E glass fishing rod cloth yarn treating compound
Technical field
The present invention relates to a kind of E fiberglass surface treating agent containing organic materials.
Background technology
E glass fibre fishing rod cloth yarn is mainly used in knitting fishing rod cloth, and fishing rod cloth is the enhancing base material producing fishing rod, requires there is good associativity with epoxy resin, unsaturated polyester, resol etc.The treating compound of traditional E glass fibre fishing rod cloth yarn production and application is with paraffin, stearic acid, transformer oil, laking agent, peregal emulsifying agent for raw material, and its component (wt%) is as follows:
Machine oil: 0.5-3.0
Vaseline: 1.0-2.0
Paraffin: 1.5-2.5
Stearic acid: 2.0-4.0
Laking agent: 2.0-6.0
Peregal: 20:0.5-1.0
Deionized water: 81.5-94.5.
There is the resins such as two shortcoming: a. and epoxy resin, unsaturated polyester, phenolic aldehyde and do not soak in the glass fibre fishing rod yarn should produced containing the treating compound of paraffin; B. the cloth that is made into needs to be dewaxed by the treating compound of fiber surface at smouldering furnace 300 DEG C-380 DEG C 24h-30h that smoulders.Fishing rod cloth strength loss 20-40% after dewaxing, directly affects the intensity of fishing rod goods.
Summary of the invention
The present invention aims to provide and a kind ofly can significantly improve the impregnability of E glass fishing rod cloth yarn and the E glass fishing rod cloth yarn treating compound of associativity.
E glass fishing rod cloth yarn treating compound of the present invention, to be made up of and mass percentage forms following:
Membrane-forming agent 2.3-15.5%
Coupling agent 0.1-1.0%
Softening agent 0.01-1.5%
Emulsifying agent 0.05-1.0%
Imidazole cation lubricant 0.1-1.0%
Static inhibitor 0.05-1.0%
Ph conditioning agent 0.05-1.0%
Deionized water 78-97.34%.
Preferably, described membrane-forming agent is made up of epoxy emulsion film forming agent and unsaturated polyester membrane-forming agent, and their mass ratio is 0.2-5.5:2.1-10.
Or more preferably, to be made up of and mass percentage forms following:
Membrane-forming agent 3.5-12.5%
Coupling agent 0.2-0.8%
Softening agent 0.02-1.0%
Emulsifying agent 0.05-0.8%
Imidazole cation lubricant 0.15-0.8%
Static inhibitor 0.1-0.8%
Ph conditioning agent 0.1-1.0%
Deionized water 81.83-95.88%.
Further preferably, described membrane-forming agent is made up of epoxy emulsion film forming agent and unsaturated polyester membrane-forming agent, and their mass ratio is 1.0-3.0:2.5-9.5.
Or more preferably, described coupling agent is silane coupling agent.
Further preferably, described silane coupling agent is silane coupling A-174 and silane coupling A-1100, and their mass ratio is 0.05-0.5:0.05-0.5.
Or more preferably, described softening agent is one or both in dibutyl phthalate and dioctyl phthalate (DOP).
Or more preferably, described emulsifying agent is peregal-20.
Or more preferably, described Ph conditioning agent is citric acid.
E glass fishing rod cloth yarn treating compound of the present invention can be prepared from the following method:
A. get the deionized water of silane coupling agent weight 30 times, add citric acid and regulate Ph value to 3-4, slowly add silane coupling agent while stirring, under the condition of 60-80rpm, stir 30-60min;
B. plastic binder and emulsifying agent, then at 80-95 DEG C, heating melts, and then in this mixture, add its weight 5-20 70-90 DEG C of deionized water doubly equably along with being stirred in 30min-60min, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. in Imidazole cation lubricant, add its quality 5-20 80-90 DEG C of deionized water doubly, stir in homogeneous transparent liquid;
D. in static inhibitor, add its quality 2-10 30-50 DEG C of deionized water doubly, stir in homogeneous transparent liquid;
E. respectively to respectively adding its quality 1-5 deionized water doubly in epoxy emulsion film forming agent and unsaturated polyester membrane-forming agent;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of surplus, under 50rpm-60rpm condition, stir 30-40min.
