CN106433941A - Water-based graphite anti-rust cutting fluid - Google Patents
Water-based graphite anti-rust cutting fluid Download PDFInfo
- Publication number
- CN106433941A CN106433941A CN201610766832.3A CN201610766832A CN106433941A CN 106433941 A CN106433941 A CN 106433941A CN 201610766832 A CN201610766832 A CN 201610766832A CN 106433941 A CN106433941 A CN 106433941A
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- China
- Prior art keywords
- water
- cutting fluid
- based graphite
- rust preventive
- rust
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/22—Acids obtained from polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/042—Siloxanes with specific structure containing aromatic substituents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Abstract
The invention relates to a water-based graphite anti-rust cutting fluid, and relates to the technical field of industrial lubricants. The water-based graphite anti-rust cutting fluid comprises the components of, by weight, 12-18% of flake graphite powder with a specification of 800-1000 meshes, 3-5% of triethanolamine oleate, 1-4% of phenolic hydroxyl modified silicone oil, 1.5-3% of nano-grade cubic boron nitride particles, 2-5% of cetyldimethylammonium bromide, 2-4% of dimer acid potassium, 0.5-2% of a water-based de-foaming agent, and balance of deionized water. The water-based graphite anti-rust cutting fluid provided by the invention has the advantages of simple formula, good lubricating performance, good extreme pressure resistance and good anti-rust performance.
Description
Technical field
The present invention relates to industrial lubricants technical field, particularly to a kind of water-based graphite rust preventive cutting fluid.
Background technology
In order to eliminate or reducing the impact of heat in metal cutting, people use cutting fluid to participate in working angles, reach to take away heat
Purpose.The cutting fluid using at present can be divided into two big classes:I.e. oil base cutting fluid and water-base cutting fluid.Oil base cutting fluid is general
It is in various straight mineral oils, add the compositions such as polar additive, also have employing vegetable oil to do Main Ingredients and Appearance.Water-base cutting fluid
Being divided into emulsion and lysate two kinds, emulsion cutting fluid is oil and the emulsion of water, dissolve cutting fluid be add in water solvable
Property syntholube formed lysate.In high-speed cutting processing, cutting fluid occupies an important position, because it has profit
Sliding, cooling, antirust, reduce cutting force and improve the effects such as workpiece surface quality.
The Chinese invention patent of Application No. " 201010551635.2 " discloses a kind of Environmental Protection Cutting Fluid, this cutting fluid
There is good resistance to extreme pressure energy, but its existence component used is more, the complicated defect of compound method.
Content of the invention
The technical problem to be solved in the present invention is to provide a kind of formula and simply and has good anti-extreme pressure energy and rust-preventing characteristic
The water-based graphite rust preventive cutting fluid of energy.
In order to solve above-mentioned technical problem, the present invention adopts the following technical scheme that:A kind of water-based graphite rust preventive cutting fluid, by
Following components forms, and the weight proportion of each component is:The crystalline graphite powder 12-18% of 800-1000 mesh, triethanolamine oleate 3-
5%th, phenol light base modified silicon oil 1-4%, nano cubic boron nitride particle 1.5-3%, cetyl dimethyl ammonium bromide 2-5%, dimerization
Acid potassium 2-4%, aqueous defoamer 0.5-2%, balance of deionized water.
Preferably, the weight proportion of each component is:The crystalline graphite powder of 800-1000 mesh the 15%th, triethanolamine oleate the 4%th, phenol
Light base modified silicon oil 3%, nano cubic boron nitride particle 2%, cetyl dimethyl ammonium bromide the 4%th, dimeric dibasic acid potassium is the 3%th, aqueous to disappear
Infusion 1.5%, balance of deionized water.
What the present invention obtained has the beneficial effects that:Although the water-based graphite rust preventive cutting fluid formula that the present invention provides is simple,
Constituent species used is less, but through four ball measurings, it has higher P equallyBValue(Although than the environmental protection in background technology
Type cutting fluid is more lower slightly, but its anti-extreme pressure can be more much higher than common cutting fluid), good wear resistance and profit
Slip energy, through antirust Test Identification, this water-based graphite rust preventive cutting fluid also has than the Environmental Protection Cutting Fluid in background technology more
Adding outstanding rustless property, the preparation method of the water-based graphite rust preventive cutting fluid that the present invention provides is compared above-mentioned environment-friendly type and is cut in addition
Cut liquid also simply too much.
Detailed description of the invention
As one embodiment of the present invention, a kind of water-based graphite rust preventive cutting fluid, composed of the following components, each component
Weight proportion be:The crystalline graphite powder 12-18% of 800-1000 mesh, triethanolamine oleate 3-5%, phenol light base modified silicon oil 1-
4%, nano cubic boron nitride particle 1.5-3%, cetyl dimethyl ammonium bromide 2-5%, dimeric dibasic acid potassium 2-4%, aqueous defoamer
0.5-2%, balance of deionized water.
