CN106426975B - A kind of preparation process of compound fishing rod - Google Patents

A kind of preparation process of compound fishing rod Download PDF

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Publication number
CN106426975B
CN106426975B CN201610856493.8A CN201610856493A CN106426975B CN 106426975 B CN106426975 B CN 106426975B CN 201610856493 A CN201610856493 A CN 201610856493A CN 106426975 B CN106426975 B CN 106426975B
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drying
curing
melt
relative humidity
fishing rod
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CN106426975A (en
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陈雨
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0092—Drying moulded articles or half products, e.g. preforms, during or after moulding or cooling
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/70—Agricultural usage or equipment
    • B29L2031/7002—Agricultural usage or equipment for fishing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Composite Materials (AREA)
  • Thermal Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

A kind of preparation process of compound fishing rod, which is characterized in that steps are as follows：(1) composite material is sent into fusion apparatus, heating fusing obtains melt；(2) non-woven fabrics is cut by being sized, and the non-woven fabrics cut is immersed in melt, melt is made to be combined with non-woven fabrics；(3) nonwoven fabric roll for being soaked with melt is wound on core material, is sent into curing apparatus and carries out curing process, remove core material, japanning drying after the completion；Present invention process step is simple, and technique is controllable, keeps manufactured fishing rod surface smooth closely knit, and have excellent mechanical property.

