CN106401051B - A kind of insulating brick - Google Patents

A kind of insulating brick Download PDF

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Publication number
CN106401051B
CN106401051B CN201610767574.0A CN201610767574A CN106401051B CN 106401051 B CN106401051 B CN 106401051B CN 201610767574 A CN201610767574 A CN 201610767574A CN 106401051 B CN106401051 B CN 106401051B
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China
Prior art keywords
parts
layer
heat preservation
insulating brick
phase change
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Expired - Fee Related
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CN201610767574.0A
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Chinese (zh)
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CN106401051A (en
Inventor
郭建培
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUIZHOU ANSHUN JIAYU NEW MATERIALS CO Ltd
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GUIZHOU ANSHUN JIAYU NEW MATERIALS CO Ltd
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Priority to CN201610767574.0A priority Critical patent/CN106401051B/en
Publication of CN106401051A publication Critical patent/CN106401051A/en
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Publication of CN106401051B publication Critical patent/CN106401051B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C1/00Building elements of block or other shape for the construction of parts of buildings
    • E04C1/40Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B30/00Compositions for artificial stone, not containing binders
    • C04B30/02Compositions for artificial stone, not containing binders containing fibrous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Building Environments (AREA)

Abstract

The present invention relates to construction materials, more particularly to a kind of insulating brick, the insulating brick is by heat preservation core layer, phase change layer and is coated on the fireprotection layer of phase transformation layer surface and constitutes, its production method are as follows: by heat preservation core layer raw material compression moulding, phase change layer is coated on heat preservation core layer surface, and sinter molding, then prefabricated fireprotection layer is sutured with phase change layer;The present invention passes through the combination of heat preservation core layer, phase change layer and fireprotection layer, improves the heat insulation effect of brick, plays the role of temperature adjustment effect, also act sound-absorbing effect and lightweight, in addition, slowing down environmental pressure using slag, paper sludge as raw material.

