CN106398019A - Low-volatility environmentally-friendly cable material for automobile - Google Patents

Low-volatility environmentally-friendly cable material for automobile Download PDF

Info

Publication number
CN106398019A
CN106398019A CN201610715066.8A CN201610715066A CN106398019A CN 106398019 A CN106398019 A CN 106398019A CN 201610715066 A CN201610715066 A CN 201610715066A CN 106398019 A CN106398019 A CN 106398019A
Authority
CN
China
Prior art keywords
parts
low
cable material
friendly cable
volatility
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610715066.8A
Other languages
Chinese (zh)
Inventor
景颖杰
邹惠忠
单永东
张雪良
方拯宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cgnpc Delta (jiangsu) Plastic Co Ltd
Original Assignee
Cgnpc Delta (jiangsu) Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cgnpc Delta (jiangsu) Plastic Co Ltd filed Critical Cgnpc Delta (jiangsu) Plastic Co Ltd
Priority to CN201610715066.8A priority Critical patent/CN106398019A/en
Publication of CN106398019A publication Critical patent/CN106398019A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/006—Additives being defined by their surface area
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention relates to a low-volatility environmentally-friendly cable material for automobiles, and the low-volatility environmentally-friendly cable material is characterized by comprising the following components in part by weight: 80 parts of PVC resin with the degree of polymerization of 1300, 15 parts of SG3 type PVC resin, 35 parts of cyclohexane-1,2-dinonyl diformate, 28 parts of acetyl butyl octyl citrate, 5 parts of antimony trioxide, 7.5 parts of zinc borate, 12 parts of a filler, 9 parts of aluminum hydroxide, 7 parts of a calcium zinc heat stabilizer, 0.3 part of antioxidant 1010, 0.45 part of a lubricant, 0.9 part of processing modifier P551J, 1 part of an inorganic silicate deodorant and 5 parts of white carbon black. The low-volatility environmentally-friendly cable material has the advantages of low volatility and low odor effects in high temperature environment, is free of harm to human body, has an atomizing value reaching 0.44mg, and has a good anti volatilization characteristic, and a product has low odor and no harm to human body.

