminium and plating
Clean wiping is bright, improves product service performance.The preparation method of aerial fog type metal decontamination polisher of the invention, is adopted first
A kind of composition of aerial fog type metal decontamination polisher is made of emulsifying process, and the composition is canned to inhalator jar, it is close
It is honored as a queen and is filled with appropriate propellant, obtain aerial fog type metal decontamination polisher, technological operation is simple, and prepared metal decontamination is polished
Agent safety and environmental protection, it is easy to use.
The above for those of ordinary skill in the art can according to the technique and scheme of the present invention and technology
Other various corresponding changes and modifications are made in design, and all these change and modification all should belong to the appended right of the present invention
It is required that protection scope.
Claims (8)
1. a kind of aerial fog type metal decontamination polisher, which is characterized in that as follows comprising component and its weight percent:
Aliphatic solvent 25.0-35.0%；Limonene 1.0-3.0%；Oleic acid 0.5-1.0%；Triethanolamine 0.5-1.5%；It is non-
Ionic emulsifying agent 3-6%；Aluminium oxide 5-10%；Diatomite 5-10%；Silica flour 5-10%；Modified manometer silicon dioxide 0.5-
1.5%；Deionized water 30-40%；Isopropanol 5-15%；Propellant 5-10%；
The propellant is dimethyl ether.
2. aerial fog type metal decontamination polisher as described in claim 1, which is characterized in that the aliphatic solvent is isomeric alkane
Hydrocarbon solvent, boiling range are 190-230 DEG C.
3. aerial fog type metal decontamination polisher as described in claim 1, which is characterized in that the nonionic emulsifier is dehydration
Sorbitan fatty acid ester, hydroxyl value 190-220mgKOH/g, saponification number 140-160mgKOH/g, hydrophilic lipophilic balance
Between 4-6.
4. aerial fog type metal decontamination polisher as described in claim 1, which is characterized in that the modified manometer silicon dioxide
Partial size is 0.2-0.3 μm, specific surface area 150-250m2/g。
5. a kind of preparation method of aerial fog type metal decontamination polisher, which comprises the steps of:
Step 1, on the basis of the total weight of estimated obtained aerial fog type metal decontamination polisher, ratio weighs rouge by weight respectively
Fat hydrocarbon solvent 25.0-35.0%, limonene 1.0-3.0%, oleic acid 0.5-1.0%, triethanolamine 0.5-1.5%, nonionic Emulsion
Agent 3-6%, it aluminium oxide 5-10%, diatomite 5-10%, silica flour 5-10%, modified manometer silicon dioxide 0.5-1.5%, goes
Ionized water 30-40%, isopropanol 5-15% prepare propellant by the weight ratio of 5-10%；
The aliphatic solvent weighed up, limonene, oleic acid, triethanolamine and nonionic emulsifier are mixed evenly step 2,
Obtain preliminary mixed solution；
Weighed aluminium oxide, diatomite and silica flour are added in the preliminary mixed liquor step 3, in 2000-2500r/
Under the effect of min high-speed stirred, weighed isopropanol and a part of weighed deionized water are carried out by the volume ratio of 1-2:1
It is slowly added to after mixing, then proceedes to the deionized water for being slowly added to surplus, dispersion and emulsion 10-20min；
Step 4 provides inhalator jar, will be fitted into the inhalator jar after material filtering that step 3 obtains, loads onto valve Zha Gai, press
The weight ratio for impinging upon 5-10% in pre- aerial fog type metal decontamination polisher obtained is filled with propellant；
The propellant is dimethyl ether.
6. the preparation method of aerial fog type metal decontamination polisher as claimed in claim 5, which is characterized in that the aliphatic hydrocarbon is molten
Agent is Isopars, and boiling range is 190-230 DEG C.
7. the preparation method of aerial fog type metal decontamination polisher as claimed in claim 5, which is characterized in that the nonionic Emulsion
Agent is sorbitan fatty ester, hydroxyl value 190-220mgKOH/g, saponification number 140-160mgKOH/g, hydrophilic
Lipophilic balance value is between 4-6.
8. the preparation method of aerial fog type metal decontamination polisher as claimed in claim 5, which is characterized in that the modified Nano
The partial size of silica is 0.2-0.3 μm, specific surface area 150-250m2/g。
Priority Applications (1)
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| CN201610429355.1A CN106011864B (en) | 2016-06-16 | 2016-06-16 | Aerial fog type metal decontamination polisher and preparation method thereof |
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| CN201610429355.1A CN106011864B (en) | 2016-06-16 | 2016-06-16 | Aerial fog type metal decontamination polisher and preparation method thereof |
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| CN106011864B true CN106011864B (en) | 2019-10-08 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674928B (en) * | 2017-10-22 | 2019-10-25 | 三门华迈化工产品有限公司 | Leather maintaining agent and leather maintaining method |
| CN111304665A (en) * | 2019-10-18 | 2020-06-19 | 广东莱雅新化工科技有限公司 | Rust removing and preventing agent |
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|---|---|---|---|---|
| US3930870A (en) * | 1973-12-28 | 1976-01-06 | International Business Machines Corporation | Silicon polishing solution preparation |
| CN102277243A (en) * | 2010-06-11 | 2011-12-14 | 东莞市大洋化工有限公司 | Formula and process of detergent |
| CN102559417A (en) * | 2011-12-26 | 2012-07-11 | 田晓琴 | Detergent production process and formula |
| CN105586159A (en) * | 2014-10-21 | 2016-05-18 | 彭绍宾 | Preparation technology of foam cleaning agent for furniture cleaning |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1162491C (en) * | 2000-11-22 | 2004-08-18 | 上海白猫有限公司 | Metal polishing agent |
| CN101230310B (en) * | 2007-01-25 | 2012-02-08 | 3M创新有限公司 | Cleaning method and combination |
| CN101671529A (en) * | 2008-09-12 | 2010-03-17 | 张卫亚 | Decontamination glazing agent |
| CN101665747A (en) * | 2009-09-16 | 2010-03-10 | 广东三和化工科技有限公司 | Environment-friendly aerial fog type foam cleaning agent and preparation and filling method thereof |
-
2016
- 2016-06-16 CN CN201610429355.1A patent/CN106011864B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3930870A (en) * | 1973-12-28 | 1976-01-06 | International Business Machines Corporation | Silicon polishing solution preparation |
| CN102277243A (en) * | 2010-06-11 | 2011-12-14 | 东莞市大洋化工有限公司 | Formula and process of detergent |
| CN102559417A (en) * | 2011-12-26 | 2012-07-11 | 田晓琴 | Detergent production process and formula |
| CN105586159A (en) * | 2014-10-21 | 2016-05-18 | 彭绍宾 | Preparation technology of foam cleaning agent for furniture cleaning |
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