Description

A kind of insulating brick
Technical field
The present invention relates to construction material more particularly to a kind of insulating bricks.
Background technique
Insulating brick, a kind of novel product of alternative ceramic tile can replace aluminium-plastic panel, cellular board, curtain wall etc. common comprehensively Ornament materials, be primarily adapted for use in toilet, kitchen, television background wall, bedroom, exterior wall etc..
Also, the thermal insulation property for improving materials for wall is to reduce the key link of building energy consumption, and use thermal insulation mortar can To achieve the purpose that easy for construction, reduction building energy consumption, but thermal insulation mortar comes with some shortcomings, and such as selects material The water absorption rate of slurry is high, condenses in hardening process and often occurs shrinkage phenomenon because of dehydration, thereby reduces thermal insulation property, it is some containing Under uv irradiation, infiltration easy to aging, easy to fall off not only reduces heat insulation effect, also results in house and return the mortar of machine object Tide.
Meanwhile with paper mill, the high-speed production of mine factory, a large amount of waste residue wastes are discharged, have seriously polluted the environment, and locate Reason expense is high, time-consuming and laborious.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of insulating bricks.
The present invention is achieved by the following technical programs.
A kind of insulating brick, the insulating brick is by heat preservation core layer, phase change layer and the fireprotection layer structure for being coated on phase transformation layer surface At production method are as follows: by heat preservation core layer raw material compression moulding, phase change layer is coated on heat preservation core layer surface, and sinter molding, then Prefabricated fireprotection layer is sutured with phase change layer.
Further, the heat preservation core layer includes following raw material: 10-15 parts of granular polystyrene, slag powders 15-20 Part, 10-20 parts of glass bead particle, 10-20 parts of thermal insulation mortar, 15-25 parts of paper sludge, 1-5 parts of medical stone, additive 2-5 Part, 5-8 parts of plant fiber.
Further, the additive is made of by mass percentage following components: 10-25% water-reducing agent, 10-20% disappear Infusion, 5-10% air entraining agent, 5-15% coagulating agent, surplus are hydrophober.
Further, the production method of the heat preservation core layer are as follows:
1) by granular polystyrene, slag powders, glass bead particle, thermal insulation mortar, paper sludge, medical stone is respectively dried to perseverance It is heavy, after milling, it is uniformly mixed, is cooled to room temperature under the conditions of temperature is 200-300 DEG C, it is spare;
2) plant fiber is uniformly mixed with 2-3 times of its weight of water, additive is added and mixes, it is spare;
3) step 2) gains are added in step 1), high-speed stirred is uniform, is placed in mold compression moulding to get heat preservation Sandwich layer.
The phase change layer includes following raw material: 25-35 parts of boraxs, 1-2 parts of carbon fibers, 5-8 parts of polyethylene glycol powder Body, 3-7 part silicon carbide.
The phase change layer is coated on heat preservation core layer surface, method are as follows: is mixed to consistency with water by phase change layer is raw materials used For 70-80mm, then it is uniformly coated on molding heat preservation core layer surface, is formed and is wrapped up with iron net, sinter molding.
The sinter molding, sintering temperature are 180-300 DEG C.
The sinter molding is then to be warming up to 230-300 first under the conditions of sintering temperature is 180-230 DEG C after sintering 1h It is sintered under the conditions of DEG C, the temperature difference in two-step sintering stage must not be lower than 10 DEG C, also must not exceed 100 DEG C.
The fireprotection layer is by following raw material: 35-40 parts of cement, 9-15 parts of aluminum oxide, phenolic group propane epoxy 6-12 parts of resin, 2-5 parts of cellulose ether, 40-45 parts of solvent.
The heat preservation core layer, phase change layer, fireprotection layer mass ratio be (4.5-5.8): 1:(0.8-1.3).
The heat preservation core layer, phase change layer, fireprotection layer mass ratio be 5:1:1.
The suture is sutured using screw.
The beneficial effects of the present invention are:
The present invention passes through the combination of heat preservation core layer, phase change layer and fireprotection layer, improves the heat insulation effect of brick, and also act as Temperature adjustment effect improves materials from bonding ability by the way that paper sludge, medical stone is added, it is therefore prevented that aging image, by the way that mine is added Ground-slag improves the mechanical strength of brick, by the way that glass bead is added, improves heat insulation effect, by the heat absorption of covert layer, stores Heat, heat release function, not only improve the heat insulation effect of heat preservation core layer, and insulating brick is also made to have thermoregulation effect, by the way that carbon is added Fiber enhances anti-crack and anti-seepage performance, by the way that silicon carbide is added, improves fire resistance, further improves abrasive resistance and resistance to compression Ability improves the tightness of structure by the control to sintering temperature, and then improves its anti-folding and anti-pressing ability, by adding Enter plant fiber, on the one hand improve materials from bonding power, on the one hand enhance its lightening effect, passes through the proportion of fireprotection layer raw material Design, effectively improves fire-proof high-temperature resistant ability.The present invention is matched by the selection of every layer of raw material, and integrated structure setting also rises Sound-absorbing effect and lightweight effect are arrived.
