CN106430364A - Water purifying agent - Google Patents

Water purifying agent Download PDF

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Publication number
CN106430364A
CN106430364A CN201611054440.0A CN201611054440A CN106430364A CN 106430364 A CN106430364 A CN 106430364A CN 201611054440 A CN201611054440 A CN 201611054440A CN 106430364 A CN106430364 A CN 106430364A
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CN
China
Prior art keywords
parts
water purification
purification agent
kieselguhr
water
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611054440.0A
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Chinese (zh)
Inventor
蓝贤波
曹戈
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fangchenggang Water Conservancy And Hydropower Survey And Design Institute
Original Assignee
Fangchenggang Water Conservancy And Hydropower Survey And Design Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201611054440.0A priority Critical patent/CN106430364A/en
Publication of CN106430364A publication Critical patent/CN106430364A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/22O2

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention discloses a water purifying agent. The water purifying agent is prepared from the following main raw materials: polydimethyl diallyl ammonium chloride, acrylamide, calcium aluminate powder, active carbon, ferrous sulfate, magnesium carbonate, ferric sulfate, sodium peroxide, modified diatomite and ferric chloride. The water purifying agent can effectively increase dissolved oxygen in water, improve water quality and absorb and degrade organic matters in water, is high in antibacterial efficiency, high in safety performance, non-toxic, pollution-free and good in stability. Pond water treated by the water purifying agent meets requirements of agricultural crop irrigation.

