CN106431206A - Spherical illite light through-hole ceramsite with air purification function - Google Patents
Spherical illite light through-hole ceramsite with air purification function Download PDFInfo
- Publication number
- CN106431206A CN106431206A CN201610831048.6A CN201610831048A CN106431206A CN 106431206 A CN106431206 A CN 106431206A CN 201610831048 A CN201610831048 A CN 201610831048A CN 106431206 A CN106431206 A CN 106431206A
- Authority
- CN
- China
- Prior art keywords
- illite
- air purification
- spheroidal
- lightweight
- purification function
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 229910052900 illite Inorganic materials 0.000 title claims abstract description 157
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 title claims abstract description 157
- 238000004887 air purification Methods 0.000 title claims abstract description 116
- 239000000843 powder Substances 0.000 claims abstract description 48
- 239000004927 clay Substances 0.000 claims abstract description 44
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 238000001035 drying Methods 0.000 claims abstract description 29
- 229960000892 attapulgite Drugs 0.000 claims abstract description 28
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 14
- 239000002699 waste material Substances 0.000 claims abstract description 13
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001388 sodium aluminate Inorganic materials 0.000 claims abstract description 7
- 238000005507 spraying Methods 0.000 claims abstract description 4
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 15
- 239000008187 granular material Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 9
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- 239000010451 perlite Substances 0.000 claims description 8
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- 238000009413 insulation Methods 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- RZYKUPXRYIOEME-UHFFFAOYSA-N CCCCCCCCCCCC[S] Chemical compound CCCCCCCCCCCC[S] RZYKUPXRYIOEME-UHFFFAOYSA-N 0.000 claims 1
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract description 5
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 4
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- 229910021536 Zeolite Inorganic materials 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
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- 241000196324 Embryophyta Species 0.000 description 3
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- 239000002689 soil Substances 0.000 description 3
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- 241001116389 Aloe Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000331528 Chlorophytum capense Species 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
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- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
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- 241001330002 Bambuseae Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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- 241001312214 Epipremnum aureum Species 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5116—Ag or Au
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
-
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Abstract
The invention discloses a spherical illite light through-hole ceramsite with an air purification function. The technical scheme has the key points that: ingredients comprise attapulgite argil powder with an air purification function, illite, activated clay waste residues, white carbon black, activated aluminum oxide, sodium aluminate, sodium dodecyl sulfate, photocatalyst spraying liquid capable of being used for scrubbing the illite and the like; stirring, squeezing granulation, drying, roasting, heat preservation, screening, soaking, drying, screening and sealed packaging are carried out on the ingredients, so as to obtain the spherical illite light through-hole ceramsite with the air purification function. The spherical illite light through-hole ceramsite with the air purification function has the characteristics of large specific surface area, low stacking density, high rate of moisture absorption, superior adsorption performance, light weight, good strength and integrated micropores and macropores and is suitable for being placed indoors and in furniture, cupboards, vehicles, airplanes, ships or other buildings for adsorbing and degrading contaminants such as formaldehyde, ammonia, benzene, TVOC (total volatile organic compounds) and the like, so as to achieve the purpose of air purification.
Description
Technical field
The present invention relates to haydite, and in particular to a kind of spheroidal has the illite lightweight through hole pottery of air purification function
Grain.
Background technology
The air purifying preparation that supplies in the market has following several types：Absorbent-type air purifying preparation, covering type taste removal
Product and Breakdown type taste removal product.Absorbent-type air purifying preparation be using materials such as activated carbon, bamboo charcoal, molecular sieve, mineral
The performance such as physical absorption, chemisorbed, catalysis oxidation and reduction removes the purification product of pollutant；Covering type taste removal product is profit
The various abnormal flavour of in the air are covered with the fragrance of aromatic hydrocarbon, abnormal flavour is not in fact removed by a lot of air fresheners, simply
With a kind of odor type, abnormal flavour is covered；Breakdown type air clearing product is more rare on the market.
Chinese patent Authorization Notice No.：103861421 B of CN, authorized announcement date：On November 18th, 2015, entitled " one
Kind of air purifying preparation ", discloses that " a kind of air purifying preparation, its preparing raw material is contained by mass fraction：Diatomite in powder, zeolite powder,
Medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder, and adopt and prepare with the following method：1) by kieselguhr
Powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder mixing；2) by step 1) gained mix
Compound pelletize；3) baking step 2) gained mixture after pelletize.Air purifying preparation specific surface obtained in the present invention is big and uniform,
Good to the adsorption-decomposition function effect of in the air harmful substance, be for interior, the depollution of environment of the closing space such as in-car and various skies
The ideal chose material of gas purifier ".