The present invention slows down environmental pressure, passes through traditional detection method, this hair using slag, paper sludge as raw material The mean compressive strength of bright insulating brick is about 10.5MPa, and average flexural strength is about 2.8MPa, by insulating brick of the invention and It is 100 DEG C that traditional polystyrene insulating brick, which is separately heated to surface temperature, then by its natural cooling, records it and is cooled to room temperature Time, it is found that the more traditional polystyrene insulating brick of soaking time of insulating brick of the present invention improves 50%.
Specific embodiment
Be described further below technical solution of the present invention, but claimed range be not limited to it is described.
Embodiment 1
A kind of insulating brick, by heat preservation core layer, phase change layer and to be coated on the fireprotection layer of phase transformation layer surface be 5:1:1 in mass ratio It constitutes, production method are as follows:
1, heat preservation core layer raw material compression moulding:
1) by granular polystyrene 12kg, slag powders 18kg, glass bead particle 15kg, thermal insulation mortar 15kg, paper sludge 20kg, medical stone 1kg are respectively dried to constant weight, after milling, are uniformly mixed, are cooled to room temperature under the conditions of temperature is 250 DEG C, standby With;
2) plant fiber 7kg is uniformly mixed with water 21kg, be added additive 3kg mix, it is spare, wherein additive by Following components forms by mass percentage: 20% water-reducing agent, 20% defoaming agent, 10% air entraining agent, 15% coagulating agent, and surplus is to hate Aqua;
3) step 2) gains are added in step 1), high-speed stirred is uniform, is placed in mold compression moulding to get heat preservation Sandwich layer;
2, phase change layer coats heat preservation core layer surface forming:
It is 70mm that borax 30kg, carbon fiber 2kg, polyethylene glycol powder 6kg, silicon carbide 5kg, which are mixed with water to consistency, then It is uniformly coated on molding heat preservation core layer surface, is formed and is wrapped up with iron net, is first sintered 1h under the conditions of sintering temperature is 200 DEG C Afterwards, sinter molding then under the conditions of being warming up to 230 DEG C;
3, the suture of prefabricated fireprotection layer and phase change layer extexine:
Cement 35kg, aluminum oxide 12kg, phenolic group propane epoxy resin 9kg, cellulose ether 4kg, solvent 43kg are mixed After even, cavity type structure is made, phase change layer coating is placed in cavity, is sutured with screw.
Embodiment 2
A kind of insulating brick, by heat preservation core layer, phase change layer and to be coated on the fireprotection layer of phase transformation layer surface be 4.5 in mass ratio: 1:1.3 is constituted, production method are as follows:
1, heat preservation core layer raw material compression moulding:
1) by granular polystyrene 10kg, slag powders 20kg, glass bead particle 20kg, thermal insulation mortar 20kg, paper sludge 15kg, medical stone 2kg are respectively dried to constant weight, after milling, are uniformly mixed, are cooled to room temperature under the conditions of temperature is 200 DEG C, standby With;
2) plant fiber 8kg is uniformly mixed with water 16kg, be added additive 2kg mix, it is spare, wherein additive by Following components forms by mass percentage: 25% water-reducing agent, 10% defoaming agent, 10% air entraining agent, 10% coagulating agent, and surplus is to hate Aqua;
3) step 2) gains are added in step 1), high-speed stirred is uniform, is placed in mold compression moulding to get heat preservation Sandwich layer;
2, phase change layer coats heat preservation core layer surface forming:
It is 75mm that borax 35kg, carbon fiber 1kg, polyethylene glycol powder 8kg, silicon carbide 7kg, which are mixed with water to consistency, then It is uniformly coated on molding heat preservation core layer surface, is formed and is wrapped up with iron net, is first sintered 1h under the conditions of sintering temperature is 230 DEG C Afterwards, sinter molding then under the conditions of being warming up to 300 DEG C;
3, the suture of prefabricated fireprotection layer and phase change layer extexine:
Cement 37kg, aluminum oxide 15kg, phenolic group propane epoxy resin 6kg, cellulose ether 5kg, solvent 40kg are mixed After even, cavity type structure is made, phase change layer coating is placed in cavity, is sutured with screw.
Embodiment 3
A kind of insulating brick, by heat preservation core layer, phase change layer and to be coated on the fireprotection layer of phase transformation layer surface be 5.8 in mass ratio: 1:0.8 is constituted, production method are as follows:
1, heat preservation core layer raw material compression moulding:
1) by granular polystyrene 15kg, slag powders 15kg, glass bead particle 10kg, thermal insulation mortar 10kg, paper sludge 25kg, medical stone 5kg are respectively dried to constant weight, after milling, are uniformly mixed, are cooled to room temperature under the conditions of temperature is 300 DEG C, standby With;
2) plant fiber 5kg is uniformly mixed with water 15kg, be added additive 5kg mix, it is spare, wherein additive by Following components forms by mass percentage: 10% water-reducing agent, 20% defoaming agent, 5% air entraining agent, 5% coagulating agent, surplus are hydrophobic Agent;
3) step 2) gains are added in step 1), high-speed stirred is uniform, is placed in mold compression moulding to get heat preservation Sandwich layer;
2, phase change layer coats heat preservation core layer surface forming:
It is 80mm that borax 25kg, carbon fiber 2kg, polyethylene glycol powder 5kg, silicon carbide 3kg, which are mixed with water to consistency, then It is uniformly coated on molding heat preservation core layer surface, is formed and is wrapped up with iron net, is first sintered 1h under the conditions of sintering temperature is 180 DEG C Afterwards, sinter molding then under the conditions of being warming up to 250 DEG C;
3, the suture of prefabricated fireprotection layer and phase change layer extexine:
Cement 40kg, aluminum oxide 9kg, phenolic group propane epoxy resin 12kg, cellulose ether 2kg, solvent 45kg are mixed After even, cavity type structure is made, phase change layer coating is placed in cavity, is sutured with screw.