Description

A kind of preparation process of compound fishing rod
Technical field
The present invention relates to fishing gear technical fields, and in particular to a kind of preparation process of compound fishing rod.
Background technology
Have become a kind of important amusement of people, stress-relieving activity with the continuous improvement of people's living standards, fishing, it is competing Skill fishing also frequent development like a raging fire.Fishing rod currently on the market is mostly carbon fiber fishing rod, is using no shuttle Carbon fiber longitudinal direction cloth tubulation is spun, is manufactured through resin pickup solidification.How much is carbon fiber content in terms of for fishing rod production, directly Determine the value and grade of fishing rod.General phosphorus content is 30%, 90% or so, fishing rod manufacture with carbon fiber with it is light, solid, The high feature of tensile strength, but do not have insulation function.
Invention content
Technical problem to be solved by the present invention lies in providing, a kind of processing step is simple, the good compound fishing of controllability The preparation process of pole.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of preparation process of compound fishing rod, its step are as follows：
(1) composite material is sent into fusion apparatus, heating fusing obtains melt；
(2) non-woven fabrics is cut by being sized, and the non-woven fabrics cut is immersed in melt, make melt and nothing Woven fabric combines；
(3) nonwoven fabric roll for being soaked with melt is wound on core material, is sent into curing apparatus and carries out curing process, removes after the completion Core material, japanning drying.
The curing process of above-mentioned curing process is as follows：
First cure stage：Solidification temperature is at 65 DEG C in control curing room, and 99%, curing time control exists relative humidity 12 hours；
Second cure stage：Solidification temperature is at 70 DEG C in control curing room, and 99%, curing time control exists relative humidity 15 hours；
Third cure stage：Solidification temperature is at 72 DEG C in control curing room, and 82%, curing time control exists relative humidity 5 hours；
First drying stage：Drying temperature is at 80 DEG C in control curing room, and 65%, drying time control exists relative humidity 2 hours；
Second drying stage：Drying temperature is at 73 DEG C in control curing room, and 40%, drying time control exists relative humidity 2 hours；
Third drying stage：Drying temperature is at 85 DEG C in control curing room, and 0.5%, drying time controls relative humidity At 18 hours.The curing process relative energy-saving, obtained product total quality are stablized, and qualification rate is up to 100%.
Above-mentioned japanning drying is carried out in drying equipment.
Above-mentioned drying equipment is steam drying equipment.
Above-mentioned fusion apparatus is double screw extruder.
Above-mentioned composite material is made of the component of following mass percent：Polyethylene terephthalate 10%, carbon Fiber 60%, glass fibre 10%, methylvinylcyclosiloxane 5%, epoxy hardener 2%, nylon 3%, imitative spider silk are fine Dimension 1%, antistatic agent 1%, tackifier 5%, glycerine 0.2%, bamboo fibre 0.8%, nano silicon dioxide 2%.
Above-mentioned tackifier are made of the component of following weight：Ethylene glycol 80g, glycidyl acrylate 15g, pitch 5g, n-butyl acrylate 10g, lauryl mercaptan 5g, lac resin 4g, microwax 2g, pure-acrylic emulsion 5g；The tackifier are special It is configured for regeneration insulation fishing rod, the speed of viscosity increasement is fast, and effect is good.
The preparation method of above-mentioned composite material is as follows：
(1) by polyethylene terephthalate, methylvinylcyclosiloxane, epoxy hardener, antistatic agent, glycerine It is sent into rotary drum and is mixed with nano silicon dioxide, while rotary drum is heated up to 80-120 DEG C, the time at 40 minutes, presses Power obtains mixture in 150-200Mpa, taking-up；
(2) by tackifier, glass fibre, imitative spider silk fiber, nylon and bamboo fibre, after being plasticized by single screw extrusion machine It is transported to high-temperature fusant reaction kettle by mouth mold, mixture is added, keeps kettle temperature in 235~240 DEG C, 2.0~2.5MPa of pressure Under the conditions of, obtain blend melt；
(3) blend melt is sent to dipping head, the temperature for impregnating head is set as 280-360 DEG C, and carbon fiber is led to It crosses dipping head die hole, after dipping, is pulled out dipping head, cooling, pelletizing obtains composite material.
Fishing rod of the present invention possesses insulation function, and advantage is good toughness, light-weight, be using high-tech carbon dimension material manufacture and At；Existing product character more in the market has occurred some changes, more superior than pure carbon fishing rod in performance, shows as：Matter Lighter, intensity bigger is measured, rod tip can be bent 180 degree, and soft rod tip is more conducive to unload power, be caused when preventing violent big fish from struggling Disconnected pole or broken string；It can avoid recreational fishing lightning stroke, electric shock accidents generation simultaneously, effectively reduce in thundery sky outdoor fishing Unexpected rate.
The beneficial effects of the invention are as follows：Present invention process step is simple, and technique is controllable, keeps manufactured fishing rod surface smooth close It is real, and there is excellent mechanical property.
Specific implementation mode
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of preparation process of compound fishing rod, its step are as follows：
(1) composite material is sent into fusion apparatus, heating fusing obtains melt；
(2) non-woven fabrics is cut by being sized, and the non-woven fabrics cut is immersed in melt, make melt and nothing Woven fabric combines；
(3) nonwoven fabric roll for being soaked with melt is wound on core material, is sent into curing apparatus and carries out curing process, removes after the completion Core material, japanning drying, drying is carried out in steam drying equipment；
The curing process of above-mentioned curing process is as follows：
First cure stage：Solidification temperature is at 65 DEG C in control curing room, and 99%, curing time control exists relative humidity 12 hours；
