CN106401705A - Environment-friendly purifier for automobile exhaust - Google Patents

Environment-friendly purifier for automobile exhaust Download PDF

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Publication number
CN106401705A
CN106401705A CN201611079813.XA CN201611079813A CN106401705A CN 106401705 A CN106401705 A CN 106401705A CN 201611079813 A CN201611079813 A CN 201611079813A CN 106401705 A CN106401705 A CN 106401705A
Authority
CN
China
Prior art keywords
cartridge filter
filter
connecting tube
group
combustion box
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611079813.XA
Other languages
Chinese (zh)
Inventor
李伟
朱莹
梁萍
张茜
陈婉秋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Mechanical and Electrical Engineering College
Original Assignee
Henan Mechanical and Electrical Engineering College
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Mechanical and Electrical Engineering College filed Critical Henan Mechanical and Electrical Engineering College
Priority to CN201611079813.XA priority Critical patent/CN106401705A/en
Publication of CN106401705A publication Critical patent/CN106401705A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/04Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust using liquids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0821Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/38Arrangements for igniting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/10Carbon or carbon oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/12Hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14Nitrogen oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y02A50/2351Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses an environment-friendly purifier for automobile exhaust. The environment-friendly purifier comprises a first filter barrel which is provided with a filter element, wherein the first filter barrel is connected with a second filter barrel through a first connection pipe; acid neutralization liquid is contained in the second filter barrel; the second filter barrel is connected with a third filter barrel through a second connection pipe; alkali neutralization liquid is contained in the third filter barrel; the third filter barrel is connected with a drying barrel through a third connection pipe; the drying barrel is connected with a combustion box through a fourth connection pipe; an air blower is arranged at the bottom of the combustion box; the air outlet of the combustion box is provided with electronic ignition nozzles; the combustion box is connected with a fourth filter barrel through a fifth connection pipe; an air pump is connected onto the fifth connection pipe; filter water is contained in the fourth filter barrel; and an air outlet pipe is connected onto the fourth filter barrel. The environment-friendly purifier has the advantages that PM2.5 particles, hydrocarbon, oxynitrides and carbon monoxide which are emitted in the automobile exhaust can be fully filtered; damage to human bodies is reduced; and the air is clean and harmless.