Claims (8)

1. a kind of insulating brick, which is characterized in that the insulating brick is by heat preservation core layer, phase change layer and is coated on phase transformation layer surface Fireprotection layer is constituted, production method are as follows: by heat preservation core layer raw material compression moulding, is mixed to consistency with water by phase change layer is raw materials used For 70-80mm, then it is uniformly coated on molding heat preservation core layer surface, is formed and is wrapped up with iron net, and sinter molding, then will be prefabricated Fireprotection layer sutured with phase change layer;
The heat preservation core layer includes following raw material: 10-15 parts of granular polystyrene, 15-20 parts of slag powders, glass bead Grain 10-20 parts, 10-20 parts of thermal insulation mortar, 15-25 parts of paper sludge, 1-5 parts of medical stone, 2-5 parts of additive, plant fiber 5-8 Part.
2. insulating brick as described in claim 1, which is characterized in that the additive is by following components group by mass percentage At: 10-25% water-reducing agent, 10-20% defoaming agent, 5-10% air entraining agent, 5-15% coagulating agent, surplus are hydrophober.
3. insulating brick as described in claim 1, which is characterized in that the production method of the heat preservation core layer are as follows:
1) by granular polystyrene, slag powders, glass bead particle, thermal insulation mortar, paper sludge, medical stone is respectively dried to constant weight, After milling, it is uniformly mixed, is cooled to room temperature under the conditions of temperature is 200-300 DEG C, it is spare;
2) plant fiber is uniformly mixed with 2-3 times of its weight of water, additive is added and mixes, it is spare;
3) step 2) gains are added in step 1), high-speed stirred is uniform, is placed in mold compression moulding to get heat preservation core Layer.
4. insulating brick as described in claim 1, which is characterized in that the phase change layer includes following raw material: 25-35 parts Borax, 1-2 part carbon fiber, 5-8 parts of polyethylene glycol powders, 3-7 parts of silicon carbide.
5. insulating brick as described in claim 1, which is characterized in that the sinter molding, sintering temperature are 180-300 DEG C.
6. insulating brick as described in claim 1, which is characterized in that the fireprotection layer is by following raw material: cement 35-40 Part, 9-15 parts of aluminum oxide, 6-12 parts of phenolic group propane epoxy resin, 2-5 parts of cellulose ether, 40-45 parts of solvent.
7. insulating brick as described in claim 1, which is characterized in that the heat preservation core layer, phase change layer, fireprotection layer mass ratio be (4.5-5.8):1:(0.8-1.3)。
8. insulating brick as described in claim 1, which is characterized in that the suture is sutured using screw.
CN201610767574.0A 2016-08-30 2016-08-30 A kind of insulating brick Expired - Fee Related CN106401051B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610767574.0A CN106401051B (en) 2016-08-30 2016-08-30 A kind of insulating brick

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CN106401051A CN106401051A (en) 2017-02-15
CN106401051B true CN106401051B (en) 2019-05-21

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107098681A (en) * 2017-06-05 2017-08-29 安徽省亚欧陶瓷有限责任公司 It is a kind of can phase-change temperature control ceramic tile and preparation method thereof
CN108865075B (en) * 2018-06-21 2020-08-28 武夷学院 Phase-change energy-storage composite material and intelligent environment-friendly brick prepared from same
CN115074090B (en) * 2022-07-25 2024-06-18 深圳市中黄实业有限公司 High-temperature composite phase-change heat storage material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201378601Y (en) * 2009-03-20 2010-01-06 徐敖奎 Temperature control shell of lithium battery pack
CN101892722A (en) * 2010-07-21 2010-11-24 安徽程氏建材有限公司 Self-temperature-adjusting phase change energy storage energy-saving building block
CN101942879A (en) * 2010-08-18 2011-01-12 广州市建筑科学研究院有限公司 Phase change insulating brick and manufacturing method thereof
CN202401602U (en) * 2012-01-09 2012-08-29 陕西亿丰绿色建筑材料有限公司 Double-sandwich heat insulating plate capable of stopping heat bridge
CN202483017U (en) * 2012-03-29 2012-10-10 曾祥彬 Heat-insulation board
CN103541484A (en) * 2013-09-22 2014-01-29 沈阳建筑大学 Internal and external multiple-phase-change thermal insulation building block
CN105780961A (en) * 2014-12-21 2016-07-20 天津市诺唯兴和科技有限公司 Prefabricated house wall plate

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201378601Y (en) * 2009-03-20 2010-01-06 徐敖奎 Temperature control shell of lithium battery pack
CN101892722A (en) * 2010-07-21 2010-11-24 安徽程氏建材有限公司 Self-temperature-adjusting phase change energy storage energy-saving building block
CN101942879A (en) * 2010-08-18 2011-01-12 广州市建筑科学研究院有限公司 Phase change insulating brick and manufacturing method thereof
CN202401602U (en) * 2012-01-09 2012-08-29 陕西亿丰绿色建筑材料有限公司 Double-sandwich heat insulating plate capable of stopping heat bridge
CN202483017U (en) * 2012-03-29 2012-10-10 曾祥彬 Heat-insulation board
CN103541484A (en) * 2013-09-22 2014-01-29 沈阳建筑大学 Internal and external multiple-phase-change thermal insulation building block
CN105780961A (en) * 2014-12-21 2016-07-20 天津市诺唯兴和科技有限公司 Prefabricated house wall plate

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Granted publication date: 20190521