Second cure stage：Solidification temperature is at 70 DEG C in control curing room, and 99%, curing time control exists relative humidity 15 hours；
Third cure stage：Solidification temperature is at 72 DEG C in control curing room, and 82%, curing time control exists relative humidity 5 hours；
First drying stage：Drying temperature is at 80 DEG C in control curing room, and 65%, drying time control exists relative humidity 2 hours；
Second drying stage：Drying temperature is at 73 DEG C in control curing room, and 40%, drying time control exists relative humidity 2 hours；
Third drying stage：Drying temperature is at 85 DEG C in control curing room, and 0.5%, drying time controls relative humidity At 18 hours.The curing process relative energy-saving, obtained product total quality are stablized, and qualification rate is up to 100%.
Embodiment 2
A kind of preparation process of compound fishing rod, its step are as follows：
(1) composite material is sent into fusion apparatus, heating fusing obtains melt；
(2) non-woven fabrics is cut by being sized, and the non-woven fabrics cut is immersed in melt, make melt and nothing Woven fabric combines；
(3) nonwoven fabric roll for being soaked with melt is wound on core material, is sent into curing apparatus and carries out curing process, removes after the completion Core material, japanning drying.
The curing process of above-mentioned curing process is as follows：
First cure stage：Solidification temperature is at 65 DEG C in control curing room, and 99%, curing time control exists relative humidity 12 hours；
Second cure stage：Solidification temperature is at 70 DEG C in control curing room, and 99%, curing time control exists relative humidity 15 hours；
Third cure stage：Solidification temperature is at 72 DEG C in control curing room, and 82%, curing time control exists relative humidity 5 hours；
First drying stage：Solidification temperature is at 80 DEG C in control curing room, and 65%, drying time control exists relative humidity 2 hours；
Second drying stage：Solidification temperature is at 73 DEG C in control curing room, and 40%, drying time control exists relative humidity 2 hours；
Third drying stage：Solidification temperature is at 85 DEG C in control curing room, and 0.5%, drying time controls relative humidity At 18 hours.The curing process relative energy-saving, obtained product total quality are stablized, and qualification rate is up to 100%.
Embodiment 3
A kind of preparation process of compound fishing rod, its step are as follows：
(1) composite material is sent into fusion apparatus, heating fusing obtains melt；
(2) non-woven fabrics is cut by being sized, and the non-woven fabrics cut is immersed in melt, make melt and nothing Woven fabric combines；
(3) nonwoven fabric roll for being soaked with melt is wound on core material, is sent into curing apparatus and carries out curing process, removes after the completion Core material, japanning drying.
The curing process of above-mentioned curing process is as follows：
First cure stage：Solidification temperature is at 65 DEG C in control curing room, and 99%, curing time control exists relative humidity 12 hours；
Second cure stage：Solidification temperature is at 70 DEG C in control curing room, and 99%, curing time control exists relative humidity 15 hours；
Third cure stage：Solidification temperature is at 72 DEG C in control curing room, and 82%, curing time control exists relative humidity 5 hours；
First drying stage：Solidification temperature is at 80 DEG C in control curing room, and 65%, drying time control exists relative humidity 2 hours；
Second drying stage：Solidification temperature is at 73 DEG C in control curing room, and 40%, drying time control exists relative humidity 2 hours；
Third drying stage：Solidification temperature is at 85 DEG C in control curing room, and 0.5%, drying time controls relative humidity At 18 hours.The curing process relative energy-saving, obtained product total quality are stablized, and qualification rate is up to 100%.
Above-mentioned composite material is made of the component of following mass percent：Polyethylene terephthalate 10%, carbon Fiber 60%, glass fibre 10%, methylvinylcyclosiloxane 5%, epoxy hardener 2%, nylon 3%, imitative spider silk are fine Dimension 1%, antistatic agent 1%, tackifier 5%, glycerine 0.2%, bamboo fibre 0.8%, nano silicon dioxide 2%.
Above-mentioned tackifier are made of the component of following weight：Ethylene glycol 80g, glycidyl acrylate 15g, pitch 5g, n-butyl acrylate 10g, lauryl mercaptan 5g, lac resin 4g, microwax 2g, pure-acrylic emulsion 5g；The tackifier are special It is configured for regeneration insulation fishing rod, the speed of viscosity increasement is fast, and effect is good.
The preparation method of above-mentioned composite material is as follows：
(1) by polyethylene terephthalate, methylvinylcyclosiloxane, epoxy hardener, antistatic agent, glycerine It is sent into rotary drum and is mixed with nano silicon dioxide, while rotary drum is heated up to 80-120 DEG C, the time at 40 minutes, presses Power obtains mixture in 150-200Mpa, taking-up；
(2) by tackifier, glass fibre, imitative spider silk fiber, nylon and bamboo fibre, after being plasticized by single screw extrusion machine It is transported to high-temperature fusant reaction kettle by mouth mold, mixture is added, keeps kettle temperature in 235~240 DEG C, 2.0~2.5MPa of pressure Under the conditions of, obtain blend melt；
(3) blend melt is sent to dipping head, the temperature for impregnating head is set as 280-360 DEG C, and carbon fiber is led to It crosses dipping head die hole, after dipping, is pulled out dipping head, cooling, pelletizing obtains composite material.
By above-described embodiment, fishing rod made from example 1~3 is tested, test performance is as shown in the table：
Performance Embodiment 1 Embodiment 2 Embodiment 3
Bending strength MPa 1560 1540 1680
Bending modulus GPa 102 106 158
Interlaminar shear strength MPa 72 80 90.2
As can be seen from the above table, 1~3 comprehensive mechanical property of the embodiment of the present invention is excellent, compared with the fishing rod of the prior art, It has been obviously improved bending strength, bending modulus, interlaminar shear strength.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (4)

