CN106431411A - T6-type carbon nano-modified silicon carbide ceramic-based composite material - Google Patents

T6-type carbon nano-modified silicon carbide ceramic-based composite material Download PDF

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Publication number
CN106431411A
CN106431411A CN201610524796.XA CN201610524796A CN106431411A CN 106431411 A CN106431411 A CN 106431411A CN 201610524796 A CN201610524796 A CN 201610524796A CN 106431411 A CN106431411 A CN 106431411A
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China
Prior art keywords
silicon carbide
type carbon
carbon nano
carbide ceramic
composite material
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CN201610524796.XA
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Chinese (zh)
Inventor
朱爱民
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Nantong Su Chemical Fiber Co Ltd
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Nantong Su Chemical Fiber Co Ltd
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Priority to CN201610524796.XA priority Critical patent/CN106431411A/en
Publication of CN106431411A publication Critical patent/CN106431411A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422Carbon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Products (AREA)

Abstract

The present invention provides a T6-type carbon nano-modified silicon carbide ceramic-based composite material. The material is prepared by the following steps: firstly, T6-type carbon nano powders and silicon carbide ceramic powders are mixed up; secondly, water and a dispersing agent are added into the above mixed materials; thirdly, an obtained mixture is stirred and ground to obtain a composite slurry; fourthly, the composite slurry is subjected to spray-drying and granulating to prepare spherical particles. In the composite material, the content of T6-type carbon nano powders is 10-15%. According to the technical scheme of the T6-type carbon nano-modified silicon carbide ceramic-based composite material, the silicon carbide ceramics is modified by T6-type carbon nano powders, so that the mechanical machining performance of the silicon carbide ceramics is improved.

Description

T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite
Technical field
The present invention relates to a kind of T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite, belong to ceramic material technology neck Territory.
Background technology
As structural material applications widely, its excellent properties such as hardness is high, intensity is high, antioxygen for silicon carbide ceramics Change and corrosion-resistant very prominent, rising especially as high-temperature material.But obtain the carbonization of good properties at high temperature The technique of silicon pottery is often more complicated, and cost is also higher.
SiC ceramic not only has excellent ambient temperature mechanical properties, such as high bending strength, excellent non-oxidizability, good Corrosion resistance, high wear-resistant and low coefficient of friction, and mechanical behavior under high temperature (intensity, creep resistance etc.) is known In ceramic material optimal.Hot pressed sintering, pressureless sintering, the material of HIP sintering, its elevated temperature strength can be maintained to 1600 DEG C, be the material that in ceramic material, elevated temperature strength is best.Non-oxidizability is also best in all non-oxide ceramicses. SiC ceramic obtains at industrial circles such as oil, chemical industry, microelectronics, automobile, space flight, aviation, papermaking, laser, mining industry and atomic energy It is widely applied.
The shortcoming of SiC ceramic is that fracture toughness is relatively low, i.e. fragility is relatively big, is this complex phase with SiC ceramic as base in recent years Pottery, such as fiber (or whisker) reinforcement, out-phase is dispersed particle-strengthened and function-graded material occurs in succession, improves monomer The toughness of material and intensity.
Content of the invention
In place of it is an object of the invention to overcome the deficiencies in the prior art, provide a kind of T6 type carbon nanometer-carbon modified SiClx pottery Porcelain based composites.
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes, by the following method by T6 type carbon After nano-powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, by being spray-dried Spheric granules is made in granulation, and in described composite, the content of T6 type carbon nanometer is 10-15%.
Described dispersant is PEG400 or PEG600.
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, by T6 type carbon nano modification carborundum Pottery, enhances the machining property of silicon carbide ceramics.
Detailed description of the invention
Embodiment 1
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes by the following method, by T6 type carbon nanometer After powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, passes through spray drying granulation Making spheric granules, in described composite, the content of T6 type carbon nanometer is 10%.Described dispersant be PEG400 or PEG600 .
Embodiment 2
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes by the following method, by T6 type carbon nanometer After powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, passes through spray drying granulation Making spheric granules, in described composite, the content of T6 type carbon nanometer is 15%.Described dispersant be PEG400 or PEG600 .
Embodiment 3
The T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite of the present invention, makes by the following method, by T6 type carbon nanometer After powder and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, passes through spray drying granulation Making spheric granules, in described composite, the content of T6 type carbon nanometer is 12%.Described dispersant be PEG400 or PEG600 .

Claims (2)

1.T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite, it is characterised in that make by the following method, by T6 type After carbon nanopowder body and Silicon Carbide Powder mixing, after adding water, dispersant, stirring grinding becomes composite mortar, dry by spraying Spheric granules is made in dry granulation, and in described composite, the content of T6 type carbon nanometer is 10-15%.
2. T6 type carbon nanometer-modification carbon/silicon carbide ceramic matrix composite according to claim 1, it is characterised in that described Dispersant be PEG400 or PEG600.
CN201610524796.XA 2016-07-06 2016-07-06 T6-type carbon nano-modified silicon carbide ceramic-based composite material Pending CN106431411A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610524796.XA CN106431411A (en) 2016-07-06 2016-07-06 T6-type carbon nano-modified silicon carbide ceramic-based composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610524796.XA CN106431411A (en) 2016-07-06 2016-07-06 T6-type carbon nano-modified silicon carbide ceramic-based composite material

Publications (1)

Publication Number Publication Date
CN106431411A true CN106431411A (en) 2017-02-22

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CN201610524796.XA Pending CN106431411A (en) 2016-07-06 2016-07-06 T6-type carbon nano-modified silicon carbide ceramic-based composite material

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115304389A (en) * 2022-08-23 2022-11-08 山东大学 Silicon carbide ceramic matrix composite slurry for direct-writing forming 3D printing and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101293772A (en) * 2008-05-30 2008-10-29 上海工程技术大学 Preparation technique for SiC/CNTs composite ceramic
CN101774814A (en) * 2010-01-14 2010-07-14 天津大学 Ceramic and carbon nano-fiber composite material and preparation method thereof
CN102731094A (en) * 2012-06-11 2012-10-17 上海德宝密封件有限公司 Silicon carbide-nano carbon tube composite toughened sealing wearing ring and preparation method thereof
CN105060896A (en) * 2015-08-13 2015-11-18 青岛科技大学 Preparation method of silicon carbide ceramic precision device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101293772A (en) * 2008-05-30 2008-10-29 上海工程技术大学 Preparation technique for SiC/CNTs composite ceramic
CN101774814A (en) * 2010-01-14 2010-07-14 天津大学 Ceramic and carbon nano-fiber composite material and preparation method thereof
CN102731094A (en) * 2012-06-11 2012-10-17 上海德宝密封件有限公司 Silicon carbide-nano carbon tube composite toughened sealing wearing ring and preparation method thereof
CN105060896A (en) * 2015-08-13 2015-11-18 青岛科技大学 Preparation method of silicon carbide ceramic precision device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115304389A (en) * 2022-08-23 2022-11-08 山东大学 Silicon carbide ceramic matrix composite slurry for direct-writing forming 3D printing and preparation method thereof

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Application publication date: 20170222