CN106417332A - Insecticidecomposition containing spirotetramat and fenoxycarb - Google Patents
Insecticidecomposition containing spirotetramat and fenoxycarb Download PDFInfo
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- CN106417332A CN106417332A CN201610729777.0A CN201610729777A CN106417332A CN 106417332 A CN106417332 A CN 106417332A CN 201610729777 A CN201610729777 A CN 201610729777A CN 106417332 A CN106417332 A CN 106417332A
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- fenoxycarb
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- spiral shell
- ethyl ester
- shell worm
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of insecticides, and particularly relates to an insecticidecomposition containing spirotetramat and fenoxycarb. The insecticidecomposition comprises spirotetramat and fenoxycarb by the weight ratio of 80:1-1:80. The insecticidecomposition is good in insect preventing and controlling effect, high in fast-acting property and long in lasting period, the dosage can be effectively reduced, and usage cost is saved.
Description
Technical field
The invention belongs to pesticide field, in particular to a kind of insecticide composition containing spiral shell worm ethyl ester and fenoxycarb
Thing.
Background technology
Citrus scale insect is one of primary pest of Orange Producing, and its species is many, breeding is fast, and generation overlap hazardness is big,
It is dispersed throughout national each Citrus producing region, especially with icerya purchasi, ceroplastes rubens, bran piece a red-spotted lizard, chaff scale, brown round a red-spotted lizard, arrowhead scales, heap wax powder a red-spotted lizard danger
Evil most serious.Adult and nymph thorn inhale the juice organized, and killed tissue can not reach full growth, and tree vigo(u)r is weak, causes fallen leaves shedding,
Impact fruit quality, and dark mildew can be induced.
Past preventing and treating a red-spotted lizard class pest commonly uses high-toxic pesticide, such as omethoate, isocarbophoss, methidathion etc., these agricultures at present
Medicine disables on Orange Producing.Due to valuable information for systematic having been draped over one's shoulders on most of coccid bodies, therefore to the preventing and treating of coccid very
Difficulty reaches ideal effect, and generally existing drug effect is shorter, the more problem of spraying times, thus leading to consumption big, cost is relatively
High.Some high-efficiency low-toxicities therefore must be selected kills coccid agent.
Content of the invention
The present invention provides for solving technical problem present in known technology that a kind of pest controling effect is good, quick-acting
The high, insecticides containing spiral shell worm ethyl ester and fenoxycarb of lasting period length, can effectively reduce dosage, save medication and become
This.
The present invention is adopted the technical scheme that by solving technical problem present in known technology：One kind contains spiral shell worm second
Ester and the insecticides of fenoxycarb, including spiral shell worm ethyl ester and fenoxycarb, the two weight is than for 80：1～1：80.
Advantages of the present invention and good effect are：Spiral shell worm ethyl ester is tetronic acid class compound, and this compound can be whole
Move down upwards in plant, arrive at blade face and bark, thus in preventing and treating such as Caulis et Folium Lactucae Sativae and Chinese cabbage internal lobe, and the evil in skin of fruit tree
Worm.Various suckings pest can effectively be prevented and treated, such as aphid, thrips, wood louse, mealybug, aleyrodid and coccid etc., and it is held
The effect phase is long, and preventive effect was up to 8 weeks.Fenoxycarb is a kind of non-terpenes carbamate compounds, is that one kind has stomach toxicity and tags
Act on and have the juvenile hormone insecticides of insect growth adjustment effect, develop and metamorphosis process by interference insect is peculiar
And producing insecticidal action, insecticide is not likely to produce resistance, can be widely applied to warehousing, health, Cotton Gossypii, orchard, vegetable garden and views and admires plant
In thing, the insect such as preventing and treating Blatta seu periplaneta, flea, Coptotermes formosanus Shtrari., Lepidoptera, coleoptera, a red-spotted lizard class, wood louse, leaf rollerses.Spiral shell worm ethyl ester and benzene oxygen
Prestige is compounded, and complex composition is used alone relative to spiral shell worm ethyl ester or fenoxycarb has notable potentiation, can effectively prevent and treat
Aphid on fruit and vegetables, thrips, wood louse, mealybug, aleyrodid and coccid etc., especially prevent and treat to the coccid on Citrus fruit tree
There is excellent effect.Because the model of action of two kinds of compounds is different, there is not cross resistance, therefore said composition can be effective
Two kinds of medicines are delayed to be used alone produced resistance problems.