Description

A kind of water purification agent
Technical field
The present invention relates to water harnessing field, more particularly to a kind of water purification agent, the water purification agent is mainly used in purifying pond water.
Background technology
Construction of water conservancy works refers to produce the water conservancy of service for developing agricultural.Basic task be by hydraulic engineering skill Art measure, changes the natural conditions for being unfavorable for Agriculture Production, is agricultural year High-effective Service.Serviced for farmland by building Water conservancy projects, including irrigation, draining, water logging control and preventing and treating salt, stain disaster etc., build high yields irrespective of drought or water logging, the basic agriculture of high and stable yields Field.At rainwater more season, the pond for hydraulic engineering that builds well, the unnecessary water yield can be accommodated.When usually, pond Can use as cultivation fishery.In arid, it is often necessary to using the pond that builds in hydraulic engineering, farmland is irrigated.So And when fishery cultivating is carried out, cultivating pool is strictly regulated as production operation lacks under the conditions of current oxygen-increasing reagent, residual Bait, Excreta, biological corpse, fishing nutrient substance and drugs used in aquiculture, pole in closing or semi-enclosed aquaculture ecosystem Pollution is easily formed so that water nutrition is raised, lower floor's water hypoxia, and depositional environment sulfide, organic matter and reducing substances contain Amount is raised, and left drug is put aside, and harmful microorganism or bites dirty biological procreation, and breeding ecological is unbalance, and all kinds of diseases frequently occur.Such as Fruit water quality receives pollution, and after irrigation, crops can also be contaminated.
The information for being disclosed in the background section is merely intended to increase the understanding of the general background to the present invention, and should not Recognize or imply in any form prior art of the information structure well known to persons skilled in the art when being considered.
Content of the invention
It is an object of the invention to provide a kind of water purification agent, so as to overcome water quality to be polluted, affects the life of aquatic animal The shortcoming that the quality of long, make crops for irrigation growth and agricultural product reduces.
For achieving the above object, the invention provides a kind of water purification agent, is mainly made up of following raw material:Poly dimethyl diene Propyl ammonium chloride, acrylamide, calcium aluminate powder, activated carbon, ferrous sulfate, magnesium carbonate, iron sulfate, peroxy acid sodium, modified diatom Soil and ferric chloride.
Preferably, in technique scheme, described water purification agent, count by weight, be mainly made up of following raw material:Poly- Dimethyl diallyl ammonium chloride 5-19 part, acrylamide 5-19 part, calcium aluminate powder 3-13 part, activated carbon 15-25 part, sulphuric acid Asia Ferrum 5-19 part, magnesium carbonate 3-12 part, iron sulfate 5-19 part, peroxy acid sodium 5-19 part, modification infusorial earth 15-28 part and ferric chloride 11-22 part.
Preferably, in technique scheme, described water purification agent, count by weight, be mainly made up of following raw material:Poly- 13 parts of dimethyl diallyl ammonium chloride, 11 parts of acrylamide, 7 parts of calcium aluminate powder, 21 parts of activated carbon, 11 parts of ferrous sulfate, carbon 6 parts of sour magnesium, 13 parts of iron sulfate, 12 parts of peroxy acid sodium, 23 parts of modification infusorial earth and 15 parts of ferric chloride.
Preferably, in technique scheme, described water purification agent, the method for the modification infusorial earth is comprised the following steps:
(1) diatomaceous pretreatment, kieselguhr and sodium bicarbonate solution are mixed;
(2) pretreated kieselguhr is mixed with manganese sulfate solution and is modified, then modified kieselguhr is entered Row calcining, obtains modification infusorial earth.
Preferably, in technique scheme, described water purification agent, the mass concentration of the sodium bicarbonate solution is 20- 30%, in step (1), kieselguhr is 1 with the solid-to-liquid ratio of sodium bicarbonate solution volume:10-30, wherein diatomaceous quality With a gram meter, the volume of sodium bicarbonate solution is in terms of milliliter.
Preferably, in technique scheme, described water purification agent, the mass concentration of manganese sulfate solution in step (2) For 15-25%, in step (2), kieselguhr is 1 with the solid-to-liquid ratio of manganese sulfate solution volume:10-30, wherein diatomaceous matter Amount and a gram meter, the volume of manganese sulfate solution is in terms of milliliter.
Preferably, in technique scheme, described water purification agent, it is 500- in temperature that the calcining in step (2) is 8-12 hour is calcined under conditions of 550 DEG C.
Compared with prior art, the present invention has the advantages that:Water purification agent of the present invention, can be effectively increased water body molten Oxygen, improves water quality, absorbs Organic substance in degraded water body, antimicrobial efficiency height.And security performance height, nontoxic pollution-free, good stability. Pond water after processing through water purification agent of the present invention meets the requirement of agricultural irrigation crops.
Specific embodiment
With reference to specific embodiment, the specific embodiment of the present invention is described in detail, it is to be understood that this Bright protection domain is not limited by specific embodiment.