Description

Low volatilization environment-friendly cable material for automobile
Technical field
The present invention relates to the low volatilization environment-friendly cable material of environment-friendly cable material, more particularly, to automobile.
Background technology
Polyvinyl chloride（PVC）As modal plastic products in life, it is widely used in manufacturing various pvc pipes, PVC board Material, PVC film, PVC wallpaper, PVC cable material etc., are purposes classes the widest in five big general-purpose plastics.
Polyvinyl chloride cable material is mainly made up of polyvinyl chloride resin, plasticizer, stabilizer, filler, lubricant and pigment, passes through Two steps type screw extruder is extruded and is granulated and processes.Wherein, the soft durometer of PVC cable material relies on plasticizer to fill a prescription in PVC In ratio adjusting, plasticizer loading is more, and CABLE MATERIALS is softer.Common CABLE MATERIALS selects some conventional plasticizer Soften PVC, due to the technique of itself characteristic and production, the CABLE MATERIALS taste produced is heavier, relatively more pungent, and sends out Smoke is big, causes different degrees of somatic damage to a line operative employee of downstream cables production unit.Some CABLE MATERIALS are due to choosing The plasticizer selected is with low quality, the problems such as causing the cable bleed producing, separate out, leads to product service life to shorten, pollutes ring Border.
Current PVC plastic market, in order to ensure the living environment of the mankind, PVC plastic system more and more harsher to environmental requirement Product except the general Rohs environmental protection requiring instruction, also European Union's REACH environmental regulation, No. 2007/47/EC finger of EU Council Order, European Union's NO.10/2011 food contact regulation, in addition, automobile component includes automotive line, automotive upholstery etc. is also to PVC plastic Requirement, such as U.S. ASTM D3960-98 standard, international standard ISO 4618/1-1998, moral are made in material smell and plastics volatilization Mark DIN 55649-2000 standard etc..
Content of the invention
It is an object of the invention to provide a kind of low volatilization environment-friendly cable material for automobile, this is used for the low volatilization ring of automobile Protect CABLE MATERIALS and there is low volatilization low odor effect in high temperature environments, to human body fanout free region, haze value reaches 0.44mg, has very Good resistance to vaporization characteristics, product smell is low, to human body fanout free region, environmentally safe；Meanwhile, provide above-mentioned novel low-odor environmental protection The preparation method of CABLE MATERIALS.
To achieve the above object of the invention, the technical solution used in the present invention is：A kind of low volatilization environmental protection electricity for automobile Cable material, described low volatilization environment-friendly cable material is grouped into by the group of following weight portion：The degree of polymerization is 1,300 80 parts of polyvinyl chloride resin, SG3 15 parts of type polyvinyl chloride resin, 35 parts of dioctyl phthalate dinonyl ester of hexamethylene 1,2,28 parts of acetyl tributyl citrate fourth monooctyl ester, 5 parts of antimony oxide, 7.5 parts of Firebrake ZB, 12 parts of filler, 9 parts of aluminium hydroxide, 7 parts of calcium zinc heat stabilizer, antioxidant 1010 are 0.3 part, lubricant 0.45 Part, 0.9 part of modifier P551J, 1 part of inorganic silicic acid salt eliminating smell agent, 5 parts of white carbon.
The further improved technical scheme of technical scheme of above-mentioned novel low-odor environment-friendly cable material is as follows：
1. in such scheme, described lubricant be selected from stearic acid, Tissuemat E, calcium stearate, in zinc stearate at least one Kind.
2., in such scheme, described filler is calcium carbonate, talcum powder, one or more mixtures kaolinic.
Due to the utilization of technique scheme, the present invention compared with prior art has following advantages：
1. the present invention is used for the low volatilization environment-friendly cable material of automobile, and it adopts 80 parts of the polyvinyl chloride resin that the degree of polymerization is 1300, SG3 type 15 ~ 20 parts of polyvinyl chloride resin, 4 ~ 6 parts of antimony oxide, 7 ~ 9 parts of Firebrake ZB, 10 ~ 40 parts of filler, 8 ~ 12 parts of aluminium hydroxide, calcium zinc heat 5 ~ 8 parts of stabilizer and antioxidant 1010 are 0.2 ~ 0.4 part, and its degree of polymerization is 1300 polyvinyl chloride resin and the combination of SG3 type polyvinyl chloride resin Substantially increase Flame Retardancy energy, and make material have good one-tenth charcoal effect in burning, thus preventing material Second-time burning and flame propagation；Secondly, add 10 ~ 40 parts of hexamethylene 1,2 dioctyl phthalate dinonyl ester in formula further and gather Right be 1300 polyvinyl chloride resin, SG3 type polyvinyl chloride resin synergy, substantially increase aging break-draw strain retention rate.