1. a kind of preparation process of compound fishing rod, which is characterized in that steps are as follows：
(1) composite material is sent into fusion apparatus, heating fusing obtains melt；
(2) non-woven fabrics is cut by being sized, and the non-woven fabrics cut is immersed in melt, make melt and non-woven fabrics In conjunction with；
(3) nonwoven fabric roll for being soaked with melt is wound on core material, is sent into curing apparatus and carries out curing process, removes core after the completion Material, japanning drying；
The curing process of above-mentioned curing process is as follows：
First cure stage：Solidification temperature is at 65 DEG C in control curing room, and for relative humidity 99%, curing time control is small 12 When；
Second cure stage：Solidification temperature is at 70 DEG C in control curing room, and for relative humidity 99%, curing time control is small 15 When；
Third cure stage：Solidification temperature is at 72 DEG C in control curing room, and for relative humidity 82%, curing time control is small 5 When；
First drying stage：Drying temperature is at 80 DEG C in control curing room, and for relative humidity 65%, drying time control is small 2 When；
Second drying stage：Drying temperature is at 73 DEG C in control curing room, and for relative humidity 40%, drying time control is small 2 When；
Third drying stage：Drying temperature is at 85 DEG C in control curing room, and 0.5%, drying time controls 18 relative humidity Hour；
Above-mentioned composite material is made of the component of following mass percent：Polyethylene terephthalate 10%, carbon fiber 60%, glass fibre 10%, methylvinylcyclosiloxane 5%, epoxy hardener 2%, nylon 3%, imitative spider silk fiber 1%, antistatic agent 1%, tackifier 5%, glycerine 0.2%, bamboo fibre 0.8%, nano silicon dioxide 2%；
Above-mentioned tackifier are made of the component of following weight：Ethylene glycol 80g, glycidyl acrylate 15g, pitch 5g, third Olefin(e) acid N-butyl 10g, lauryl mercaptan 5g, lac resin 4g, microwax 2g, pure-acrylic emulsion 5g；
The preparation method of above-mentioned composite material is as follows：
(1) it by polyethylene terephthalate, methylvinylcyclosiloxane, epoxy hardener, antistatic agent, glycerine and receives Rice silica, which is sent into rotary drum, to be mixed, while rotary drum is heated up to 80-120 DEG C, and the time, pressure existed at 40 minutes 150-200Mpa, taking-up obtain mixture；
(2) by tackifier, glass fibre, imitative spider silk fiber, nylon and bamboo fibre, pass through after being plasticized by single screw extrusion machine Mouth mold is transported to high-temperature fusant reaction kettle, and mixture is added, and keeps kettle temperature in 235~240 DEG C, pressure 2.0~2.5MPa conditions Under, obtain blend melt；
(3) blend melt is sent to dipping head, the temperature for impregnating head is set as 280-360 DEG C, and carbon fiber is passed through leaching Stain head die hole after dipping, is pulled out dipping head, and cooling, pelletizing obtains composite material.
2. a kind of preparation process of compound fishing rod according to claim 1, which is characterized in that the drying of above-mentioned japanning be It is carried out in drying equipment.
3. a kind of preparation process of compound fishing rod according to claim 2, which is characterized in that above-mentioned drying equipment is to steam Vapour drying equipment.
4. a kind of preparation process of compound fishing rod according to claim 1, which is characterized in that above-mentioned fusion apparatus is double Screw extruder.
CN201610856493.8A 2016-09-27 2016-09-27 A kind of preparation process of compound fishing rod Active CN106426975B (en)

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Publication number Priority date Publication date Assignee Title
CN112352748B (en) * 2017-02-28 2022-06-24 威海金七星新材料有限公司 Preparation method of fishing rod guide hole
CN106916392A (en) * 2017-03-24 2017-07-04 合肥悦兰信息技术有限公司 Laminated bow material for producing the light-duty bow and arrow of high resiliency

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0549372A (en) * 1991-08-19 1993-03-02 Shimano Inc Fishing rod and its production
JP2007089478A (en) * 2005-09-29 2007-04-12 Daiwa Seiko Inc Tubular body
CN101513177A (en) * 2008-02-18 2009-08-26 周鸢 Fishing rod doped with carbon nanometer particles and preparation method thereof

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