CN106427105A - Power plant chimney inner wall anti-corrosion and anti-seepage lining, and method for realizing chimney on-site mounting with vertical overturning method - Google Patents

Power plant chimney inner wall anti-corrosion and anti-seepage lining, and method for realizing chimney on-site mounting with vertical overturning method Download PDF

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Publication number
CN106427105A
CN106427105A CN201610707623.1A CN201610707623A CN106427105A CN 106427105 A CN106427105 A CN 106427105A CN 201610707623 A CN201610707623 A CN 201610707623A CN 106427105 A CN106427105 A CN 106427105A
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chimney
resin
fiber
layer
composite
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CN201610707623.1A
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CN106427105B (en
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林永志
梁玉顺
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/38Layered products comprising a layer of synthetic resin comprising epoxy resins
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J13/00Fittings for chimneys or flues 
    • F23J13/02Linings; Jackets; Casings
    • F23J13/025Linings; Jackets; Casings composed of concentric elements, e.g. double walled
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • B32B2262/0269Aromatic polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • B32B2262/0284Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chimneys And Flues (AREA)
  • Working Measures On Existing Buildindgs (AREA)

Abstract

The invention relates to a power plant chimney inner wall anti-corrosion and anti-seepage lining, and a method for realizing chimney on-site mounting with a vertical overturning method. According to the invention, a separation membrane layer, a woven fiber cloth layer, a composite resin layer, a composite fiber layer, a composite resin layer, a deep-hole woven fiber cloth layer and a composite membrane layer are sequentially arranged on the inner wall of the chimney. A special-purposed woven fiber cloth tube is suspended on the inner wall of the chimney; and dot matrix fixing is carried out with fast-binding resin. Composite resin flowability is regulated, and the composite resin is uniformly sprayed on the surface of composite fiber, wherein the spraying length is equal to the length of lining to be overturned. An integral airtight tube prepared with the composite membrane and the deep-hole woven fiber cloth is overturned upwards or downwards through air pressure onto the surface of composite fiber impregnated with resin. Under a constant pressure, a certain curing time is kept until the composite resin is completely cured. Finally, a hard anti-corrosion and anti-seepage resin fiber lining with enough strength is formed. The lining formed after curing has high tensile strength and compressive strength, and is combined tightly with the inner wall of the chimney.

Description

Chimney of electric plant inner wall anti-corrosive antiseepage liner and utilize flip vertical method to realize that chimney is on-the-spot The method installed
Technical field
The invention belongs to technical field of electric power, particularly relate to a kind of chimney of electric plant inner wall anti-corrosive antiseepage liner and utilize vertical Straight inversion method realizes the field erected method of chimney.
Background technology
With implementing continuing to increase of national environmental protection policy dynamics in power industry, Thermal generation unit must time limit install additional Wet desulphurization device.The environmental protection policy of response country of Ge great thermoelectricity group, strengthens flue gas desulfurization dynamics, progressively makes respective power plant Smoke density reaches the environmental protection standard of national regulation.
Owing to being all discharge high-temperature flue gas before China's Thermal Power Generation Industry, at this moment flue gas is lighter to the corrosion of flue, chimney.State Interior power industry is substantially not provided with materials specialty, let alone anticorrosive specialty.It is faced with now the big of the whole industry Scale desulfurization project, whole power industry, in face of thing followed heavy corrosion, also lacks the enough understanding to corrosion harmfulness. During installing wet desulphurization device additional, particularly relating to desulfurizing tower, flue and chimney anticorrosion corrosion material and anticorrosion During scheme, being affected by various reasons, result causes substantial amounts of chimney anticorrosion erosion project quality problems occur, to power industry band Carry out serious economic loss, and leave serious potential hazard to the safety in production of power plant.
Before wet desulphurization, coal unit discharge is the flue gas without desulfurization, enters the flue-gas temperature of chimney on 125 DEG C of left sides Right.With this understanding, inner wall of stack is in drying regime, and flue gas does not directly produce corrosion to inner wall of stack material.Install wet method additional After desulfurizer, discharge is wet flue gas.If without flue gas heat-exchange unit heat temperature raising, enter the flue-gas temperature of chimney 50 ± 5 DEG C, inner wall of stack has serious condensation, and the condensation acid solution of generation is trickled downwards along barrel.The temperature of acid solution when 40 DEG C~50 DEG C, Strong especially to the corrosivity of structural material.As a example by steel, etch ratio when 40 DEG C~50 DEG C exceeds when other temperature About 3~8 times.After wet desulphurization, when desulfuration efficiency reaches Theoretical Design value 95%, the pH value of the acid condensate liquid of inner wall of stack It is 1.9~2.2, belong to highly acid state.If wet flue gas is for the corrosion rate of unlike material:The corrosion rate of Q235A steel is high Reach 159.54mm/~200.00mm/;The stainless corrosion rate of 10CrMnCuTi is also up to 23.9268mm/;These Actual test data have absolutely proved that this condensation water has very strong corrosive power.When the concentration of inner wall of stack dilute sulfuric acid is 15% When, it to the corrosion rate of concrete is:Corrosion rate for C25 concrete is 8mm/10 days;Corrosion for C30 concrete Speed is 2.4mm/10 days;Corrosion rate for C50 concrete is 2.4mm/10 days.