Preferably：Also include carrier, described carrier is natural or the mineral of regeneration or organic solvent or solubilizing agent or table
Face activating agent or thickening agent or adhesive or disintegrating agent or antifreezing agent, wherein surfactant are emulsifying agent or dispersant or moistening
Agent, at least contains two kinds of carriers and wherein at least one is surfactant.
Preferably：Described organic solvent is toluene, dimethylbenzene, mixed benzene, isopropanol, butanol, ethylene glycol, diethylene glycol, three sweet
Alcohol, propylene glycol, glycerol, Sorbitol, benzyl alcohol, Hexalin, and acetone, methyl iso-butyl ketone (MIBK), Ketohexamethylene, dimethyl formyl
Amine, dimethyl sulfoxide, ketopyrrolidine, dichloromethane, chloroform, carbon tetrachloride, dimethyldecamide, No. 100 solvent naphthas, No. 150
Solvent naphtha, one or more of No. 200 solvent naphthas, vegetable oil, methyl oleate, sec-Butyl Acetates.
Preferably：Described emulsifying agent is sodium lauryl sulphate, secondary pareth sulfate, detergent alkylate sulphur
Sour sodium, calcium dodecyl benzene sulfonate, polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, Polyoxyethylene fatty ammonia, agriculture breast
No. 500, agriculture breast 0201B, one or more of agriculture breast 0203B.
Preferably：Described dispersant or wetting agent are sodium lignin sulfonate, pull open powder, calcium lignosulfonate, lauric acid sulfur
Sour sodium, alkylol polyoxyethylene base ether sodium sulfate, octylphenol polyethylene oxyethylene group ether sulfate, alkylphenol-polyethenoxy base ether formaldehyde
In condensate sulfate, sodium alkyl sulfonate, dodecylbenzene sodium sulfonate, penetrating agent JFC, penetrant t, Tween 80, polysorbas20
One or more.
Preferably：Described adhesive or thickening agent are carboxymethyl cellulose, methylcellulose, polyvinyl alcohol, silicic acid, silicic acid
Magnalium, starch derivatives, dextrin, soybean protein, osseocolla, sodium sulfate, Gypsum Fibrosum, Colophonium, xanthan gum, gelatin, arabic gum, poly- second
One or more of alkene pyrrolidone, sodium alginate.
Preferably：Described disintegrating agent be one of ammonium sulfate, calcium chloride, magnesium chloride, aluminum chloride, bentonite, carbamide or
Multiple.
Preferably：Described mineral carrier is solid carrier or particulate vector, and described solid carrier is the rock naturally occurring
Stone powder, quartz, clay, montmorillonite, silicon dioxide, kieselguhr, Pumex, Gypsum Fibrosum, Talcum, bentonite, Kaolin, potter's clay, white
One or more of white carbon black；Described particulate vector is the natural rock pulverized and be classified.
Preferably：Can prepare creaming agent or aqueous emulsion or microemulsion or wettable powder or suspending agent or effervescent tablet or
Micro-capsule suspension or water dispersible granules.
Preferably：The gross weight of spiral shell worm ethyl ester and fenoxycarb accounts for the 1～80% of total formulation weight.
Specific embodiment
For content of the invention, feature and effect of the present invention can be further appreciated that, hereby enumerate following examples and describe in detail such as
Under：
, including spiral shell worm ethyl ester and fenoxycarb, the two weight is than for 80 for the present invention：1～1：80；Also include carrier, described
Carrier is natural or the mineral of regeneration or organic solvent or solubilizing agent or surfactant or thickening agent or adhesive or disintegrate
Agent or antifreezing agent, wherein surfactant are emulsifying agent or dispersant or wetting agent, at least contain two kinds of carriers and wherein at least
A kind of is surfactant.
Creaming agent or aqueous emulsion or microemulsion or wettable powder or suspending agent or effervescent tablet or microcapsule can be prepared
Suspending agent or water dispersible granules.The gross weight of spiral shell worm ethyl ester and fenoxycarb accounts for the 1～80% of total formulation weight.
