CN106400474A - High-extraction rate green walnut peel multifunctional finishing agent and preparation method thereof - Google Patents
High-extraction rate green walnut peel multifunctional finishing agent and preparation method thereof Download PDFInfo
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- CN106400474A CN106400474A CN201610838909.3A CN201610838909A CN106400474A CN 106400474 A CN106400474 A CN 106400474A CN 201610838909 A CN201610838909 A CN 201610838909A CN 106400474 A CN106400474 A CN 106400474A
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- finishing agent
- exocarpium juglandis
- juglandis immaturus
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- extraction
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- 238000000605 extraction Methods 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 235000009496 Juglans regia Nutrition 0.000 title abstract description 9
- 235000020234 walnut Nutrition 0.000 title abstract description 9
- 240000007049 Juglans regia Species 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 78
- 239000000706 filtrate Substances 0.000 claims abstract description 49
- 238000000855 fermentation Methods 0.000 claims abstract description 31
- 230000004151 fermentation Effects 0.000 claims abstract description 31
- 238000003756 stirring Methods 0.000 claims abstract description 31
- 238000001914 filtration Methods 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 238000004108 freeze drying Methods 0.000 claims abstract description 11
- 238000000746 purification Methods 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 102000004190 Enzymes Human genes 0.000 claims abstract description 7
- 108090000790 Enzymes Proteins 0.000 claims abstract description 7
- 239000003094 microcapsule Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 41
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 36
- 239000007788 liquid Substances 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 230000002255 enzymatic effect Effects 0.000 claims description 16
- 238000004140 cleaning Methods 0.000 claims description 11
- -1 flavanone compound Chemical class 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 238000000638 solvent extraction Methods 0.000 claims description 5
- 229930192627 Naphthoquinone Natural products 0.000 claims description 4
- ZONYXWQDUYMKFB-UHFFFAOYSA-N SJ000286395 Natural products O1C2=CC=CC=C2C(=O)CC1C1=CC=CC=C1 ZONYXWQDUYMKFB-UHFFFAOYSA-N 0.000 claims description 4
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical group O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 4
- 229930003949 flavanone Natural products 0.000 claims description 4
- 235000011981 flavanones Nutrition 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 150000002989 phenols Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 241000758789 Juglans Species 0.000 abstract description 10
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 238000004043 dyeing Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000009210 therapy by ultrasound Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 9
- 239000003125 aqueous solvent Substances 0.000 description 8
- 239000000975 dye Substances 0.000 description 8
- 239000003292 glue Substances 0.000 description 8
- 239000000284 extract Substances 0.000 description 7
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 5
- 235000017491 Bambusa tulda Nutrition 0.000 description 5
- 241001330002 Bambuseae Species 0.000 description 5
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 5
- 239000011425 bamboo Substances 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 235000014571 nuts Nutrition 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 210000000582 semen Anatomy 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001093501 Rutaceae Species 0.000 description 1
- 206010040007 Sense of oppression Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002207 flavanone derivatives Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/123—Polyaldehydes; Polyketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65112—Compounds containing aldehyde or ketone groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Plant Substances (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a preparation method for a high-extraction rate green walnut peel multifunctional finishing agent. The preparation method comprises the following steps: separating fresh green walnut peel in an early stage of maturity, washing, cutting, performing freeze drying so as to obtain pretreated green walnut peel, adding an enzyme solution, and performing low-temperature fermentation so as to obtain a fermented product of the green walnut peel; crushing the fermented product of the green walnut peel into paste, performing ultrasonic treatment with an extraction solvent twice, performing heating stirring extraction, filtering so as to obtain primary filtrate and secondary filtrate, adding a micro capsule wall material into the secondary filtrate, and stirring so as to obtain a slow-release agent; and combining the primary filtrate with the slow-release agent, adding a surfactant, stirring uniformly, and performing purification concentration to obtain the high-extraction rate green walnut peel multifunctional finishing agent. The preparation method provided by the invention is simple, convenient and efficient, and the finishing agent can be used as a dyeing finishing agent, an antibacterial finishing agent, an anti-ultraviolet finishing agent and a skin-friendly finishing agent.
