CN106418686B - A kind of quick-fried pearl pearly-lustre of cigarette is coated membrane material and pearly-lustre the cigarette preparation method of quick-fried pearl - Google Patents
A kind of quick-fried pearl pearly-lustre of cigarette is coated membrane material and pearly-lustre the cigarette preparation method of quick-fried pearl Download PDFInfo
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- CN106418686B CN106418686B CN201610935665.0A CN201610935665A CN106418686B CN 106418686 B CN106418686 B CN 106418686B CN 201610935665 A CN201610935665 A CN 201610935665A CN 106418686 B CN106418686 B CN 106418686B
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- fried pearl
- pearly
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- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 66
- 239000000463 material Substances 0.000 title claims abstract description 14
- 239000012528 membrane Substances 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 57
- 239000011230 binding agent Substances 0.000 claims abstract description 41
- 239000000243 solution Substances 0.000 claims abstract description 32
- 239000007864 aqueous solution Substances 0.000 claims abstract description 30
- 230000001070 adhesive effect Effects 0.000 claims abstract description 24
- 239000000853 adhesive Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 5
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 230000001360 synchronised effect Effects 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 239000011324 bead Substances 0.000 abstract description 6
- 230000000007 visual effect Effects 0.000 abstract description 2
- 239000004834 spray adhesive Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 11
- 239000000049 pigment Substances 0.000 description 4
- 230000000391 smoking effect Effects 0.000 description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical group C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 229940069328 povidone Drugs 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
Abstract
The present invention provides a kind of quick-fried pearl pearly-lustre of cigarette and is coated membrane material and pearly-lustre the cigarette preparation method of quick-fried pearl.The pearly-lustre cigarette with quick-fried pearl is added to the adhesive of 2~30 parts by weight in 25 ± 5 DEG C of water of 70~98 parts by weight, and stirring is dissolved into binder aqueous solution in 0.5~2 hour, and stands defoaming 2~12 hours；Then molded and dried cigarette is placed in granulator coater with quick-fried pearl, opening device, make quick-fried pearl product uniform roll in granulator coater, and spray adhesive aqueous solution, pearl powder is at the uniform velocity added simultaneously, the addition of binder aqueous solution and pearl powder is completed in 1~2 hour, then the cigarette of binder solution and pearl powder will be sprayed with quick-fried pearl at 18 ± 2 DEG C of temperature, 2~12 hours are dried in the environment of humidity 40% ± 5% to get pearly-lustre cigarette is arrived with quick-fried pearl.It is not soluble in water that the present invention solves pearl powder, can not be applied to the problems in water-soluble quick-fried bead system, enhance the apparent visual effect of quick-fried pearl well.
Description
Technical field
The invention belongs to technical field of cigarettes, and in particular to a kind of to carry out the quick-fried Zhu Zhuguangbao of the cigarette of pearl effect to tobacco rolling belt
Clothing film material and pearly-lustre the cigarette preparation method of quick-fried pearl.
Background technique
Quick-fried pearl, also referred to as pomander, brittleness capsule, pearl, with the feeling to pop when racking, presently mainly in cigarette
It uses, that is, the quick-fried pearl cigarette often said.Quick-fried pearl cigarette just refers to: the cigarette of a small glue bead of liquid is had in filter tip, this is small
Liquid in glue bead can make cigarette more raw fragrant during sucking, and strengthen fragrance or characteristic, smoker is made more to be relaxed
Suitable experience.But existing quick-fried pearl cigarette is that quick-fried pearl is wrapped in cigarette filter rod mostly, and consumer can not see, can only pass through finger
It touches, pinches quick-fried pearl and release essence therein.Current quick-fried pearl mainly acts to wrap up essence, producer only focus on as
The technology of what more essence of package, because quick-fried pearl is not exposed outside, so few consider quick-fried pearl to cigarette exterior quality institute
It can play the role of.
The use of transparent filter stick can be such that quick-fried pearl is visible by the consumer, therefore the external appearance characteristic of quick-fried pearl is increasingly closed
Note.Quick-fried pearl product appearance currently on the market is the ball-type capsule of various colors, is mainly reflected in not being same as above for color, other not have
There is more attractive appearance characteristic.
Pearlescent pigment cross section has the physical structure similar to pearl；Kernel is the mica of low optical refractive index, package
Outer layer be high refractive index metal oxide, such as titanium dioxide or iron oxide.It applies in an ideal case, pearlescent pigment
It is homogeneously dispersed in coating, and is parallel to material surface and forms Multi-layers distributing, in pearl, incident ray can lead to
Multipath reflection is crossed, pearl effect at embodiment is interfered.With the development that pearlescent pigment produces, the application of pearlescent pigment is increasingly by people
It is known.It can be used for automobile, motorcycle, bicycle coating, powdery paints, building coating, pearl ink, pearly-lustre plastics system
Product, pearlescent cosmetic can also be applied to papermaking, printing and dyeing, stamp rubber, the industries such as ceramics.
