CN106398128A - 无卤阻燃长玻纤增强tpee复合材料及其制备方法 - Google Patents
无卤阻燃长玻纤增强tpee复合材料及其制备方法 Download PDFInfo
- Publication number
- CN106398128A CN106398128A CN201610779443.4A CN201610779443A CN106398128A CN 106398128 A CN106398128 A CN 106398128A CN 201610779443 A CN201610779443 A CN 201610779443A CN 106398128 A CN106398128 A CN 106398128A
- Authority
- CN
- China
- Prior art keywords
- halogen
- fiber reinforced
- glass fiber
- long glass
- tpee
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 title claims abstract description 55
- 239000003365 glass fiber Substances 0.000 title claims abstract description 54
- 239000002131 composite material Substances 0.000 title claims abstract description 40
- 239000003063 flame retardant Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 10
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000012545 processing Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 4
- 239000012747 synergistic agent Substances 0.000 claims abstract description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 17
- 230000003078 antioxidant effect Effects 0.000 claims description 17
- 235000006708 antioxidants Nutrition 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- MYOXMAQGEINAEF-UHFFFAOYSA-N [C].N1=NN=CC=C1 Chemical compound [C].N1=NN=CC=C1 MYOXMAQGEINAEF-UHFFFAOYSA-N 0.000 claims description 11
- 238000007598 dipping method Methods 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 7
- 230000002687 intercalation Effects 0.000 claims description 7
- 238000009830 intercalation Methods 0.000 claims description 7
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000005453 pelletization Methods 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 238000004781 supercooling Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 16
- 239000000463 material Substances 0.000 abstract description 13
- 239000011159 matrix material Substances 0.000 abstract description 9
- 229920005989 resin Polymers 0.000 abstract description 9
- 239000011347 resin Substances 0.000 abstract description 9
- 239000000835 fiber Substances 0.000 abstract description 8
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 238000001816 cooling Methods 0.000 abstract description 3
- 238000005470 impregnation Methods 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 150000004714 phosphonium salts Chemical class 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- 238000001802 infusion Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 238000005253 cladding Methods 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000011208 reinforced composite material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610779443.4A CN106398128B (zh) | 2016-08-31 | 2016-08-31 | 无卤阻燃长玻纤增强tpee复合材料及其制备方法 |
Applications Claiming Priority (1)
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CN201610779443.4A CN106398128B (zh) | 2016-08-31 | 2016-08-31 | 无卤阻燃长玻纤增强tpee复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN106398128A true CN106398128A (zh) | 2017-02-15 |
CN106398128B CN106398128B (zh) | 2019-02-15 |
Family
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CN201610779443.4A Active CN106398128B (zh) | 2016-08-31 | 2016-08-31 | 无卤阻燃长玻纤增强tpee复合材料及其制备方法 |
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CN (1) | CN106398128B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107201023A (zh) * | 2017-06-05 | 2017-09-26 | 江林(贵州)高科发展股份有限公司 | 抗滴落透明阻燃tpu材料及其制备方法 |
CN108485208A (zh) * | 2018-03-29 | 2018-09-04 | 贵州省材料产业技术研究院 | 一种dopo衍生物阻燃pet透明复合材料及制备方法 |
CN109021506A (zh) * | 2018-02-09 | 2018-12-18 | 扬州金森光电材料有限公司 | 一种耐超低温的玻纤改性tpee光缆松套管料及其制备方法 |
CN112812508A (zh) * | 2020-12-22 | 2021-05-18 | 江阴爱科森博顿聚合体有限公司 | 一种汽车电缆用阻燃tpee材料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1509314A (zh) * | 2001-05-15 | 2004-06-30 | ������������ʽ���� | 阻燃性树脂组合物及由其形成的成形品 |
CN102741335A (zh) * | 2009-12-31 | 2012-10-17 | 化学制造布敦海姆两合公司 | 用于热塑性模塑化合物的阻燃剂组合物 |
-
2016
- 2016-08-31 CN CN201610779443.4A patent/CN106398128B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1509314A (zh) * | 2001-05-15 | 2004-06-30 | ������������ʽ���� | 阻燃性树脂组合物及由其形成的成形品 |
CN102741335A (zh) * | 2009-12-31 | 2012-10-17 | 化学制造布敦海姆两合公司 | 用于热塑性模塑化合物的阻燃剂组合物 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107201023A (zh) * | 2017-06-05 | 2017-09-26 | 江林(贵州)高科发展股份有限公司 | 抗滴落透明阻燃tpu材料及其制备方法 |
CN109021506A (zh) * | 2018-02-09 | 2018-12-18 | 扬州金森光电材料有限公司 | 一种耐超低温的玻纤改性tpee光缆松套管料及其制备方法 |
CN108485208A (zh) * | 2018-03-29 | 2018-09-04 | 贵州省材料产业技术研究院 | 一种dopo衍生物阻燃pet透明复合材料及制备方法 |
CN112812508A (zh) * | 2020-12-22 | 2021-05-18 | 江阴爱科森博顿聚合体有限公司 | 一种汽车电缆用阻燃tpee材料及其制备方法 |
Also Published As
Publication number | Publication date |
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CN106398128B (zh) | 2019-02-15 |
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GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Halogen-free flame retardant long glass fiber reinforced TPEE composite and its preparation method Effective date of registration: 20230310 Granted publication date: 20190215 Pledgee: Bank of Communications Co.,Ltd. Guizhou Branch Pledgor: GUIZHOU GS TECHNOLOGY PLASTIC PIPE CO.,LTD. Registration number: Y2023520000011 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20190215 Pledgee: Bank of Communications Co.,Ltd. Guizhou Branch Pledgor: GUIZHOU GS TECHNOLOGY PLASTIC PIPE CO.,LTD. Registration number: Y2023520000011 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Halogen free flame retardant long glass fiber reinforced TPEE composite material and its preparation method Granted publication date: 20190215 Pledgee: Bank of Communications Co.,Ltd. Guizhou Branch Pledgor: GUIZHOU GS TECHNOLOGY PLASTIC PIPE CO.,LTD. Registration number: Y2024520000012 |