Described organic solvent is toluene, dimethylbenzene, mixed benzene, isopropanol, butanol, ethylene glycol, diethylene glycol, 2,2'-ethylenedioxybis(ethanol)., the third two
Alcohol, glycerol, Sorbitol, benzyl alcohol, Hexalin, and acetone, methyl iso-butyl ketone (MIBK), Ketohexamethylene, dimethylformamide, diformazan
Base sulfoxide, ketopyrrolidine, dichloromethane, chloroform, carbon tetrachloride, dimethyldecamide, No. 100 solvent naphthas, No. 150 solvent naphthas,
One or more of No. 200 solvent naphthas, vegetable oil, methyl oleate, sec-Butyl Acetates.
Described emulsifying agent be sodium lauryl sulphate, secondary pareth sulfate, dodecylbenzene sodium sulfonate, ten
Dialkyl benzene sulfonic acids calcium, polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, Polyoxyethylene fatty ammonia or commercially available emulsifying agent
One or more of (as agriculture breast 500, agriculture breast 0201B, agriculture breast 0203B etc.).
Described dispersant or wetting agent are sodium lignin sulfonate, pull open powder, calcium lignosulfonate, sulfonate of laurate sodium sulphate, alkane
Base alcohol polyoxyethylene groups ether sodium sulfate, octylphenol polyethylene oxyethylene group ether sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products
One of sulfate, sodium alkyl sulfonate, dodecylbenzene sodium sulfonate, penetrating agent JFC, penetrant t, Tween 80, polysorbas20 or
Multiple.
Described adhesive or thickening agent are carboxymethyl cellulose, methylcellulose, polyvinyl alcohol, silicic acid, aluminium-magnesium silicate, shallow lake
Powder derivant, dextrin, soybean protein, osseocolla, sodium sulfate, Gypsum Fibrosum, Colophonium, xanthan gum, gelatin, arabic gum, polyvinyl pyrrole
One or more of alkanone, sodium alginate.
Described disintegrating agent is one or more of ammonium sulfate, calcium chloride, magnesium chloride, aluminum chloride, bentonite, carbamide.
Described mineral carrier is divided into solid carrier and particulate vector, the rock that described solid carrier can be naturally occurring
Powder, quartz, clay, montmorillonite, silicon dioxide, kieselguhr, Pumex, Gypsum Fibrosum, Talcum, bentonite, Kaolin, potter's clay, Linesless charcoal
The mineral grinding, for example microdispersed silicic acid or aluminium oxide black and that synthesize.Particulate vector includes sky that pulverize and classification
So rock, the synthesis that for example calcite, marble, Pumex, meerschaum, dolomite and the powder by Organic substance and inorganic matters are made
Granule etc..
Embodiment 1
The preparation of the emulsifiable concentrate of 1% spiral shell worm ethyl ester+4% fenoxycarb：
By recipe requirements, be separately added into solvent, active compound, emulsifying agent, mix homogeneously, if necessary can slightly heat of solution, obtain final product
To transparence cream.
Embodiment 2
The preparation of the emulsifiable concentrate of 10% spiral shell worm ethyl ester+5% fenoxycarb：
By recipe requirements, be separately added into solvent, active compound, emulsifying agent, mix homogeneously, if necessary can slightly heat of solution, obtain final product
To transparence cream.
Embodiment 3
The preparation of the wettable powder of 20% spiral shell worm ethyl ester+30% fenoxycarb：
By recipe requirements, active compound, various auxiliary agent and filler etc. are sufficiently mixed, pulverize through jet mill, until granule
Fineness reaches wettable powder standard value (fineness is more than 325 mesh).
Embodiment 4
The preparation of the aqueous emulsion of 5% spiral shell worm ethyl ester+5% fenoxycarb：
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous transparent oil phase, by water, ethylene glycol, xanthan gum etc.
It is mixed, become homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added to oil phase or oil phase is added to aqueous phase, formed point
The good aqueous emulsion of scattered property.
Embodiment 5
The preparation of the microemulsion of 5% spiral shell worm ethyl ester+10% fenoxycarb：
Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous transparent oil phase, water, ethylene glycol etc. are mixed one
Rise, become homogeneous aqueous phase.Under agitation, aqueous phase is slowly added to oil phase, continues stirring formation homogeneous transparent and be microemulsion.
Embodiment 5
The preparation of the water dispersion granule of 20% spiral shell worm ethyl ester+60% fenoxycarb：
Active compound and powder carrier, wetting agent, dispersant, disintegrating agent etc. are mixed in proportion, through jet mill powder
Broken, add a certain amount of moisture content kneading, pelletize in comminutor, then drying, screening (by screen cloth scope) and obtain final product graininess and produce
Product.
