CN106426859A - Extrusion method and die achieving synergistic effect of ultrasonic vibration and uniform tensile stress - Google Patents

Extrusion method and die achieving synergistic effect of ultrasonic vibration and uniform tensile stress Download PDF

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Publication number
CN106426859A
CN106426859A CN201610955244.4A CN201610955244A CN106426859A CN 106426859 A CN106426859 A CN 106426859A CN 201610955244 A CN201610955244 A CN 201610955244A CN 106426859 A CN106426859 A CN 106426859A
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ultrasonic vibration
ultrasonic
extrusion
synergistic
uniform tension
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殷小春
冯彦洪
李赛
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South China University of Technology SCUT
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South China University of Technology SCUT
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/305Extrusion nozzles or dies having a wide opening, e.g. for forming sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses an extrusion method and die achieving the synergistic effect of ultrasonic vibration and uniform tensile stress. The extrusion die comprises a die body, a first ultrasonic vibration device and a second ultrasonic vibration device. The first ultrasonic vibration device and the second ultrasonic vibration device each mainly comprise an amplitude-change rod, a vibration transmission rod, a transducer, a signal line and an ultrasonic generator; through holes are symmetrically formed in the die body; the small ends of the amplitude-change rods of the first ultrasonic vibration device and the second ultrasonic vibration device communicate with a die runner through the through holes; and the amplitude-change rods extend into the through holes of the extrusion die in the mode of being perpendicular to flanges. Through the extrusion process that ultrasonic vibration is perpendicularly overlapped on a melt, the pressure action of pulse change acts on the melt, and the synergistic effect of ultrasonic vibration and uniform tensile stress is achieved. According to the extrusion method and die, the pressure fluctuation during extrusion of the plastic melt is reduced, the apparent viscosity of the melt is reduced, the compatibility of polymer blends is improved, the flow uniformity of materials is improved, and thus the combination property of a finished product is improved.

Description

A kind of ultrasonic vibration and the synergistic extrusion method of Uniform Tension stress and mouth mould
Technical field
The present invention relates to a kind of polymer material extrusion shaping, more particularly to a kind of ultrasonic vibration and Uniform Tension stress Synergistic polymer material extrusion product molding processing method and mouth mould.
Background technology
Extruded product accounts for more than half of plastic products total amount, all of extruded product be required for by extrusion neck ring mold Lai Processing and forming, the shaping realizing macromolecular material becomes second nature.Extrusion neck ring mold is not only the important component part of extruding production line, simultaneously Also material impact can be produced to the performance of extruded product.In most of extrusion neck ring mold, melt is mainly made by shear stress at present With, or the local convergence/dissipate due to cross section of fluid channel and be subject to the tensile stress of transient changing to act on, shearing deformation effect is easily Cause localized hyperthermia so that macromolecular material molecular chain rupture and reduce product macro-mechanical property and surface quality, transient changing Tensile stress effect to easily cause extrusion unstable and make extruded product surface the defect such as uneven.
Tensile deformation domination and oscillatory shear stress Extrusion Molding processing method are to molding process and product Important impact be can will produce, Chinese scholars and the common concern of related research institutes have been subject to.Theoretical in a large number and experiment is ground Study carefully and show, the introducing of Vibrational force field has reduction apparent melt viscosity, reduces power consumption of polymer processing, improve dispersive property, improve plasticizing The advantages of efficiency and plasticizing quality, product properties can be improved by affecting product condensed state structure simultaneously.Ultrasonic wave is frequency The elastic mechanical vibration wave of more than 20KHz, parallel or perpendicular to overlapped high-frequency ultrasonic wave on flow direction, is contributing in polymerization High vibration is produced, thus affecting Polymer moulding process and product properties inside thing melt.Draw at extruding dies Entering ultrasonic vibration is to introduce in molding process that the oscillatory shear field of force is the simplest and one of direct method.In addition, Ultrasonic wave as a kind of density of detection means on-line measurement melt, in injection nozzle and mould superposition ultrasonic wave in order to improve The aspect such as the mobility of melt and pack effectiveness is applied;Chinese patent 201210052745.3,201310121160.7 is public Open injection moulding method and the device that a kind of vibrational energy using ultrasonic wave generation is directly used in high polymer material plasticizing, this All achieve certain effect a bit.