Description

A kind of environmental-protection purifying for vehicle exhaust
Technical field
The present invention relates to vehicle maintenance service, more particularly, to a kind of environmental-protection purifying for vehicle exhaust.
Background technology
With the fast development of modern industry, discharge sharply increasing with garbage of vehicle etc., atmosphere polluting problem is got over Come more serious, also make environment for the survival of mankind obtain severe contamination, particularly the PM2.5 fine particle of in the air The involuntary health having jeopardized mankind itself.PM2.5 fine particle is mainly derived from motor vehicle exhaust emission and industry Waste gas, PM2.5 fine particle may pass through respiratory tract and organizes as deep as alveolar etc. and deposit, and then enters blood circulation, finally causes The various disease such as pulmonary carcinoma.And traditional automobile exhaust gas processing apparatus have preferable filtration for the larger microgranule of granule, and Filtration to PM2.5 fine particle is poor, also there is Hydrocarbon, nitrogen in vehicle exhaust in addition to PM2.5 granule The pollutant such as oxygenate and carbon monoxide.
Content of the invention
The invention aims to shortcoming present in solution prior art, and propose a kind of for vehicle exhaust Environmental-protection purifying.
To achieve these goals, present invention employs following technical scheme:
A kind of environmental-protection purifying for vehicle exhaust it is characterised in that:Including the first cartridge filter, the one of the first cartridge filter End is provided with air inlet pipe, the other end is provided with the first connecting tube, is provided with filter element in the first cartridge filter, and the first connecting tube connects the second mistake Filter cylinder, is provided with acid neutralizer in the second cartridge filter, and the gas outlet of the first connecting tube is arranged in acid neutralizer, the second mistake Filter cylinder passes through the second connecting tube and connects the 3rd cartridge filter, is provided with alkaline neutralizer in the 3rd cartridge filter, the going out of the second connecting tube QI KOU is arranged in alkaline neutralizer, and the 3rd cartridge filter passes through the 3rd connecting tube and connects drying, is connected in drying One group of drying layer, drying passes through the 4th connecting tube and connects combustion box, is provided with aerator in the bottom of combustion box, in combustion box Air outlet installs one group of electronic ignition mouth, and combustion box passes through the 5th connecting tube and connects the 4th cartridge filter, connects in the 5th connecting tube Connect air pump, be provided with filter water in the 4th cartridge filter, the gas outlet of the 5th connecting tube is arranged in filter water, in the 4th cartridge filter Upper connection escape pipe.
Preferably, one group of first dividing plate of spaced and parallel setting in described second cartridge filter, the one of each the first dividing plate Side is equipped with one group of first through hole, and the first through hole on two the first dividing plates of arbitrary neighborhood all shifts to install.
Preferably, one group of second partition of spaced and parallel setting in described 3rd cartridge filter, the one of each second partition Side is equipped with one group of second through hole, and the second through hole on two second partitions of arbitrary neighborhood all shifts to install.
Preferably, described drying layer includes two web plates be arrangeding in parallel, fills adsorbent charcoal between two web plates.
It is an advantage of the current invention that:A kind of environmental-protection purifying for vehicle exhaust provided by the present invention, can be by vapour The PM2.5 granule of tail gas discharge, Hydrocarbon, nitrogen oxygenate and carbon monoxide fully filter, and reduce the harm to human body, Make air cleaner harmless.
Brief description
Fig. 1 is a kind of structural representation of environmental-protection purifying for vehicle exhaust provided by the present invention.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with drawings and Examples, right The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only in order to explain the present invention, and It is not used in the restriction present invention.
As shown in figure 1, a kind of environmental-protection purifying for vehicle exhaust that the present invention provides, including the first cartridge filter 1, the One end of one cartridge filter 1 is provided with air inlet pipe 2, the other end is provided with the first connecting tube 3, is provided with filter element 4 in the first cartridge filter 1, the One connecting tube 3 connects the second cartridge filter 5, is provided with acid neutralizer 6, the gas outlet of the first connecting tube 3 sets in the second cartridge filter 5 Put in acid neutralizer 6, one group of first dividing plate 7 of interior spaced and parallel setting in the acid neutralizer 6 of the second cartridge filter 5, The side of each the first dividing plate 7 is equipped with one group of first through hole 8, the equal mistake of first through hole 8 on two the first dividing plates 7 of arbitrary neighborhood Position setting.
Second cartridge filter 5 connects the 3rd cartridge filter 10 by the second connecting tube 9, is provided with alkalescence in the 3rd cartridge filter 10 With liquid 11, the gas outlet of the second connecting tube 9 is arranged in alkaline neutralizer 11, in the alkaline neutralizer 11 of the 3rd cartridge filter 10 One group of second partition 12 of spaced and parallel setting, is equipped with one group of second through hole 13, any phase in the side of each second partition 12 The second through hole 13 on adjacent two second partitions 12 all shifts to install.
3rd cartridge filter 10 connects drying 15 by the 3rd connecting tube 14, and be connected in drying 15 one group of drying Layer 16, drying layer 16 includes two web plates be arrangeding in parallel, fills adsorbent charcoal between two web plates.Drying 15 passes through the 4th Connecting tube 17 connects combustion box 18, is provided with aerator 19 in the bottom of combustion box 18, installs one group in the air outlet of combustion box 18 Electronic ignition mouth 20, combustion box 18 connects the 4th cartridge filter 24 by the 5th connecting tube 21, connects gas in the 5th connecting tube 21 Pump 23, is provided with filter water 24, the gas outlet of the 5th connecting tube 21 is arranged in filter water 24, the 4th in the 4th cartridge filter 24 Escape pipe 25 is connected on cartridge filter 24.

Claims (4)