Embodiment 6
The preparation of the suspending agent of 15% spiral shell worm ethyl ester+10% fenoxycarb：
By recipe requirements, with water as medium, active compound, dispersant, suspending agent and antifreezing agent etc. are added in sand milling kettle, carries out
Sand milling, is obtained suspending agent after reaching regulation fineness.
Embodiment 7
The preparation of the micro-capsule suspension of 2% spiral shell worm ethyl ester+8% fenoxycarb：
By recipe requirements, spiral shell worm ethyl ester, fenoxycarb are dissolved in solvent, add emulsifying agent, defoamer, the stirring of part water
Obtain oil-in-water emulsion within 20 minutes.Carbamide is mixed with formalin and dissolves, adjust PH to 8.0 with sodium hydroxide solution, and
Obtain urea resin prepolymer solution 70 DEG C of reaction certain times.Prepolymer solution is mixed with emulsion, is adjusted with hydrochloric acid solution
Save PH and heating cure certain time obtains microcapsule suspensions, add wetting agent, dispersant, thickening agent stirring and dissolving to be obtained micro-
Capsule suspension.
Embodiment 8
The preparation of the effervescent tablet of 3% spiral shell worm ethyl ester+17% fenoxycarb：
By formula by after each component mix homogeneously, make female powder through comminution by gas stream, using double roller cylinder tablet machine, dry method pressure
Piece becomes the effervescent tablet of monolithic weight 1g.
Spiral shell worm ethyl ester is tetronic acid class compound, is to have one of modern pesticides of two-way Uptake and translocation performance so far.
This compound can move down in whole plant upwards, arrives at blade face and bark, thus in preventing and treating such as Caulis et Folium Lactucae Sativae and Chinese cabbage
Insect on Ye Shang, and skin of fruit tree.Various suckings pest can effectively be prevented and treated, such as aphid, thrips, wood louse, mealybug, aleyrodid
With coccid etc..And its lasting period is long, preventive effect was up to 8 weeks.The chemical name of spiral shell worm ethyl ester：Cis-3- (2,5- dimethyl benzene
Base) -8- methoxyl group -2- oxo -1- azaspiro [4.5]-decyl- 3- alkene -4- ethyl, its chemical structural formula is：
Fenoxycarb is a kind of non-terpenes carbamate compounds, is that one kind has stomach toxicity and action of contace poison and has
The juvenile hormone insecticides of insect growth adjustment effect, are produced parasite killing and are made by the peculiar growth of interference insect and metamorphosis process
With insecticide is not likely to produce resistance, can be widely applied in warehousing, health, Cotton Gossypii, orchard, vegetable garden and ornamental plant, prevents and treats roach
The insects such as dung beetle, flea, Coptotermes formosanus Shtrari., Lepidoptera, coleoptera, a red-spotted lizard class, wood louse, leaf rollerses.Chemical name：2- (p- phenoxy group benzene oxygen
Base) ethyl carbamic acid ethyl ester, its chemical structural formula is：
The present invention is compounded with spiral shell worm ethyl ester and fenoxycarb, and complex composition individually makes relative to spiral shell worm ethyl ester or fenoxycarb
With having notable potentiation, can effectively prevent and treat aphid on fruit and vegetables, thrips, wood louse, mealybug, aleyrodid and coccid
Deng, especially on Citrus fruit tree coccid preventing and treating there is excellent effect.Because the model of action of two kinds of compounds is different, do not deposit
In cross resistance, therefore said composition can effectively delay two kinds of medicines to be used alone produced resistance problems.The present invention
The potentiation of compositionss is notable, therefore significantly reduces dosage, and extends the lasting period, effectively saves drug cost.
The present invention is illustrated by tests below effect：
Test 1
The emulsifiable concentrate of preparation embodiment 2 is used for preventing and treating the field control effectiveness test of Citrus scale insect：
Demonstrate this medicament to the prevention effect of Citrus scale insect and effective dose.Test medicine and dosage refer to table 1, and
If blank.Each processes 4 repetitions, and each repeats to process one plant of mandarin tree.Before dispenser and 5,10,20 after dispenser
It carries out borer population investigation of living.6 fixing brachyplasts of every plant of mandarin tree investigation, each brachyplast investigates 5 blades.Record scale insect is lived
Borer population simultaneously calculates Revision insect recluced rate and Rectifying efficacies.