The weak point of above-mentioned patent is：(1) diatomite in powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder and sea
Afrodite powder is not through necessary modification, it is difficult to really play the effect of its effective purify air.(2) gained mixed powder
Granulating disc pelletize is adopted after the clear water stirring for adding 20-30%, be a kind of circular granular of a diameter of 1.2-1.6mm.Should
Itself normal moisture content of the mixed powder of invention is more than 10%, and the circular granular moisture content after the pelletize that adds water will be greater than 30%, and
Drying temperature less than in the case of 100 DEG C, it is difficult to circular granular be dried in 3 hours.Kieselguhr, zeolite, Maifanitum,
After tourmaline and meerschaum carry out heat treatment process at 250～450 DEG C, its absorption property is relatively good, and this is the technology of this area
Personnel know altogether；The circular granular of the invention is dried in the case of less than 100 DEG C, can not effectively improve the work of purify air
With, and the comprcssive strength of circular granular also very little, gently one pinched with handss, circular granular will be crumbed as powdered.
Spheroidal air purifying preparation, molecular sieve, desiccant or the other spherical granules that supplies on market, in pelletize
It is first powdery dispensing to be processed into a kind of bead of diameter less than 0.5 millimeter, then by the vaporific aqueous solution for preparing, spray in journey
Spill in the bead in comminutor in operation, then powdery dispensing is trickled down the surface of the bead in moistening, through being repeated several times
The vaporific aqueous solution of sprinkling and powdery dispensing is trickled down the surface of the bead in moistening, through the parcel of layer upon layer, bead
Volume constantly increase, be finally completed the overall process of pelletize, be prepared into a kind of spherical granules, due to spherical granules internal junction
Structure is very closely knit, greatly reduces the effective specific surface area of spherical granules, the proportion of spherical granules and bulk density all than
Larger, directly influence the absorption purifying effect of spherical granules.
Content of the invention
The purpose of the present invention is to overcome weak point in prior art, provides a kind of spheroidal and has air purification function
Illite lightweight through hole haydite.
Spheroidal has the dispensing of the illite lightweight through hole haydite of air purification function by with air purification function
Attapulgite potter's clay powder, illite, active white clay waste slag, white carbon, precipitated calcium carbonate, light magnesium oxide, activated alumina, aluminic acid
Sodium, cenosphere, gesso, expanded perlite, sodium lauryl sulphate and washable illite photocatalytic spray liquid composition.
Spheroidal has the production method of the illite lightweight through hole haydite of air purification function：Spheroidal is had and is purified
The dispensing of the illite lightweight through hole semi-finished product of air function is stirred, extruder grain, drying, roasting, insulation, sieve
Divide, soak, drying, sieving, packing the illite lightweight through hole haydite that there is air purification function for spheroidal.
Attapulgite potter's clay powder with air purification function is by high viscous Concave-convex clay rod, attapulite constant humidity amendment, day
So mineral adsorption filtering agent, Cacumen Platycladi, aluminium silicate fiber peacekeeping polyacrylamide composition, with preferable caking property, plasticity, touch
Degeneration, fire resistance and heat stability, can effectively adsorb harmful substance, environmental protection and the enhancements such as formaldehyde in air, ammonia and benzene
People's is healthy, and the present invention selects fineness of the particles≤0.074 millimeter of the attapulgite potter's clay powder with air purification function.
Illite is a kind of sedimentary rock, complicated component, but all has the joint of thin laminated or thin slice stratiform, mainly by sticking
The rock that soil deposition is formed through pressure and temperature, but quartz, the chip of Anhydrite and other chemical substances is wherein contaminated with, utilize
The product produced by illite has that body is light, insulation, energy-conservation the features such as, the present invention selects illitic fineness of the particles≤0.074
Millimeter.
Active hargil is a kind of odorless, tasteless, nontoxic white or cream-coloured powder or granule, and the activity after decolourizing is white
Soil loses activity and becomes active white clay waste slag, and these active white clay waste slags are all abandoned by some oily factories, if cannot and
When process, produces after the fermentation of lipid organic matter in active white clay waste slag and goes mouldy and stench, the not only wasting of resources, pollute environment and
Groundwater quality, and fire hazardous, will cause certain loss to society and enterprise；The present invention is from active white clay waste slag
Fineness of the particles≤0.149 millimeter.
White carbon is a kind of ultra tiny inorganic porous property material, due to its particle diameter very little, with specific surface area is big, surface is inhaled
Attached power is strong, chemical purity is high, dispersive property is good, superior stability, reinforcing, thickening property, adhesive force and thixotropy etc. are special
Performance.
Precipitated calcium carbonate fine particles, surface are rougher, and specific surface area is big, and precipitated calcium carbonate easily divides also with not settling
Dissipate, the characteristic such as good luster, the present invention is from fineness of the particles≤0.074 millimeter of precipitated calcium carbonate.