1. a kind of environmental-protection purifying for vehicle exhaust it is characterised in that:Including the first cartridge filter (1), the first cartridge filter (1) One end be provided with air inlet pipe (2), the other end is provided with the first connecting tube (3), is provided with filter element (4) in the first cartridge filter (1), first Connecting tube (3) connects the second cartridge filter (5), is provided with acid neutralizer (6) in the second cartridge filter (5), the first connecting tube (3) Gas outlet is arranged in acid neutralizer (6), and the second cartridge filter (5) connects the 3rd cartridge filter (10) by the second connecting tube (9), It is provided with alkaline neutralizer (11) in the 3rd cartridge filter (10), the gas outlet of the second connecting tube (9) is arranged on alkaline neutralizer (11), in, the 3rd cartridge filter (10) passes through the 3rd connecting tube (14) and connects drying (15), is connected in drying (15) One group of drying layer (16), drying (15) passes through the 4th connecting tube (17) and connects combustion box (18), in the bottom of combustion box (18) It is provided with aerator (19), in the air outlet of combustion box (18), one group of electronic ignition mouth (20) is installed, combustion box (18) passes through the 5th Connecting tube (21) connects the 4th cartridge filter (24), in the 5th connecting tube (21) upper connection air pump (23), in the 4th cartridge filter (24) Inside it is provided with filter water (24), the gas outlet of the 5th connecting tube (21) is arranged in filter water (24), on the 4th cartridge filter (24) Connect escape pipe (25).
2. a kind of environmental-protection purifying for vehicle exhaust according to claim 1 it is characterised in that:In described second mistake One group of first dividing plate (7) of spaced and parallel setting in filter cylinder (5), is equipped with one group first in the side of each the first dividing plate (7) and leads to Hole (8), the first through hole (8) on two the first dividing plates (7) of arbitrary neighborhood all shifts to install.
3. a kind of environmental-protection purifying for vehicle exhaust according to claim 1 it is characterised in that:In described 3rd mistake In filter cylinder (10), one group of second partition (12) of spaced and parallel setting, is equipped with one group second in the side of each second partition (12) Through hole (13), the second through hole (13) on two second partitions (12) of arbitrary neighborhood all shifts to install.
4. a kind of environmental-protection purifying for vehicle exhaust according to claim 1 it is characterised in that:Described drying layer (16) include two web plates be arrangeding in parallel, fill adsorbent charcoal between two web plates.
CN201611079813.XA 2016-11-30 2016-11-30 Environment-friendly purifier for automobile exhaust Pending CN106401705A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611079813.XA CN106401705A (en) 2016-11-30 2016-11-30 Environment-friendly purifier for automobile exhaust

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611079813.XA CN106401705A (en) 2016-11-30 2016-11-30 Environment-friendly purifier for automobile exhaust

Publications (1)

Publication Number Publication Date
CN106401705A true CN106401705A (en) 2017-02-15

Family

ID=58084089

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611079813.XA Pending CN106401705A (en) 2016-11-30 2016-11-30 Environment-friendly purifier for automobile exhaust

Country Status (1)

Country Link
CN (1) CN106401705A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2554360Y (en) * 2002-08-01 2003-06-04 王廷 Filter tube of tail gas of vehicle
CN102861496A (en) * 2012-09-27 2013-01-09 安徽省电力科学研究院 Purification treatment device of flue gas produced by combusting electric wires
CN104196599A (en) * 2014-08-22 2014-12-10 山东商业职业技术学院 Haze reduction exhaust funnel
CN204024773U (en) * 2014-08-06 2014-12-17 天津市圣威科技发展有限公司 Automobile exhaust purifier
CN204327244U (en) * 2014-12-22 2015-05-13 广东梅雁吉祥水电股份有限公司 Internal combustion engine part associative ring insurance system
CN205277540U (en) * 2015-11-25 2016-06-01 重庆新卓汇汽车净化器有限公司 Automobile tail gas purifying device
CN205435334U (en) * 2016-03-02 2016-08-10 李伟杰 Industrial oil cigarette processing apparatus of improvement structure
CN206290309U (en) * 2016-11-30 2017-06-30 河南机电高等专科学校 A kind of environmental-protection purifying for vehicle exhaust

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2554360Y (en) * 2002-08-01 2003-06-04 王廷 Filter tube of tail gas of vehicle
CN102861496A (en) * 2012-09-27 2013-01-09 安徽省电力科学研究院 Purification treatment device of flue gas produced by combusting electric wires
CN204024773U (en) * 2014-08-06 2014-12-17 天津市圣威科技发展有限公司 Automobile exhaust purifier
CN104196599A (en) * 2014-08-22 2014-12-10 山东商业职业技术学院 Haze reduction exhaust funnel
CN204327244U (en) * 2014-12-22 2015-05-13 广东梅雁吉祥水电股份有限公司 Internal combustion engine part associative ring insurance system
CN205277540U (en) * 2015-11-25 2016-06-01 重庆新卓汇汽车净化器有限公司 Automobile tail gas purifying device
CN205435334U (en) * 2016-03-02 2016-08-10 李伟杰 Industrial oil cigarette processing apparatus of improvement structure
CN206290309U (en) * 2016-11-30 2017-06-30 河南机电高等专科学校 A kind of environmental-protection purifying for vehicle exhaust

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Application publication date: 20170215

RJ01 Rejection of invention patent application after publication