The E glass fishing rod cloth yarn treating compound that the present invention obtains can use with the following method: the glass metal of melting is from each middle outflow of leting slip a remark, taper silk root is formed under drawing wire machine is to its effect of drawing, by many fibrous whole covering of the fans, through the single filament oiling equipment that is rotated, by single filament oiling equipment, described E glass fishing rod cloth yarn treating compound is applied to the surface of every root fiber, then assemble filament tow by buncher, be referred to as precursor.Precursor is guided on drawing wire machine from buncher, then takes off from drawing wire machine, carries out unwinding, is plied to required yarn through twisting frame.
E glass fishing rod cloth yarn treating compound of the present invention can be used for processing E glass fibre fishing rod yarn, make it have soak into fast, with epoxy resin, unsaturated polyester resin, premium properties that resol associativity is good; And the cloth of its weaving does not need dewaxing of smouldering, and effectively reduces energy consumption, improves fishing rod quality; This E glass fibre fishing rod yarn also has the characteristic that adhesive rate is low, brute force is high, weaving efficiency is high simultaneously.
Embodiment
Embodiment one.
A. get the deionized water of 9 kilograms, add 0.05 kilogram of citric acid and regulate Ph value to 3-4, slowly add the silane coupling A-174 (U.S. GESilicones) of 0.3 kilogram while stirring, under the condition of 60-80rpm, stir 30-60min;
B. 0.02 kilogram of plasticizer phthalic acid and 0.4 kilogram of emulsifying agent peregal-20 is mixed, then at 80-95 DEG C, heating melts, then along with being stirred in 30min-60min the 70-90 DEG C of deionized water adding 8.4 kilograms equably, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. the condensation material company limited that reconstructs in the Imidazole cation lubricant ZB09(Xi'an of 0.1 kilogram produces) in add the 80-90 DEG C of deionized water of 1 kilogram, stir in homogeneous transparent liquid;
D. to 0.05 kilogram of static inhibitor 6660A(U.S. EMERY) in add the 30-50 DEG C of deionized water of 0.36 kilogram, stir in homogeneous transparent liquid;
E. produce to the epoxy emulsion film forming agent YG101(Xi'an friend based composites company limited of 1.0 kilograms) in add the deionized water of 5 kilograms;
Produce to the unsaturated polyester membrane-forming agent YG2880(Xi'an friend based composites company limited of 3.0 kilograms) in add the deionized water of 12 kilograms;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of 45.32 kilograms, under 50rpm-60rpm condition, stir 30-40min namely obtain E glass fishing rod cloth yarn treating compound 1;
G. applied under the speed of 65-85m/min by the E glass fishing rod cloth yarn treating compound of gained, the yarn Performance Detection of production is as follows:
。
Embodiment two.
A. get the deionized water of 10.5 kilograms, add 0.05 kilogram of citric acid and regulate Ph value to 3-4, slowly add the silane coupling A-174 (U.S. GESilicones) of 0.35 kilogram while stirring, under the condition of 60-80rpm, stir 30-60min;
B. 0.04 kilogram of plasticizer phthalic acid dibutylester and 0.6 kilogram of emulsifying agent peregal-20 is mixed, then at 80-95 DEG C, heating melts, then along with being stirred in 30min-60min the 70-90 DEG C of deionized water adding 12.8 kilograms equably, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. the condensation material company limited that reconstructs in the Imidazole cation lubricant ZB09(Xi'an of 0.15 kilogram produces) in add the 80-90 DEG C of deionized water of 2.25 kilograms, stir in homogeneous transparent liquid;
D. to 0.08 kilogram of static inhibitor 6660A(U.S. EMERY) in add the 30-50 DEG C of deionized water of 0.64 kilogram, stir in homogeneous transparent liquid;
E. produce to the epoxy emulsion film forming agent YG101(Xi'an friend based composites company limited of 2.0 kilograms) in add the deionized water of 10 kilograms;
Produce to the unsaturated polyester membrane-forming agent YG2880(Xi'an friend based composites company limited of 3.2 kilograms) in add the deionized water of 6 kilograms;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of 51.34 kilograms, under 50rpm-60rpm condition, stir 30-40min namely obtain E glass fishing rod cloth yarn treating compound 2;
G. applied under the speed of 65-85m/min by the E glass fishing rod cloth yarn treating compound of gained, the yarn Performance Detection of production is as follows:
。
Embodiment three.