Description
Technical field
The invention belongs to textile material technical field is and in particular to a kind of Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction
And preparation method thereof.
Background technology
Pericarpium Citri Reticulatae Viride be rutaceae orange and the plantation young fruit of mutation or immature fruit peel is dried.Juglans plants
In green Pericarpium Citri Reticulatae Viride in the fruit that comprises fall within one kind of Pericarpium Citri Reticulatae Viride.Abundant saccharide, protein, amino is contained in Exocarpium Juglandis Immaturus
Acid, inorganic salt and vitamin etc., also have phenols, flavanone, naphthoquinone class bioactive substance, therefore Pericarpium Citri Reticulatae Viride is normal since ancient times
It is used as Chinese crude drug, have functions that depressed liver-energy dispersing and QI regulating, removing food stagnancyization be stagnant, relieving distension and oppression.Therefore Exocarpium Juglandis Immaturus is applied to woven face
Also can give fabric new function in material, improve the added value of fabric.
Disclosed Exocarpium Juglandis Immaturus dye liquor prepared by Exocarpium Juglandis Immaturus of Chinese patent CN 102516804B and preparation method thereof with
And the method being dyeed with its fabric, Exocarpium Juglandis Immaturus is dried into black, then after pulverizing cleaning, dechlorinated softening hot water is clear
Wash the dust on surface, then be soaked in filtering and concentrating in alkali liquor and obtain Pericarpium Citri Reticulatae Viride filtrate, then adopt green vitriol and chlorination
Sodium, as medium, dyes to fabric through mordant dyeing color method, prepares the fabric being applied to baby.Chinese patent CN
A kind of antioxidant containing macadimia nut Pericarpium Citri Reticulatae Viride extract and preparation method and application disclosed in 104323395A, Australia is hard
Fruit takes Pericarpium Citri Reticulatae Viride after spontaneously drying, and Pericarpium Citri Reticulatae Viride is pulverized and forms powder, then carried with ethanol, acetone, isobutanol or ethyl acetate
Take, concentrate, volatilize completely to organic solvent and obtain macadimia nut Pericarpium Citri Reticulatae Viride extract, finally macadimia nut Pericarpium Citri Reticulatae Viride extract is dissolved
In above-mentioned organic solvent, standing obtains the antioxidant containing macadimia nut Pericarpium Citri Reticulatae Viride extract.From above-mentioned prior art, mesh
Mostly application in terms of weaving for the front Exocarpium Juglandis Immaturus is to go out pigment or functional component by organic solvent extraction, and Exocarpium Juglandis Immaturus is carried
Thing is taken as dyestuff or functional finishing agent, fabric to be dyeed or arrange, but the extraction maneuver of walnut peel extract
Simply, extraction ratio is limited, still has many resources to be wasted.Cortex walnut plant dye disclosed in Chinese patent CN 102172937B
Material dye bamboo chip method, by walnut husk bank up fermentation dried obtain auburn bulk dye for fabrics raw material, fabric is contaminated
Material raw material pulverizing becomes dye powder, adds penetrating agent, body lotion water and bamboo chip and is contaminated, and taking-up bamboo chip washing is dried and contaminated
The bamboo chip of color.Prepare dye powder using fermentation technique bamboo chip is dyeed, take full advantage of the composition inside Pericarpium Citri Reticulatae Viride, but
Hot fermentation can cause certain injury to the active component inside Pericarpium Citri Reticulatae Viride, therefore, researches and develops a kind of Exocarpium Juglandis Immaturus of high extraction
Extracting method seems very necessary.
Low temperature enzyme fermentation is combined by applicant of the present invention with solvent extraction techniques, and the Semen Juglandiss preparing high extraction are blue or green
Skin finishing agent, remains pigment in Exocarpium Juglandis Immaturus, antimicrobial component, antioxidant content and pro-skin composition etc. to greatest extent, makes
The finishing agent of preparation has several functions.