As one preferred embodiment, in this water-based graphite rust preventive cutting fluid, the weight proportion of each component is:800-
The light base modified silicon oil 3% of the crystalline graphite powder of 1000 mesh the 15%th, triethanolamine oleate the 4%th, phenol, nano cubic boron nitride particle 2%, ten
Six alkyl dimethyl ammonium bromides the 4%th, dimeric dibasic acid potassium the 3%th, aqueous defoamer 1.5%, balance of deionized water.
The method preparing above-mentioned water-based graphite rust preventive cutting fluid is:At ambient temperature and pressure, appropriate amount of deionized water is taken, first past
Wherein add nano cubic boron nitride particle, the crystalline graphite powder of 800-1000 mesh and triethanolamine oleate, ultrasonic emulsification 40-50
Minute, then add phenol light base modified silicon oil, cetyl dimethyl ammonium bromide, dimeric dibasic acid potassium, aqueous defoamer and residue
Deionized water, be uniformly mixed.
For the ease of the understanding of those skilled in the art, below in conjunction with 3 embodiments, the present invention is further illustrated.
Embodiment 1:
Prepare each component raw material according to the weight proportion of following components, at ambient temperature and pressure, take appropriate amount of deionized water and toward it
Middle addition nano cubic boron nitride particle, the crystalline graphite powder of 800-1000 mesh and triethanolamine oleate, ultrasonic emulsification 40-50 is divided
Clock, then adds phenol light base modified silicon oil, cetyl dimethyl ammonium bromide, dimeric dibasic acid potassium, aqueous defoamer and remaining
Deionized water, is uniformly mixed.
Each component and weight proportion thereof are:
The light base modified silicon oil 1% of the crystalline graphite powder of 800-1000 mesh the 12%th, triethanolamine oleate the 3%th, phenol, nano cubic boron nitride
Particle 3%, cetyl dimethyl ammonium bromide the 5%th, dimeric dibasic acid potassium the 4%th, aqueous defoamer 2%, balance of deionized water.
Hereafter, the water-based graphite rust preventive cutting fluid obtaining is divided into two parts, a by four its P of ball experiment testBValue is simultaneously
Measure it under the conditions of normal temperature, the speed of mainshaft 1450 revs/min, load 519N(With 201010551635.2 in background technology
Number patent experiment condition is identical)Wear scar diameter.Another part uses and " 201010551635.2 " number in background technology
The same mode of Chinese invention patent tests its rustless property.
In the present embodiment, water-based graphite rust preventive cutting fluid records its P through four ball experimentsBValue is 710N, and wear scar diameter is big
Little for 0.45mm.Its 33 hours antirust duration of antirust measurements determination.
Embodiment 2:
Embodiment 2 is compared with embodiment 1, and simply the weight proportion of each component changes, and other guide is identical, embodiment
The weight proportion of each component of 2 is as follows:
The weight proportion of each component is:The light base modified silicon of the crystalline graphite powder of 800-1000 mesh the 18%th, triethanolamine oleate the 5%th, phenol
Oil 4%, nano cubic boron nitride particle 1.5%, cetyl dimethyl ammonium bromide the 2%th, dimeric dibasic acid potassium the 2%th, aqueous defoamer 0.5%,
Balance of deionized water.
Hereafter, the water-based graphite rust preventive cutting fluid obtaining is divided into two parts, a by four its P of ball experiment testBValue is simultaneously
Measure it under the conditions of normal temperature, the speed of mainshaft 1450 revs/min, load 519N(With 201010551635.2 in background technology
Number patent experiment condition is identical)Wear scar diameter.Another part uses and " 201010551635.2 " number in background technology
The same mode of Chinese invention patent tests its rustless property.
In the present embodiment, water-based graphite rust preventive cutting fluid records its P through four ball experimentsBValue is 730N, and wear scar diameter is big
Little for 0.43mm, the antirust duration is 35 hours.
Embodiment 3:
Embodiment 3 is compared with embodiment 1, and simply the weight proportion of each component changes, and other guide is identical, embodiment
The weight proportion of each component of 3 is as follows:
The light base modified silicon oil 3% of the crystalline graphite powder of 800-1000 mesh the 15%th, triethanolamine oleate the 4%th, phenol, nano cubic boron nitride
Particle 2%, cetyl dimethyl ammonium bromide the 4%th, dimeric dibasic acid potassium the 3%th, aqueous defoamer 1.5%, balance of deionized water.
Hereafter, the water-based graphite rust preventive cutting fluid obtaining is divided into two parts, a by four its P of ball experiment testBValue is simultaneously
Measure it under the conditions of normal temperature, the speed of mainshaft 1450 revs/min, load 519N(With 201010551635.2 in background technology
Number patent experiment condition is identical)Wear scar diameter.Another part uses and " 201010551635.2 " number in background technology
The same mode of Chinese invention patent tests its rustless property.
