CN106398164A - Environmental-friendly novel foamed plastic - Google Patents
Environmental-friendly novel foamed plastic Download PDFInfo
- Publication number
- CN106398164A CN106398164A CN201610810248.3A CN201610810248A CN106398164A CN 106398164 A CN106398164 A CN 106398164A CN 201610810248 A CN201610810248 A CN 201610810248A CN 106398164 A CN106398164 A CN 106398164A
- Authority
- CN
- China
- Prior art keywords
- agent
- stabilizer
- friendly novel
- parts
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses environmental-friendly novel foamed plastic. The environmental-friendly novel foamed plastic is prepared from the following materials: polyether polyol, vinyl tri(beta-methoxyethoxy)silane, fungacetin, polyester resin, broad bean protein powder, modified starch, talcum powder, titanium dioxide, linen fiber, polyarmide fiber, glass fiber, polyethylene wax, maleic anhydride, dibutyltin dilaurate, ethylene-ethyl acrylate copolymer, isopentane, potassium isocaprylate, polyvinyl acetate emulsion, dimethyl silicon oil, triethanolamine, an initiator, a crosslinking agent, a catalyst, a promoter, a plasticizer, a toughing agent,a foaming agent, a foaming regulator, a foam stabilizer, an antibacterial agent, a degradation agent, an antioxidant and a stabilizer. The environmental-friendly novel foamed plastic disclosed by the invention has the advantages that the foamed plastic can be completely degraded into carbon dioxide and water, the environment is almost not harmed; the decomposition speed is slow, so that the service life of the foamed plastic is prolonged; and the environmental-friendly novel foamed plastic has the characteristic of good sound-insulating effect.
Description
【Technical field】
The invention belongs to plastics technology of preparing and field of Environment Protection are and in particular to a kind of environment-friendly novel foam plasticss.
【Background technology】
With the progress of urbanization, urban population density is increasing, the raising of people's living standard, and private car is also increasingly
Many, due to increasing sharply so that traffic noise becomes the Main Noise Sources in city of motor vehicles number.Additionally, numerous businessmans
In order to attract client, music is play using loudspeaker, is also the important sources of noise.City noise increasing shadow
Ring our life.The pernicious stimulation of noise, has a strong impact on our sleep quality, and can lead to dizziness, headache, insomnia,
Dreaminess, hypomnesis, the neurasthenia symptom such as absent minded and nausea, tending to vomit, stomachache, abdominal distention, appetite are dull etc. to disappear
Change road symptom.
In order to reduce the impact to our daily life for the noise, between floors, the measure taken is mainly insulates against sound and inhales
Sound.Sound insulation is exactly to isolate sound source, prevents the noise that sound source produces to indoor propagation.Plant tree on both sides of the street, to both sides house
Sound insulation effect just can be played.The sandwich between floors Multilayer compact material porous material being separated and making,
Good defening effect can be played.For eliminating noise, conventional sound-absorbing material is mainly sound-absorbing porous material, such as glass cotton, ore deposit
Cotton, expanded perlite, perforated acoustic board etc..The sound absorbing capabilities of material be decided by it roughening, flexibility, the factor such as porous.
Foam plasticss are also aerated plastics, and the inside made for primary raw material with resin has the plastics of countless micropores, tool
There are light weight, thermal insulation, shockproof, corrosion resistant effect, be extensively used as packaging material and car and boat housing processed etc..
【Content of the invention】
The technical problem to be solved in the present invention is to provide a kind of environment-friendly novel foam plasticss, to solve existing foam plasticss sound insulation effect
Really poor, the problems such as degradability is weak.The environment-friendly novel foam plasticss of the present invention can degradable one-tenth carbon dioxide and water, almost to ring
Border does not produce harm, and the environment-friendly novel foam plasticss decomposition rate of the present invention is slow, substantially prolongs the environment-friendly novel of the present invention
The service life of foam plasticss；Additionally, the environment-friendly novel foam plasticss of the present invention also have the characteristics that soundproof effect is good.
In order to solve above technical problem, the present invention employs the following technical solutions：
A kind of environment-friendly novel foam plasticss, in units of weight portion, including following raw material：Polyether polyol 124-148 part, second
Thiazolinyl three ('beta '-methoxy ethyoxyl) silane 22-39 part, triacetin 18-28 part, polyester resin 16-28 part, degeneration
Starch 10-15 part, Pulvis Talci 4-8 part, titanium dioxide 2-5 part, flax fiber 4-10 part, Fypro 7-14 part, glass fibers
Dimension 3-8 part, Tissuemat E 8-13 part, maleic anhydride 2-3 part, dibutyl tin laurate 1-3 part, ethylene-ethylacrylate are common
Polymers 2-3 part, isopentane 1-4 part, different potassium zincate 2-4 part, polyvinyl acetate emulsion 3-6 part, dimethicone 2-5 part, three second
Hydramine 1-2 part, initiator 0.4-0.7 part, cross-linking agent 0.3-0.5 part, catalyst 0.1-0.3 part, accelerator 0.1-0.2 part, increasing
Mould agent 0.3-0.8 part, toughener 0.3-0.6 part, foaming agent 0.3-0.5 part, foaming control agent 0.1-0.2 part, foam stabilizer 0.2-