Content of the invention
The technical problem to be solved in the present invention is Exocarpium Juglandis Immaturus multifunction finishing agent and its system providing a kind of high extraction
Preparation Method, using cryodesiccated Exocarpium Juglandis Immaturus as raw material, after low temperature enzyme fermentation, through ethanol water and methanol solution after elder generation
Extraction obtains first-time filtrate and secondary filtrate, and secondary filtrate adds microcapsule to form slow releasing agent, and both are combined rear addition auxiliary agent
Form Exocarpium Juglandis Immaturus multifunction finishing agent.Preparation method of the present invention is simple, using the extracting method of multiple low-cost high-efficiency, makes
For obtaining high extraction multi-functional Exocarpium Juglandis Immaturus finishing agent, make full use of the effective ingredient of Exocarpium Juglandis Immaturus, reduce and waste.
For solving above-mentioned technical problem, the technical scheme is that：
A kind of Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction, the Exocarpium Juglandis Immaturus multifunction finishing agent of described high extraction
Include Pericarpium Citri Reticulatae Viride pigment, phenolic compound, flavanone compound, naphthoquinone compound and auxiliary agent, the core of described high extraction
Microencapsulated Slow composition is also included, described auxiliary agent is surfactant in Fructus Persicae Pericarpium Citri Reticulatae Viride multifunction finishing agent.
Preferred as technique scheme, the Exocarpium Juglandis Immaturus multifunction finishing agent of described high extraction is by enzymatic solution low temperature
Fermentation is prepared from reference to multiple solvent extraction techniques.
The present invention also provides a kind of preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction, walks including following
Suddenly：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms the Semen Juglandiss of pretreatment
Pericarpium Citri Reticulatae Viride, will add enzymatic solution, low temperature fermentation obtains the tunning of Exocarpium Juglandis Immaturus in the Pericarpium Citri Reticulatae Viride of pretreatment；
(2) tunning of the Exocarpium Juglandis Immaturus preparing step (1) is broken into mud, adds in an Extraction solvent, ultrasonic
After process, heated and stirred, filters to obtain first-time filtrate and a filtering residue；
(3) filtering residue prepared by step (2) is added in second extraction solvent, after supersound process, heated and stirred, filters
Obtain secondary filtrate and secondary filtering residue, microcapsule wall material, stirring will be added in secondary filtrate, and obtain slow releasing agent；
(4) slow releasing agent prepared by the first-time filtrate in step (2) and step (3) is merged, add surfactant, stirring
Uniformly, purification is concentrated to give the Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction.
Preferred as technique scheme, in described step (1), the length of the Exocarpium Juglandis Immaturus of pretreatment is less than 1cm.
Preferred as technique scheme, in described step (1), the mass fraction of enzymatic solution is 3-5%, and described enzyme is
Fermentation enzyme.
Preferred as technique scheme, in described step (1), the Pericarpium Citri Reticulatae Viride of pretreatment with the solid-liquid ratio of enzymatic solution is
1g:8-10ml.
Preferred as technique scheme, in described step (2), Extraction solvent is ethanol water, ethanol with
The volume ratio of water is 2-4:1.
Preferred as technique scheme, in described step (3), second extraction solvent is methanol.
Preferred as technique scheme, in described step (3), described microcapsule wall material is gelatin.
Preferred as technique scheme, in described step (4), described surfactant is paregal O.
Compared with prior art, the invention has the advantages that：
(1) the Exocarpium Juglandis Immaturus multifunction finishing agent of the high extraction of present invention preparation is using the core of first freeze-dried process
, as raw material, the freeze-dried process of fresh Exocarpium Juglandis Immaturus can be in the moisture in eliminating fresh Exocarpium Juglandis Immaturus for Fructus Persicae Pericarpium Citri Reticulatae Viride
Meanwhile, the effective ingredient in Exocarpium Juglandis Immaturus, the fermentation after being conducive to and extraction process are remained to greatest extent.