Light magnesium oxide is the loose unformed powder of white lightweight, odorless, tasteless, and nontoxic, volume shared by light magnesium oxide is about
Three times for heavy-burned magnesia or so, have an extremely fireproof heat-insulating property, reinforcing agent, adhesive, and the present invention selects light magnesium oxide
Fineness of the particles≤0.074 millimeter.
Activated alumina is the solid material of a kind of porous, high degree of dispersion, has very big surface area, its micropore surface tool
Standby characteristic required by catalytic action, such as absorption property, surface activity, excellent heat stability etc., so be widely used as
The catalyst of chemical reaction and catalyst carrier, the present invention is from fineness of the particles≤0.074 millimeter of activated alumina.
Sodium aluminate also known as sodium metaaluminate, are a kind of general chemical articles, white, odorless, tasteless, in alkaline solid,
Moisture content and carbon dioxide are easily absorbed in atmosphere, the present invention is from fineness of the particles≤0.074 millimeter of sodium aluminate.
Natural dihydrate gypsum is also called Gypsum Fibrosum, through calcining, levigate obtain gesso, Gypsum Fibrosum preparata has more micropore
Structure, is allowed to have excellent sound insulation, heat-insulated and fire protecting performance, and the present invention is from fineness of the particles≤0.074 millimeter of gesso.
Cenosphere outward appearance is canescence, is a kind of loose, powder body material of good fluidity, and cenosphere proportion is little, table
Face is smooth, intensity is big, easily disperse, the present invention from cenosphere fineness of the particles≤≤ 0.149 millimeter.
Perlite is expanded and becomes a kind of lightweight, multifunctional novel shaped material, with apparent density light, heat conductivity is low,
The features such as chemical stability is good, the present invention is from fineness of the particles≤0.074 millimeter of expanded perlite.
Sodium lauryl sulphate is white or faint yellow powdery, is dissolved in water, insensitive to alkali and hard water, with decontamination, breast
Change and excellent foaming power, be a kind of nontoxic anion surfactant.
Washable illite photocatalytic spray liquid is sprayed on building or decorative material surface, under the irradiation of light, permissible
Continual absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene,toluene,xylene, TVOC, and with extremely strong sterilization, remove
Smelly, mould proof, anti-fouling and self-cleaning and the function of purify air.
The technical scheme is that：
1st, spheroidal has the dispensing of the illite lightweight through hole haydite of air purification function by weight percentage by following component
Composition：Spheroidal has the illite lightweight through hole semi-finished product 55～95% of air purification function and washable illite light
Catalyzed spraying liquid 5～45%.
2nd, spheroidal has the production method of the illite lightweight through hole haydite of air purification function：First by washable she
Sharp stone photocatalytic spray liquid is put in fermentation vat, then spheroidal is had the illite lightweight through hole haydite half of air purification function
Finished product is slowly added in the washable illite photocatalytic spray liquid in fermentation vat, and spheroidal has the Erie of air purification function
Micropore inside and outside stone lightweight through hole semi-finished product, constantly sucks washable illite photocatalytic spray liquid, until being in saturation
State；From fermentation vat take out be filled washable illite photocatalytic spray liquid spheroidal have air purification function she
Sharp stone lightweight through hole haydite, is transported in low temperature rotary drying oven and is dried, and drying temperature controls at 150～180 DEG C, dries
Dry time control was at 1～3 hour；(3) the spheroidal after oven drying at low temperature is had the illite lightweight through hole pottery of air purification function
Grain is transported in flat vibrating screen and is sieved, and weeds out broken granule and powder, packs and has purification for spheroidal
The finished product of the illite lightweight through hole haydite of air function.
3rd, spheroidal has the dispensing of the illite lightweight through hole semi-finished product of air purification function by weight percentage
It is made up of following component：Attapulgite potter's clay powder 10～45%, illite 5～25%, active hargil with air purification function
Waste residue 2～10%, white carbon 1～8%, precipitated calcium carbonate 1～5%, light magnesium oxide 1～5%, activated alumina 1～5%,
Sodium aluminate 0.5～5%, cenosphere 0.5～5%, gesso 0.5～5%, expanded perlite 0.5～5%, dodecyl
Sodium sulfate 0.5～5% and water 10～40%.