A.I.Isayev(Ultrasound assisted twin screw extrusion of polymer– Nanocomposites containing carbon nanotubes, Polymer, 50, (2009) 250 260.) et al. pass through Vltrasonic device is arranged on preparation PEI/CNTs composite on the slit shape mouth mould of double screw extruder.Test result indicate that: By applying ultrasonic vibration, the rheological property such as storage modulus, loss modulus and complex viscosity of composite and stretching are strong Degree and Young's modulus all improve to some extent, and its main cause is that ultrasonic vibration makes the CNTs aggregate in melt crush, and makes Obtain CNTs and disperse more uniform in matrix PEI, thus improving the performance of material.But due in above-mentioned slit die melt with Based on shearing laminar flow, interface updates slowly, reduces the chance that Composite Melt is contacted with ultrasonic wave, so that ultrasonic air The scope of change effect diminishes, and constrains the impact effect of ultrasonic vibration, simultaneously because being subject to ul-trasonic irradiation and not receiving ultrasonic wave The melt of effect is different at aspects such as rheological property, admixtures, have impact on the uniformity of melt, thus does not enable to extrude In journey, both is effectively collaborative.
Existing ultrasonic-assisted polymerization thing composite extrusion mainly passes through ultrasonic activation and melt shear laminar flow Longitudinal stack, achieve the synergy of ultrasonic vibration and shearing deformation in local space.But due to identical rate of deformation Down cut Laminar flow mixing efficiency is low for effect, mixed effect is poor, have impact on the uniform of blend melt after ultrasonic vibration booster action Property, constrain the raising further of ultrasonic activation action effect.
If boundary can be improved by active flow process is overlapped mutually with tensile deformation by ultrasonic assistant vibration Face renewal rate, will effectively improve the sphere of action of ultrasonic activation, improve the uniformity of melt after ultrasonic vibration effect, thus Improve ultrasonic vibration and the synergistic efficiency of tensile stress and effect.
Content of the invention
Present invention aims to the problems of extrusion neck ring mold based on shearing deformation, provide a kind of ultrasonic shake Move and Uniform Tension stress synergistic extrusion molding processing method and mouth mould, effectively reduce polymer melt in process Apparent viscosity, improve the compatibility of Polymer Blending System and mixing quality, improve material flow irregularity in runner, So that the combination property of extruded product is improved.
By the mouth mould runner coupling ultrasonic vibration of invention Uniform Tension deformation domination in polymer material molding processing In advantage, form ultrasonic vibration and Uniform Tension stress synergistic extrusion molding processing method, it will to macromolecule material The performance of material extruded product improves the important impact of generation.
The purpose of the present invention is achieved through the following technical solutions:
A kind of ultrasonic vibration and the synergistic extrusion neck ring mold of Uniform Tension stress, including mouth mould, the first ultrasonic vibration dress Put and the second ultrasonic vibration installation;First ultrasonic vibration installation and the second ultrasonic vibration installation are symmetricly set on mouthful mould both sides;The One ultrasonic vibration installation and the second ultrasonic vibration installation are all mainly sent out by ultrasonic transformer, vibration-sensing rod, transducer, holding wire and ultrasonic wave Raw device composition;Vibration-sensing rod one end is connected with the big end of ultrasonic transformer, and the other end of vibration-sensing rod and transducer are welded to connect, and transducer leads to Cross holding wire to be connected with supersonic generator;It is arranged with through hole on mouth mould;First ultrasonic vibration installation and the second ultrasonic vibration The small end of the ultrasonic transformer of device passes through through hole and mouth mould flow passage;Ultrasonic transformer stretches into the through hole of extrusion neck ring mold perpendicular to flange Interior;The section of the runner of described mouth mould is circle, and its bus is parabolic type;Or the runner section of described mouth mould is square Shape, its bus is hyperbolic-type.
For realizing the object of the invention further it is preferable that described luffing bar node outer end is provided with flange, flange passes through screw It is fixed on mouthful mould;The outer end at the big end of ultrasonic transformer is provided with rebound;It is provided with lower seal between ultrasonic transformer and flange;Ultrasonic transformer with It is provided with sealing ring between rebound.
Preferably, the gap of 0.3-0.7mm, ultrasonic transformer small end and receipts are left between described ultrasonic transformer and flange and rebound Hold back and leave gap between the through hole on mouthful mould.
Preferably, described rebound and flange are connected by screw.
Preferably, described vibration-sensing rod has cooling water inlet and coolant outlet.
Preferably, described flange is screwed on mouth mould.
Preferably, described vibration-sensing rod one end and the big end of ultrasonic transformer are threaded connection.
Preferably, the ultrasonic vibration frequency of described supersonic generator is 20-40KHZ, and supersonic generator power is 300-1200W.
The ultrasonic vibration of described extrusion neck ring mold and the synergistic polymer material extrusion of Uniform Tension stress is applied to be molded Processing method:Material, during flow-in-bore, is being acted on by ultrasonic vibration perpendicular to Flow of Goods and Materials direction, material is being produced Periodically variable compression and expansion, promote the dispersion mixing of dispersion phase and polymer molecule in material multiphase co-mixing system The disentanglement of chain;The constant convergence survey of acceleration made in mouth mould by material simultaneously, is uniformly drawn by consistent with flow direction Stretch deformation effect, promote the renewal rate of polymer blend interface, increased material and contact with ultrasonic wave, enhance ultrasonic wave to material The distributed rendering material of effect and co-mixing system distributed rendering, realize ultrasonic vibration synergistic with Uniform Tension stress Extrusion.
The present invention is mainly by ultrasonic vibration installation and have the mouth mould of different cross section shape astringent runner and form.According to processing The difference of article section shape, extrusion neck ring mold flow passage structure form is different.For the extrusion molding of bar product, processing is circular to cut During Flour product, the section of extrusion neck ring mold runner is circle, runner be circle into and out of material mouth, its bus is parabolic type, tool There is parabolic type astringent runner.During processing square-section product (sheet material, sheet material), the section of extrusion neck ring mold runner is rectangle, its Bus is hyperbolic-type.Due to the change of mouth mould cross section of fluid channel area after melt entrance extrusion neck ring mold out from extruder, Make the flowing velocity even variation of melt, thus melt is subject to the deformation effect of even variation;Because melt is made in mouth mould Convergence survey, thus melt is mainly subjected to tensile stress, realizes the flow process of Uniform Tension deformation domination;Along melt Flow direction arranges ultrasonic vibration installation, will vibrate the shaping of the stress longitudinal stack of change to product by polymer melt Cheng Zhong, mutually synergistic macromolecule material product becomes second nature with the direct stress of even variation to realize ultrasonic vibration.This Bright by screw, the mouth mould with parabola astringent runner is connected with extruder barrel flange, with screw by ultrasonic vibration installation On the converging portion that ultrasonic vibration installation is vertically fixed on mouthful mould.
The present invention, compared with existing extruding forming method and device, has the advantage that:
1st, in extrusion of the present invention, acted on by ultrasonic vibration perpendicular to flow direction material, in ultrasonic vibration effect Lower polymer molecular chain and heterogeneous system are subject to periodically variable compression and expansion, may advantageously facilitate dispersion phase in matrix In dispersion mixing and strand disentanglement, simultaneously improve strand locomitivity, reduce viscosity;Meanwhile, along stream On dynamic direction, the constant convergence survey of acceleration made in mouth mould by material, is made by the Uniform Tension deformation consistent with flow direction With tensile deformation effect promotes the renewal rate of polymer blend interface, increased the chance that material is contacted with ultrasonic wave, enhances The effect to material for the ultrasonic wave and the distributed rendering of co-mixing system, it is achieved thereby that ultrasonic vibration is worked in coordination with Uniform Tension stress make Extrusion.Therefore, combined stress mutually collaborative for the tensile stress of ultrasonic vibration and even variation is acted on by the present invention In the extrusion molding process of macromolecule material product, synergistic extrusion molding processing subtracts with Uniform Tension stress for ultrasonic vibration Lack the pressure oscillation in extrusion for the plastic melt, reduced the apparent viscosity of melt, improve the compatible of blend polymer Property and the flow uniformity improving material, so that the combination property of product is improved.
2nd, the present invention passes through to be superimposed ultrasonic vibration in melt flows direction, reduces the flow resistance of melt, and specific energy consumption drops Low, it is advantageously implemented the green processing and forming of macromolecule material product.
3 present invention achieves oscillatory shear deformation and the synergistic shaping of Uniform Tension deformation become second nature process, equipment ties Structure is simple, easy to operate.
4th, it is directed to polymer matrix composite wire rod, bar and articles of sheet material, by designing parabolic type or hyperbolic-type The mouth mould of runner, realizes material and is acted on by uniform and stable direct stress in extrusion.
Brief description
Fig. 1 is ultrasonic vibration of the present invention and the synergistic extrusion neck ring mold of Uniform Tension stress (parabolic type convergence) structure Schematic diagram;
Fig. 2 is ultrasonic vibration installation structural representation of the present invention;
Fig. 3 restrains the structural representation of mouth mould for parabolic type of the present invention;
Fig. 4 restrains the A-A face sectional view of mouth mould for parabolic type of the present invention;
Fig. 5 is parabolic type astringent runner structural representation of the present invention;
Fig. 6 is ultrasonic vibration of the present invention and the synergistic extrusion neck ring mold of Uniform Tension stress (hyperbolic-type convergence) structure Schematic diagram;
Fig. 7 is the structural representation that this hyperbolic-type restrains mouth mould;
Fig. 8 restrains the A-A face sectional view of mouth mould for hyperbolic-type of the present invention;
Fig. 9 is hyperbolic-type astringent runner structural representation of the present invention;
The transmission electron microscope picture of the HDPE/MMT blend that Figure 10 conventional extrusion method prepares;
The transmission electron microscope picture of the HDPE/MMT blend that Figure 11 new method prepares.
Specific embodiment
For more fully understanding the present invention, the present invention is described further with reference to the accompanying drawings and examples, but this Bright claimed scope is not limited to the scope of embodiment statement.
Embodiment 1
With reference to Fig. 1, Fig. 2, Fig. 3, a kind of ultrasonic vibration and the synergistic extrusion neck ring mold of Uniform Tension stress, including having The mouth mould 1 of parabolic type astringent runner, the first ultrasonic vibration installation I and the second ultrasonic vibration installation II;First ultrasonic vibration dress Put and be symmetricly set on mouthful mould both sides with the second ultrasonic vibration installation.For the extrusion molding of bar product, runner into and out of material mouth It is circle, and its bus is parabola, converges to round exit by parabola.Parabola convergent current will be had by screw The mouth mould 1 in road is connected with extruder barrel flange, is vertically fixed on ultrasonic vibration installation I and ultrasonic vibration installation II with screw On the converging portion of mouth mould 1.First ultrasonic vibration installation I and the second ultrasonic vibration installation II all mainly by ultrasonic transformer 5, flange 6, under Sealing ring 7, upper sealing ring 8, rebound 9, vibration-sensing rod 10, cooling water inlet 11, coolant outlet 12, transducer 13, holding wire 14 and supersonic generator 15 form;Vibration-sensing rod 10 one end is threaded connection with the big end of ultrasonic transformer 5, vibration-sensing rod 10 another End is welded to connect with transducer 13, and transducer 13 is connected with supersonic generator 15 by holding wire 14, by setting ultrasonic wave Parameter on generator 15 is thus be adjusted to vibration frequency and amplitude.It is arranged with through hole 4 on mouth mould 1;First ultrasonic shakes The small end of the ultrasonic transformer 5 of dynamic device I and the second ultrasonic vibration installation II passes through through hole 4 and mouth mould 1 flow passage.
Ultrasonic transformer 5 is in the through hole 4 that flange 6 stretches into extrusion neck ring mold;Ultrasonic transformer 5 node outer end is provided with flange 6, flange 6 are fixed by screws on mouthful mould 1;The outer end at ultrasonic transformer 5 end greatly is provided with rebound 9;It is provided with down between ultrasonic transformer 5 and flange 6 Sealing ring 7;It is provided with sealing ring 8 between ultrasonic transformer 5 and rebound 9;0.3- is left between ultrasonic transformer 5 and flange 6 and rebound 9 The gap of 0.7mm, leaves gap between the through hole 4 on ultrasonic transformer 5 small end and convergence mouth mould.Preferably rebound 9 and flange 6 pass through Mode connects for screw;Preferably cooling water inlet 11 and coolant outlet 12 are had on vibration-sensing rod 10, during work, logical cooling water prevents heat It is delivered on transducer 13.
Installing and fixing method on mouth mould 1 for the first ultrasonic vibration installation I is as follows:First flange 6 is screwed in mouth On mould 1, then by ultrasonic transformer 5 in the through hole 4 that flange 6 stretches into extrusion neck ring mold (Fig. 3), by lower seal 7 and upper sealing ring 8 Be enclosed within ultrasonic transformer 5 node and ultrasonic transformer 5 big end;Mounting flange 6 and rebound 9;It is connected by screw rebound 9 and method Blue 6;Ultrasonic transformer 5 is made effectively to prevent material leakage while fixing.During installation, control and stay between ultrasonic transformer 5 and flange 6 and rebound 9 Have a gap of 0.5mm, and leave gap between the through hole 4 on ultrasonic transformer 5 small end and convergence mouth mould, thus avoid ultrasonic transformer 5 with Metal directly contact, thus protecting ultrasonic transformer 5, and guarantees ultrasonic unit normal work.When extruder works, ultrasonic transformer 5 is little Melt contacts in end and mouth mould runner 2, the ultrasonic vibration that transducer is produced is melted to polymer by vibration amplitude arm longitudinal stack On body;Second ultrasonic vibration installation II is in the installing and fixing method on mouth mould 1 and the first ultrasonic vibration installation I on mouth mould 1 Installing and fixing method is the same.
In extrusion, acted on by ultrasonic vibration perpendicular to flow direction material, polymer under ultrasonic vibration effect Strand and heterogeneous system are subject to periodically variable compression and expansion, may advantageously facilitate dispersion phase dispersion in the base Mixing and the disentanglement of strand, improve the locomitivity of strand simultaneously, reduce viscosity;On streamwise, material is in mouth mould Middle make the constant convergence survey of acceleration, by the Uniform Tension deformation effect consistent with flow direction, tensile deformation effect promotees Enter the renewal rate of polymer blend interface, increased the chance that material is contacted with ultrasonic wave, enhance the work to material for the ultrasonic wave With the distributed rendering with co-mixing system, it is achieved thereby that ultrasonic vibration and the synergistic extrusion of Uniform Tension stress.
Present invention can apply to polymer modification extrusion, such as polymer/inorganic filler blending extrusion, polymer/polymer Binary blending extrusion or tertiary blending extrusion or poly-blended extrusion.
With reference to Fig. 3, Fig. 4, Fig. 5, mouth mould runner is parabolic type, and extruded product has circular cross section.With conventional straight flow Unlike the mould of road junction, melt based on shear flow, is mainly acted on by shearing deformation, and melt flows through in straight mouth mould Have astringent runner mouth mould when, due to mouth mould parabolically type convergence, because circulation area reduce and make melt be accelerated, melt Body is stretched deformation effect, improves the mixing efficiency in extrusion and mixed effect, improves quality of item;Melt with Unlike in tapered runner, when melt flows in bus is for parabolical astringent runner, its acceleration keeps constant, melt Velocity attitude substantially parallel with its acceleration direction, melt be subject to Uniform Tension stress;By ultrasonic vibration longitudinal stack To in the extrusion of melt, melt is made to be subject to the pressure of pulsatile change to act on, thus the rheological behaviour generation to melt is important Impact.Uniform Tension deformation effect one side promotes the renewal of melt interface layer, increased the machine that melt is contacted with ultrasonic wave Meeting, improves melt temperature, uniformity that pressure, group are graded;On the other hand because melt is acted on by uniform tensile stress, Avoid the material causing because the temperature caused by shear action and nonuniform stretching deformation effect, pressure distribution are uneven etc. The defects such as degraded, thus realize ultrasonic vibration and Uniform Tension flow field synergistic circular cross-section product (bar, wire rod etc.) Extrusion molding processing.
In order to verify the effect of the present invention, carry out following Experimental comparison:Using identical plasticizing system, screw speed 60rpm, die temperature is 200 DEG C, by the blend of die extrusion HDPE/MMT (montmorillonite) shown in embodiment 1, wherein MMT Mass fraction is 5%.Contrast test is carried out using Conventional cone mouth mould and the present embodiment new mouth mould superposition ultrasonic wave, mouth mould enters Unanimously, ultrasonic vibration frequency is 20KHz for mouth and outlet, mouth mould length dimension, and ultrasonic power changes in 500-800w.Commonsense method Extrusion and ultrasonic vibration work in coordination with Uniform Tension stress extrusion preparation HDPE/MMT blend utilize transmission electron microscope (TEM, JEOL1011) to montmorillonite, the deployment conditions in HDPE polymeric matrix characterize, transmission electron microscope photo such as Figure 10, Figure 11 Shown.Contrast Figure 10 and Figure 11 can be seen that MMT in blend prepared by new method extrusion and be uniformly dispersed in matrix HDPE, MMT interlamellar spacing increases, and illustrates that the stripping that Uniform Tension stress is conducive to MMT is worked in coordination with ultrasonic vibration, thus improve blending The combination property of thing HDPE/MMT.Dispersing uniformity improves and the increase of MMT interlamellar spacing is mainly attributed to following two aspects:Hanging down Straight on Flow of Goods and Materials direction, material under ultrasonic vibration effect by periodic compression with expand, periodically compression with swollen Swollen raising promotes the disentanglement of the dispersion mixing of dispersion phase and substrate molecule chain in heterogeneous system;Streamwise material is in mouth Make the constant convergence survey of acceleration, by the Uniform Tension deformation effect consistent with flow direction, tensile deformation acts in mould Promote the interface renewal rate of heterogeneous system, increased the chance that blend contacted with ultrasonic wave and the distribution of heterogeneous system mixes Close efficiency, enhance the effect to material for the ultrasonic vibration, it is achieved thereby that ultrasonic vibration is synergistic with Uniform Tension stress Extrusion.
Embodiment 2
For its mouthful of mould runner gateway of product of rectangle, rectangle is for section, width keeps constant, thickness side It is gradually reduced to products thickness to along bus for hyperbola.With reference to Fig. 2, Fig. 3, Fig. 6, Fig. 7, a kind of ultrasonic vibration and Uniform Tension The synergistic extrusion neck ring mold of stress, including mouth mould 1, the first ultrasonic vibration installation I and with parabolic type astringent runner Two ultrasonic vibration installation II.By screw, the mouth mould 1 with hyperbola astringent runner is connected with extruder barrel flange, uses spiral shell Ultrasonic vibration installation I and ultrasonic vibration installation II is vertically fixed on the converging portion of mouthful mould 1 nail.
First ultrasonic vibration installation I and the second ultrasonic vibration installation II all mainly by ultrasonic transformer 5, flange 6, lower seal 7, Upper sealing ring 8, rebound 9, vibration-sensing rod 10, cooling water inlet 11, coolant outlet 12, transducer 13, holding wire 14 and ultrasonic Wave producer 15 forms;Vibration-sensing rod 10 one end is threaded connection with the big end of ultrasonic transformer 5, the other end of vibration-sensing rod 10 and transducing Device 13 is welded to connect, and transducer 13 is connected with supersonic generator 15 by holding wire 14, by setting supersonic generator 15 On parameter thus being adjusted to vibration frequency and amplitude.It is arranged with through hole 4 on mouth mould 1;First ultrasonic vibration installation I and The small end of the ultrasonic transformer 5 of the second ultrasonic vibration installation II passes through through hole 4 and mouth mould 1 flow passage;
Ultrasonic transformer 5 is in the through hole 4 that flange 6 stretches into extrusion neck ring mold;Ultrasonic transformer 5 node outer end is provided with flange 6, flange 6 are fixed by screws on mouthful mould 1;The outer end at ultrasonic transformer 5 end greatly is provided with rebound 9;It is provided with down between ultrasonic transformer 5 and flange 6 Sealing ring 7;It is provided with sealing ring 8 between ultrasonic transformer 5 and rebound 9;0.3- is left between ultrasonic transformer 5 and flange 6 and rebound 9 The gap of 0.7mm, leaves gap between the through hole 4 on ultrasonic transformer 5 small end and convergence mouth mould.Preferably rebound 9 and flange 6 pass through Mode connects for screw;Preferably cooling water inlet 11 and coolant outlet 12 are had on vibration-sensing rod 10, during work, logical cooling water prevents heat It is delivered on transducer 13.Fixing means on mouth mould I for the ultrasonic vibration installation I and ultrasonic vibration installation II and embodiment 1 phase Similar.
With reference to Fig. 7, Fig. 8, Fig. 9, when described mouth mould runner 2 is hyperbolic-type, it is rectangle into and out of material mouth.Work as melt When flowing through the mouth mould with astringent runner, streamwise thickness tapers into, thus melt is accelerated.Because mouth mould is in hyperbolic Line style restrains, and the constant airspeed that cross-sectional area reduces causes the acceleration of melt constant, and melt is subject to the stretching shape of even variation Change acts on, and the flowing of melt is mainly arranged by tensile deformation;By by ultrasonic vibration longitudinal stack in the extrusion of melt, Melt is made to be subject to the pressure of pulsatile change to act on, thus realizing ultrasonic vibration and the synergistic board product of Uniform Tension stress Extrusion molding is processed.

Claims (9)

1. a kind of ultrasonic vibration with Uniform Tension stress synergistic extrusion neck ring mold it is characterised in that include mouth mould, the first surpass Acoustic vibration device and the second ultrasonic vibration installation;First ultrasonic vibration installation and the second ultrasonic vibration installation are symmetricly set on a mouthful mould Both sides;First ultrasonic vibration installation and the second ultrasonic vibration installation all mainly by ultrasonic transformer, vibration-sensing rod, transducer, holding wire and Supersonic generator forms;Vibration-sensing rod one end is connected with the big end of ultrasonic transformer, and the other end of vibration-sensing rod and transducer are welded to connect, Transducer is connected with supersonic generator by holding wire;It is arranged with through hole on mouth mould;First ultrasonic vibration installation and second The small end of the ultrasonic transformer of ultrasonic vibration installation passes through through hole and mouth mould flow passage;Ultrasonic transformer stretches into extrusion neck ring mold perpendicular to flange Through hole in;The section of the runner of described mouth mould is circle, and its bus is parabolic type;Or the runner section of described mouth mould For rectangle, its bus is hyperbolic-type.
2. ultrasonic vibration according to claim 1 and the synergistic extrusion neck ring mold of Uniform Tension stress it is characterised in that Described luffing bar node outer end is provided with flange, and flange is fixed by screws on mouthful mould;The outer end at the big end of ultrasonic transformer is provided with transition Plate;It is provided with lower seal between ultrasonic transformer and flange;It is provided with sealing ring between ultrasonic transformer and rebound.
3. ultrasonic vibration according to claim 2 and the synergistic extrusion neck ring mold of Uniform Tension stress it is characterised in that The gap of 0.3-0.7mm, ultrasonic transformer small end and the through hole restrained on mouth mould is left between described ultrasonic transformer and flange and rebound Between leave gap.
4. ultrasonic vibration according to claim 2 and the synergistic extrusion neck ring mold of Uniform Tension stress it is characterised in that Described rebound and flange are connected by screw.
5. ultrasonic vibration according to claim 1 and the synergistic extrusion neck ring mold of Uniform Tension stress it is characterised in that Cooling water inlet and coolant outlet are had on described vibration-sensing rod.
6. ultrasonic vibration according to claim 2 and the synergistic extrusion neck ring mold of Uniform Tension stress it is characterised in that Described flange is screwed on mouth mould.
7. ultrasonic vibration according to claim 1 and the synergistic extrusion neck ring mold of Uniform Tension stress it is characterised in that Described vibration-sensing rod one end is threaded connection with the big end of ultrasonic transformer.
8. ultrasonic vibration according to claim 1 and the synergistic extrusion neck ring mold of Uniform Tension stress it is characterised in that The ultrasonic vibration frequency of described supersonic generator is 20-40KHZ, and supersonic generator power is 300-1200W.
9. the ultrasonic vibration of extrusion neck ring mold and the synergistic high score of Uniform Tension stress described in application any one of claim 1-8 Sub- material extrusion molding processing method it is characterised in that:Material, during flow-in-bore, is being subject to perpendicular to Flow of Goods and Materials direction To ultrasonic vibration effect, periodically variable compression and expansion are produced to material, promote to divide in material multiphase co-mixing system The dispersion mixing of dephasing and the disentanglement of polymer molecular chain;The constant convergence survey of acceleration made in mouth mould by material simultaneously, It is subject to the Uniform Tension deformation effect consistent with flow direction, promotes the renewal rate of polymer blend interface, increased material and surpass Acoustic wave touch, enhances the distributed rendering to the effect of material and the distributed rendering material of co-mixing system for the ultrasonic wave, realizes ultrasonic Vibration and the synergistic extrusion of Uniform Tension stress.
CN201610955244.4A 2016-10-27 2016-10-27 Extrusion method and die achieving synergistic effect of ultrasonic vibration and uniform tensile stress Pending CN106426859A (en)

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CN115339099A (en) * 2022-08-23 2022-11-15 西安交通大学 High-viscosity material extrusion device based on double ultrasonic vibrator resonance
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CN110328843B (en) * 2019-06-25 2021-06-18 同济大学 Ultrasonic-assisted impregnated composite material 3D printing device
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CN113681852A (en) * 2021-07-23 2021-11-23 华南理工大学 Production equipment and method for LCP film under action of space electric field
CN115339099A (en) * 2022-08-23 2022-11-15 西安交通大学 High-viscosity material extrusion device based on double ultrasonic vibrator resonance
CN115972533A (en) * 2022-12-19 2023-04-18 四川大学 Polymer melt composite vibration extrusion molding device

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Application publication date: 20170222