CN107556739A - A kind of degradable foamed billboard of safe environment protection type - Google Patents
A kind of degradable foamed billboard of safe environment protection type Download PDFInfo
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- CN107556739A CN107556739A CN201710903278.3A CN201710903278A CN107556739A CN 107556739 A CN107556739 A CN 107556739A CN 201710903278 A CN201710903278 A CN 201710903278A CN 107556739 A CN107556739 A CN 107556739A
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- billboard
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- safe environment
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Abstract
A kind of degradable foamed billboard of safe environment protection type, belongs to billboard technical field.Each component including following parts by weight is prepared：PPG, polyester resin, ABS resin, sepiolite powder, different potassium zincate, the ethyl acrylate copolymers of ethene one, polyisocyanates, maleic anhydride, Tissuemat E, kaolin, initiator, dibutyl tin laurate, precipitated calcium carbonate, foaming agent, plant amylum, natural gum, composite flame-retardant agent, degradation agent, catalyst, glass fibre, abaca fibre, plasticizer, antiseptic.Billboard produced by the present invention has many excellent performances：It is light, intensity is high, absorbable impact loads property is good, biodegradable, the present invention is a kind of green product of safety and environmental protection nonhazardous, is had wide market using various plants starch, string.
Description
Technical field
The present invention relates to a kind of degradable foamed billboard of safe environment protection type, belong to billboard technical field.
Background technology
Foamed plastics is a kind of high polymer material formed by a large amount of gas micropore dispersions in solid plastic, has matter
The characteristics such as gently, heat-insulated, sound-absorbing, damping, and dielectric properties are better than matrix resin, have many uses；Almost various plastics can be made
Foamed plastics, foaming turn into a key areas in plastic processing.
Foamed plastics is integrally covered with countless interconnect or mutually disconnected micropore and the modeling that makes apparent density substantially reduce
Material, there is light, adiabatic, sound-absorbing, shockproof, moisture resistance, corrosion-resistant.Foamed plastics is using plastics as solvent and contained
The polymeric material of a large amount of bubbles, therefore could also say that the composite plastic using gas as filler.
There is high hardness, matter weight in billboard in the market, anti-seismic performance is short of, anticorrosion effect is bad and can not drop
It is the defects of solution, environmentally safe serious threat to be present.
The content of the invention
The purpose of the present invention is to be directed to above-mentioned the deficiencies in the prior art, there is provided a kind of degradable foamed advertisement of safe environment protection type
Plate.
Technical scheme is as follows：A kind of degradable foamed billboard of safe environment protection type, it is characterized in that, including it is following
The each component of parts by weight is prepared：PPG 60-120 parts, polyester resin 40-80 parts, ABS resin 50-70 parts, Hai Pao
Stone flour 20-45 parts, different potassium zincate 5-15 parts, the ethyl acrylate copolymers 8-13 parts of ethene one, polyisocyanates 5-15 parts, maleic acid
It is acid anhydride 10-15 parts, Tissuemat E 1-5 parts, kaolin 10-15 parts, initiator 15-30 parts, dibutyl tin laurate 2-8 parts, light
Matter calcium carbonate 5-12 parts, foaming agent 20-35 parts, plant amylum 15-25 parts, gummy 10-15 parts, composite flame-retardant agent 5-8 parts, degraded
Agent 1-6 parts, catalyst 2-5 parts, glass fibre 5-13 parts, abaca fibre 2-8 parts, plasticizer 1-3 parts, antiseptic 1-3 parts.
The composite flame-retardant agent is WinGel.
The plant amylum is tapioca, cornstarch, farina, wheaten starch mixture.
The initiator is dibenzoyl peroxide.
The degradation agent include ATMP, ethylenediamine tetra-acetic acid, alkyl benzene sulphonate, dimethyl,
Base Benzylphosphonium Bromide ammonium is prepared.
PPG（Abbreviation polyethers）It is by initiator（Compound containing active hydrogen group）With oxirane（EO）, ring
Ethylene Oxide（PO）, epoxy butane（BO）Deng being made in the presence of a catalyst through sudden reaction.Polyethers yield the maximum is with glycerine
（Glycerine）Make initiator and epoxides（Usually PO and EO is used in combination）, by the feed way for changing PO and EO（Mixing adds
Or separately add）, dosage ratio, the charging condition such as order, produce various general PPGs.