4th, spheroidal has the production method of the illite lightweight through hole semi-finished product of air purification function：(1) by ball
Shape has in the stirring mixer that the dispensing input of the illite lightweight through hole semi-finished product of air purification function has operated,
Stirring is mixed into the mixture that spheroidal has the illite lightweight through hole haydite of air purification function；(2) spheroidal is had net
The mixture for changing the illite lightweight through hole haydite of air function is transported in Squeezinggranulator, and extruder grain has for spheroidal
The illite lightweight through hole haydite blank material of air purification function, spheroidal has the illite lightweight through hole of air purification function
The macropore at haydite blank material center is through hole；(3) spheroidal is had the illite lightweight through hole haydite blank of air purification function
Material is transported in swinging drying oven is dried, and drying temperature control is at 200～250 DEG C, and drying time control is little 1～4
When；(4) the illite lightweight through hole haydite blank material for the spheroidal after drying being had air purification function is transported to swinging roasting
Kiln roasting is burnt, the temperature control of combustor is at 900～950 DEG C, and roasting time controlled at 1～3 hour；(5) by the circle after roasting
The spherical illite lightweight through hole haydite blank material with air purification function, input is incubated in rustless steel cylinder storehouse, during insulation
Between control at 24～72 hours；(6) the spheroidal after insulation cooling is had the illite lightweight through hole haydite of air purification function
Blank material is transported in roller vibrating screen and is sieved, and weeds out broken granule and powder and has purify air work(for spheroidal
The illite lightweight through hole semi-finished product of energy.
5th, the production method of the attapulgite potter's clay powder with air purification function is：(1) by with the recessed of air purification function
It is input in pulverizer after the dispensing mixing of convex rod potter's clay powder and is crushed, the compound particles fineness after crushing is less than 0.5 millimeter；
(2) pulverulent mixture is added and soak that to be carried out in old pond soaking old process with water be semi-finished product, soak old time control and exist
7～30 days；(3) semi-finished product are input in vacuum-extruder and cylindrical bar is squeezed into, the diameter control of cylindrical bar exists
2～10 millimeters；(4) cylindrical bar being input to cement threshing ground carries out dry in the sun, and the cylindrical bar water content after dry in the sun is little
In 15%；(5) pulverizing will be carried out for powder in the cylindrical bar input grinding machine after dry in the sun, the fineness of the particles of powder is little
In 0.074 millimeter.
The dispensing of the attapulgite potter's clay powder with air purification function is made up of following component by weight percentage：High viscous recessed
Convex rod stone clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Cacumen Platycladi 2
～15%, alumina silicate fibre 1～5% and polyacrylamide 0.1～3%.
Attapulgite potter's clay powder with air purification function is using being applied on 2 25th, 2011 by the present inventor
" the attapulgite potter's clay powder with air purification function ", Chinese patent Authorization Notice No. is：102173743 B of CN, Granted publication
Day：On July 25th, 2012.
High viscous Concave-convex clay rod is glued using the attapulgite of the processing technique production for improving viscosity of attapulgite clay
Soil, from the attapulgite clay of mining area exploitation, needs the weathering through 30～120 days；Modification processing method is：With weight
Percentage ratio is calculated, and is taken the attapulgite clay after weathering 94～98%, is uniformly added into 2～6% sodium carbonate, common input leaching
In bubble pond, clear water is added to carry out immersion ageing, soak time is 72～120 hours；Take the attapulgite clay after soaking, input
Being stirred in blender, and by the attapulgite clay after stirring, thin slice being extruded into through extruder, its THICKNESS CONTROL is 0.5～2
Millimeter, attapulgite clay thin slice carries out dry in the sun, the attapulgite clay thin slice after dry in the sun, its water content≤15%；Dispensing
Calculated in weight percent：Attapulgite clay 94～98%, High hydrophilous resin 0.5～5% after dry in the sun and cellulose 0.5～
3%, above-mentioned dispensing is stirred, after stirring, in input grinding machine, carries out pulverizing, fineness of the particles≤0.074 millimeter；
Above-mentioned production technology is " to improve viscosity of attapulgite clay using filed in 20 days June in 2005 of the present inventor
Processing technique ", Chinese patent Authorization Notice No. is：CN 1317067C, authorized announcement date：On May 23rd, 2007.
The detection method of high viscous Concave-convex clay rod：28.0g attapulgite clay powder sample is taken, adds homogenizer
In suspension cup, 372g water is added, suspension cup is placed on homogenizer, stir under 11000 revs/min of rotating speed
20 minutes, then by the beaker that high-speed stirred sample suspension pours 250mL into, tested using NDJ-1 type rotating cylinder viscometer
The viscosity of suspension, tested viscosity value >=2200 mPa s is high viscous Concave-convex clay rod.
6th, the dispensing of washable illite photocatalytic spray liquid is made up of following component by weight percentage：Illite 5～
12%th, attapulgite clay after the acidify 4～10%, high viscous Concave-convex clay rod 2～8%, nano titanium oxide 1～5%, white
White carbon black 1～5%, nano silver-supported antibacterial powder 0.5～5%, nano magnesia 0.5～5%, nano zirconium dioxide 0～5%, nanometer
Aluminium oxide 0～5%, nano zine oxide 0～5%, polyvinyl alcohol 0.5～5%, Polyethylene Glycol 0.1～3%, polydimethylsiloxanes
Alkane 0.1～2% and deionized water 50～82%；
The production method of washable illite photocatalytic spray liquid：(1) the dispensing of washable illite photocatalytic spray liquid is input into
Strong stirring, dispersion and emulsifying is carried out in the high speed dispersor for having operated, and is then ground in input three-roll grinder erasable
Wash the semi-finished product of illite photocatalytic spray liquid；(2) the semi-finished product of washable illite photocatalytic spray liquid are input into colloid mill
In, carry out again disperseing, emulsifying, crushing, homogenizing, froth breaking and grinding；(3) the washable illite photocatalytic spray liquid after grinding
Granularity≤0.01 millimeter of middle solid particle, canned for washable illite photocatalytic spray liquid.
Washable illite photocatalytic spray liquid be using by " washable filed in the applicant on 07 29th, 2016
Illite photocatalytic spray liquid ", Chinese Patent Application No. is：201610612681.6.
Heretofore described PCm is weight percentage.
There are substantial amounts of micropore and activated carbon in the attapulgite potter's clay powder with air purification function in the present invention, with relatively
Good caking property, plasticity, thixotropy, fire resistance and heat stability, can effectively adsorb formaldehyde in air, ammonia and benzene etc. harmful
Material.
It is primary raw material using the attapulgite potter's clay powder with air purification function, production spheroidal has purify air work(
The illite lightweight through hole haydite of energy, has given full play to the effective efficiency of the attapulgite potter's clay powder with air purification function.
Illite has rich potassium, high alumina, low ferrum and superior chemistry, the physical property such as smooth, bright, fine and smooth, heat-resisting, she
Sharp stone can free anion releasing and far infrared, can improve spheroidal have air purification function illite lightweight through hole pottery
The absorbability of grain, increases the granule strength that spheroidal has the illite lightweight through hole haydite of air purification function.
Active white clay waste slag is in roasting process, and the lipid in active white clay waste slag and organic matter participate in spheroidal tool jointly
Have the roasting of the illite lightweight through hole haydite of air purification function, improve the heat of combustion-gas flow, not only can save energy,
The inside for also helping the illite lightweight through hole haydite that spheroidal has air purification function can be grilled thoroughly completely, increase spheroidal
The porosity inside illite lightweight through hole haydite with air purification function.
White carbon, light magnesium oxide, activated alumina and sodium aluminate can improve spheroidal have air purification function she
The absorbability of sharp stone lightweight through hole haydite, increase spheroidal have air purification function illite lightweight through hole haydite
Grain intensity.
Spheroidal has using dodecyl in the dispensing of the illite lightweight through hole semi-finished product of air purification function
Sodium sulfate, is conducive to produce substantial amounts of foam in stirring mixed process, has air purification function to increase spheroidal
Micropore inside illite lightweight through hole haydite.
Precipitated calcium carbonate, gesso, cenosphere and expanded perlite can reduce spheroidal and have air purification function
Illite lightweight through hole haydite bulk density, increase spheroidal and there is the illite lightweight through hole haydite of air purification function
Internal porosity.
The spheroidal for sucking washable illite photocatalytic spray liquid has the illite lightweight through hole of air purification function
Semi-finished product, the illite lightweight through hole haydite for spheroidal after drying with air purification function, in the irradiation of light
Under, spheroidal have air purification function illite lightweight through hole haydite can continual absorption and degradation of formaldehyde, ammonia,
The pollutant such as benzene and TVOC, and the function with extremely strong sterilization, deodorization, mould proof, anti-fouling and self-cleaning and purify air.
The illite lightweight through hole haydite blank material moisture content that spheroidal after extruder grain has air purification function is big
In 30%, swinging roaster high temperature roasting is delivered directly to, in high-temperature calcination process, the surface of haydite blank material is first opened
Beginning sintering curing, and the water vapour of inside is difficult rapid evaporation out, haydite blank material will produce explosion, nor can be by
Grill thoroughly inside haydite blank material.
The illite lightweight through hole haydite blank material that spheroidal is first had air purification function by the present invention is transported to revolution
Prebake is slowly carried out in formula drying oven, drying temperature controls at 150～250 DEG C, then the spheroidal after drying is had purification
The illite lightweight through hole haydite blank material of air function is transported to swinging roasting kiln roasting, and the temperature control of combustor exists
900～950 DEG C, it can be ensured that spheroidal is had in roasting process the illite lightweight through hole haydite hair of air purification function
Blank is grilled thoroughly, and will not produce explosion.
Spheroidal after roasting has in the illite lightweight through hole haydite blank material of air purification function in temperature still
Up to more than 700 DEG C, the spheroidal after roasting is had the illite lightweight through hole haydite blank material input of air purification function
It is incubated in rustless steel cylinder storehouse, it is possible to use the waste heat of itself, the illite for continuing to have spheroidal air purification function is light
Matter through hole haydite blank material is uniformly heated, and not only can ensure that the illite lightweight through hole that spheroidal is had air purification function is made pottery
Grilled thoroughly inside grain blank material completely, moreover it is possible to play a part of uniformly dispersing heat, to improve spheroidal, there is air purification function
Illite lightweight through hole haydite blank material inherent quality.
Spheroidal has an illite lightweight through hole haydite blank material surface of air purification function and inside have substantial amounts of micro-
Hole, is a kind of open pore, open pore not only each other insertion also communicate with the external world, spheroidal has the illite of air purification function
The macropore at lightweight through hole haydite blank material center is a kind of through hole, is conducive in roasting process, can haydite internal complete
Grill thoroughly, and effective ratio area, intensity and the reduction bulk density of haydite can be increased.
Spheroidal has the illite lightweight through hole haydite of air purification function and have that specific surface area is big, bulk density is low,
The feature that hydroscopicity is high, absorption property is superior, appearance and modeling free from extraneous odour attractive in appearance, lightweight intensity are good, micropore and macropore are integrated, circle
The spherical illite lightweight through hole haydite with air purification function can adsorb in the air big in the dry state without dust
The pollutant such as the formaldehyde of amount, ammonia, benzene and TVOC, are immersed in water all the year round and will not also produce disintegrate.
The spheroidal for sucking washable illite photocatalytic spray liquid has the illite lightweight through hole of air purification function
Haydite, is degraded on the basis of absorption, improve comprehensively spheroidal have air purification function illite lightweight lead to
Hole haydite absorption and the ability of purify air.
The illite lightweight through hole haydite that spheroidal has air purification function is used through prolonged, is adsorbed a certain amount of
Pollutant after, illite photocatalyst degradation capability begins to decline, and can present saturation, using 90～100 DEG C of hot water,
The illite lightweight through hole haydite that the spheroidal that will already be at saturation has air purification function carries out backwash, cleaning
Stick to spheroidal and there is illite photo-catalyst film or microgranule inside and outside the illite lightweight through hole haydite of air purification function,
After cleaning up, the new washable illite photocatalytic spray liquid for preparing sprays or is dipped into spheroidal and has purify air
Inside and outside the illite lightweight through hole haydite of function, and dried or dried, performance spheroidal can be continued there is purify air
The effect of the illite lightweight through hole haydite purify air of function.
The microgranule waste residue for washing down can be used for planting bracketplant, Aloe, Folium Sansevieriae Trifasclatae, pocket Cortex cocois radiciss, Caulis Hederae Sinensiies and Epipremnum aureum (Linde et Andre) (Bunting.)
In green plantss, the interior thing that stays not decomposed of microgranule waste residue will slowly be adsorbed by green plantss such as bracketplant, Aloe, Folium Sansevieriae Trifasclataes
Decompose, new pollution will not be produced.
Spheroidal have air purification function illite lightweight through hole haydite be applied to place indoors, furniture cabinet,
Vehicle, aircraft, ship, subway, tunnel, highway baffle, military installations, ornament materials, public place or other buildings
In thing, absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene, TVOC are carried out, to reach the purpose of long-time purify air.
Description of the drawings
Fig. 1 is the illite lightweight through hole haydite schematic diagram that spheroidal has air purification function, and Fig. 2 is that spheroidal has
The illite lightweight through hole haydite A-A profile of air purification function.
As shown in the figure：1 is the illite lightweight through hole haydite that spheroidal has air purification function, and 2 is that spheroidal has
The through hole of the illite lightweight through hole haydite of air purification function.
Specific embodiment
With reference to embodiment, the invention will be further described：
1st, spheroidal has the dispensing of the illite lightweight through hole haydite 1 of air purification function by weight percentage by following component
Composition：Spheroidal has 1 semi-finished product 88% of illite lightweight through hole haydite of air purification function and washable illite light is touched
Matchmaker's spray coating liquor 12%.
2nd, spheroidal has the production method of the illite lightweight through hole haydite 1 of air purification function：(1) first will be washable
Illite photocatalytic spray liquid is put in fermentation vat, then spheroidal has the illite lightweight through hole haydite 1 of air purification function
Semi-finished product are slowly added in the washable illite photocatalytic spray liquid in fermentation vat, and spheroidal has she of air purification function
Micropore inside and outside sharp 1 semi-finished product of stone lightweight through hole haydite, constantly sucks washable illite photocatalytic spray liquid, until in full
And state；(2) take out from fermentation vat and be filled the spheroidal of washable illite photocatalytic spray liquid there is air purification function
Illite lightweight through hole haydite 1, is transported in low temperature rotary drying oven and is dried, and drying temperature controls 160～180
DEG C, drying time controlled at 2 hours；(3) the spheroidal after oven drying at low temperature is had the illite lightweight through hole of air purification function
Haydite 1 is transported in flat vibrating screen and is sieved, and weeds out broken granule and powder, packs and has only for spheroidal
Change the finished product of the illite lightweight through hole haydite 1 of air function.
3rd, spheroidal has the dispensing of 1 semi-finished product of illite lightweight through hole haydite of air purification function by weight percentage
It is made up of following component：Attapulgite potter's clay powder 38%, illite 10%, active white clay waste slag 4% with air purification function,
White carbon 4%, precipitated calcium carbonate 3%, light magnesium oxide 2%, activated alumina 2%, sodium aluminate 2%, cenosphere 1%, ripe
Gypsum Fibrosum powder 1%, expanded perlite 1%, sodium lauryl sulphate 2% and water 30%.
4th, spheroidal has the production method of 1 semi-finished product of illite lightweight through hole haydite of air purification function：(1) will circle
The stirring mixer that the dispensing input of spherical 1 semi-finished product of illite lightweight through hole haydite with air purification function has operated
In, stirring is mixed into the mixture that spheroidal has the illite lightweight through hole haydite 1 of air purification function；(2) spheroidal is had
The mixture for having the illite lightweight through hole haydite 1 of air purification function is transported in Squeezinggranulator, and extruder grain is ball
Shape has 1 blank material of illite lightweight through hole haydite of air purification function, and spheroidal has the illite of air purification function
The macropore at 1 blank material center of lightweight through hole haydite is through hole 2；(3) the illite lightweight for spheroidal being had air purification function is led to
Haydite 1 blank material in hole is transported in swinging drying oven is dried, drying temperature control at 220～240 DEG C, drying time control
System was at 2 hours；(4) 1 blank material of illite lightweight through hole haydite for the spheroidal after drying being had air purification function is transported to
Swinging roasting kiln roasting, the temperature control of combustor is at 900～920 DEG C, and roasting time controlled at 1 hour；(5) by roasting
Spheroidal afterwards has 1 blank material of illite lightweight through hole haydite of air purification function, and input is incubated in rustless steel cylinder storehouse,
Temperature retention time controlled at 48 hours；(6) the spheroidal after insulation cooling is had the illite lightweight through hole pottery of air purification function
1 blank material of grain is transported in roller vibrating screen is sieved, and is weeded out broken granule and powder and is had purification sky for spheroidal
1 semi-finished product of illite lightweight through hole haydite of airway dysfunction.
Claims (3)
1. a kind of spheroidal has the illite lightweight through hole haydite of air purification function, it is characterised in that spheroidal has net
The dispensing for changing the illite lightweight through hole haydite of air function is made up of following component by weight percentage：Spheroidal has purification
The illite lightweight through hole semi-finished product 55～95% of air function and washable illite photocatalytic spray liquid 5～45%；
The spheroidal have the dispensing of the illite lightweight through hole semi-finished product of air purification function by weight percentage by
Following component constitutes：Attapulgite potter's clay powder 10～45%, illite 5～25%, active hargil with air purification function gives up
Slag 2～10%, white carbon 1～8%, precipitated calcium carbonate 1～5%, light magnesium oxide 1～5%, activated alumina 1～5%, aluminum
Sour sodium 0.5～5%, cenosphere 0.5～5%, gesso 0.5～5%, expanded perlite 0.5～5%, dodecyl sulfur
Sour sodium 0.5～5% and water 10～40%；
Spheroidal has the production method of the illite lightweight through hole semi-finished product of air purification function：(1) spheroidal is had
In the stirring mixer that the dispensing input of the illite lightweight through hole semi-finished product of air purification function has operated, stirring is mixed
It is combined into the mixture that spheroidal has the illite lightweight through hole haydite of air purification function；(2) spheroidal had purify air
The mixture of the illite lightweight through hole haydite of function is transported in Squeezinggranulator, and it is empty that extruder grain has purification for spheroidal
The illite lightweight through hole haydite blank material of airway dysfunction, spheroidal has the illite lightweight through hole haydite hair of air purification function
The macropore at blank center is through hole；(3) spheroidal is had the illite lightweight through hole haydite blank material conveying of air purification function
Dried in swinging drying oven, drying temperature control is at 200～250 DEG C, and drying time controlled at 1～4 hour；(4) will
The illite lightweight through hole haydite blank material that spheroidal after drying has air purification function is transported in swinging roaster
Roasting, the temperature control of combustor is at 900～950 DEG C, and roasting time controlled at 1～3 hour；(5) the spheroidal after roasting is had
There is the illite lightweight through hole haydite blank material of air purification function, input is incubated in rustless steel cylinder storehouse, and temperature retention time controls
At 24～72 hours；(6) the spheroidal after insulation cooling is had the illite lightweight through hole haydite blank material of air purification function
Be transported in roller vibrating screen and sieved, weed out broken granule and powder have for spheroidal air purification function she
Sharp stone lightweight through hole semi-finished product；
The dispensing of the washable illite photocatalytic spray liquid is made up of following component by weight percentage：Illite 5～
12%th, attapulgite clay after the acidify 4～10%, high viscous Concave-convex clay rod 2～8%, nano titanium oxide 1～5%, white
White carbon black 1～5%, nano silver-supported antibacterial powder 0.5～5%, nano magnesia 0.5～5%, nano zirconium dioxide 0～5%, nanometer
Aluminium oxide 0～5%, nano zine oxide 0～5%, polyvinyl alcohol 0.5～5%, Polyethylene Glycol 0.1～3%, polydimethylsiloxanes
Alkane 0.1～2% and deionized water 50～82%；
The production method of washable illite photocatalytic spray liquid：(1) the dispensing of washable illite photocatalytic spray liquid is input into
Strong stirring, dispersion and emulsifying is carried out in the high speed dispersor for having operated, and is then ground in input three-roll grinder erasable
Wash the semi-finished product of illite photocatalytic spray liquid；(2) the semi-finished product of washable illite photocatalytic spray liquid are input into colloid mill
In, carry out again disperseing, emulsifying, crushing, homogenizing, froth breaking and grinding；(3) the washable illite photocatalytic spray liquid after grinding
Granularity≤0.01 millimeter of middle solid particle, canned for washable illite photocatalytic spray liquid.
2. spheroidal according to claim 1 has the illite lightweight through hole haydite of air purification function, and its feature exists
In, fineness of the particles≤0.074 millimeter of the attapulgite potter's clay powder with air purification function, illitic fineness of the particles≤
0.074 millimeter, fineness of the particles≤0.149 millimeter of active white clay waste slag, fineness of the particles≤0.074 millimeter of precipitated calcium carbonate,
Fineness of the particles≤0.074 millimeter of light magnesium oxide, fineness of the particles≤0.074 millimeter of activated alumina, the granule of sodium aluminate
Fineness≤0.074 millimeter, fineness of the particles≤0.149 millimeter of cenosphere, fineness of the particles≤0.074 millimeter of gesso,
Fineness of the particles≤0.074 millimeter of expanded perlite.
3. spheroidal according to claim 1 has the illite lightweight through hole haydite of air purification function, and its feature exists
In spheroidal has the production method of the illite lightweight through hole haydite of air purification function：(1) first by washable illite light
Catalyzed spraying liquid is put in fermentation vat, then the illite lightweight through hole semi-finished product that spheroidal is had air purification function is delayed
In the slow washable illite photocatalytic spray liquid for adding in fermentation vat, spheroidal has the illite lightweight of air purification function
Micropore inside and outside through hole semi-finished product, constantly sucks washable illite photocatalytic spray liquid, until being in saturation；⑵
From fermentation vat take out be filled washable illite photocatalytic spray liquid spheroidal have air purification function illite light
Matter through hole haydite, is transported in low temperature rotary drying oven and is dried, drying temperature control at 150～180 DEG C, drying time
Control was at 1～3 hour；(3) the spheroidal after oven drying at low temperature is had the illite lightweight through hole haydite conveying of air purification function
Sieved in flat vibrating screen, broken granule and powder is weeded out, pack, for spheroidal, there is purify air work(
The finished product of the illite lightweight through hole haydite of energy.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610831048.6A CN106431206A (en) | 2016-09-19 | 2016-09-19 | Spherical illite light through-hole ceramsite with air purification function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610831048.6A CN106431206A (en) | 2016-09-19 | 2016-09-19 | Spherical illite light through-hole ceramsite with air purification function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106431206A true CN106431206A (en) | 2017-02-22 |
Family
ID=58169191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610831048.6A Withdrawn CN106431206A (en) | 2016-09-19 | 2016-09-19 | Spherical illite light through-hole ceramsite with air purification function |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106431206A (en) |
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2016
- 2016-09-19 CN CN201610831048.6A patent/CN106431206A/en not_active Withdrawn
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Application publication date: 20170222 |