(2) the Exocarpium Juglandis Immaturus multifunction finishing agent of the high extraction of present invention preparation first adopts ferment treatment low temperature fermentation skill
Art, what ferment treatment can be the fastest is decomposed into less molecule by the cellulose macromolecule in Exocarpium Juglandis Immaturus and protein macromolecule,
Accelerate the speed decomposed in conjunction with low temperature fermentation technology, and do not affect pigment in Fructus Persicae skin Pericarpium Citri Reticulatae Viride, phenolic compound, flavanone
Compound, naphthoquinone compound, advantageously quickly effective in solvent extraction afterwards.
(3) the Exocarpium Juglandis Immaturus multifunction finishing agent of the high extraction of present invention preparation is using solution extractive technique twice, first
With ethanol-water extraction, again with methanol is extracted, in conjunction with ultrasonic wave added and heated and stirred technology, will be fast for the effective ingredient in Exocarpium Juglandis Immaturus
Speed efficiently extracts.
(4) additionally, also carrying out Microencapsulated Slow process to secondary filtrate, be conducive to finishing agent that fabric is effectively made for a long time
With, qucik-acting agent is combined with slow releasing agent, prepare multifunction long-acting finishing agent.
(5) preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction of present invention preparation is simply efficient, by core
Effective ingredient in Fructus Persicae Pericarpium Citri Reticulatae Viride fully extracts, and prepares the finishing agent of antibacterial, antioxidation and pro-skin, but also can be to weaving
Product carry out plant dyeing, and color fastness is high.
Specific embodiment
To describe the present invention, the illustrative examples of the here present invention and explanation below in conjunction with specific embodiment in detail
It is used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 8ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 3%, 40
At DEG C, low temperature fermentation 1d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g:30ml, adds volume ratio to be 2:1 ethanol
In aqueous solvent, after supersound process 30min, heated and stirred 30min at 60 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:10ml, a filtering residue is added in methanol, and supersound process 60min heats at 60 DEG C
Stirring 30min, filter mass fraction be 10% secondary filtrate, with solid-liquid ratio as 10ml:1g, bright by adding in secondary filtrate
Glue, stirs 20min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of the high extraction of 10-25%.
Embodiment 2：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 10ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 5%, 50
At DEG C, low temperature fermentation 2d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g:50ml, adds volume ratio to be 4:1 ethanol
In aqueous solvent, after supersound process 30min, heated and stirred 60min at 70 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:20ml, a filtering residue is added in methanol, and supersound process 60min heats at 70 DEG C
Stirring 60min, filter mass fraction be 15% secondary filtrate, with solid-liquid ratio as 20ml:1g, bright by adding in secondary filtrate
Glue, stirs 30min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of the high extraction of 10-25%.
Embodiment 3：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 9ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 4%, 45
At DEG C, low temperature fermentation 1-2d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g40ml, addition volume ratio is 2-4:1 second
In alcohol aqueous solvent, after supersound process 30min, heated and stirred 40min at 65 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:15ml, a filtering residue is added in methanol, and supersound process 60min heats at 70 DEG C
Stirring 40min, filter mass fraction be 12% secondary filtrate, with solid-liquid ratio as 15ml:1g, bright by adding in secondary filtrate
Glue, stirs 25min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of the high extraction of 10-25%.
Embodiment 4：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 10ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 3%, 40
At DEG C, low temperature fermentation 1.5d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g:35ml, adds volume ratio to be 2:1 ethanol
In aqueous solvent, after supersound process 30min, heated and stirred 60min at 60 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:10ml, a filtering residue is added in methanol, and supersound process 60min heats at 70 DEG C
Stirring 40min, filter mass fraction be 10% secondary filtrate, with solid-liquid ratio as 10ml:1g, bright by adding in secondary filtrate
Glue, stirs 20min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of 15% high extraction.