2. the present invention is used for the low volatilization environment-friendly cable material of automobile, and its formula further includes inorganic silicic acid salt taste removal 1 ~ 2 part of agent, acetyl tributyl citrate fourth monooctyl ester have the low odor effect of low volatilization in high temperature environments for 20 ~ 35 parts, and human body is no hindered Evil, this product meets European Union's REACH environmental regulation, EU Council's 2007/47/EC medical instructions, and obtains Japanese health The food contact accreditation of PVC association, and pass through Volkswagen《The component odor detection of PV 3900 inner space of vehicle》, smell Detection passes through 3.0 grades（Require to be less than 4.0 grades）；Pass through simultaneously《PV 3015 interior trim nonmetallic materials condensable components are surveyed Fixed》, haze value reaches 0.44mg（Require to be less than 1.5mg）, there are resistance to vaporization characteristics very well, product smell is low, and human body is no hindered Evil, environmentally safe；Secondly, in formula, interpolation 10 ~ 40 parts of dioctyl phthalate dinonyl ester of hexamethylene 1,2, acetyl tributyl citrate fourth are pungent Ester is 10 ~ 25 parts, with 5 ~ 10 parts of synergies of white carbon, improves CABLE MATERIALS specific insulation, simultaneously aging to CABLE MATERIALS Performance also makes moderate progress, and ensures the abrasion resistant effect of product.
Specific embodiment
With reference to embodiment, the invention will be further described：
Embodiment：A kind of low volatilization environment-friendly cable material for automobile, described low volatilization environment-friendly cable material is by following weight portion Group is grouped into：The degree of polymerization be 1300 80 parts of polyvinyl chloride resin, 15 parts of SG3 type polyvinyl chloride resin, hexamethylene 1,2 dioctyl phthalate dinonyl ester 35 Part, 28 parts of acetyl tributyl citrate fourth monooctyl ester, 5 parts of antimony oxide, 7.5 parts of Firebrake ZB, 12 parts of filler, 9 parts of aluminium hydroxide, calcium zinc heat 7 parts of stabilizer, antioxidant 1010 are 0.3 part, 0.45 part of lubricant, 0.9 part of modifier P551J, inorganic silicic acid salt remove 1 part of taste agent, 5 parts of white carbon.
At least one in stearic acid, Tissuemat E, calcium stearate, zinc stearate for the above-mentioned lubricant.
Above-mentioned filler is calcium carbonate, talcum powder, one or more mixtures kaolinic.
Described modifier P551J produces for MIT.
Described inorganic silicic acid salt eliminating smell agent is bought from Ningbo Bo Er chemical industry and is obtained, and it is mainly inorganic silicate material, Specific surface area 400-600 m/g.
A kind of low volatilization environment-friendly cable material for automobile, comprises the following steps：
Step one, the degree of polymerization is 1300 polyvinyl chloride resin, SG3 type polyvinyl chloride resin, hexamethylene 1,2 dioctyl phthalate dinonyl ester, acetyl Citric acid fourth monooctyl ester and charcoal blacks put into high-speed kneading machine, high-speed kneading 3-5 minute, and temperature reaches 90 ~ 100 DEG C；
Step 2, again low speed are mediated 1 minute, put into antimony oxide, Firebrake ZB, 10 ~ 40 parts of filler, aluminium hydroxide, calcium simultaneously Zinc heat stabilizer, antioxidant 1010 are, after lubricant, modifier P551J, eliminating smell agent and white carbon, then 6 points of high-speed kneading Clock, treats that temperature reaches 120 DEG C, is sufficiently mixed all even preplasticizing, discharge；
When step 3, extrusion, the extruder temperature in twin-screw is 120 DEG C to 150 DEG C, screw speed 30Hz；
When step 4, mill, roller temperature is 160 DEG C；
Step 5, use single screw rod granulator granulation again, single screw rod comminutor design temperature is 80 DEG C to 100 DEG C；
Step 6, cooling are sieved.
The low volatilization environment-friendly cable material being used for automobile that the embodiment of the present invention is obtained is tested, result with common It is as shown in table 2 that PVC cable material compares the data obtained：
Table 2
To sum up, the present invention is used for the low volatilization environment-friendly cable material of automobile, substantially increases Flame Retardancy energy, and makes material In burning, there is good one-tenth charcoal effect, thus preventing second-time burning and the flame propagation of material；Secondly, enter one in formula Step adds hexamethylene 1,2 dioctyl phthalate dinonyl ester, acetyl tributyl citrate fourth monooctyl ester, inorganic silicic acid salt eliminating smell agent, white carbon with The degree of polymerization is 1300 polyvinyl chloride resin, SG3 type polyvinyl chloride resin synergy, substantially increases aging break-draw strain retention rate； Secondly there is low volatilization low odor effect in high temperature environments, to human body fanout free region, this product meets European Union's REACH environmental law Rule, EU Council's 2007/47/EC medical instructions, and obtain the food contact accreditation of Japanese health PVC association, and pass through Volkswagen《The component odor detection of PV 3900 inner space of vehicle》, odor detection is by 2.5 grades（Require to be less than 4.0 grades）； Pass through simultaneously《PV 3015 interior trim nonmetallic materials condensable components measure》, haze value reaches 0.44mg（Requirement is less than 1.5mg）, there are resistance to vaporization characteristics very well, product smell is low, to human body fanout free region, environmentally safe；Again, add in formula Plus hexamethylene 1,2 dioctyl phthalate dinonyl ester, acetyl tributyl citrate fourth monooctyl ester are, with white carbon synergy, improve CABLE MATERIALS body The ageing properties of CABLE MATERIALS are also made moderate progress by long-pending resistivity simultaneously, and ensure the abrasion resistant effect of product.
Above-described embodiment only technology design to illustrate the invention and feature, its object is to allow person skilled in the art Scholar will appreciate that present disclosure and implements according to this, can not be limited the scope of the invention with this.All according to the present invention Equivalence changes or modification that Spirit Essence is made, all should be included within the scope of the present invention.