Computational methods：
Revision insect recluced rate (%)=(insect population number after before processing insect population number-process)/before processing insect population number × 100%
Rectifying efficacies (%)=(treatment region Revision insect recluced rate-check plot Revision insect recluced rate)/(1- check plot insect population goes down
Rate) × 100%
Table 1 reagent agent EXPERIMENTAL DESIGN
Table 2 embodiment 2 prevents and treats Citrus scale insect result statistical table
From table 2 it can be seen that 3000 times of liquid being diluted with embodiment 2 and carrying out spraying preventing and treating Citrus scale insect, there is good preventing
Control effect, preventive effect is close to 100%.Embodiment 2 dilutes 3500 times of liquid and 4000 times of liquid also can reach to the preventive effect of Citrus scale insect
More than 90%.Process 5 days preventive effects of D, E suitable with processing A, but 20 days preventive effects are more lower slightly than processing A, and holding of complex preparation is described
Effect property is better than single dose.When outstanding using 22.4% spiral shell worm ethyl ester diluting 3000 times of liquid identical effective ingredient concentration with embodiment 2
During floating agent preventing and treating, 22.4% spiral shell worm ethyl ester suspending agent preventive effect is 91.74%, more obvious than the embodiment 2 of identical effective ingredient concentration
Poor, the fenoxycarb single dose of routine dose is also significantly lower than complex preparation to 20 days preventive effects of Citrus scale insect, and spiral shell worm second is described
Ester is compounded with fenoxycarb has significantly potentiation.
Test 2
The suspending agent of preparation embodiment 6 is used for preventing and treating the test of Citrus scale insect, and reagent agent and dosage are as shown in table 3.
Table 3 reagent agent EXPERIMENTAL DESIGN
Table 4 embodiment 6 prevents and treats Citrus scale insect result statistical table
Note：Preventive effect (%) in upper table is each repetition meansigma methodss.
After embodiment 6 (suspending agent of 15% spiral shell worm ethyl ester+10% fenoxycarb) prevents and treats Citrus scale insect, dispenser 5 days, process
The preventive effect of A, B, C, D, E is respectively 87.96%, 92.59%, 94.31%, 84.26%, 84.47%, processes C preventive effect highest, with
Process A, B, D, E and all there is significant difference, process A and B with processing D, E and all there is significant difference, process D and process no aobvious between E
Write difference.The preventive effect of dispenser 10 days post processings A, B, C, D, E be respectively 94.32%, 98.13%, 99.18%, 89.88%,
89.70%, process B and C no significant difference, the two all has significant difference with processing A, D, E, processing A has significantly with processing D, E
Difference, processes D and processes no significant difference between E.After dispenser 20 days process A, B, C, D, E preventive effect be respectively 96.85%,
99.87%th, 99.94%, 91.74%, 89.49%, after each process significant difference and dispenser, 10 days results are close, only process
Between D and process E, the significance of difference changes, significant difference between the two.By result of the test as can be seen that embodiment 6 prevents and treats Citrus chachiensis Hort.
Fructus Citri tangerinae scale insect has good prevention effect, reaches preferable preventive effect when extension rate is 5000 times, and has better than identical
Effect 22.4% spiral shell worm ethyl ester suspending agent of constituent concentration and the preventive effect of relatively high concentration of 25% fenoxycarb wettable powder.
In sum, composition pesticide of the present invention is the compound scheme of two kinds of active components, and its activity and parasite killing are imitated
Fruit is not the simple superposition of each composition activity, has significantly potentiation, show excellent compared with existing unitary agent
Lasting effect, reduce usage amount, save drug cost, meet the security requirement of pesticidal preparations.
Claims (10)
1. a kind of insecticides containing spiral shell worm ethyl ester and fenoxycarb it is characterised in that：Including spiral shell worm ethyl ester and fenoxycarb,
The two weight ratio is for 80：1～1：80.
2. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 1 it is characterised in that：Also include carrying
Body, described carrier is natural or the mineral of regeneration or organic solvent or solubilizing agent or surfactant or thickening agent or adhesive
Or disintegrating agent or antifreezing agent, wherein surfactant be emulsifying agent or dispersant or wetting agent, at least contain two kinds of carriers and its
At least one of be surfactant.
3. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 2 it is characterised in that：Described organic
Solvent is toluene, dimethylbenzene, mixed benzene, isopropanol, butanol, ethylene glycol, diethylene glycol, 2,2'-ethylenedioxybis(ethanol)., propylene glycol, glycerol, Sorbitol,
Benzyl alcohol, Hexalin, and acetone, methyl iso-butyl ketone (MIBK), Ketohexamethylene, dimethylformamide, dimethyl sulfoxide, ketopyrrolidine,
Dichloromethane, chloroform, carbon tetrachloride, dimethyldecamide, No. 100 solvent naphthas, No. 150 solvent naphthas, No. 200 solvent naphthas, plants
One or more of oil, methyl oleate, sec-Butyl Acetate.
4. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 2 it is characterised in that：Described emulsifying
Agent be sodium lauryl sulphate, secondary pareth sulfate, dodecylbenzene sodium sulfonate, calcium dodecyl benzene sulfonate,
Polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, Polyoxyethylene fatty ammonia, agriculture breast 500, agriculture breast 0201B, agriculture breast
One or more of 0203B.
5. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 2 it is characterised in that：Described dispersion
Agent or wetting agent are sodium lignin sulfonate, pull open powder, calcium lignosulfonate, sulfonate of laurate sodium sulphate, alkylol polyoxyethylene base ether
Sodium sulfate, octylphenol polyethylene oxyethylene group ether sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, alkyl sulfonic acid
One or more of sodium, dodecylbenzene sodium sulfonate, penetrating agent JFC, penetrant t, Tween 80, polysorbas20.
6. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 2 it is characterised in that：Described bonding
Agent or thickening agent are carboxymethyl cellulose, methylcellulose, polyvinyl alcohol, silicic acid, aluminium-magnesium silicate, starch derivatives, dextrin, big
In soybean protein, osseocolla, sodium sulfate, Gypsum Fibrosum, Colophonium, xanthan gum, gelatin, arabic gum, Polyvinylpyrrolidone, sodium alginate
One or more.
7. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 2 it is characterised in that：Described disintegrate
Agent is one or more of ammonium sulfate, calcium chloride, magnesium chloride, aluminum chloride, bentonite, carbamide.
8. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 2 it is characterised in that：Described mineral
Matter carrier be solid carrier or particulate vector, described solid carrier be naturally occur rock dust, quartz, clay, montmorillonite,
One or more of silicon dioxide, kieselguhr, Pumex, Gypsum Fibrosum, Talcum, bentonite, Kaolin, potter's clay, white carbon；Described
Grain carrier is the natural rock pulverized and be classified.
9. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 2 it is characterised in that：Can be prepared into
Emulsifiable concentrate or aqueous emulsion or microemulsion or wettable powder or suspending agent or effervescent tablet or micro-capsule suspension or water-dispersible grain
Agent.
10. the insecticides containing spiral shell worm ethyl ester and fenoxycarb as claimed in claim 9 it is characterised in that：Spiral shell worm second
The gross weight of ester and fenoxycarb accounts for the 1～80% of total formulation weight.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115104612A (en) * | 2021-08-24 | 2022-09-27 | 汝阳自强生物科技有限公司 | Granular formulation for treating melon wilt and preparation method and application thereof |
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| CN103283774A (en) * | 2012-02-22 | 2013-09-11 | 陕西美邦农药有限公司 | Spirotetramat containing pesticide composition |
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|---|---|---|---|---|
| CN1471358A (en) * | 2000-08-31 | 2004-01-28 | �ݶ�ũ�����ѧ�ɷݹ�˾ | Active ingredient combinations comprising insecticidal and acaricidal properties |
| CN1692099A (en) * | 2002-07-11 | 2005-11-02 | 拜尔农作物科学股份公司 | Cis-alkoxy-substituted spirocyclic 1-h-pyrrolidine-2,4-dione derivatives serving as pesticides |
| CN103283774A (en) * | 2012-02-22 | 2013-09-11 | 陕西美邦农药有限公司 | Spirotetramat containing pesticide composition |
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| CN115104612A (en) * | 2021-08-24 | 2022-09-27 | 汝阳自强生物科技有限公司 | Granular formulation for treating melon wilt and preparation method and application thereof |
| CN115104612B (en) * | 2021-08-24 | 2023-10-27 | 汝阳自强生物科技有限公司 | Granule for treating melon wilt and preparation method and application thereof |
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