In the present embodiment, water-based graphite rust preventive cutting fluid records its P through four ball experimentsBValue is 770N, and wear scar diameter is big
Little for 0.41mm.Its 35 hours antirust duration of antirust measurements determination.
By above-mentioned experimental result it can be seen that the present invention provide water-based graphite rust preventive cutting fluid greasy property and resistance to pole
Press functional, there is splendid rustless property simultaneously, and in the above-described embodiments, used by water-base cutting fluid, component is only 8
Kind(Including deionized water), and its manner of formulation to compare No. 201010551635.2 patents simply too much.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can realize with alternate manner,
On the premise of design without departing from the technical program, any obvious replacement is all within protection scope of the present invention.
Finally it should be emphasised that, in order to allow those of ordinary skill in the art understand the present invention relative to now more easily
Having the improvements of technology, some descriptions of the present invention have been simplified, and for the sake of clarity, present specification is also omitted
Some other elements, those of ordinary skill in the art it is to be appreciated that these elements omitting also may make up the interior of the present invention
Hold.
Claims (2)
1. a water-based graphite rust preventive cutting fluid, it is characterised in that composed of the following components and each component weight proportion is:
The crystalline graphite powder 12-18% of 800-1000 mesh, triethanolamine oleate 3-5%, phenol light base modified silicon oil 1-4%, nano cubic nitrogenizes
Boron particles 1.5-3%, cetyl dimethyl ammonium bromide 2-5%, dimeric dibasic acid potassium 2-4%, aqueous defoamer 0.5-2%, balance of go
Ionized water.
2. water-based graphite rust preventive cutting fluid according to claim 1, it is characterised in that the weight proportion of each component is:
The light base modified silicon oil 3% of the crystalline graphite powder of 800-1000 mesh the 15%th, triethanolamine oleate the 4%th, phenol, nano cubic boron nitride particle
2%, cetyl dimethyl ammonium bromide the 4%th, dimeric dibasic acid potassium the 3%th, aqueous defoamer 1.5%, balance of deionized water.
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CN201610766832.3A CN106433941A (en) | 2016-08-31 | 2016-08-31 | Water-based graphite anti-rust cutting fluid |
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CN201610766832.3A CN106433941A (en) | 2016-08-31 | 2016-08-31 | Water-based graphite anti-rust cutting fluid |
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CN106433941A true CN106433941A (en) | 2017-02-22 |
Family
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CN201610766832.3A Pending CN106433941A (en) | 2016-08-31 | 2016-08-31 | Water-based graphite anti-rust cutting fluid |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111088096A (en) * | 2019-12-30 | 2020-05-01 | 河北科技大学 | Graphene oxide grafted modified oleic soap, concentrated solution for hydraulic support, preparation method and application |
CN113430038A (en) * | 2021-06-23 | 2021-09-24 | 中国船舶重工集团公司第七0七研究所 | Cutting fluid with nano-particle trace lubrication cutting synergy and preparation method thereof |
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CN104342261A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Emulsified oil composition and use thereof |
CN104711106A (en) * | 2014-12-02 | 2015-06-17 | 青岛理工大学 | Novel cutting fluid capable of effectively reducing wear of titanium-alloy high-speed cutting tool |
CN105154203A (en) * | 2015-10-20 | 2015-12-16 | 湖南金化科技集团有限公司 | Water-based graphite finish rolling lubricant |
CN105441181A (en) * | 2015-12-25 | 2016-03-30 | 富耐克超硬材料股份有限公司 | Metal cutting fluid and preparation method thereof |
-
2016
- 2016-08-31 CN CN201610766832.3A patent/CN106433941A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104342261A (en) * | 2014-09-24 | 2015-02-11 | 中国石油化工股份有限公司 | Emulsified oil composition and use thereof |
CN104711106A (en) * | 2014-12-02 | 2015-06-17 | 青岛理工大学 | Novel cutting fluid capable of effectively reducing wear of titanium-alloy high-speed cutting tool |
CN105154203A (en) * | 2015-10-20 | 2015-12-16 | 湖南金化科技集团有限公司 | Water-based graphite finish rolling lubricant |
CN105441181A (en) * | 2015-12-25 | 2016-03-30 | 富耐克超硬材料股份有限公司 | Metal cutting fluid and preparation method thereof |
Non-Patent Citations (1)
Title |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111088096A (en) * | 2019-12-30 | 2020-05-01 | 河北科技大学 | Graphene oxide grafted modified oleic soap, concentrated solution for hydraulic support, preparation method and application |
CN113430038A (en) * | 2021-06-23 | 2021-09-24 | 中国船舶重工集团公司第七0七研究所 | Cutting fluid with nano-particle trace lubrication cutting synergy and preparation method thereof |
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