ABS resin is one of five big synthetic resin, its impact resistance, heat resistance, lower temperature resistance, chemical proofing and electricity
Gas function admirable, also have the characteristics that easy processing, product size are stable, lustrous surface is good, easy application, coloring can be with
Carry out the secondary operation such as surface metallization, plating, welding, hot pressing and bonding, be widely used in machinery, automobile, electronic apparatus,
The industrial circles such as instrument and meter, weaving and building, it is a kind of extremely wide thermoplastic engineering plastic of purposes.Acrylonitrile-butadiene-benzene
Ethylene copolymer is by the terpolymer of acrylonitrile, butadiene and styrene composition.
Billboard produced by the present invention has many excellent performances：It is light, intensity is high, absorbable impact loads property
Good, biodegradable, the present invention uses various plants starch, string, is a kind of green product of safety and environmental protection nonhazardous,
With wide market.
Embodiment
Embodiment 1
A kind of degradable foamed billboard of safe environment protection type, including each component of following parts by weight are prepared：PPG
60-120 parts, polyester resin 40-80 parts, ABS resin 50-70 parts, sepiolite powder 20-45 parts, different potassium zincate 5-15 parts, ethene one
Ethyl acrylate copolymers 8-13 parts, polyisocyanates 5-15 parts, maleic anhydride 10-15 parts, Tissuemat E 1-5 parts, kaolin 10-
15 parts, initiator 15-30 parts, dibutyl tin laurate 2-8 parts, precipitated calcium carbonate 5-12 parts, foaming agent 20-35 parts, plant
Starch 15-25 parts, gummy 10-15 parts, composite flame-retardant agent 5-8 parts, degradation agent 1-6 parts, catalyst 2-5 parts, glass fibre 5-13
Part, abaca fibre 2-8 parts, plasticizer 1-3 parts, antiseptic 1-3 parts.
Composite flame-retardant agent is WinGel, and plant amylum is tapioca, cornstarch, Ma Ling
Sweet potato starch, wheaten starch mixture, initiator are dibenzoyl peroxide；Degradation agent includes ATMP, second two
Amine tetraacethyl, alkyl benzene sulphonate, dimethyl, base Benzylphosphonium Bromide ammonium are prepared.
Embodiment 2
A kind of degradable foamed billboard of safe environment protection type, including each component of following parts by weight are prepared：PPG
120 parts, 80 parts of polyester resin, 50 parts of ABS resin, sepiolite powder 20-45 parts, different potassium zincate 5-15 parts, the acrylic acid second of ethene one
3 parts of ester copolymer-1, polyisocyanates 5-15 parts, 15 parts of maleic anhydride, 5 parts of Tissuemat E, 15 parts of kaolin, 30 parts of initiator, two
8 parts of dibutyl tin laurate, 12 parts of precipitated calcium carbonate, 35 parts of foaming agent, 15 parts of plant amylum, gummy 15 parts, composite flame-retardant agent 8
Part, 6 parts of degradation agent, 5 parts of catalyst, 13 parts of glass fibre, 8 parts of abaca fibre, 3 parts of plasticizer, 3 parts of antiseptic.
Composite flame-retardant agent is WinGel, and plant amylum is tapioca, cornstarch, Ma Ling
Sweet potato starch, wheaten starch mixture, initiator are dibenzoyl peroxide；Degradation agent includes ATMP, second two
Amine tetraacethyl, alkyl benzene sulphonate, dimethyl, base Benzylphosphonium Bromide ammonium are prepared.
Embodiment 3
A kind of degradable foamed billboard of safe environment protection type, including each component of following parts by weight are prepared：PPG
60 parts, 40 parts of polyester resin, 50 parts of ABS resin, 20 parts of sepiolite powder, 5 parts of different potassium zincate, the ethyl acrylate copolymers 8 of ethene one
Part, 5 parts of polyisocyanates, maleic anhydride 10- parts, 1 part of Tissuemat E, 10 parts of kaolin, 15 parts of initiator, the fourth of tin dilaurate two
2 parts of base tin, 5 parts of precipitated calcium carbonate, 20 parts of foaming agent, 15 parts of plant amylum, 10 parts of natural gum, 5 parts of composite flame-retardant agent, degradation agent 1
Part, 2 parts of catalyst, 5 parts of glass fibre, 2 parts of abaca fibre, 1 part of plasticizer, 1 part of antiseptic.