Can be seen that from the conclusion of above flue gas corrosion Journal of Sex Research and test, although installing wet flue gas desulfurizer additional After, in flue gas about 90%~95% SO2By removing from flue gas, but, big owing to the flue gas after desulfurization introducing Amount moisture and flue-gas temperature is down to about 50 ± 5 DEG C, so that the flue gas after desulfurization is provided with very strong corrosivity.
By investigating discovery to the chimney of electric plant installing wet desulphurization device additional, current inner wall of stack mainly uses foaming Glass brick layer, due to the reason such as material and construction, occur temperature become ftracture, come off, corrosion leakage situation, install expanded glass block additional anti- The chimney of rotten liner, 2-3 occur as soon as glass block breakage come off, gap leakage, steel chimney in 1 year with regard to corrosion failure, Even casting concrete outer tube wall corrosion air-leakage, has influence on the safe operation of generating set.
For the chimney installing frp lining additional, due to fiberglass pipe nipple 3-6 rice, therefore in the height of 220 meters of chimneys Need numerous fiberglass pipe nipple to connect and could realize that liner installs additional;In addition, frp lining pipe diameter is big, usually 8-9 rice, Heavy Weight, it is difficult to ensure that seal at tie point, it may appear that gap leakage simultaneously causes heavy corrosion.
The titanium alloy liner of current more employing, although good endurance, design, processing and fabricating, welded and installed have GB, But there is also two major issues.One is that cost is high, and general diameter 8 meters, high 220 meters of chimneys need 2000-3000 ten thousand yuan, and two are Construction period is long, month duration 4-6.
The problem existing due to inner wall of stack anticorrosive coat and construction technology, solution is presently required is to installing wet desulphurization additional How the chimney of electric plant of device carries out anticorrosion, needs to propose the new preserving timber bed of material and method of operating.
Content of the invention
According to the problem that presently, there are and the deficiencies in the prior art, we, through research and experiment, have invented chimney of electric plant Inner wall anti-corrosive antiseepage liner and utilize flip vertical to realize the field erected method of chimney;
Concrete technical scheme is as follows:
A kind of chimney of electric plant inner wall anti-corrosive antiseepage liner;Inner wall of stack 7 sets gradually separating film layer the 6th, woven fabric Layer of cloth the 5th, compound resin layer the 4th, composite fibre layer the 3rd, compound resin layer the 4th, deep hole machine textured fiber layer of cloth the 2nd, composite film 1.
Described composite membrane 1 be have uvioresistant, oxidation resistant polyvinyl chloride (PVC), thermo-plastic polyurethane (TPUR) and Elastomeric material and high-molecular coating material;Composite film thickness 0.5-2mm.
Described deep hole machine textured fiber layer of cloth 2 is that weight per square meter exists:400≤W≤800 gram by polypropylene fiber, terylene The fiber cloth that fiber, carbon fiber, nylon fibre or aramid fiber are made into.
Described composite fibre layer 3 is that glass fibre passes through acupuncture or loop bonding with polyester fiber, polyster fibre or polypropylene fiber Multi-layer fiber;The thickness 2-6mm of usual composite fibre.
Described compound resin layer 4 is epoxy resin, unsaturated polyester resin, furane resins, vinylite and curing agent The cured layer being formed;Compound resin layer thickness 1-4mm.
Described woven fabric layer of cloth 5 is that weight per square meter exists:300≤weight W≤500 gram by polypropylene fiber, terylene The fiber cloth that fiber, carbon fiber, nylon fibre or aramid fiber are made into.
Described barrier film 6 is the film adding every 5-10 rice in chimney height;The width of film is 5-10cm, and thickness is 0.5-2mm;Barrier film is polyethylene (PE), polyvinyl chloride (PVC), thermo-plastic polyurethane (TPUR) and elastomeric material and macromolecule Coating material.
Described inner wall of stack 7 is chimney of electric plant steel cylinder or has installed expanded glass block.