Embodiment 1
A kind of water purification agent, is counted by weight, is mainly made up of following raw material:PDDA 13 Part, 11 parts of acrylamide, 7 parts of calcium aluminate powder, 21 parts of activated carbon, 11 parts of ferrous sulfate, 6 parts of magnesium carbonate, 13 parts of iron sulfate, peroxide 12 parts of sour sodium, 23 parts of modification infusorial earth and 15 parts of ferric chloride.
Described water purification agent, the method for the modification infusorial earth is comprised the following steps:
(1) diatomaceous pretreatment, kieselguhr and sodium bicarbonate solution are mixed;The quality of the sodium bicarbonate solution is dense Spend for 25%, in step (1), kieselguhr is 1 with the solid-to-liquid ratio of sodium bicarbonate solution volume:20, wherein diatomaceous quality With a gram meter, the volume of sodium bicarbonate solution is in terms of milliliter.
(2) pretreated kieselguhr is mixed with manganese sulfate solution and is modified, the mass concentration of manganese sulfate solution is 19%, kieselguhr is 1 with the solid-to-liquid ratio of manganese sulfate solution volume:20, wherein diatomaceous quality with gram meter, manganese sulfate solution Modified kieselguhr in terms of milliliter and then is calcined by volume, and calcining is to calcine under conditions of temperature is for 500-550 DEG C 10 hours.Obtain modification infusorial earth.
A kind of preparation method of water purification agent, by modified kieselguhr and PDDA, acryloyl Amine, calcium aluminate powder, activated carbon, ferrous sulfate, carbonic acid, iron sulfate, peroxy acid sodium and ferric chloride mix homogeneously, obtain water purification Agent.
Embodiment 2
A kind of water purification agent, is counted by weight, is mainly made up of following raw material:5 parts of PDDA, 5 parts of acrylamide, 3 parts of calcium aluminate powder, 15 parts of activated carbon, 5 parts of ferrous sulfate, 3 parts of magnesium carbonate, 5 parts of iron sulfate, peroxy acid sodium 5 Part, 15 parts of modification infusorial earth and 11 parts of ferric chloride.
Described water purification agent, the method for the modification infusorial earth is comprised the following steps:
(1) diatomaceous pretreatment, kieselguhr and sodium bicarbonate solution are mixed;The quality of the sodium bicarbonate solution is dense Spend for 20%, in step (1), kieselguhr is 1 with the solid-to-liquid ratio of sodium bicarbonate solution volume:10, wherein diatomaceous quality With a gram meter, the volume of sodium bicarbonate solution is in terms of milliliter.
(2) pretreated kieselguhr is mixed with manganese sulfate solution and is modified, the mass concentration of manganese sulfate solution is 15%, kieselguhr is 1 with the solid-to-liquid ratio of manganese sulfate solution volume:10, wherein diatomaceous quality with gram meter, manganese sulfate solution Modified kieselguhr in terms of milliliter and then is calcined by volume, and calcining is to calcine 8 under conditions of temperature is for 500-550 DEG C Hour.Obtain modification infusorial earth.
A kind of preparation method of water purification agent, by modified kieselguhr and PDDA, acryloyl Amine, calcium aluminate powder, activated carbon, ferrous sulfate, carbonic acid, iron sulfate, peroxy acid sodium and ferric chloride mix homogeneously, obtain water purification Agent.
Embodiment 3
A kind of water purification agent, is counted by weight, is mainly made up of following raw material:PDDA 19 Part, 19 parts of acrylamide, 13 parts of calcium aluminate powder, 25 parts of activated carbon, 19 parts of ferrous sulfate, 12 parts of magnesium carbonate, 19 parts of iron sulfate, mistake Oxygen 19 parts of sodium of acid, 28 parts of modification infusorial earth and 22 parts of ferric chloride.
Described water purification agent, the method for the modification infusorial earth is comprised the following steps:
(1) diatomaceous pretreatment, kieselguhr and sodium bicarbonate solution are mixed;The quality of the sodium bicarbonate solution is dense Spend for 30%, in step (1), kieselguhr is 1 with the solid-to-liquid ratio of sodium bicarbonate solution volume:30, wherein diatomaceous quality With a gram meter, the volume of sodium bicarbonate solution is in terms of milliliter.
(2) pretreated kieselguhr is mixed with manganese sulfate solution and is modified, the mass concentration of manganese sulfate solution is 25%, kieselguhr is 1 with the solid-to-liquid ratio of manganese sulfate solution volume:30, wherein diatomaceous quality with gram meter, manganese sulfate solution Modified kieselguhr in terms of milliliter and then is calcined by volume, and calcining is to calcine under conditions of temperature is for 500-550 DEG C 12 hours.Obtain modification infusorial earth.
A kind of preparation method of water purification agent, by modified kieselguhr and PDDA, acryloyl Amine, calcium aluminate powder, activated carbon, ferrous sulfate, carbonic acid, iron sulfate, peroxy acid sodium and ferric chloride mix homogeneously, obtain water purification Agent.
The description of the aforementioned specific illustrative embodiment to the present invention illustrate that and illustration purpose.These descriptions It is not wishing to disclosed precise forms are limited the invention to, and it will be apparent that according to above-mentioned teaching, much can be changed And change.The purpose of selecting and describing the exemplary embodiment is that explaining that the certain principles of the present invention and its reality should With so that those skilled in the art can realize and a variety of exemplary using the present invention and A variety of selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.

Claims (7)

1. a kind of water purification agent, it is characterised in that be mainly made up of following raw material:PDDA, acryloyl Amine, calcium aluminate powder, activated carbon, ferrous sulfate, magnesium carbonate, iron sulfate, peroxy acid sodium, modification infusorial earth and ferric chloride.
2. water purification agent according to claim 1, it is characterised in that count by weight, be mainly made up of following raw material:Poly- Dimethyl diallyl ammonium chloride 5-19 part, acrylamide 5-19 part, calcium aluminate powder 3-13 part, activated carbon 15-25 part, sulphuric acid Asia Ferrum 5-19 part, magnesium carbonate 3-12 part, iron sulfate 5-19 part, peroxy acid sodium 5-19 part, modification infusorial earth 15-28 part and ferric chloride 11-22 part.
3. water purification agent according to claim 1, it is characterised in that count by weight, be mainly made up of following raw material:Poly- 13 parts of dimethyl diallyl ammonium chloride, 11 parts of acrylamide, 7 parts of calcium aluminate powder, 21 parts of activated carbon, 11 parts of ferrous sulfate, carbon 6 parts of sour magnesium, 13 parts of iron sulfate, 12 parts of peroxy acid sodium, 23 parts of modification infusorial earth and 15 parts of ferric chloride.
4. water purification agent according to claim 1, it is characterised in that the method for the modification infusorial earth is comprised the following steps:
(1) diatomaceous pretreatment, kieselguhr and sodium bicarbonate solution are mixed;
(2) pretreated kieselguhr is mixed with manganese sulfate solution and is modified, then modified kieselguhr is forged Burn, obtain modification infusorial earth.
5. water purification agent according to claim 4, it is characterised in that the mass concentration of the sodium bicarbonate solution be 30%, in step (1), kieselguhr is 1 with the solid-to-liquid ratio of sodium bicarbonate solution volume:10-30, wherein diatomaceous quality With a gram meter, the volume of sodium bicarbonate solution is in terms of milliliter.
6. water purification agent according to claim 4, it is characterised in that the mass concentration of manganese sulfate solution in step (2) For 15-25%, in step (2), kieselguhr is 1 with the solid-to-liquid ratio of manganese sulfate solution volume:10-30, wherein diatomaceous matter Amount and a gram meter, the volume of manganese sulfate solution is in terms of milliliter.
7. water purification agent according to claim 4, it is characterised in that it is 500- in temperature that the calcining in step (2) is 8-12 hour is calcined under conditions of 550 DEG C.
CN201611054440.0A 2016-11-25 2016-11-25 Water purifying agent Pending CN106430364A (en)

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Application Number Priority Date Filing Date Title
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103432987A (en) * 2013-08-30 2013-12-11 华北水利水电大学 Preparation method of modified kieselguhr water purifying agent
CN103508553A (en) * 2013-10-18 2014-01-15 丹阳市现代生态水产养殖场 Aquaculture water purifying agent
CN103663655A (en) * 2013-12-17 2014-03-26 中国林业科学研究院林产化学工业研究所 Water purifying agent for advanced treatment of pulping, papermaking, printing and dyeing wastewater as well as preparation method of water purifying agent
US20140175015A1 (en) * 2011-06-20 2014-06-26 Fujifilm Corporation Water purification method
CN104628096A (en) * 2013-11-11 2015-05-20 青岛水世界环保科技有限公司 Livestock and poultry drinking water purifying agent
CN105906010A (en) * 2016-06-15 2016-08-31 江门市江海区炜洁净水材料有限公司 Household water purifying agent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140175015A1 (en) * 2011-06-20 2014-06-26 Fujifilm Corporation Water purification method
CN103432987A (en) * 2013-08-30 2013-12-11 华北水利水电大学 Preparation method of modified kieselguhr water purifying agent
CN103508553A (en) * 2013-10-18 2014-01-15 丹阳市现代生态水产养殖场 Aquaculture water purifying agent
CN104628096A (en) * 2013-11-11 2015-05-20 青岛水世界环保科技有限公司 Livestock and poultry drinking water purifying agent
CN103663655A (en) * 2013-12-17 2014-03-26 中国林业科学研究院林产化学工业研究所 Water purifying agent for advanced treatment of pulping, papermaking, printing and dyeing wastewater as well as preparation method of water purifying agent
CN105906010A (en) * 2016-06-15 2016-08-31 江门市江海区炜洁净水材料有限公司 Household water purifying agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
朱健,等: "<<中国环境科学学会学术年会论文集(2013)>>", 1 August 2013 *

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Application publication date: 20170222

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