Embodiment 5：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 8.5ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 3.5%,
At 50 DEG C, low temperature fermentation 1d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g:45ml, adds volume ratio to be 3:1 ethanol
In aqueous solvent, after supersound process 30min, heated and stirred 35min at 70 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:20ml, a filtering residue is added in methanol, and supersound process 60min heats at 70 DEG C
Stirring 50min, filter mass fraction be 15% secondary filtrate, with solid-liquid ratio as 20ml:1g, bright by adding in secondary filtrate
Glue, stirs 30min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of 15% high extraction.
Embodiment 6：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 10ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 4%, 40
At DEG C, low temperature fermentation 2d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g:45ml, adds volume ratio to be 4:1 ethanol
In aqueous solvent, after supersound process 30min, heated and stirred 50min at 70 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:20ml, a filtering residue is added in methanol, and supersound process 60min heats at 60 DEG C
Stirring 45min, filter mass fraction be 15% secondary filtrate, with solid-liquid ratio as 20ml:1g, bright by adding in secondary filtrate
Glue, stirs 25min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of 20% high extraction.
Embodiment 7：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 10ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 4.5%,
At 45 DEG C, low temperature fermentation 2d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g:45ml, adds volume ratio to be 4:1 ethanol
In aqueous solvent, after supersound process 30min, heated and stirred 60min at 70 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:20ml, a filtering residue is added in methanol, and supersound process 60min heats at 65 DEG C
Stirring 50min, filter mass fraction be 15% secondary filtrate, with solid-liquid ratio as 10ml:1g, bright by adding in secondary filtrate
Glue, stirs 25min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of 20% high extraction.
Embodiment 8：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms length and is less than 1cm's
The Exocarpium Juglandis Immaturus of pretreatment, the fermentation enzymatic solution that the mass fraction adding 9.5ml in the Pericarpium Citri Reticulatae Viride of the pretreatment of 1g is 4.5%,
At 45 DEG C, low temperature fermentation 2d obtains the tunning of Exocarpium Juglandis Immaturus.
(2) tunning of Exocarpium Juglandis Immaturus is broken into mud, with solid-liquid ratio as 1g:45ml, adds volume ratio to be 4:1 ethanol
In aqueous solvent, after supersound process 30min, heated and stirred 55min at 65 DEG C, filters to obtain first-time filtrate and a filtering residue；
(3) with solid-liquid ratio as 1g:10ml, a filtering residue is added in methanol, and supersound process 60min heats at 70 DEG C
Stirring 55min, filter mass fraction be 15% secondary filtrate, with solid-liquid ratio as 10ml:1g, bright by adding in secondary filtrate
Glue, stirs 20min at 50 DEG C, obtains slow releasing agent.
(4) first-time filtrate and slow releasing agent are merged, add paregal O surfactant, stir, purification is concentrated to give
Mass fraction is the Exocarpium Juglandis Immaturus multifunction finishing agent of 22% high extraction.
After testing, embodiment 1-8 preparation the extraction ratio of Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction, antibiotic property,
The result of dyeability, non-oxidizability and pro-skin is as follows：
As seen from the above table, the extraction ratio of the Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction of present invention preparation is high, has
The performance of antibacterial antioxidation pro-skin, dye-uptake might as well.
Above-described embodiment only principle of the illustrative present invention and its effect, not for the restriction present invention.Any ripe
The personage knowing this technology all can carry out modifications and changes without prejudice under the spirit and the scope of the present invention to above-described embodiment.Cause
This, those of ordinary skill in the art is complete with institute under technological thought without departing from disclosed spirit such as
All equivalent modifications becoming or change, must be covered by the claim of the present invention.
Claims (10)
1. a kind of high extraction Exocarpium Juglandis Immaturus multifunction finishing agent it is characterised in that：The Exocarpium Juglandis Immaturus of described high extraction is many
Functional finishing agent includes Pericarpium Citri Reticulatae Viride pigment, phenolic compound, flavanone compound, naphthoquinone compound and auxiliary agent, described height
Microencapsulated Slow composition is also included, described auxiliary agent is surfactant in the Exocarpium Juglandis Immaturus multifunction finishing agent of extraction ratio.