Claims (3)

1. a kind of low volatilization environment-friendly cable material for automobile it is characterised in that：Described low volatilization environment-friendly cable material is by following heavy The group of amount part is grouped into：The degree of polymerization be 1300 80 parts of polyvinyl chloride resin, 15 parts of SG3 type polyvinyl chloride resin, hexamethylene 1,2 dioctyl phthalate two nonyl 35 parts of base ester, 28 parts of acetyl tributyl citrate fourth monooctyl ester, 5 parts of antimony oxide, 7.5 parts of Firebrake ZB, 12 parts of filler, 9 parts of aluminium hydroxide, 7 parts of calcium zinc heat stabilizer, antioxidant 1010 are 0.3 part, 0.45 part of lubricant, 0.9 part of modifier P551J, inorganic silicic acid 1 part of salt eliminating smell agent, 5 parts of white carbon.
2. the low volatilization environment-friendly cable material for automobile according to claim 1 it is characterised in that：Described filler is carbonic acid Calcium, talcum powder, one or more mixtures kaolinic.
3. the low volatilization environment-friendly cable material for automobile according to claim 1 it is characterised in that：Described lubricant is selected from At least one in stearic acid, Tissuemat E, calcium stearate, zinc stearate.
CN201610715066.8A 2014-11-27 2014-11-27 Low-volatility environmentally-friendly cable material for automobile Pending CN106398019A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610715066.8A CN106398019A (en) 2014-11-27 2014-11-27 Low-volatility environmentally-friendly cable material for automobile

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201410695868.8A CN104387703A (en) 2014-11-27 2014-11-27 Novel low-odor environment-friendly electric cable material and preparation method thereof
CN201610715066.8A CN106398019A (en) 2014-11-27 2014-11-27 Low-volatility environmentally-friendly cable material for automobile

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN201410695868.8A Division CN104387703A (en) 2014-11-27 2014-11-27 Novel low-odor environment-friendly electric cable material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106398019A true CN106398019A (en) 2017-02-15

Family

ID=52605670

Family Applications (4)

Application Number Title Priority Date Filing Date
CN201610715066.8A Pending CN106398019A (en) 2014-11-27 2014-11-27 Low-volatility environmentally-friendly cable material for automobile
CN201410695868.8A Pending CN104387703A (en) 2014-11-27 2014-11-27 Novel low-odor environment-friendly electric cable material and preparation method thereof
CN201610714947.8A Pending CN106398018A (en) 2014-11-27 2014-11-27 Process for preparing polyvinyl chloride cable material
CN201610714766.5A Pending CN106432948A (en) 2014-11-27 2014-11-27 Wear-resistant polyvinyl chloride cable material

Family Applications After (3)

Application Number Title Priority Date Filing Date
CN201410695868.8A Pending CN104387703A (en) 2014-11-27 2014-11-27 Novel low-odor environment-friendly electric cable material and preparation method thereof
CN201610714947.8A Pending CN106398018A (en) 2014-11-27 2014-11-27 Process for preparing polyvinyl chloride cable material
CN201610714766.5A Pending CN106432948A (en) 2014-11-27 2014-11-27 Wear-resistant polyvinyl chloride cable material

Country Status (1)

Country Link
CN (4) CN106398019A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114426747A (en) * 2020-10-29 2022-05-03 中广核三角洲（江苏）塑化有限公司 Deformation-resistant PVC elastomer automotive interior material

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108164863A (en) * 2016-12-07 2018-06-15 上海凯波特种电缆料厂有限公司 A kind of automobile electric wire PVC Insulation Materials and preparation method thereof
CN107379490A (en) * 2017-05-25 2017-11-24 郁华 It is low to distribute composite PVC material fabrication process
CN107418093A (en) * 2017-06-21 2017-12-01 合肥博创机械制造有限公司 A kind of high-strength abrasion-proof CABLE MATERIALS and preparation method thereof
CN107286534A (en) * 2017-08-03 2017-10-24 安徽华能电缆集团有限公司 A kind of Anti-ultraviolet-ray fire-retardant cable material formula
CN109735021A (en) * 2018-12-27 2019-05-10 中广核三角洲（江苏）塑化有限公司 Welding robot high temperature resistant oil resistant flame retarding PVC composition for cable and preparation method thereof
CN109721884A (en) * 2018-12-27 2019-05-07 江苏盈泰新材料科技有限公司 A kind of low smell environmental protection wall paper and its production technology
CN111686473B (en) * 2019-03-13 2022-02-11 北京石油化工学院 Method for separating iron oxide waste desulfurizer from sulfur