The present invention utilizes flip vertical to realize the field erected method of inner wall of stack anti-corrosion leak-proof liner;Step is as follows:
1) measurement of reconnoitring according to on-the-spot chimney, diameter and the height of foundation chimney are sewn into the woven fabric matching therewith Cloth cylinder;Every 5-10 rice at woven fabric cloth 5 overlying barrier film 6;By the membrane material heat seal of selection or be sprayed on woven fabric cloth On;
2) multiple-layer stacked is made to required thickness composite fibre cylinder with composite fibre 3 according to the diameter of chimney and height;
3) high-altitude hanging basket and lifting means are utilized by step 1) the woven fabric cloth cylinder that sewed is suspended on chimney top lock Fastening, remainder fast-curing resin carries out a little fixing;
4) by step 2) composite fibre cylinder is lifted on the inboard of woven fabric cloth cylinder, and top is locked, and remaining position is used Fast-curing resin carries out a little fixing;
5) diameter of the thickness according to anti-corrosion leak-proof liner and chimney and compound resin 4 needed for high computational;Utilize lifting Hanging basket by high-pressure metering pump and spray gun by the compound resin even application for preparing to composite fibre cylinder surface;
6) by heat seal or spraying, composite membrane 1 and deep hole machine textured fiber cloth 2 are formed one, the then height according to chimney Make overall airtight cylinder with internal diameter;
7) by airtight for above-mentioned entirety cylinder by constant air pressure flip vertical to the composite fibre cylinder having sprayed compound resin On, adjust gas pressure, make compound resin uniformly extrude transmission and be impregnated into composite fibre cylinder and woven fabric cylinder until arriving chimney Inner wall surface;
8) after liner is fully cured, excision two ends redundance, then carry out port sealing with resin glue.
The method of the present invention also can carry out local directed complete set, adopts and utilizes flip vertical to realize that inner wall of stack is prevented with the following method Rotten antiseepage liner in-site installation:
Adjusted Option one:
1) carry out on-the-spot chimney reconnoitres measurement, and the diameter according to chimney and height are sewn into the woven fabric matching therewith Cloth cylinder;Every 5-10 rice at woven fabric cloth 5 overlying barrier film 6;By the membrane material heat seal of selection or be sprayed on woven fabric cloth On;
2) according to the anti-corrosion leak-proof thickness of inner lining determining, composite fibre 3 and deep hole machine textured fiber cloth 2 are made with composite membrane 1 Become the complex fiber hose that the diameter with chimney and height match;
3) high-altitude hanging basket and lifting means are utilized by step 1) the woven fabric cloth cylinder that sewed is suspended on chimney top lock Fastening, remainder fast-curing resin carries out a little fixing;
4) diameter of the thickness according to liner and chimney and compound resin needed for high computational 4 amount;Pass through high-pressure metering pump Be circulated into step 2) complex fiber hose in, then carry out rolling and impregnate uniformly with twin rollers, form adventitia resin fibre Flexible pipe;
5) resin fibre flexible pipe is by air pressure flip vertical to the chimney 7 already equipped with woven fabric cloth 5;Adjust gas Pressure, makes resin fibre flexible pipe overturn up or down continuously;Compound resin 4 in flexible pipe uniformly extrudes and is impregnated into woven fibre Dimension cloth 5 is until the inner wall surface of chimney 7.
6) after liner is fully cured, excision two ends redundance, then seal with resin glue.The method of the present invention is also Local directed complete set can be carried out, adopt and utilize flip vertical to realize once completing inner wall of stack anti-corrosion leak-proof liner scene with the following method Install.
Adjusted Option two:
1) carry out on-the-spot chimney and reconnoitre measurement, be sewn into, according to diameter and the height of chimney, the MULTILAYER COMPOSITE matching therewith soft Pipe.MULTILAYER COMPOSITE flexible pipe is weaved cotton cloth by woven fabric cloth 5 and composite fibre 3 and deep hole machine and 2 is made with composite membrane 1.
2) diameter of the thickness according to liner and chimney and compound resin needed for high computational 4 amount;Will be multiple by measuring pump Resin 4 is circulated into step 1) MULTILAYER COMPOSITE flexible pipe in, then carry out rolling and impregnate uniformly with twin rollers, form multilayer fine Dimension resin hose;
3) multi-layer fiber resin hose is by air pressure flip vertical to chimney 7;Adjust gas pressure, make multi-layer fiber tree Fat flexible pipe overturns continuously up or down;Last integral with the inner wall surface close adhesion of chimney 7.
4) multi-layer fiber resin hose was fully cured through certain time, excision two ends redundance, then used resin glue Seal.Form complete anti-corrosion leak-proof liner.
Inventive technique is described as follows
1st, flip vertical lining technique:
First specialized woven fiber cloth 5 is suspended on inner wall of stack, then carries out dot matrix with quick binding resin and fix.
Secondly adjust compound resin 4 flowing degree and be sprayed on composite fibre 3 surface equably, in spraying length and overturning The length of lining is equal.Then the airtight cylinder of entirety again composite membrane 1 and deep hole machine textured fiber cloth 2 made, by air pressure vertically to Composite fibre 3 surface that is upper or that downwardly turn over impregnating resin, under a constant, keeps certain hardening time until being combined Resin is fully cured.Eventually form the hard anti-corrosion leak-proof resin fibre liner with sufficient intensity.
This resin fibre liner both can become one with the steel stack in the outside adhesive solidification such as (or glass block corrosion protective lining) Body, it is also possible to fit tightly with the steel chimney in outside corrosion protective linings such as (or) glass blocks to be formed and independent there is sufficient intensity Independent anti-corrosion leak-proof liner.
2nd, flip vertical inner lining structure feature
Outermost layer is that composite membrane 1 has certain elastic anti-corrosion antiseepage, and intermediate layer is composite fibre 3 and compound resin 4, in Layer is barrier film 6 and compound resin layer.The liner tension, the compression strength that are formed after solidification are high, combine closely with inner wall of stack.
Flip vertical liner is the most inboard forms discontinuous structure by barrier film.It thus then can absorb what the chimney temperature difference was brought Expand and shrinkage stress.
Flip vertical liner top layer is overall continuous seamless in chimney, overcomes conventional anti-corrosion leak-proof technique seam to leak The shortcoming causing corrosion.
Beneficial effects of the present invention and innovative point are described as follows:
Beneficial effects of the present invention:
1. flip vertical liner cured in place globality is strong.Form continuous jointless complete compound lining so that former The wet flue gas that the whole inwall of chimney is extremely strong with corrosivity is completely isolated.
2. flip vertical liner cured in place is acidproof excellent.The fiber reinforced resin layer of the polymer compound film on top layer and nexine is equal It is the material to acidic liquid or gas with superior anti-corrosion.
3. flip vertical liner cured in place quick construction.This method can be worked continuously, cured in place.One diameter 8 The construction period of the chimney of high 240 meters of rice completed in 30 days.
4. flip vertical liner cured in place economical rationality.Save 20-30% than titanium plate alloy lining, than expanded glass block 10-20%.
5. flip vertical liner cured in place non-environmental-pollution.Resin used and fiber are all nonpoisonous and tasteless, to environment without dirt Dye, harmless to workers ' health.
6. flip vertical liner cured in place is heat-resist.Less than 80 DEG C can longtime running, short-term impact high temperature reaches 160 Degree.
7. the flip vertical liner cured in place life-span is long.Inner lining material can be with long period of soaking in inorganic acid.Use the longevity Life is more than 40 years.
The innovative point of this technology is:
1. utilize principle and the lower feature equalizing atmospherically of upset, by inner lining film vertically upward or downward upset, Resin is made effectively to transmit and dipping under continuous equilibrium extruding.Combine closely with resin fibre and inner wall of stack and solidify.
2. the resin in this technology has the curing characteristics of uniqueness, is up to 48 hours in 25 degree of operating times of normal temperature.Resin In the case of not heating, absorb the intensity after environment temperature can realize spontaneous curing, and solidification and meet design requirement.
3. contact with chimney side at woven fabric cloth, install, every certain length, the barrier film that width is length 1% additional. Ensure that resin-lined and chimney is in the NAG laminating in local state, to eliminate because temperature changes the different coefficient of expansion materials causing The stress that material produces.
4. regulation compound resin viscosity is directly sprayed on the composite fibre of vertical hanging and is formed uniform resin bed, The extruding utilizing horizontal air pressure makes it transmit and is impregnated on composite fibre, and last and inner side barrier film and inner wall of stack bonding are solid Chemical conversion one.
Brief description
Fig. 1:Inner wall of stack anti-corrosion leak-proof inner lining structure schematic diagram;
Fig. 2:The process flow diagram of embodiment 1;
Fig. 3:The process flow diagram of embodiment 2;
Fig. 4:The process flow diagram of embodiment 3.
Detailed description of the invention
The present invention is described in further detail below in conjunction with the accompanying drawings:
As shown in Figure 1:The anti-corrosion leak-proof liner that the present invention proposes, sets gradually separating film layer the 6th, machine on inner wall of stack 7 Textured fiber layer of cloth the 5th, compound resin layer the 4th, composite fibre layer the 3rd, compound resin layer the 4th, deep hole machine textured fiber layer of cloth the 2nd, composite film 1;
Described composite membrane 1 be have uvioresistant, oxidation resistant polyvinyl chloride (PVC), thermo-plastic polyurethane (TPUR) and Elastomeric material and high-molecular coating material.Composite film thickness 0.5-2mm.
Described deep hole machine textured fiber layer of cloth 2 is that weight per square meter exists:400≤W≤800 gram by polypropylene fiber, terylene The fiber cloth that fiber, carbon fiber, nylon fibre or aramid fiber are made into.
Described composite fibre layer 3 is that glass fibre passes through acupuncture or loop bonding with polyester fiber, polyster fibre or polypropylene fiber Multi-layer fiber.The thickness 2-6mm of usual composite fibre.
Described compound resin layer 4 is epoxy resin, unsaturated polyester resin, furane resins, vinylite and curing agent The cured layer being formed.Compound resin layer thickness 1-4mm.
Described woven fabric layer of cloth 5 is that weight per square meter exists:300≤W≤600 gram by polypropylene fiber, polyster fibre, The fiber cloth that carbon fiber, nylon fibre or aramid fiber are made into.
Described barrier film 6 is the film of one fixed width and the thickness adding every 5-10 rice in chimney height.Usual film Width is 5-10cm, and thickness is 0.5-2mm.Barrier film can be polyethylene (PE), polyvinyl chloride (PVC), thermo-plastic polyurethane And elastomeric material and high-molecular coating material (TPUR).
Described inner wall of stack 7 is chimney of electric plant steel cylinder or has installed expanded glass block.
Change according to manufacture craft can be combined processing, as by composite membrane 1 and deep hole machine textured fiber cloth 2 heat seal or Spraying forms certain thickness material.Barrier film 6 is formed certain thickness material with woven fabric cloth 5 heat seal or spraying.Root Determine resin requirement according to the gross thickness of anti-corrosion leak-proof liner.
Embodiment 1:
Use processing step as shown in Figure 2:
For diameter 6-9 rice, first the key that the high chimney of high 220-240 rice carries out overall anti-corrosion leak-proof determines that used Material and structure, next to that the technique implemented.According to material required in the overall anti-corrosion leak-proof inner lining structure schematic diagram of chimney It is prepared.First the diameter according to chimney and height customizes deep hole machine textured fiber cloth 2 and woven fabric cloth 5, then according to want Ask and composite membrane 1 and deep hole machine textured fiber cloth 2 are fabricated to an integral membrane, and barrier film 5 and woven fabric cloth 6 are synthesized one Body.Require customization composite fibre 3 according to thickness of inner lining, finally determine compound resin 4.Utilize upset principle, by integral membrane with The flexible pipe matching with Diameter of chimney and height made by composite fibre, woven fabric cloth, then required compound resin 4 is poured into soft Pipe carries out homogeneous impregnation process, utilizes air pressure to overturn, make compound resin and inner wall of stack 7 enrich bonding, barrier film 6 with Inner wall of stack fits tightly.Barrier film is used for absorbing steel chimney and the swelling stress that compound lining produces because material is different, Eventually pass and solidify to form the overall anti-corrosion leak-proof liner of hard chimney.This resin fibre liner both can be with the steel cigarette in outside The chimney adhesive solidification such as (or glass block corrosion protective lining) is integral, it is also possible to the steel chimney in outside (or the anticorrosion lining such as glass block In) fit tightly the independent independent anti-corrosion leak-proof liner with sufficient intensity of formation.Total thickness according to anti-corrosion leak-proof liner Degree determines resin requirement.Gross thickness 6-12mm of anti-corrosion leak-proof liner.The liner of this thickness is fully able to meet chimney Anti-corrosion leak-proof requires.
1st, chimney site inspection measurement
The overview of chimney is understood, as chimney diameter, height and extent of corrosion measure determination.
2nd, inner wall of stack cleaning
Inner wall of stack generally has expanded glass block anticorrosive coat, and inwall there will be peeling, fragmentation and corrosion spot.Manually carry out After dismounting, can use mechanical grinding or carry out shot blastinog with water under high pressure.
3rd, woven fabric cloth and barrier film cylinder
As requested, every 5-10 rice at woven fabric cloth 5 overlying barrier film 6.By the membrane material heat seal selected or spraying On woven fabric cloth.With being sewn into, according to the diameter of chimney and height, the woven fabric cloth cylinder matching therewith.Woven fabric cloth is used 500g/m2, barrier film is thick with 1mm, the wide TPUR of 8cm.
4th, woven fabric cloth cylinder is hung
Utilize high-altitude hanging basket and lifting means that the woven fabric cloth cylinder having sewed is suspended on chimney top.Top locking is solid Fixed, remainder fast-curing resin carries out a little fixing.Rapid curing available epoxy forms with T31 curing agent mixture.
5th, made composite fiber cylinder
Make composite fibre cylinder with composite fibre 3 according to the diameter of chimney and height.Foundation requires can with multiple-layer stacked extremely Required thickness.Available double glazing fiber forms with polyester fiber loop bonding, thickness 4mm.
6th, composite fibre cylinder is fixed
By Special-purpose lifting equipment, composite fibre cylinder is lifted on the inboard of woven fabric cloth cylinder.Top is locked, its Remaining part position fast-curing resin carries out a little fixing.
7th, compound resin is prepared
The diameter of the thickness according to anti-corrosion leak-proof liner and chimney and compound resin 4 total amount needed for high computational.According to tree The proportioning of fat and curing agent is accurately measured, and is stirred mixing with rotary folding stream as requested.Resin epoxy resin is joined With polyethers curing agent, the control resin presetting period is more than 48 hours.
8th, compound resin is sprayed
Utilize Lifting basket by high-pressure metering pump and spray gun by the compound resin even application for preparing to composite fibre Cylinder surface.The spraying rate 300kg/ hour of spray gun
9th, woven fabric cloth and composite membrane make cylinder
By heat seal or spraying composite membrane 1 and deep hole machine textured fiber cloth 2 formed one, then the height according to chimney and Internal diameter makes overall airtight cylinder.Deep hole machine is weaved cotton cloth and is used 600g/m2, composite membrane thermal polyurethane TPU.
10th, vertical Pneumatic turnover
By airtight for above-mentioned entirety cylinder by constant air pressure flip vertical to the composite fibre cylinder having sprayed compound resin, Adjust gas pressure, make compound resin uniformly extrude transmission and be impregnated into composite fibre cylinder and woven fabric cylinder until arriving the interior of chimney Wall surface.Pressure controllable system is high at 30-50cm water column.
11st, constant voltage solidification is maintained.
Overturn successful liner and kept constant pressure, maintained certain time resin i.e. curable, and ultimately form heavily fortified point Hard meets the liner that anti-corrosion leak-proof requires.Maintain constant voltage high more than 100 hours at 40cm water column.
12nd, port process
After liner is fully cured, excision two ends redundance, then carry out port sealing with resin glue.
13rd, inspection and acceptance
After completing lining processing, carry out liner intensity and Thickness sensitivity.Reach requirement.
Embodiment 2
Use processing step as shown in Figure 3:
1st, chimney site inspection measurement
The overview of chimney is understood, as chimney diameter, height and extent of corrosion measure determination.
2nd, inner wall of stack cleaning
Inner wall of stack generally has expanded glass block anticorrosive coat, and inwall there will be peeling, fragmentation and corrosion spot.Manually carry out After dismounting, can use mechanical grinding or carry out shot blastinog with water under high pressure.
3rd, woven fabric cloth and barrier film cylinder
As requested, every 5-10 rice at woven fabric cloth 5 overlying barrier film 6.By the membrane material heat seal selected or spraying On woven fabric cloth.Woven fabric cloth 550g/m2, barrier film thickness 1.2mm, the PVC of width 10cm.With according to chimney Diameter and height are sewn into the woven fabric cloth cylinder matching therewith.
4th, woven fabric cloth cylinder is hung
Utilize high-altitude hanging basket and lifting means that the woven fabric cloth cylinder having sewed is suspended on chimney top.Top locking is solid Fixed, remainder fast-curing resin carries out a little fixing.Rapid curing uses epoxy resin to add T31 curing agent.
5th, made composite fiber flexible pipe
According to the anti-corrosion leak-proof thickness of inner lining determining, composite fibre 3 and deep hole machine textured fiber cloth 2 are made with composite membrane 1 The complex fiber hose matching with diameter and the height of chimney.Composite fibre is glass fibre addition polymerization ester fiber.Thickness 3mm. Deep hole machine is weaved cotton cloth and is used 680g/m2Polypropylene, the PVC of composite membrane 1mm.
6th, compound resin is prepared
The diameter of the thickness according to liner and chimney and compound resin 4 total amount needed for high computational.According to resin and solidification The proportioning of agent is accurately measured, and is stirred mixing as requested.Resin furane resins, during curing agent control solidification initial set Between be more than 40 hours.
7th, compound resin pours into flexible pipe roll-in dipping
The compound resin 4 preparing is circulated in complex fiber hose by high-pressure metering pump, then carries out with twin rollers Roll and impregnate uniformly, forming adventitia resin fibre flexible pipe.Before being irrigated, carry out vacuumizing process to flexible pipe.Vacuum 0.05MPa.
8th, flip vertical resin fibre flexible pipe
Resin fibre flexible pipe is by air pressure flip vertical to the chimney 7 already equipped with woven fabric cloth 5.Adjust gas pressure Power, makes resin fibre flexible pipe be flipped up continuously.Compound resin 4 in flexible pipe uniformly extrudes and is impregnated into woven fabric cloth 5 Until the inner wall surface of chimney 7.
9th, maintain constant voltage to solidification
Keep constant pressure to having overturn successful resin fibre liner, maintain certain time resin i.e. curable, and Ultimately form and hard meet the liner that anti-corrosion leak-proof requires.Under the high pressure of 50cm water column, maintain and be more than 110 hours Solidification.
10th, port process
After liner is fully cured, excision two ends redundance, then seal with resin glue.
11st, inspection and acceptance
Example 3
Processing step as shown in Figure 4 is used to implement.
1st, chimney site inspection measurement
The overview of chimney is understood, as chimney diameter, height and extent of corrosion measure determination.
2nd, inner wall of stack cleaning
Inner wall of stack generally has expanded glass block anticorrosive coat, and inwall there will be peeling, fragmentation and corrosion spot.Manually carry out After dismounting, can use mechanical grinding or carry out shot blastinog with water under high pressure.
3rd, it is sewn into, according to the diameter and height of chimney site inspection measurement, the MULTILAYER COMPOSITE flexible pipe matching therewith.Multilayer is multiple Close flexible pipe to be weaved cotton cloth by woven fabric cloth 5 and composite fibre 3 and deep hole machine and 2 make with composite membrane 1.This flexible pipe is complete in customization workshop Become, if allowing to make nearby near chimney.Consider that flexible pipe volume is very large, be equipped with large-scale lifting appliance and move.
4th, the diameter of the thickness according to liner and chimney and compound resin needed for high computational 4 amount;Will be multiple by measuring pump Resin 4 is circulated into step 1) MULTILAYER COMPOSITE flexible pipe in, then carry out rolling and impregnate uniformly with distribution machine, form multilayer fine Dimension resin hose.The thickness 4-8mm of usual flexible pipe, the consumption of compound resin is at 6-9kg/m2
5th, multi-layer fiber resin hose is by air pressure flip vertical to chimney 7;Adjust gas pressure, make multi-layer fiber tree Fat flexible pipe overturns continuously up or down;Last integral with the inner wall surface close adhesion of chimney 7.The multilayer having impregnated is fine Dimension resin hose is transported to outside chimney bottom, utilizes air pressure to overturn, and source of the gas is by 2 10m3The air compressor machine of/min provides.Turn over Turn Stress control at 20-50cm water column, in switching process, water seal overflow valve is controlled pressure.
6th, multi-layer fiber resin hose is combined closely with inner wall of stack after upset.Resin side is glued with inner wall of stack Knot, the side of film becomes the new smooth inner wall of chimney.Through certain time, after being more than 5 days, resin is fully cured.Excision two ends Redundance, then carries out port sealing with resin glue, forms complete anti-corrosion leak-proof liner.
Due to the fact that the anti-corrosion leak-proof liner using composite fibre resin to be formed has light weight, anti-corrosive properties by force, integrally The high feature of property, it can be ensured that run steadily in the long term after chimney of electric plant wet type desulfurizing.The speed of application of the other present invention is permissible soon Bring great economic benefit for power plant.
The present invention is open and the chimney of electric plant inner wall anti-corrosive antiseepage liner that proposes and utilize flip vertical method to realize that chimney is existing The method that field is installed, those skilled in the art can suitably change the link realizations such as condition route by using for reference present disclosure, although The method of the present invention and technology of preparing are described by preferred embodiment, person skilled substantially can without departing from In present invention, spirit and scope, methods and techniques described herein route is modified or reconfigures, realize Whole technology of preparing.Special needs to be pointed out is, all similar replacements and change are aobvious for a person skilled in the art And be clear to, they are considered as including in present invention spirit, scope and content.

Claims (10)

1. a chimney of electric plant inner wall anti-corrosive antiseepage liner;It is characterized in that setting gradually separating film layer on inner wall of stack (7) (6), woven fabric layer of cloth (5), compound resin layer (4), composite fibre layer (3), compound resin layer (4), deep hole machine textured fiber cloth Layer (2), composite film (1).
2. anti-corrosion leak-proof liner as claimed in claim 1;It is characterized in that described composite membrane (1) is to have uvioresistant, antioxygen Polyvinyl chloride, thermo-plastic polyurethane and the elastomeric material changed and high-molecular coating material;Composite film thickness 0.5-2mm.
3. antiseepage liner as claimed in claim 1;It is characterized in that described deep hole machine textured fiber layer of cloth (2) is weight per square meter ?:The fiber cloth being made into by polypropylene fiber, polyster fibre, carbon fiber, nylon fibre or aramid fiber of 400≤W≤800 gram.
4. anti-corrosion leak-proof liner as claimed in claim 1;It is characterized in that described composite fibre layer (3) is glass fibre and polyester Fiber, polyster fibre or polypropylene fiber are by the multi-layer fiber of acupuncture or loop bonding;The thickness 2-6mm of usual composite fibre.
5. anti-corrosion leak-proof liner as claimed in claim 1;It is characterized in that described compound resin layer (4) is epoxy resin, insatiable hunger The cured layer being formed with curing agent with polyester resin, furane resins, vinylite;Compound resin layer thickness 1-4mm.
6. anti-corrosion leak-proof liner as claimed in claim 1;It is characterized in that described woven fabric layer of cloth (5) is weight per square meter ?:The fiber cloth being made into by polypropylene fiber, polyster fibre, carbon fiber, nylon fibre or aramid fiber of 300≤W≤500 gram.
7. anti-corrosion leak-proof liner as claimed in claim 1;It is characterized in that described barrier film (6) is every 5-in chimney height 10 meters of films adding;The width of film is 5-10cm, and thickness is 0.5-2mm;Barrier film is polyethylene, polyvinyl chloride, the poly-ammonia of thermoplastic Ester and elastomeric material and high-molecular coating material;Described inner wall of stack (7) is chimney of electric plant steel cylinder or has installed expanded Glass block.
8. utilize flip vertical method to realize the field erected method of inner wall of stack anti-corrosion leak-proof liner;It is characterized in that step is as follows:
1) carry out on-the-spot chimney and reconnoitre measurement, be sewn into, according to the diameter and height of chimney, the woven fabric cloth cylinder matching therewith; Every 5-10 rice at woven fabric cloth (5) overlying barrier film (6);By the membrane material heat seal of selection or be sprayed on woven fabric cloth On;
2) multiple-layer stacked is made to required thickness composite fibre cylinder with composite fibre (3) according to the diameter of chimney and height;
3) high-altitude hanging basket and lifting means are utilized by step 1) to be suspended on the locking of chimney top solid for the woven fabric cloth cylinder that sewed Fixed, remainder fast-curing resin carries out a little fixing;
4) by step 2) composite fibre cylinder is lifted on the inboard of woven fabric cloth cylinder, and top is locked, and remaining position is with quick Solidification resin carries out a little fixing;
5) diameter of the thickness according to anti-corrosion leak-proof liner and chimney and compound resin (4) needed for high computational;Utilize lifting hanger Basket by high-pressure metering pump and spray gun by the compound resin even application for preparing to composite fibre cylinder surface;
6) pass through heat seal or composite membrane (1) is formed one, the then height according to chimney with deep hole machine textured fiber cloth (2) by spraying Make overall airtight cylinder with internal diameter;
7) by airtight for above-mentioned entirety cylinder by constant air pressure flip vertical to the composite fibre cylinder having sprayed compound resin, adjust Whole gas pressure, makes compound resin uniformly extrude transmission and is impregnated into composite fibre cylinder and woven fabric cylinder until arriving the inwall of chimney Surface;
8) after liner is fully cured, excision two ends redundance, then carry out port sealing with resin glue.
9. utilize flip vertical method to realize the field erected method of inner wall of stack anti-corrosion leak-proof liner;It is characterized in that step is as follows:
1) carry out on-the-spot chimney and reconnoitre measurement, be sewn into, according to the diameter and height of chimney, the woven fabric cloth cylinder matching therewith; Every 5-10 rice at woven fabric cloth (5) overlying barrier film (6);By the membrane material heat seal of selection or be sprayed on woven fabric cloth On;
2) according to the anti-corrosion leak-proof thickness of inner lining determining, by composite fibre (3) and deep hole machine textured fiber cloth (2) and composite membrane (1) Make the diameter with chimney and the complex fiber hose highly matching;
3) high-altitude hanging basket and lifting means are utilized by step 1) to be suspended on the locking of chimney top solid for the woven fabric cloth cylinder that sewed Fixed, remainder fast-curing resin carries out a little fixing;
4) diameter of the thickness according to liner and chimney and compound resin (4) amount needed for high computational;Filled by high-pressure metering pump Enter to step 2) complex fiber hose in, then carry out rolling and impregnate uniformly with twin rollers, form adventitia resin fibre soft Pipe;
5) resin fibre flexible pipe is by air pressure flip vertical to the chimney (7) already equipped with woven fabric cloth (5);Adjust gas Pressure, makes resin fibre flexible pipe overturn up or down continuously;Compound resin (4) in flexible pipe uniformly extrudes and is impregnated into woven Fiber cloth (5) cylinder is until the inner wall surface of chimney (7);
6) after liner is fully cured, excision two ends redundance, then seal with resin glue.
10. utilize flip vertical method to realize the field erected method of inner wall of stack anti-corrosion leak-proof liner;It is characterized in that step is as follows:
1) carry out on-the-spot chimney and reconnoitre measurement, be sewn into, according to the diameter and height of chimney, the MULTILAYER COMPOSITE flexible pipe matching therewith; MULTILAYER COMPOSITE flexible pipe by woven fabric cloth (5) and composite fibre (3) and deep hole machine weave cotton cloth (2) make with composite membrane (1);
2) diameter of the thickness according to liner and chimney and compound resin (4) amount needed for high computational;Will be compound by measuring pump Resin (4) is circulated into step 1) MULTILAYER COMPOSITE flexible pipe in, then carry out rolling and impregnate uniformly with distribution machine, form multilayer fine Dimension resin hose;
3) multi-layer fiber resin hose is by air pressure flip vertical to chimney (7);Adjust gas pressure, make multi-layer fiber resin Flexible pipe overturns continuously up or down;Last integral with the inner wall surface close adhesion of chimney (7);
4) after multi-layer fiber resin hose is combined positioning with inner wall of stack, being fully cured through certain time, excision two ends are unnecessary Part, then carries out port sealing with resin glue, forms complete anti-corrosion leak-proof liner.
CN201610707623.1A 2016-08-23 2016-08-23 Chimney of electric plant inner wall anti-corrosive antiseepage liner and utilization flip vertical method realize the field erected method of chimney Expired - Fee Related CN106427105B (en)

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