CN106431411A - T6-type carbon nano-modified silicon carbide ceramic-based composite material - Google Patents
T6-type carbon nano-modified silicon carbide ceramic-based composite material Download PDFInfo
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- CN106431411A CN106431411A CN201610524796.XA CN201610524796A CN106431411A CN 106431411 A CN106431411 A CN 106431411A CN 201610524796 A CN201610524796 A CN 201610524796A CN 106431411 A CN106431411 A CN 106431411A
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- Prior art keywords
- silicon carbide
- type carbon
- carbon nano
- carbide ceramic
- composite material
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/6303—Inorganic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The present invention provides a T6-type carbon nano-modified silicon carbide ceramic-based composite material. The material is prepared by the following steps: firstly, T6-type carbon nano powders and silicon carbide ceramic powders are mixed up; secondly, water and a dispersing agent are added into the above mixed materials; thirdly, an obtained mixture is stirred and ground to obtain a composite slurry; fourthly, the composite slurry is subjected to spray-drying and granulating to prepare spherical particles. In the composite material, the content of T6-type carbon nano powders is 10-15%. According to the technical scheme of the T6-type carbon nano-modified silicon carbide ceramic-based composite material, the silicon carbide ceramics is modified by T6-type carbon nano powders, so that the mechanical machining performance of the silicon carbide ceramics is improved.
Description
Technical field
The present invention relates to a kind of T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite, belong to ceramic material technology neck
Territory.
Background technology
As structural material applications widely, its excellent properties such as hardness is high, intensity is high, antioxygen for silicon carbide ceramics
Change and corrosion-resistant very prominent, rising especially as high-temperature material.But obtain the carbonization of good properties at high temperature
The technique of silicon pottery is often more complicated, and cost is also higher.
SiC ceramic not only has excellent ambient temperature mechanical properties, such as high bending strength, excellent non-oxidizability, good
Corrosion resistance, high wear-resistant and low coefficient of friction, and mechanical behavior under high temperature (intensity, creep resistance etc.) is known
In ceramic material optimal.Hot pressed sintering, pressureless sintering, the material of HIP sintering, its elevated temperature strength can be maintained to
1600 DEG C, be the material that in ceramic material, elevated temperature strength is best.Non-oxidizability is also best in all non-oxide ceramicses.
SiC ceramic obtains at industrial circles such as oil, chemical industry, microelectronics, automobile, space flight, aviation, papermaking, laser, mining industry and atomic energy
It is widely applied.
The shortcoming of SiC ceramic is that fracture toughness is relatively low, i.e. fragility is relatively big, is this complex phase with SiC ceramic as base in recent years
Pottery, such as fiber (or whisker) reinforcement, out-phase is dispersed particle-strengthened and function-graded material occurs in succession, improves monomer
The toughness of material and intensity.
Content of the invention
In place of it is an object of the invention to overcome the deficiencies in the prior art, provide a kind of T6 type carbon nanometer-carbon modified SiClx pottery
Porcelain based composites.
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes, by the following method by T6 type carbon
After nano-powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, by being spray-dried
Spheric granules is made in granulation, and in described composite, the content of T6 type carbon nanometer is 10-15%.
Described dispersant is PEG400 or PEG600.
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, by T6 type carbon nano modification carborundum
Pottery, enhances the machining property of silicon carbide ceramics.
Detailed description of the invention
Embodiment 1
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes by the following method, by T6 type carbon nanometer
After powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, passes through spray drying granulation
Making spheric granules, in described composite, the content of T6 type carbon nanometer is 10%.Described dispersant be PEG400 or
PEG600 .
Embodiment 2
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes by the following method, by T6 type carbon nanometer
After powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, passes through spray drying granulation
Making spheric granules, in described composite, the content of T6 type carbon nanometer is 15%.Described dispersant be PEG400 or
PEG600 .
Embodiment 3
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes by the following method, by T6 type carbon nanometer
After powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, passes through spray drying granulation
Making spheric granules, in described composite, the content of T6 type carbon nanometer is 12%.Described dispersant be PEG400 or
PEG600 .
Claims (2)
1.T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite, it is characterised in that make by the following method, by T6 type
After carbon nanopowder body and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, dry by spraying
Spheric granules is made in dry granulation, and in described composite, the content of T6 type carbon nanometer is 10-15%.
2. T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite according to claim 1, it is characterised in that described
Dispersant be PEG400 or PEG600.
Priority Applications (1)
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CN201610524796.XA CN106431411A (en) | 2016-07-06 | 2016-07-06 | T6-type carbon nano-modified silicon carbide ceramic-based composite material |
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CN201610524796.XA CN106431411A (en) | 2016-07-06 | 2016-07-06 | T6-type carbon nano-modified silicon carbide ceramic-based composite material |
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CN106431411A true CN106431411A (en) | 2017-02-22 |
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CN201610524796.XA Pending CN106431411A (en) | 2016-07-06 | 2016-07-06 | T6-type carbon nano-modified silicon carbide ceramic-based composite material |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115304389A (en) * | 2022-08-23 | 2022-11-08 | 山东大学 | Silicon carbide ceramic matrix composite slurry for direct-writing forming 3D printing and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101293772A (en) * | 2008-05-30 | 2008-10-29 | 上海工程技术大学 | Preparation technique for SiC/CNTs composite ceramic |
CN101774814A (en) * | 2010-01-14 | 2010-07-14 | 天津大学 | Ceramic and carbon nano-fiber composite material and preparation method thereof |
CN102731094A (en) * | 2012-06-11 | 2012-10-17 | 上海德宝密封件有限公司 | Silicon carbide-nano carbon tube composite toughened sealing wearing ring and preparation method thereof |
CN105060896A (en) * | 2015-08-13 | 2015-11-18 | 青岛科技大学 | Preparation method of silicon carbide ceramic precision device |
-
2016
- 2016-07-06 CN CN201610524796.XA patent/CN106431411A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101293772A (en) * | 2008-05-30 | 2008-10-29 | 上海工程技术大学 | Preparation technique for SiC/CNTs composite ceramic |
CN101774814A (en) * | 2010-01-14 | 2010-07-14 | 天津大学 | Ceramic and carbon nano-fiber composite material and preparation method thereof |
CN102731094A (en) * | 2012-06-11 | 2012-10-17 | 上海德宝密封件有限公司 | Silicon carbide-nano carbon tube composite toughened sealing wearing ring and preparation method thereof |
CN105060896A (en) * | 2015-08-13 | 2015-11-18 | 青岛科技大学 | Preparation method of silicon carbide ceramic precision device |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115304389A (en) * | 2022-08-23 | 2022-11-08 | 山东大学 | Silicon carbide ceramic matrix composite slurry for direct-writing forming 3D printing and preparation method thereof |
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Application publication date: 20170222 |