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070096091A (en) * 2005-12-14 2007-10-02 엘에스전선 주식회사 Odor-reduced poly(vinyl chloride) composition for cable covering material and electric wire using the same
CN101456998A (en) * 2008-12-30 2009-06-17 深圳市领亚电子有限公司 Odorless polyvinyl chloride composition for wire cable and preparation method
CN102250435A (en) * 2011-05-25 2011-11-23 无锡市明珠电缆有限公司 Polyvinyl chloride (PVC) cable sheath material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070096091A (en) * 2005-12-14 2007-10-02 엘에스전선 주식회사 Odor-reduced poly(vinyl chloride) composition for cable covering material and electric wire using the same
CN101456998A (en) * 2008-12-30 2009-06-17 深圳市领亚电子有限公司 Odorless polyvinyl chloride composition for wire cable and preparation method
CN102250435A (en) * 2011-05-25 2011-11-23 无锡市明珠电缆有限公司 Polyvinyl chloride (PVC) cable sheath material and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
杨涛: "《聚氯乙烯配方设计与制品加工》", 30 June 2011 *
杨鸣波等: "《中国材料工程大典 第6卷 高分子材料工程（上）》", 31 March 2006 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114426747A (en) * 2020-10-29 2022-05-03 中广核三角洲（江苏）塑化有限公司 Deformation-resistant PVC elastomer automotive interior material

Also Published As

Publication number Publication date
CN104387703A (en) 2015-03-04
CN106398018A (en) 2017-02-15
CN106432948A (en) 2017-02-22

Similar Documents

Publication Publication Date Title
CN106398019A (en) Low-volatility environmentally-friendly cable material for automobile
CN103937086B (en) 125 DEG C of cross-linking radiation oil-resistant low-smoke halogen-free flame-retardant CABLE MATERIALS and preparation method thereof
CN102464821B (en) Antibacterial aging-resistant antistatic plastic master batch and preparation method thereof
CN104250406B (en) CPE/CPVC insulating rubber plastic and preparation method thereof
CN109627636B (en) Frosted PVC material for automobile internal and external decoration strips and manufacturing method thereof
CN102181108A (en) Crosslinked high flame-retardant foamed polyvinyl chloride modified material
CN104744791B (en) A kind of low smoke halogen-free fire retardant polyolefin cable material and preparation method thereof
CN104448613A (en) Environment-friendly, low-volatility and low-odor PVC (polyvinyl chloride) cable material and preparation method thereof
CN105295271B (en) A kind of heat-resisting high transparency CPVC compositions
CN103525000B (en) A kind of low smell ABS/PVC/PETG alloy material and preparation method thereof
CN105086283A (en) High-fluidity and flame-retardant PVC/ABS (acrylonitrile butadiene styrene) alloy material and preparation method thereof
CN103214764B (en) A kind of Flexible full-matte composite material and preparation method
CN104744849B (en) A kind of Environmental-friendantistatic antistatic high-flame-retardantPVC PVC sheath material and preparation method thereof
CN103937124B (en) High speed extrusion cloudy surface polyvinyl chloride cable material and preparation method thereof
CN104403232A (en) Low-volatile environment-friendly polyvinyl chloride (PVC) cable material and manufacturing process thereof
CN108659371B (en) Low-odor polyvinyl chloride cable material composition for automobile wire harness and preparation method thereof
CN104212106A (en) Antistatic agent composition, antistatic thermoplastic synthetic resin composition and molded product
CN106496863A (en) A kind of mildew-proof flame retarded polrvinyl chloride sheath material of novel environment friendly
KR101213568B1 (en) Rubber foam heat insulating product with excellent pollution prevention at installing
CN104672692A (en) Polyethylene foamed master batch and preparation method thereof
CN105131415A (en) Thermoplastic low-smoke halogen-free flame-retardant polyolefin composite material for data cable and preparation method of polyolefin composite material
CN103642129A (en) Preparation method of antistatic and fire-retardant polypropylene composite material
CN105504502B (en) One kind can selfreparing squeeze out grade polypropylene composite material and preparation method thereof
CN110951182A (en) PVC film for automotive interior night warning and preparation method
CN108690298A (en) A kind of polyvinyl chloride calendered film and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170215