Summary of the invention
For the above-mentioned deficiency of the prior art, the technical problem to be solved in the present invention is to provide one kind to carry out pearly-lustre to tobacco rolling belt
The pearly-lustre coating membrane material and pearly-lustre cigarette of the effect preparation method of quick-fried pearl, this method is after the molding of quick-fried pearl, in quick-fried pearl outer layer
One layer of pulvis being made of adhesive, pearl powder is sprayed, pearl powder is made to be attached to quick-fried hulls, is then applied to quick-fried pearl transparent
In filter stick.In smoking cigarette, it can be seen that the quick-fried pearl in cigarette filter rod radiates pearl effect, experiences band to the suction of cigarette
Carry out completely new experience.
Technical solution provided by the invention are as follows: it is by pearl powder and bonding that a kind of cigarette, which is coated membrane material with quick-fried pearl pearly-lustre,
For agent solution according to made of the mixed preparing of 5~30:70 of mass ratio~95, it is 100 that wherein described adhesive solution, which is by total weight,
The following raw material composition of part:
Adhesive 2~30
Water 70~98
In above-mentioned formula, the pearl powder partial size is 5-60 μm, TiO2Clad ratio is 20-60%；
The adhesive is povidone, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, one in carboxymethyl cellulose
Kind is a variety of；
The water is pure water.
A kind of pearly-lustre cigarette provided by the invention preparation method of quick-fried pearl, it is characterised in that specific step is as follows:
(1) adhesive of 2~30 parts by weight in above-mentioned formula is added in 25 ± 5 DEG C of water of 70~98 parts by weight,
Stirring is dissolved into binder aqueous solution in 0.5~2 hour, and stands defoaming 2~12 hours；The adhesive is povidone, hydroxyl
One of propyl cellulose, hydroxypropyl methyl cellulose, carboxymethyl cellulose are a variety of；
(2) molded and dried cigarette is placed in granulator coater with quick-fried pearl, is used according to cigarette in granulator coater
The binder aqueous solution prepared in step (1) is added in the 1%~10% of quick-fried pearl total weight in the solution injection apparatus of seed-coating machine, together
When pearl powder is added in the powder feed arrangement of granulator coater；It is then turned on device, rolls quick-fried pearl product at the uniform velocity in pot
It is dynamic, by the binder aqueous solution configured in solution injection apparatus sprinkling step (1), while being synchronized by powder feed arrangement even
Speed sprinkling pearl powder, completes the addition of binder aqueous solution and pearl powder in 1~2 hour；The additive amount of the pearl powder accounts for
The 5%~30% of binder solution quality, the pearl powder partial size are 5-60 μm, TiO2Clad ratio is 20-60%；
(3) after binder aqueous solution and pearl powder addition are completed, the cigarette of binder solution and pearl powder will be sprayed with
2~12 hours are dried in the environment of 18 ± 2 DEG C of temperature, humidity 40% ± 5% with quick-fried pearl to get pearly-lustre cigarette is arrived with quick-fried pearl.
The granulator coater is existing equipment, can use CF type granulator coater.
Advantages of the present invention: the present invention is bonded to quick-fried bead surface using binder aqueous solution as medium, by pearl powder, solves
Pearl powder is not soluble in water, can not be applied to the problems in water-soluble quick-fried bead system, enhance the apparent visual of quick-fried pearl well
Effect.
Specific embodiment
A specific embodiment of the invention is described in further detail below with reference to embodiment.Following embodiment is
Laboratory data.
A kind of embodiment 1: preparation of the quick-fried pearl of cigarette pearly-lustre, the specific steps are as follows:
(1) binder solution that the quick-fried pearl pearly-lustre of cigarette is coated in membrane material is prepared according to formula as below table:
Cigarette is coated the binder solution formula table in membrane material with quick-fried pearl pearly-lustre
| Raw material type | Specification | Weight ratio |
| Adhesive | Hydroxypropyl cellulose | 10 |
| Water | Pure water | 90 |
The adhesive of total weight part in above-mentioned formula is added in 25 ± 5 DEG C of water, stirring is dissolved into bonding in 0.5 hour
Agent aqueous solution, and stand defoaming 2 hours；
(2) molded and dried cigarette is placed in CF type granulator coater with quick-fried pearl, is sprayed in the solution of seed-coating machine
The binder aqueous solution prepared in step (1) is added in injection device, the additive amount of described adhesive aqueous solution accounts for granulator coater
Pearl powder is added in the powder feed arrangement of granulator coater with the 2% of quick-fried pearl total weight in interior cigarette, the pearl powder
Additive amount accounts for the 10% of binder solution quality；It is then turned on device, makes quick-fried pearl product uniform roll in pot, and pass through solution
Injection apparatus sprays the binder aqueous solution configured in step (1), while spraying pearly-lustre by powder feed arrangement synchronous uniform velocity
Powder, 10 μm of the pearl powder partial size, TiO2Clad ratio 20% completes the addition of binder aqueous solution and pearl powder in 1 hour；
(3) after binder aqueous solution and pearl powder addition are completed, the cigarette of binder solution and pearl powder will be sprayed with
10 hours are dried in the environment of 18 ± 2 DEG C of temperature, humidity 40% ± 5% with quick-fried pearl to get pearly-lustre cigarette is arrived with quick-fried pearl.
The cigarette visible light pearl effect of quick-fried pearl in embodiment 1, for having preferable vision effect in transparent filter stick
The cigarette smoking mass change of fruit, application is little, is able to maintain original suction flavor substantially.
A kind of embodiment 2: preparation of the quick-fried pearl of cigarette pearly-lustre, the specific steps are as follows:
(1) binder solution that the quick-fried pearl pearly-lustre of cigarette is coated in membrane material is prepared according to formula as below table:
Cigarette is coated the binder solution formula table in membrane material with quick-fried pearl pearly-lustre
| Raw material type | Specification | Weight ratio |
| Adhesive | Hydroxypropyl cellulose: carboxymethyl cellulose 2:1 | 20 |
| Water | Pure water | 80 |
The adhesive of total weight part in above-mentioned formula is added in 25 ± 5 DEG C of water, 1 hour dissolution composite adhesives is stirred
Aqueous solution, and stand defoaming 5 hours；
(2) molded and dried cigarette is placed in CF type granulator coater with quick-fried pearl, is sprayed in the solution of seed-coating machine
The binder aqueous solution prepared in step (1) is added in injection device, the additive amount of described adhesive aqueous solution accounts for granulator coater
Pearl powder is added in the powder feed arrangement of granulator coater with the 5% of quick-fried pearl total weight in interior cigarette, the pearl powder
Additive amount accounts for the 20% of binder solution quality；It is then turned on device, makes quick-fried pearl product uniform roll in pot, and pass through solution
Injection apparatus sprays the binder aqueous solution configured in step (1), sprays pearl powder, pearl by powder feed arrangement synchronous uniform velocity
40 μm of light powder diameter, TiO2Clad ratio 40% completes the addition of binder aqueous solution and pearl powder in 1.5 hours；
(3) after binder aqueous solution and pearl powder addition are completed, the cigarette of binder solution and pearl powder will be sprayed with
6 hours are dried in the environment of 18 ± 2 DEG C of temperature, humidity 40% ± 5% with quick-fried pearl to get pearly-lustre cigarette is arrived with quick-fried pearl.
The cigarette visible apparent pearl effect of quick-fried pearl in embodiment 2, for having good vision effect in transparent filter stick
Fruit.The cigarette smoking mass change of application is little, is able to maintain original suction flavor substantially.
A kind of embodiment 3: preparation of the quick-fried pearl of cigarette pearly-lustre, the specific steps are as follows:
(1) binder solution that the quick-fried pearl pearly-lustre of cigarette is coated in membrane material is prepared according to formula as below table:
Cigarette is coated the binder solution formula table in membrane material with quick-fried pearl pearly-lustre
| Raw material type | Specification | Weight ratio |
| Adhesive | Povidone: carboxymethyl cellulose 1:1 | 35 |
| Water | Pure water | 65 |
The adhesive of total weight part in above-mentioned formula is added in 25 ± 5 DEG C of water, 2 hours dissolution composite adhesives are stirred
Aqueous solution, and stand defoaming 8 hours；
(2) molded and dried cigarette is placed in CF type granulator coater with quick-fried pearl, is sprayed in the solution of seed-coating machine
The binder aqueous solution prepared in step (1) is added in injection device, the additive amount of described adhesive aqueous solution is granulator coater
Pearl powder is added in the powder feed arrangement of granulator coater with the 10% of quick-fried pearl total weight in interior cigarette, the pearl powder
Additive amount accounts for the 30% of binder solution quality；It is then turned on device, makes quick-fried pearl product uniform roll in pot, and pass through solution
Injection apparatus sprays the binder aqueous solution configured in step (1), sprays pearl powder, pearl by powder feed arrangement synchronous uniform velocity
60 μm of light powder diameter, TiO2Clad ratio 60% is completed in 2 hours；
(3) after binder aqueous solution and pearl powder addition are completed, the cigarette of binder solution and pearl powder will be sprayed with
3 hours are dried in the environment of 18 ± 2 DEG C of temperature, humidity 40% ± 5% with quick-fried pearl to get pearly-lustre cigarette is arrived with quick-fried pearl.
The cigarette visible apparent pearl effect of quick-fried pearl in embodiment 3, for having good vision effect in transparent filter stick
Fruit, but because pearl powder partial size is larger, additive amount is more, and it is not so good with the adhesive effect of quick-fried bead surface, when causing to shake cigarette, meeting
There are part pearly-lustre powder particles to fall from quick-fried pearl.The cigarette smoking quality of application has certain change, and flue gas irritation increases, pleasant impression
It is deteriorated.
Claims (1)
1. a kind of pearly-lustre cigarette preparation method of quick-fried pearl, which is characterized in that the pearly-lustre cigarette with the coating membrane material of quick-fried pearl be by
Made of pearl powder and binder solution mixed preparing, wherein described adhesive solution is the following weight for being 100 parts by total weight
Measure part raw material composition:
Adhesive 10~20
Water 80~90
The adhesive is that hydroxypropyl cellulose or hydroxypropyl cellulose are mixed with carboxymethyl cellulose according to mass ratio 2:1；
The water is pure water；
Specific preparation process is as follows with quick-fried pearl for the pearly-lustre cigarette:
(1) in 25 ± 5 DEG C of water for being added to the adhesive in above-mentioned formula, 0.5~1 hour dissolution composite adhesives of stirring is water-soluble
Liquid, and stand defoaming 2~5 hours；
(2) molded and dried cigarette is placed in granulator coater with quick-fried pearl, according to cigarette in granulator coater with quick-fried pearl
The 2%~5% of total weight is added the binder aqueous solution prepared in step (1) in the solution injection apparatus of seed-coating machine, while
Pearl powder is added in the powder feed arrangement of granulator coater, is then turned on device, keeps quick-fried pearl product even in granulator coater
Speed rolls, and the binder aqueous solution by configuring in solution injection apparatus sprinkling step (1), while passing through powder feed arrangement
Synchronous uniform velocity sprays pearl powder, and the addition of binder aqueous solution and pearl powder is completed in 1~1.5 hour；The pearl powder
Additive amount accounts for the 10%~20% of binder solution quality, and the pearl powder partial size is 10-40 μm, TiO2Clad ratio is 20-
40%；
(3) after binder aqueous solution and pearl powder addition are completed, the cigarette of binder solution and pearl powder will be sprayed with quick-fried
Pearl dries 6~10 hours in the environment of 18 ± 2 DEG C of temperature, humidity 40% ± 5% to get pearly-lustre cigarette is arrived with quick-fried pearl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610935665.0A CN106418686B (en) | 2016-11-01 | 2016-11-01 | A kind of quick-fried pearl pearly-lustre of cigarette is coated membrane material and pearly-lustre the cigarette preparation method of quick-fried pearl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610935665.0A CN106418686B (en) | 2016-11-01 | 2016-11-01 | A kind of quick-fried pearl pearly-lustre of cigarette is coated membrane material and pearly-lustre the cigarette preparation method of quick-fried pearl |
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| Publication Number | Publication Date |
|---|---|
| CN106418686A CN106418686A (en) | 2017-02-22 |
| CN106418686B true CN106418686B (en) | 2019-09-10 |
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| CN111436648A (en) * | 2019-01-16 | 2020-07-24 | 深圳波顿香料有限公司 | Preparation method of pellet for cigarette and application of pellet in cigarette filter |
| CN111557470A (en) * | 2020-05-26 | 2020-08-21 | 福建中烟工业有限责任公司 | Method for preparing bead-blasting filter stick |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2006136197A1 (en) * | 2005-06-21 | 2006-12-28 | V. Mane Fils | Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule |
| CN102911408B (en) * | 2012-09-26 | 2014-10-22 | 广西中烟工业有限责任公司 | Method for preparing pearl-powder composite porous starch crystalline particles and application of pearl-powder composite porous starch crystalline particles to cigarette filtering tip |
| CN103498386B (en) * | 2013-10-16 | 2015-06-24 | 湖北工业大学 | Pearlescent pigment anti-fake cigarette paper and manufacturing method thereof |
| CN105520191A (en) * | 2015-12-29 | 2016-04-27 | 东莞波顿香料有限公司 | Capsule for cigarette and preparing method of capsule |
| CN205492610U (en) * | 2016-03-29 | 2016-08-24 | 红塔烟草(集团)有限责任公司 | Visual multi -flavor cigarette of modified |
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