2. a kind of high extraction according to claim 1 Exocarpium Juglandis Immaturus multifunction finishing agent it is characterised in that：Described height
The Exocarpium Juglandis Immaturus multifunction finishing agent of extraction ratio is prepared from reference to multiple solvent extraction techniques by enzymatic solution low temperature fermentation.
3. a kind of preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction is it is characterised in that comprise the following steps：
(1) Exocarpium Juglandis Immaturus fresh prematuration period is gone down, after cleaning, chopping, lyophilization forms the Exocarpium Juglandis Immaturus of pretreatment,
Enzymatic solution will be added, low temperature fermentation obtains the tunning of Exocarpium Juglandis Immaturus in the Pericarpium Citri Reticulatae Viride of pretreatment；
(2) tunning of the Exocarpium Juglandis Immaturus preparing step (1) is broken into mud, adds in an Extraction solvent, supersound process
Afterwards, heated and stirred, filters to obtain first-time filtrate and a filtering residue；
(3) filtering residue preparing step (2) adds in second extraction solvent, after supersound process, heated and stirred, filter two
Secondary filtrate and secondary filtering residue, will add microcapsule wall material, stirring, obtain slow releasing agent in secondary filtrate；
(4) slow releasing agent prepared by the first-time filtrate in step (2) and step (3) is merged, add surfactant, stirring is all
Even, purification is concentrated to give the Exocarpium Juglandis Immaturus multifunction finishing agent of high extraction.
4. the preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of a kind of high extraction according to claim 3, its feature
It is：In described step (1), the length of the Exocarpium Juglandis Immaturus of pretreatment is less than 1cm.
5. the preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of a kind of high extraction according to claim 3, its feature
It is：In described step (1), the mass fraction of enzymatic solution is 3-5%, and described enzyme is fermentation enzyme.
6. the preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of a kind of high extraction according to claim 3, its feature
It is：In described step (1), the Pericarpium Citri Reticulatae Viride of pretreatment and the solid-liquid ratio of enzymatic solution are 1g:8-10ml.
7. the preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of a kind of high extraction according to claim 3, its feature
It is：In described step (2), an Extraction solvent is ethanol water, and ethanol is 2-4 with the volume ratio of water:1.
8. the preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of a kind of high extraction according to claim 3, its feature
It is：In described step (3), second extraction solvent is methanol.
9. the preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of a kind of high extraction according to claim 3, its feature
It is：In described step (3), described microcapsule wall material is gelatin.
10. the preparation method of the Exocarpium Juglandis Immaturus multifunction finishing agent of a kind of high extraction according to claim 3, its feature
It is：In described step (4), described surfactant is paregal O.
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| CN108991026A (en) * | 2018-08-09 | 2018-12-14 | 兴义市天瑞核桃种植农民专业合作社 | A kind of walnut disease and pest control agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103461470A (en) * | 2013-09-03 | 2013-12-25 | 新疆农业科学院农产品贮藏加工研究所 | Walnut green seedcase extract compound preservative as well as preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103461470A (en) * | 2013-09-03 | 2013-12-25 | 新疆农业科学院农产品贮藏加工研究所 | Walnut green seedcase extract compound preservative as well as preparation method and application thereof |
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| 江天: ""微胶囊技术及其在新型功能织物开发中的应用"", 《产业用纺织品》 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108991026A (en) * | 2018-08-09 | 2018-12-14 | 兴义市天瑞核桃种植农民专业合作社 | A kind of walnut disease and pest control agent |
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Denomination of invention: A multifunctional finishing agent with high extraction rate for walnut green peel and its preparation method Granted publication date: 20190226 Pledgee: Chengxian Rural Credit Cooperative Union Pledgor: Gansu Jiuyuan agriculture and Forestry Technology Co.,Ltd. Registration number: Y2024980043834 |