A. the deionized water of 12 kilograms is got, adding 0.06 kilogram of citric acid regulates Ph value to 3-4, slowly add the silane coupling A-174 (U.S. GESilicones) of 0.2 kilogram and the silane coupling A-1100 (U.S. GESilicones) of 0.2 kilogram while stirring, under the condition of 60-80rpm, stir 30-60min;
B. 0.04 kilogram of plasticizer phthalic acid dibutylester and 0.6 kilogram of emulsifying agent peregal-20 is mixed, then at 80-95 DEG C, heating melts, then along with being stirred in 30min-60min the 70-90 DEG C of deionized water adding 12.8 kilograms equably, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. the condensation material company limited that reconstructs in the Imidazole cation lubricant ZB09(Xi'an of 0.15 kilogram produces) in add the 80-90 DEG C of deionized water of 2.25 kilograms, stir in homogeneous transparent liquid;
D. to 0.1 kilogram of static inhibitor 6660A(U.S. EMERY) in add the 30-50 DEG C of deionized water of 1 kilogram, stir in homogeneous transparent liquid;
E. produce to the epoxy emulsion film forming agent YG101(Xi'an friend based composites company limited of 3.0 kilograms) in add the deionized water of 12.5 kilograms;
Produce to the unsaturated polyester membrane-forming agent YG2880(Xi'an friend based composites company limited of 3.5 kilograms) in add the deionized water of 12.5 kilograms;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of 39.1 kilograms, under 50rpm-60rpm condition, stir 30-40min namely obtain E glass fishing rod cloth yarn treating compound 3;
G. applied under the speed of 65-85m/min by the E glass fishing rod cloth yarn treating compound of gained, the yarn Performance Detection of production is as follows:
。
Embodiment four.
A. the deionized water of 12 kilograms is got, adding 0.06 kilogram of citric acid regulates Ph value to 3-4, slowly add the silane coupling A-174 (U.S. GESilicones) of 0.2 kilogram and the silane coupling A-1100 (U.S. GESilicones) of 0.2 kilogram while stirring, under the condition of 60-80rpm, stir 30-60min;
B. 0.04 kilogram of plasticizer phthalic acid dibutylester and 0.8 kilogram of emulsifying agent peregal-20 is mixed, then at 80-95 DEG C, heating melts, then along with being stirred in 30min-60min the 70-90 DEG C of deionized water adding 16.8 kilograms equably, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. the condensation material company limited that reconstructs in the Imidazole cation lubricant ZB09(Xi'an of 0.2 kilogram produces) in add the 80-90 DEG C of deionized water of 3.2 kilograms, stir in homogeneous transparent liquid;
D. to 0.15 kilogram of static inhibitor 6660A(U.S. EMERY) in add the 30-50 DEG C of deionized water of 1.2 kilograms, stir in homogeneous transparent liquid;
E. produce to the epoxy emulsion film forming agent YG101(Xi'an friend based composites company limited of 4.8 kilograms) in add the deionized water of 19.2 kilograms;
Produce to the unsaturated polyester membrane-forming agent YG2880(Xi'an friend based composites company limited of 2.6 kilograms) in add the deionized water of 10.4 kilograms;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of 28.15 kilograms, under 50rpm-60rpm condition, stir 30-40min namely obtain E glass fishing rod cloth yarn treating compound 4;
G. applied under the speed of 65-85m/min by the E glass fishing rod cloth yarn treating compound of gained, the yarn Performance Detection of production is as follows:
。
Embodiment five.
A. the deionized water of 15 kilograms is got, adding 0.07 kilogram of citric acid regulates Ph value to 3-4, slowly add the silane coupling A-174 (U.S. GESilicones) of 0.1 kilogram and the silane coupling A-1100 (U.S. GESilicones) of 0.4 kilogram while stirring, under the condition of 60-80rpm, stir 30-60min;
B. 0.02 kilogram of plasticizer phthalic acid dioctyl ester and 0.6 kilogram of emulsifying agent peregal-20 is mixed, then at 80-95 DEG C, heating melts, then along with being stirred in 30min-60min the 70-90 DEG C of deionized water adding 12.4 kilograms equably, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. the condensation material company limited that reconstructs in the Imidazole cation lubricant ZB09(Xi'an of 0.2 kilogram produces) in add the 80-90 DEG C of deionized water of 4 kilograms, stir in homogeneous transparent liquid;
D. to 0.1 kilogram of static inhibitor 6660A(U.S. EMERY) in add the 30-50 DEG C of deionized water of 0.8 kilogram, stir in homogeneous transparent liquid;
E. produce to the epoxy emulsion film forming agent YG101(Xi'an friend based composites company limited of 1.0 kilograms) in add the deionized water of 4 kilograms;
Produce to the unsaturated polyester membrane-forming agent YG2880(Xi'an friend based composites company limited of 5.5 kilograms) in add the deionized water of 22 kilograms;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of 33.81 kilograms, under 50rpm-60rpm condition, stir 30-40min namely obtain E glass fishing rod cloth yarn treating compound 5;
G. applied under the speed of 65-85m/min by the E glass fishing rod cloth yarn treating compound of gained, the yarn Performance Detection of production is as follows:
。
Embodiment six.