0.4 part, antibacterial 0.7-1.2 part, degradation agent 1.2-2.4 part, antioxidant 0.5-1 part, stabilizer 0.3-0.6 part；
Described modified starch, in units of weight portion, including following raw material：Tapioca 70-120 part, Glutaric Acid Dimethyl ester 9-
14 parts, percarbamide 7-12 part, epoxychloropropane 2-4 part, carbamide 1.2-3.2 part, sodium hydroxide 1-2 part, 2,5- dimethyl -2,
5- double (benzoyl peroxide)-hexane 0.3-0.7 part, platinum catalyst 0.1-0.2 part, organic tin stabilizer 0.2-0.3 part, polyoxy
Ethylene polyoxypropylene tetramethylolmethane ether 0.3-0.6 part, propyl trimethoxy silicane 0.3-0.5 part, boric acid 0.2-0.4 part；
Described initiator is dibenzoyl peroxide；
Described cross-linking agent is Methacrylamide；
Described catalyst is three（Dimethylamino-propyl）Hexahydrotriazine；
Described accelerator is colourless cobalt；
Described degradation agent in units of weight, including following raw material：Sorbitan fatty acid monoester 12-30 part, ammonium phosphate 10-
18 parts, ATMP 8-15 part, ethylenediaminetetraacetic acid 7-14 part, alkyl benzene sulphonate 6-10 part, dimethyl
Base Benzylphosphonium Bromide ammonium 2-6 part, ferrous sulfate 0.6-1.5 part, 2- hydroxyl -1,2,3- three sour 0.2-0.4 parts；
Described antioxidant is antioxidant 626；
Described stabilizer is light stabilizer HS-3203；
The preparation method of described environment-friendly novel foam plasticss, comprises the following steps：
S1：By polyether polyol, vinyl three ('beta '-methoxy ethyoxyl) silane, triacetin, polyester resin mixing,
It is 112-118 DEG C in temperature, rotating speed is to stir 8-12min, prepared mixture I under 300-400r/min；
S2：Under nitrogen protection, Pulvis Talci, titanium dioxide, flax fiber, polyamides are added to step 1 in the mixture I being obtained
Amine fiber, glass fibre, Tissuemat E, maleic anhydride, dibutyl tin laurate, ethylene-ethyl acrylate copolymer, isoamyl
Alkane, different potassium zincate, polyvinyl acetate emulsion, dimethicone, triethanolamine, initiator, cross-linking agent, catalyst, accelerator, increasing
Mould agent, toughener, foaming agent, foaming control agent, foam stabilizer, be 140-220W in microwave power, temperature is 92-95 DEG C, rotating speed
For stirring 1.5-2.5h, prepared mixture II under 200-300r/min；
S3：To step 2 be obtained mixture II in add Broad Bean Protein, modified starch, antibacterial, degradation agent, antioxidant,
Stabilizer, is 67-72 DEG C in temperature, and rotating speed is to stir 0.8-1 h, prepared mixture III under 100-200r/min；
The preparation method of described modified starch, comprises the following steps：
（A）Compound concentration is 12-22Be ', the para arrowroot slurry I for 3.2-3.6 for the pH value；
（B）The Glutaric Acid Dimethyl ester that concentration is 2%-6%, percarbamide, 2,5- diformazan is added in the para arrowroot slurry I of step A
Base -2,5- double (benzoyl peroxide)-hexane, platinum catalyst, then it is 48-54 DEG C in temperature, speed of agitator is 80-120r/
Carry out cross-linked graft reaction 2-3.2h, prepared slurry II under min；
（C）Add paste agent in the slurry II of step B, adjusting pH value is 9.3-9.6, is subsequently added into epoxychloropropane, urine
Element, propyl trimethoxy silicane, boric acid, are then 58-60 DEG C in temperature, and speed of agitator is to carry out crosslinking under 90-150r/min
Reaction 1-1.5h, prepared slurry III；
（D）Organic tin stabilizer will be added, regulation pH value is 8.5-8.7, is warming up to 75-78 DEG C, gelatinizing in the slurry III of step C
48-52min, gelatinizing is down to 32-34 DEG C after terminating, and adds polyoxyethylene polyoxypropylene tetramethylolmethane ether, is 70- in rotating speed
10-15min, prepared modified starch is stirred under 100r/min；
The preparation method of described degradation agent, comprises the following steps：
（a）By sorbitan fatty acid monoester, ammonium phosphate, ATMP, ethylenediaminetetraacetic acid, benzene sulfonamide
Acid, dodecyl dimethyl benzyl ammonium bromide mixing, are 120-180W in ultrasonic power, temperature is 90-96 DEG C, rotating speed is
2-2.5h, prepared mixture a is stirred under 200-300r/min；
（b）It is obtained in mixture a to step a and adds ferrous sulfate, 2- hydroxyl -1,2,3- three acid, are 150- in microwave power
200W, temperature is 80-85 DEG C, and rotating speed is to stir 1-1.5h, prepared degradation agent under 100-200r/min；
S4：The mixture III that step 3 is obtained sends into twin screw earnestly in air-cooled extruding granulator, makes at 138-146 DEG C
Grain, prepared environment-friendly novel foam plasticss.
Further, described plasticizer is citrate.
Further, described toughener is poly- propylene diene rubber.
Further, described foaming agent is azodicarbonamide.
Further, described foaming control agent is esters of acrylic acid foaming control agent.
Further, described foam stabilizer is silicone amide.
Further, described antibacterial is lithium carbonate.
The invention has the advantages that：
The environment-friendly novel foam plasticss of the present invention can degradable one-tenth carbon dioxide and water, almost harm is not produced to environment, and
The environment-friendly novel foam plasticss decomposition rate of the present invention is slow, just degradable after 136-138 days, substantially prolongs the present invention's
The service life of environment-friendly novel foam plasticss；Oise insulation factor is 23.56-25.89dB, and the environment-friendly novel foam plasticss of the present invention are described
Soundproof effect is good.
【Specific embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the protection of the present invention
Scope, but do not limit the scope of the invention.
In an embodiment, described environment-friendly novel foam plasticss, in units of weight portion, including following raw material：Polyether polyols
Alcohol 124-148 part, vinyl three ('beta '-methoxy ethyoxyl) silane 22-39 part, triacetin 18-28 part, polyester
Resin 16-28 part, Broad Bean Protein 12-16 part, modified starch 10-15 part, Pulvis Talci 4-8 part, titanium dioxide 2-5 part, Caulis et Folium Lini
Fiber 4-10 part, Fypro 7-14 part, glass fibre 3-8 part, Tissuemat E 8-13 part, maleic anhydride 2-3 part, two Laurels
Sour dibutyl tin 1-3 part, ethylene-ethyl acrylate copolymer 2-3 part, isopentane 1-4 part, different potassium zincate 2-4 part, poly-vinegar acid second
Alkene emulsion 3-6 part, dimethicone 2-5 part, triethanolamine 1-2 part, initiator 0.4-0.7 part, cross-linking agent 0.3-0.5 part, urge
Agent 0.1-0.3 part, accelerator 0.1-0.2 part, plasticizer 0.3-0.8 part, toughener 0.3-0.6 part, foaming agent 0.3-0.5
Part, foaming control agent 0.1-0.2 part, foam stabilizer 0.2-0.4 part, antibacterial 0.7-1.2 part, degradation agent 1.2-2.4 part, antioxidant
0.5-1 part, stabilizer 0.3-0.6 part；
Described modified starch, in units of weight portion, including following raw material：Tapioca 70-120 part, Glutaric Acid Dimethyl ester 9-
14 parts, percarbamide 7-12 part, epoxychloropropane 2-4 part, carbamide 1.2-3.2 part, sodium hydroxide 1-2 part, 2,5- dimethyl -2,
5- double (benzoyl peroxide)-hexane 0.3-0.7 part, platinum catalyst 0.1-0.2 part, organic tin stabilizer 0.2-0.3 part, polyoxy
Ethylene polyoxypropylene tetramethylolmethane ether 0.3-0.6 part, propyl trimethoxy silicane 0.3-0.5 part, boric acid 0.2-0.4 part；
Described initiator is dibenzoyl peroxide；
Described cross-linking agent is Methacrylamide；
Described catalyst is three（Dimethylamino-propyl）Hexahydrotriazine；
Described accelerator is colourless cobalt；
Described plasticizer is citrate；
Described toughener is poly- propylene diene rubber；
Described foaming agent is azodicarbonamide；
Described foaming control agent is esters of acrylic acid foaming control agent；
Described foam stabilizer is silicone amide；
Described antibacterial is lithium carbonate；
Described degradation agent in units of weight, including following raw material：Sorbitan fatty acid monoester 12-30 part, ammonium phosphate 10-
18 parts, ATMP 8-15 part, ethylenediaminetetraacetic acid 7-14 part, alkyl benzene sulphonate 6-10 part, dimethyl
Base Benzylphosphonium Bromide ammonium 2-6 part, ferrous sulfate 0.6-1.5 part, 2- hydroxyl -1,2,3- three sour 0.2-0.4 parts；
Described antioxidant is antioxidant 626；
Described stabilizer is light stabilizer HS-3203；
The preparation method of described environment-friendly novel foam plasticss, comprises the following steps：
S1：By polyether polyol, vinyl three ('beta '-methoxy ethyoxyl) silane, triacetin, polyester resin mixing,
It is 112-118 DEG C in temperature, rotating speed is to stir 8-12min, prepared mixture I under 300-400r/min；
S2：Under nitrogen protection, Pulvis Talci, titanium dioxide, flax fiber, polyamides are added to step 1 in the mixture I being obtained
Amine fiber, glass fibre, Tissuemat E, maleic anhydride, dibutyl tin laurate, ethylene-ethyl acrylate copolymer, isoamyl
Alkane, different potassium zincate, polyvinyl acetate emulsion, dimethicone, triethanolamine, initiator, cross-linking agent, catalyst, accelerator, increasing
Mould agent, toughener, foaming agent, foaming control agent, foam stabilizer, be 140-220W in microwave power, temperature is 92-95 DEG C, rotating speed
For stirring 1.5-2.5h, prepared mixture II under 200-300r/min；
S3：To step 2 be obtained mixture II in add Broad Bean Protein, modified starch, antibacterial, degradation agent, antioxidant,
Stabilizer, is 67-72 DEG C in temperature, and rotating speed is to stir 0.8-1 h, prepared mixture III under 100-200r/min；
The preparation method of described modified starch, comprises the following steps：
（A）Compound concentration is 12-22Be ', the para arrowroot slurry I for 3.2-3.6 for the pH value；
（B）The Glutaric Acid Dimethyl ester that concentration is 2%-6%, percarbamide, 2,5- diformazan is added in the para arrowroot slurry I of step A
Base -2,5- double (benzoyl peroxide)-hexane, platinum catalyst, then it is 48-54 DEG C in temperature, speed of agitator is 80-120r/
Carry out cross-linked graft reaction 2-3.2h, prepared slurry II under min；
（C）Add paste agent in the slurry II of step B, adjusting pH value is 9.3-9.6, is subsequently added into epoxychloropropane, urine
Element, propyl trimethoxy silicane, boric acid, are then 58-60 DEG C in temperature, and speed of agitator is to carry out crosslinking under 90-150r/min
Reaction 1-1.5h, prepared slurry III；
（D）Organic tin stabilizer will be added, regulation pH value is 8.5-8.7, is warming up to 75-78 DEG C, gelatinizing in the slurry III of step C
48-52min, gelatinizing is down to 32-34 DEG C after terminating, and adds polyoxyethylene polyoxypropylene tetramethylolmethane ether, is 70- in rotating speed
10-15min, prepared modified starch is stirred under 100r/min；
The preparation method of described degradation agent, comprises the following steps：
（a）By sorbitan fatty acid monoester, ammonium phosphate, ATMP, ethylenediaminetetraacetic acid, benzene sulfonamide
Acid, dodecyl dimethyl benzyl ammonium bromide mixing, are 120-180W in ultrasonic power, temperature is 90-96 DEG C, rotating speed is
2-2.5h, prepared mixture a is stirred under 200-300r/min；
（b）It is obtained in mixture a to step a and adds ferrous sulfate, 2- hydroxyl -1,2,3- three acid, are 150- in microwave power
200W, temperature is 80-85 DEG C, and rotating speed is to stir 1-1.5h, prepared degradation agent under 100-200r/min；
S4：The mixture III that step 3 is obtained sends into twin screw earnestly in air-cooled extruding granulator, makes at 138-146 DEG C
Grain, prepared environment-friendly novel foam plasticss.
Below by more specific embodiment, the present invention will be described.
Embodiment 1
A kind of environment-friendly novel foam plasticss, in units of weight portion, including following raw material：135 parts of polyether polyol, vinyl
30 parts of three ('beta '-methoxy ethyoxyl) silane, 24 parts of triacetin, 23 parts of polyester resin, 14 parts of Broad Bean Protein, change
13 parts of starch of property, 6 parts of Pulvis Talci, 3 parts of titanium dioxide, 7 parts of flax fiber, 10 parts of Fypro, 6 parts of glass fibre, poly- second
10 parts of alkene wax, 2 parts of maleic anhydride, 2 parts of dibutyl tin laurate, 2 parts of ethylene-ethyl acrylate copolymer, 3 parts of isopentane,
3 parts of different potassium zincate, 5 parts of polyvinyl acetate emulsion, 4 parts of dimethicone, 1 part of triethanolamine, 0.6 part of initiator, cross-linking agent 0.4
Part, 0.2 part of catalyst, 0.1 part of accelerator, 0.6 part of plasticizer, 0.5 part of toughener, 0.4 part of foaming agent, foaming control agent 0.1
Part, 0.3 part of foam stabilizer, 1 part of antibacterial, 1.8 parts of degradation agent, 0.7 part of antioxidant, 0.5 part of stabilizer；
Described modified starch, in units of weight portion, including following raw material：100 parts of tapioca, 12 parts of Glutaric Acid Dimethyl ester,
10 parts of percarbamide, 3 parts of epoxychloropropane, 2.2 parts of carbamide, 1.5 parts of sodium hydroxide, 2,5- dimethyl -2, the double (benzoyl of 5-
Peroxide) 0.5 part of-hexane, 0.1 part of platinum catalyst, 0.2 part of organic tin stabilizer, polyoxyethylene polyoxypropylene tetramethylolmethane ether 0.5
Part, 0.4 part of propyl trimethoxy silicane, 0.3 part of boric acid；
Described initiator is dibenzoyl peroxide；
Described cross-linking agent is Methacrylamide；
Described catalyst is three（Dimethylamino-propyl）Hexahydrotriazine；
Described accelerator is colourless cobalt；
Described plasticizer is citrate；
Described toughener is poly- propylene diene rubber；
Described foaming agent is azodicarbonamide；
Described foaming control agent is esters of acrylic acid foaming control agent；
Described foam stabilizer is silicone amide；
Described antibacterial is lithium carbonate；
Described degradation agent in units of weight, including following raw material：20 parts of sorbitan fatty acid monoester, 14 parts of ammonium phosphate,
12 parts of ATMP, 10 parts of ethylenediaminetetraacetic acid, 8 parts of alkyl benzene sulphonate, dodecyl dimethyl benzyl ammonium bromide 4
Part, 1 part of ferrous sulfate, 2- hydroxyl -1,2,3- three 0.3 part of acid；
Described antioxidant is antioxidant 626；
Described stabilizer is light stabilizer HS-3203；
The preparation method of described environment-friendly novel foam plasticss, comprises the following steps：
S1：By polyether polyol, vinyl three ('beta '-methoxy ethyoxyl) silane, triacetin, polyester resin mixing,
It is 115 DEG C in temperature, rotating speed is to stir 10min, prepared mixture I under 300r/min；
S2：Under nitrogen protection, Pulvis Talci, titanium dioxide, flax fiber, polyamides are added to step 1 in the mixture I being obtained
Amine fiber, glass fibre, Tissuemat E, maleic anhydride, dibutyl tin laurate, ethylene-ethyl acrylate copolymer, isoamyl
Alkane, different potassium zincate, polyvinyl acetate emulsion, dimethicone, triethanolamine, initiator, cross-linking agent, catalyst, accelerator, increasing
Mould agent, toughener, foaming agent, foaming control agent, foam stabilizer, be 180W in microwave power, temperature is 93 DEG C, rotating speed is 200r/
2h, prepared mixture II is stirred under min；
S3：To step 2 be obtained mixture II in add Broad Bean Protein, modified starch, antibacterial, degradation agent, antioxidant,
Stabilizer, is 70 DEG C in temperature, and rotating speed is to stir 0.9 h, prepared mixture III under 100r/min；
The preparation method of described modified starch, comprises the following steps：
（A）Compound concentration is 18Be ', the para arrowroot slurry I for 3.4 for the pH value；
（B）To in the para arrowroot slurry I of step A add concentration be 4% Glutaric Acid Dimethyl ester, percarbamide, 2,5- dimethyl-
2,5- double (benzoyl peroxide)-hexane, platinum catalysts, are then 50 DEG C in temperature, and speed of agitator is to be handed under 100r/min
Connection graft reaction 2.6h, prepared slurry II；
（C）To in the slurry II of step B add paste agent, adjust pH value be 9.5, be subsequently added into epoxychloropropane, carbamide, third
Base trimethoxy silane, boric acid, are then 59 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction 1.3h under 120r/min, system
Obtain slurry III；
（D）Organic tin stabilizer will be added, adjusting pH value is 8.6, is warming up to 76 DEG C, gelatinizing 50min in the slurry III of step C,
Gelatinizing is down to 33 DEG C after terminating, add polyoxyethylene polyoxypropylene tetramethylolmethane ether, stirs 12min under rotating speed is for 90r/min,
Prepared modified starch；
The preparation method of described degradation agent, comprises the following steps：
（a）By sorbitan fatty acid monoester, ammonium phosphate, ATMP, ethylenediaminetetraacetic acid, benzene sulfonamide
Acid, dodecyl dimethyl benzyl ammonium bromide mixing, are 150W in ultrasonic power, temperature is 93 DEG C, and rotating speed is 200r/min
Lower stirring 2.3h, prepared mixture a；
（b）It is obtained in mixture a to step a and adds ferrous sulfate, 2- hydroxyl -1,2,3- three acid, are 180W in microwave power,
Temperature is 82 DEG C, and rotating speed is to stir 1.3h, prepared degradation agent under 100r/min；
S4：The mixture III that step 3 is obtained sends into twin screw earnestly in air-cooled extruding granulator, pelletize at 142 DEG C, system
Obtain environment-friendly novel foam plasticss.
Embodiment 2
A kind of environment-friendly novel foam plasticss, in units of weight portion, including following raw material：124 parts of polyether polyol, vinyl
22 parts of three ('beta '-methoxy ethyoxyl) silane, 18 parts of triacetin, 16 parts of polyester resin, 12 parts of Broad Bean Protein, change
10 parts of starch of property, 4 parts of Pulvis Talci, 2 parts of titanium dioxide, 4 parts of flax fiber, 7 parts of Fypro, 3 parts of glass fibre, polyethylene
8 parts of wax, 2 parts of maleic anhydride, 1 part of dibutyl tin laurate, 2 parts of ethylene-ethyl acrylate copolymer, 1 part of isopentane, different zinc
2 parts of sour potassium, 3 parts of polyvinyl acetate emulsion, 2 parts of dimethicone, 1 part of triethanolamine, 0.4 part of initiator, 0.3 part of cross-linking agent,
0.1 part of catalyst, 0.1 part of accelerator, 0.3 part of plasticizer, 0.3 part of toughener, 0.3 part of foaming agent, 0.1 part of foaming control agent,
0.2 part of foam stabilizer, 0.7 part of antibacterial, 1.2 parts of degradation agent, 0.5 part of antioxidant, 0.3 part of stabilizer；
Described modified starch, in units of weight portion, including following raw material：70 parts of tapioca, 9 parts of Glutaric Acid Dimethyl ester, mistake
7 parts of phosphoamide, 2 parts of epoxychloropropane, 1.2 parts of carbamide, 1 part of sodium hydroxide, 2,5- dimethyl -2,5- double (benzoyl peroxide) -
0.3 part of hexane, 0.1 part of platinum catalyst, 0.2 part of organic tin stabilizer, 0.3 part of polyoxyethylene polyoxypropylene tetramethylolmethane ether, third
0.3 part of base trimethoxy silane, 0.2 part of boric acid；
Described initiator is dibenzoyl peroxide；
Described cross-linking agent is Methacrylamide；
Described catalyst is three（Dimethylamino-propyl）Hexahydrotriazine；
Described accelerator is colourless cobalt；
Described plasticizer is citrate；
Described toughener is poly- propylene diene rubber；
Described foaming agent is azodicarbonamide；
Described foaming control agent is esters of acrylic acid foaming control agent；
Described foam stabilizer is silicone amide；
Described antibacterial is lithium carbonate；
Described degradation agent in units of weight, including following raw material：12 parts of sorbitan fatty acid monoester, 10 parts of ammonium phosphate,
8 parts of ATMP, 7 parts of ethylenediaminetetraacetic acid, 6 parts of alkyl benzene sulphonate, dodecyl dimethyl benzyl ammonium bromide 2
Part, 0.6 part of ferrous sulfate, 2- hydroxyl -1,2,3- three 0.2 part of acid；
Described antioxidant is antioxidant 626；
Described stabilizer is light stabilizer HS-3203；
The preparation method of described environment-friendly novel foam plasticss, comprises the following steps：
S1：By polyether polyol, vinyl three ('beta '-methoxy ethyoxyl) silane, triacetin, polyester resin mixing,
It is 112 DEG C in temperature, rotating speed is to stir 12min, prepared mixture I under 300r/min；
S2：Under nitrogen protection, Pulvis Talci, titanium dioxide, flax fiber, polyamides are added to step 1 in the mixture I being obtained
Amine fiber, glass fibre, Tissuemat E, maleic anhydride, dibutyl tin laurate, ethylene-ethyl acrylate copolymer, isoamyl
Alkane, different potassium zincate, polyvinyl acetate emulsion, dimethicone, triethanolamine, initiator, cross-linking agent, catalyst, accelerator, increasing
Mould agent, toughener, foaming agent, foaming control agent, foam stabilizer, be 140W in microwave power, temperature is 92 DEG C, rotating speed is 200r/
2.5h, prepared mixture II is stirred under min；
S3：To step 2 be obtained mixture II in add Broad Bean Protein, modified starch, antibacterial, degradation agent, antioxidant,
Stabilizer, is 67 DEG C in temperature, and rotating speed is to stir 1 h, prepared mixture III under 100r/min；
The preparation method of described modified starch, comprises the following steps：
（A）Compound concentration is 12Be ', the para arrowroot slurry I for 3.2 for the pH value；
（B）To in the para arrowroot slurry I of step A add concentration be 2% Glutaric Acid Dimethyl ester, percarbamide, 2,5- dimethyl-
2,5- double (benzoyl peroxide)-hexane, platinum catalysts, are then 48 DEG C in temperature, and speed of agitator is to be handed under 80r/min
Connection graft reaction 3.2h, prepared slurry II；
（C）To in the slurry II of step B add paste agent, adjust pH value be 9.3, be subsequently added into epoxychloropropane, carbamide, third
Base trimethoxy silane, boric acid, are then 58 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction 1.5h under 90r/min, is obtained
Slurry III；
（D）Organic tin stabilizer will be added, adjusting pH value is 8.5, is warming up to 75 DEG C, gelatinizing 52min in the slurry III of step C,
Gelatinizing is down to 32 DEG C after terminating, add polyoxyethylene polyoxypropylene tetramethylolmethane ether, stirs 15min under rotating speed is for 70r/min,
Prepared modified starch；
The preparation method of described degradation agent, comprises the following steps：
（a）By sorbitan fatty acid monoester, ammonium phosphate, ATMP, ethylenediaminetetraacetic acid, benzene sulfonamide
Acid, dodecyl dimethyl benzyl ammonium bromide mixing, are 120W in ultrasonic power, temperature is 90 DEG C, and rotating speed is 200r/min
Lower stirring 2.5h, prepared mixture a；
（b）It is obtained in mixture a to step a and adds ferrous sulfate, 2- hydroxyl -1,2,3- three acid, are 150W in microwave power,
Temperature is 80 DEG C, and rotating speed is to stir 1.5h, prepared degradation agent under 100r/min；
S4：The mixture III that step 3 is obtained sends into twin screw earnestly in air-cooled extruding granulator, pelletize at 138 DEG C, system
Obtain environment-friendly novel foam plasticss.
Embodiment 3
A kind of environment-friendly novel foam plasticss, in units of weight portion, including following raw material：148 parts of polyether polyol, vinyl
39 parts of three ('beta '-methoxy ethyoxyl) silane, 28 parts of triacetin, 28 parts of polyester resin, 16 parts of Broad Bean Protein, change
15 parts of starch of property, 8 parts of Pulvis Talci, 5 parts of titanium dioxide, 10 parts of flax fiber, 14 parts of Fypro, 8 parts of glass fibre, poly- second
13 parts of alkene wax, 3 parts of maleic anhydride, 3 parts of dibutyl tin laurate, 3 parts of ethylene-ethyl acrylate copolymer, 4 parts of isopentane,
4 parts of different potassium zincate, 6 parts of polyvinyl acetate emulsion, 5 parts of dimethicone, 2 parts of triethanolamine, 0.7 part of initiator, cross-linking agent 0.5
Part, 0.3 part of catalyst, 0.2 part of accelerator, 0.8 part of plasticizer, 0.6 part of toughener, 0.5 part of foaming agent, foaming control agent 0.2
Part, 0.4 part of foam stabilizer, 1.2 parts of antibacterial, 2.4 parts of degradation agent, 1 part of antioxidant, 0.6 part of stabilizer；
Described modified starch, in units of weight portion, including following raw material：120 parts of tapioca, 14 parts of Glutaric Acid Dimethyl ester,
12 parts of percarbamide, 4 parts of epoxychloropropane, 3.2 parts of carbamide, 2 parts of sodium hydroxide, 2,5- dimethyl -2, double (the benzoyl mistake of 5-
Oxygen) 0.7 part of-hexane, 0.2 part of platinum catalyst, 0.3 part of organic tin stabilizer, polyoxyethylene polyoxypropylene tetramethylolmethane ether 0.6
Part, 0.5 part of propyl trimethoxy silicane, 0.4 part of boric acid；
Described initiator is dibenzoyl peroxide；
Described cross-linking agent is Methacrylamide；
Described catalyst is three（Dimethylamino-propyl）Hexahydrotriazine；
Described accelerator is colourless cobalt；
Described plasticizer is citrate；
Described toughener is poly- propylene diene rubber；
Described foaming agent is azodicarbonamide；
Described foaming control agent is esters of acrylic acid foaming control agent；
Described foam stabilizer is silicone amide；
Described antibacterial is lithium carbonate；
Described degradation agent in units of weight, including following raw material：30 parts of sorbitan fatty acid monoester, 18 parts of ammonium phosphate,
15 parts of ATMP, 14 parts of ethylenediaminetetraacetic acid, 10 parts of alkyl benzene sulphonate, dodecyl dimethyl benzyl ammonium bromide
6 parts, 1.5 parts of ferrous sulfate, 2- hydroxyl -1,2,3- three acid 0.4 part；
Described antioxidant is antioxidant 626；
Described stabilizer is light stabilizer HS-3203；
The preparation method of described environment-friendly novel foam plasticss, comprises the following steps：
S1：By polyether polyol, vinyl three ('beta '-methoxy ethyoxyl) silane, triacetin, polyester resin mixing,
It is 118 DEG C in temperature, rotating speed is to stir 8min, prepared mixture I under 400r/min；
S2：Under nitrogen protection, Pulvis Talci, titanium dioxide, flax fiber, polyamides are added to step 1 in the mixture I being obtained
Amine fiber, glass fibre, Tissuemat E, maleic anhydride, dibutyl tin laurate, ethylene-ethyl acrylate copolymer, isoamyl
Alkane, different potassium zincate, polyvinyl acetate emulsion, dimethicone, triethanolamine, initiator, cross-linking agent, catalyst, accelerator, increasing
Mould agent, toughener, foaming agent, foaming control agent, foam stabilizer, be 220W in microwave power, temperature is 95 DEG C, rotating speed is 300r/
2.5h, prepared mixture II is stirred under min；
S3：To step 2 be obtained mixture II in add Broad Bean Protein, modified starch, antibacterial, degradation agent, antioxidant,
Stabilizer, is 72 DEG C in temperature, and rotating speed is to stir 0.8 h, prepared mixture III under 200r/min；
The preparation method of described modified starch, comprises the following steps：
（A）Compound concentration is 22Be ', the para arrowroot slurry I for 3.6 for the pH value；
（B）To in the para arrowroot slurry I of step A add concentration be 6% Glutaric Acid Dimethyl ester, percarbamide, 2,5- dimethyl-
2,5- double (benzoyl peroxide)-hexane, platinum catalysts, are then 54 DEG C in temperature, and speed of agitator is to be handed under 120r/min
Connection graft reaction 2h, prepared slurry II；
（C）To in the slurry II of step B add paste agent, adjust pH value be 9.6, be subsequently added into epoxychloropropane, carbamide, third
Base trimethoxy silane, boric acid, are then 60 DEG C in temperature, and speed of agitator is to carry out cross-linking reaction 1h under 150r/min, is obtained
Slurry III；
（D）Organic tin stabilizer will be added, adjusting pH value is 8.7, is warming up to 78 DEG C, gelatinizing 48min in the slurry III of step C,
Gelatinizing is down to 34 DEG C after terminating, add polyoxyethylene polyoxypropylene tetramethylolmethane ether, stirs under rotating speed is for 100r/min
10min, prepared modified starch；
The preparation method of described degradation agent, comprises the following steps：
（a）By sorbitan fatty acid monoester, ammonium phosphate, ATMP, ethylenediaminetetraacetic acid, benzene sulfonamide
Acid, dodecyl dimethyl benzyl ammonium bromide mixing, are 180W in ultrasonic power, temperature is 96 DEG C, and rotating speed is 300r/min
Lower stirring 2h, prepared mixture a；
（b）It is obtained in mixture a to step a and adds ferrous sulfate, 2- hydroxyl -1,2,3- three acid, are 200W in microwave power,
Temperature is 85 DEG C, and rotating speed is to stir 1h, prepared degradation agent under 200r/min；
S4：The mixture III that step 3 is obtained sends into twin screw earnestly in air-cooled extruding granulator, makes at 138-146 DEG C
Grain, prepared environment-friendly novel foam plasticss.
Performance test is carried out to embodiment 1-3, experimental data is as shown in the table：
By upper table it is concluded that：The present invention can degradable one-tenth carbon dioxide and water, almost harm is not produced to environment, but
Decomposition rate of the present invention is slow, just degradable after 136-138 days, extends the service life of the present invention；Oise insulation factor is
23.56-25.89dB, illustrate that the environment-friendly novel foam plasticss soundproof effect of the present invention is good.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations, the affiliated technology neck for the present invention
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the present invention is determined all should be considered as belonging to by the claims submitted to.
Claims (7)
1. a kind of environment-friendly novel foam plasticss are it is characterised in that in units of weight portion, including following raw material：Polyether polyol
124-148 part, vinyl three ('beta '-methoxy ethyoxyl) silane 22-39 part, triacetin 18-28 part, polyester resin
16-28 part, Broad Bean Protein 12-16 part, modified starch 10-15 part, Pulvis Talci 4-8 part, titanium dioxide 2-5 part, flax fiber
4-10 part, Fypro 7-14 part, glass fibre 3-8 part, Tissuemat E 8-13 part, maleic anhydride 2-3 part, tin dilaurate two
Butyl tin 1-3 part, ethylene-ethyl acrylate copolymer 2-3 part, isopentane 1-4 part, different potassium zincate 2-4 part, poly vinyl acetate emulsion
Liquid 3-6 part, dimethicone 2-5 part, triethanolamine 1-2 part, initiator 0.4-0.7 part, cross-linking agent 0.3-0.5 part, catalyst
0.1-0.3 part, accelerator 0.1-0.2 part, plasticizer 0.3-0.8 part, toughener 0.3-0.6 part, foaming agent 0.3-0.5 part, send out
Bubble regulator 0.1-0.2 part, foam stabilizer 0.2-0.4 part, antibacterial 0.7-1.2 part, degradation agent 1.2-2.4 part, antioxidant 0.5-1
Part, stabilizer 0.3-0.6 part；
Described modified starch, in units of weight portion, including following raw material：Tapioca 70-120 part, Glutaric Acid Dimethyl ester 9-
14 parts, percarbamide 7-12 part, epoxychloropropane 2-4 part, carbamide 1.2-3.2 part, sodium hydroxide 1-2 part, 2,5- dimethyl -2,
5- double (benzoyl peroxide)-hexane 0.3-0.7 part, platinum catalyst 0.1-0.2 part, organic tin stabilizer 0.2-0.3 part, polyoxy
Ethylene polyoxypropylene tetramethylolmethane ether 0.3-0.6 part, propyl trimethoxy silicane 0.3-0.5 part, boric acid 0.2-0.4 part；
Described initiator is dibenzoyl peroxide；
Described cross-linking agent is Methacrylamide；
Described catalyst is three（Dimethylamino-propyl）Hexahydrotriazine；
Described accelerator is colourless cobalt；
Described degradation agent in units of weight, including following raw material：Sorbitan fatty acid monoester 12-30 part, ammonium phosphate 10-
18 parts, ATMP 8-15 part, ethylenediaminetetraacetic acid 7-14 part, alkyl benzene sulphonate 6-10 part, dimethyl
Base Benzylphosphonium Bromide ammonium 2-6 part, ferrous sulfate 0.6-1.5 part, 2- hydroxyl -1,2,3- three sour 0.2-0.4 parts；
Described antioxidant is antioxidant 626；
Described stabilizer is light stabilizer HS-3203；
The preparation method of described environment-friendly novel foam plasticss, comprises the following steps：
S1：By polyether polyol, vinyl three ('beta '-methoxy ethyoxyl) silane, triacetin, polyester resin mixing,
It is 112-118 DEG C in temperature, rotating speed is to stir 8-12min, prepared mixture I under 300-400r/min；
S2：Under nitrogen protection, Pulvis Talci, titanium dioxide, flax fiber, polyamides are added to step 1 in the mixture I being obtained
Amine fiber, glass fibre, Tissuemat E, maleic anhydride, dibutyl tin laurate, ethylene-ethyl acrylate copolymer, isoamyl
Alkane, different potassium zincate, polyvinyl acetate emulsion, dimethicone, triethanolamine, initiator, cross-linking agent, catalyst, accelerator, increasing
Mould agent, toughener, foaming agent, foaming control agent, foam stabilizer, be 140-220W in microwave power, temperature is 92-95 DEG C, rotating speed
For stirring 1.5-2.5h, prepared mixture II under 200-300r/min；
S3：To step 2 be obtained mixture II in add Broad Bean Protein, modified starch, antibacterial, degradation agent, antioxidant,
Stabilizer, is 67-72 DEG C in temperature, and rotating speed is to stir 0.8-1 h, prepared mixture III under 100-200r/min；
The preparation method of described modified starch, comprises the following steps：
（A）Compound concentration is 12-22Be ', the para arrowroot slurry I for 3.2-3.6 for the pH value；
（B）The Glutaric Acid Dimethyl ester that concentration is 2%-6%, percarbamide, 2,5- diformazan is added in the para arrowroot slurry I of step A
Base -2,5- double (benzoyl peroxide)-hexane, platinum catalyst, then it is 48-54 DEG C in temperature, speed of agitator is 80-120r/
Carry out cross-linked graft reaction 2-3.2h, prepared slurry II under min；
（C）Add paste agent in the slurry II of step B, adjusting pH value is 9.3-9.6, is subsequently added into epoxychloropropane, urine
Element, propyl trimethoxy silicane, boric acid, are then 58-60 DEG C in temperature, and speed of agitator is to carry out crosslinking under 90-150r/min
Reaction 1-1.5h, prepared slurry III；
（D）Organic tin stabilizer will be added, regulation pH value is 8.5-8.7, is warming up to 75-78 DEG C, gelatinizing in the slurry III of step C
48-52min, gelatinizing is down to 32-34 DEG C after terminating, and adds polyoxyethylene polyoxypropylene tetramethylolmethane ether, is 70- in rotating speed
10-15min, prepared modified starch is stirred under 100r/min；
The preparation method of described degradation agent, comprises the following steps：
（a）By sorbitan fatty acid monoester, ammonium phosphate, ATMP, ethylenediaminetetraacetic acid, benzene sulfonamide
Acid, dodecyl dimethyl benzyl ammonium bromide mixing, are 120-180W in ultrasonic power, temperature is 90-96 DEG C, rotating speed is
2-2.5h, prepared mixture a is stirred under 200-300r/min；
（b）It is obtained in mixture a to step a and adds ferrous sulfate, 2- hydroxyl -1,2,3- three acid, are 150- in microwave power
200W, temperature is 80-85 DEG C, and rotating speed is to stir 1-1.5h, prepared degradation agent under 100-200r/min；
S4：The mixture III that step 3 is obtained sends into twin screw earnestly in air-cooled extruding granulator, makes at 138-146 DEG C
Grain, prepared environment-friendly novel foam plasticss.
2. environment-friendly novel foam plasticss according to claim 1 are it is characterised in that described plasticizer is citrate.
3. environment-friendly novel foam plasticss according to claim 1 are it is characterised in that described toughener is poly- allene rubber
Glue.
4. environment-friendly novel foam plasticss according to claim 1 are it is characterised in that described foaming agent is azo two formyl
Amine.
5. environment-friendly novel foam plasticss according to claim 1 are it is characterised in that described foaming control agent is acrylate
Class foaming control agent.
6. environment-friendly novel foam plasticss according to claim 1 are it is characterised in that described foam stabilizer is silicone amide.
7. environment-friendly novel foam plasticss according to claim 1 are it is characterised in that described antibacterial is lithium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610810248.3A CN106398164A (en) | 2016-09-08 | 2016-09-08 | Environmental-friendly novel foamed plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610810248.3A CN106398164A (en) | 2016-09-08 | 2016-09-08 | Environmental-friendly novel foamed plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106398164A true CN106398164A (en) | 2017-02-15 |
Family
ID=57998703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610810248.3A Pending CN106398164A (en) | 2016-09-08 | 2016-09-08 | Environmental-friendly novel foamed plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106398164A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556739A (en) * | 2017-09-29 | 2018-01-09 | 镇江中广告制品有限公司 | A kind of degradable foamed billboard of safe environment protection type |
| CN107652655A (en) * | 2017-09-29 | 2018-02-02 | 句容市武杭传动机械制造有限公司 | One kind is packed for vapor-permeable type sound-proof foam plastics and its production method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102676098A (en) * | 2012-06-11 | 2012-09-19 | 合肥工业大学 | Modified-starch-based wood adhesive and preparation method thereof |
| CN103554897A (en) * | 2013-10-25 | 2014-02-05 | 马鞍山科信咨询有限公司 | Hard polyurethane foaming plastic |
| CN104004230A (en) * | 2014-06-10 | 2014-08-27 | 杨云 | Degradable mulching film and preparation method thereof |
| CN104212426A (en) * | 2013-06-05 | 2014-12-17 | 中国石油天然气股份有限公司 | Wrapped profile control degradation agent |
-
2016
- 2016-09-08 CN CN201610810248.3A patent/CN106398164A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102676098A (en) * | 2012-06-11 | 2012-09-19 | 合肥工业大学 | Modified-starch-based wood adhesive and preparation method thereof |
| CN104212426A (en) * | 2013-06-05 | 2014-12-17 | 中国石油天然气股份有限公司 | Wrapped profile control degradation agent |
| CN103554897A (en) * | 2013-10-25 | 2014-02-05 | 马鞍山科信咨询有限公司 | Hard polyurethane foaming plastic |
| CN104004230A (en) * | 2014-06-10 | 2014-08-27 | 杨云 | Degradable mulching film and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556739A (en) * | 2017-09-29 | 2018-01-09 | 镇江中广告制品有限公司 | A kind of degradable foamed billboard of safe environment protection type |
| CN107652655A (en) * | 2017-09-29 | 2018-02-02 | 句容市武杭传动机械制造有限公司 | One kind is packed for vapor-permeable type sound-proof foam plastics and its production method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106398167A (en) | Novel foamed plastic | |
| CN106366614A (en) | Novel environment-friendly foam plastic | |
| CN106317840A (en) | Novel high-performance foamed plastic | |
| CN106398164A (en) | Environmental-friendly novel foamed plastic | |
| CN106398166A (en) | High performance foam plastic | |
| CN106433081A (en) | Environment-friendly foamed plastic with high performances | |
| CN106398165A (en) | Environment-friendly foamed plastic | |
| CN107129647A (en) | A kind of fire-retardant degradable environmental protection macromolecule foamed material and preparation method thereof | |
| CN107298776A (en) | A kind of environment-friendly rubber soundproof construction composition and preparation method thereof | |
| CN106497112A (en) | A kind of preparation method of anti-corrosion moisture resistance Plant fiber's acoustic board | |
| CN108410021A (en) | A kind of cable insulation material and preparation method thereof | |
| CN111606679B (en) | Paper-surface gypsum board and preparation method thereof | |
| CN112812471A (en) | Environment-friendly wear-resistant bamboo-wood fiber wallboard and preparation method thereof | |
| CN110015860A (en) | A kind of water-fast lightweight Thistle board and preparation method thereof | |
| CN109956700B (en) | Water-resistant paper-surface gypsum board | |
| CN107892835A (en) | A kind of preparation method of powder of lacquer putty for use on | |
| CN111100469A (en) | High-strength polyester fiber acoustic board and preparation method thereof | |
| CN108558307A (en) | A kind of FA@CNTs enhanced foaming cement heat preserving plates | |
| CN110436854A (en) | A kind of waterproof fireproofing light heat insulation material and preparation method thereof | |
| CN108285572A (en) | A kind of bactericidal, fire retardant suppression moisture-proof asepsis environment-protecting acoustic material of cigarette and preparation method thereof | |
| CN115180889B (en) | Flame-retardant heat-insulating noise-reducing decorative plate and preparation method thereof | |
| CN108586785A (en) | A kind of novel rubber floor and preparation method thereof | |
| CN115466455B (en) | Rubber and plastic heat-insulation plate with good sound insulation effect and preparation method thereof | |
| CN107033393A (en) | A kind of preparation method of the fibrous material with low frequency absorption sound insulation function | |
| CN106380227A (en) | Novel hollow brick |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170215 |
|
| RJ01 | Rejection of invention patent application after publication |