Composite flame-retardant agent is WinGel, and plant amylum is tapioca, cornstarch, Ma Ling
Sweet potato starch, wheaten starch mixture, initiator are dibenzoyl peroxide；Degradation agent includes ATMP, second two
Amine tetraacethyl, alkyl benzene sulphonate, dimethyl, base Benzylphosphonium Bromide ammonium are prepared.
Claims (5)
1. a kind of degradable foamed billboard of safe environment protection type, it is characterized in that, including each component of following parts by weight is prepared：
PPG 60-120 parts, polyester resin 40-80 parts, ABS resin 50-70 parts, sepiolite powder 20-45 parts, different potassium zincate 5-
15 parts, the ethyl acrylate copolymers 8-13 parts of ethene one, polyisocyanates 5-15 parts, maleic anhydride 10-15 parts, Tissuemat E 1-5
Part, kaolin 10-15 parts, initiator 15-30 parts, dibutyl tin laurate 2-8 parts, precipitated calcium carbonate 5-12 parts, foaming agent
20-35 parts, plant amylum 15-25 parts, gummy 10-15 parts, composite flame-retardant agent 5-8 parts, degradation agent 1-6 parts, catalyst 2-5 parts,
Glass fibre 5-13 parts, abaca fibre 2-8 parts, plasticizer 1-3 parts, antiseptic 1-3 parts.
2. the degradable foamed billboard of a kind of safe environment protection type according to claim 1, it is characterized in that, the composite flame-proof
Agent is WinGel.
3. the degradable foamed billboard of a kind of safe environment protection type according to claim 1, it is characterized in that, the plant amylum
For tapioca, cornstarch, farina, wheaten starch mixture.
4. the degradable foamed billboard of a kind of safe environment protection type according to claim 1, it is characterized in that, the initiator is
Dibenzoyl peroxide.
5. the degradable foamed billboard of a kind of safe environment protection type according to claim 1, it is characterized in that, the degradation agent bag
ATMP, ethylenediamine tetra-acetic acid, alkyl benzene sulphonate, dimethyl, base Benzylphosphonium Bromide ammonium is included to be prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710903278.3A CN107556739A (en) | 2017-09-29 | 2017-09-29 | A kind of degradable foamed billboard of safe environment protection type |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710903278.3A CN107556739A (en) | 2017-09-29 | 2017-09-29 | A kind of degradable foamed billboard of safe environment protection type |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107556739A true CN107556739A (en) | 2018-01-09 |
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ID=60984317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710903278.3A Pending CN107556739A (en) | 2017-09-29 | 2017-09-29 | A kind of degradable foamed billboard of safe environment protection type |
Country Status (1)
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317840A (en) * | 2016-09-08 | 2017-01-11 | 广西南宁桂尔创环保科技有限公司 | Novel high-performance foamed plastic |
| CN106366614A (en) * | 2016-09-08 | 2017-02-01 | 广西南宁桂尔创环保科技有限公司 | Novel environment-friendly foam plastic |
| CN106398164A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | Environmental-friendly novel foamed plastic |
| CN106398165A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | Environment-friendly foamed plastic |
| CN106398166A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | High performance foam plastic |
| CN106398167A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | Novel foamed plastic |
| CN106433081A (en) * | 2016-09-08 | 2017-02-22 | 广西南宁桂尔创环保科技有限公司 | Environment-friendly foamed plastic with high performances |
-
2017
- 2017-09-29 CN CN201710903278.3A patent/CN107556739A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317840A (en) * | 2016-09-08 | 2017-01-11 | 广西南宁桂尔创环保科技有限公司 | Novel high-performance foamed plastic |
| CN106366614A (en) * | 2016-09-08 | 2017-02-01 | 广西南宁桂尔创环保科技有限公司 | Novel environment-friendly foam plastic |
| CN106398164A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | Environmental-friendly novel foamed plastic |
| CN106398165A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | Environment-friendly foamed plastic |
| CN106398166A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | High performance foam plastic |
| CN106398167A (en) * | 2016-09-08 | 2017-02-15 | 广西南宁桂尔创环保科技有限公司 | Novel foamed plastic |
| CN106433081A (en) * | 2016-09-08 | 2017-02-22 | 广西南宁桂尔创环保科技有限公司 | Environment-friendly foamed plastic with high performances |
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Application publication date: 20180109 |