A. the deionized water of 16.5 kilograms is got, adding 0.07 kilogram of citric acid regulates Ph value to 3-4, slowly add the silane coupling A-174 (U.S. GESilicones) of 0.05 kilogram and the silane coupling A-1100 (U.S. GESilicones) of 0.5 kilogram while stirring, under the condition of 60-80rpm, stir 30-60min;
B. 0.05 kilogram of plasticizer phthalic acid dioctyl ester and 0.6 kilogram of emulsifying agent peregal-20 is mixed, then at 80-95 DEG C, heating melts, then along with being stirred in 30min-60min the 70-90 DEG C of deionized water adding 13 kilograms equably, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. the condensation material company limited that reconstructs in the Imidazole cation lubricant ZB09(Xi'an of 0.3 kilogram produces) in add the 80-90 DEG C of deionized water of 6 kilograms, stir in homogeneous transparent liquid;
D. to 0.15 kilogram of static inhibitor 6660A(U.S. EMERY) in add the 30-50 DEG C of deionized water of 1.5 kilograms, stir in homogeneous transparent liquid;
E. produce to the epoxy emulsion film forming agent YG101(Xi'an friend based composites company limited of 3.5 kilograms) in add the deionized water of 4.5 kilograms;
Produce to the unsaturated polyester membrane-forming agent YG2880(Xi'an friend based composites company limited of 9.5 kilograms) in add the deionized water of 18 kilograms;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of 45.28 kilograms, under 50rpm-60rpm condition, stir 30-40min namely obtain E glass fishing rod cloth yarn treating compound 6;
G. applied under the speed of 65-85m/min by the E glass fishing rod cloth yarn treating compound of gained, the yarn Performance Detection of production is as follows:
。
Embodiment seven.
A. the deionized water of 30 kilograms is got, adding 1.0 citric acids regulates Ph values to 3-4, slowly adds the silane coupling A-174 (U.S. GESilicones) of 0.5 kilogram while stirring and the silane coupling A 1100 (U.S. GESilicones) of 0.5 kilogram stirs 30-60min under the condition of 60-80rpm;
B. 1.5 kilograms of plasticizer phthalic acid dioctyl esters and 1.0 kilograms of emulsifying agent peregals-20 are mixed, then at 80-95 DEG C, heating melts, then along with being stirred in 30min-60min the 70-90 DEG C of deionized water adding 12.5 kilograms equably, stirring velocity is 1000rpm-3000rpm; Be cooled to less than 30 DEG C again;
C. the condensation material company limited that reconstructs in the Imidazole cation lubricant ZB09(Xi'an of 1.0 kilograms produces) in add the 80-90 DEG C of deionized water of 7.5 kilograms, stir in homogeneous transparent liquid;
D. to 1.0 kilograms of static inhibitor 6660A(U.S. EMERY) in add the 30-50 DEG C of deionized water of 10 kilograms, stir in homogeneous transparent liquid;
E. produce to the epoxy emulsion film forming agent YG101(Xi'an friend based composites company limited of 5.5 kilograms) in add the deionized water of 5.5 kilograms;
Produce to the unsaturated polyester membrane-forming agent YG2880(Xi'an friend based composites company limited of 10 kilograms) in add the deionized water of 10 kilograms;
F. the material that step a, b, c, Step d obtain is mixed, then add the deionized water of 1.0 kilograms, under 50rpm-60rpm condition, stir 30-40min namely obtain E glass fishing rod cloth yarn treating compound 7;
G. applied under the speed of 65-85m/min by the E glass fishing rod cloth yarn treating compound of gained, the yarn Performance Detection of production is as follows: