CN106397857A - High-strength cold-resistance soft rubber sheath material - Google Patents

High-strength cold-resistance soft rubber sheath material Download PDF

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Publication number
CN106397857A
CN106397857A CN201610794871.4A CN201610794871A CN106397857A CN 106397857 A CN106397857 A CN 106397857A CN 201610794871 A CN201610794871 A CN 201610794871A CN 106397857 A CN106397857 A CN 106397857A
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China
Prior art keywords
parts
cold
sheath material
rubber sheath
soft rubber
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Granted
Application number
CN201610794871.4A
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Chinese (zh)
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CN106397857B (en
Inventor
姜绪宏
姜茂盛
张小平
何元元
刘美法
李健
余小葵
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Anhui Hongyuan Special Cable Ltd By Share Ltd
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Anhui Hongyuan Special Cable Ltd By Share Ltd
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Priority to CN201610794871.4A priority Critical patent/CN106397857B/en
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Application granted granted Critical
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention relates to a high-strength cold-resistance soft rubber sheath material which consists of the following raw materials in parts by weight: 50-60 parts of SCR5 natural rubber, 40-50 parts of SBR1503 butadiene styrene rubber, 2-2.5 parts of a vulcanization accelerator DM, 1-1.5 parts of an accelerator M, 0.5-1.0 part of an anti-aging agent DNP, 2-2.5 parts of an anti-aging agent MB, 0.5-1.0 part of an anti-aging agent RD, 6-8 parts of zinc oxide, 4-6 parts of paraffin, 0.2-0.5 part of a scorch retarder CTP (PVI), 2.5-3.0 parts of coumarone resin, 1-1.5 parts of stearic acid, 1.5-2.0 parts of a vulcanizing agent (VA-7-70), 0.4-0.6 part of an accelerator ZDC, 25-30 parts of calcium carbonate, 25-30 parts of talcum powder, 20-25 parts of N330 carbon black, 20-25 parts of potty clay, 15-20 parts of semi-reinforced carbon black, 3-5 parts of rubber oil, 5-7 parts of engine oil and 3-5 parts of a cold resisting agent. The high-strength cold-resistance soft rubber sheath material is good in cold resistance, has flexibility under an environment condition of 55 DEG C below zero and can be randomly moved and laid, and dragging and use requirements of cables in outdoor severe environments can be improved.

Description

A kind of high intensity cold-resistant flexible rubber sheath material
Technical field
The present invention relates to technical field of electric wires and cables, specifically a kind of high intensity cold-resistant flexible rubber sheath material.
Background technology
In northern China and western extremely frigid zones, winter temperature is low, at present many cold-resistant cable materials, and it is -55 DEG C and during lower temperature cable sheath material hard, have not a particle of flexibility and can not lay and move bending, on such as digger The drag chain cable using, needs to bend back and forth in cold district operation cable, cable of lift etc., if cable does not reach Cold-resistant condition, these cables hardening cannot can bend and move back and forth, and serious situation cable skin ftractures, and causes short circuit and equipment Fault.
Content of the invention
For deficiency of the prior art, the present invention proposes a kind of high intensity cold-resistant flexible rubber sheath material, Ci Zhongcai It is good that material has cold resistance, and has flexibility under -55 DEG C of environmental conditions, its tension and the high feature of tearing strength.
A kind of high intensity cold-resistant flexible rubber sheath material, is made up of the raw material of following weight parts:
The invention has the beneficial effects as follows:
Cold resistance of the present invention is good, can have flexibility under -55 DEG C of environmental conditions, can arbitrarily move and lay.This It is that common sheath material is beyond one's reach, its tensile strength can reach 22.0N/mm2More than, tearing strength reaches 12.5N/ Mm, improves towing use requirement in the wild under adverse circumstances for the cable.
Specific embodiment
In order that the technological means realized of the present invention, creation characteristic, reached purpose and effect are easy to understand, below right The present invention is expanded on further.
Embodiment one:
A kind of high intensity cold-resistant flexible rubber sheath material, is made up of the raw material of following weight parts:
Embodiment two:
A kind of high intensity cold-resistant flexible rubber sheath material, is made up of the raw material of following weight parts:
Embodiment three:
A kind of high intensity cold-resistant flexible rubber sheath material, is made up of the raw material of following weight parts:
The preparation method of the high intensity cold-resistant flexible rubber sheath material of the present invention comprises the following steps:
Natural rubber and butadiene-styrene rubber are poured in banbury, plasticates at 70~80 DEG C 5 minutes, after pouring out, be pressed into thin slice Packing puts into banbury again, is sequentially added into accelerator DM, captax, antioxidant D NP, antioxidant MB, age resistor RD, zinc oxide, paraffin, anti-scorching agent CTP (PVI), coumarone indene resin, stearic acid, knead 3~5 minutes at 80~85 DEG C, then plus Enter calcium carbonate, talcum powder, N330 carbon black, potter's clay, semi-reinforcing hydrocarbon black, rubber oil, machine oil, cold-resistant agent DOS mixed at 80~90 DEG C Refining 5 minutes, pours out and is pressed into thin slice and has dried in the air cooling, by the compound input mill after cooling, addition vulcanizing agent (VA-7- 70), accelerator ZDC, compressing tablet breaks into triangle bag, and compressing tablet becomes the horizontal compressing tablet that wraps again to break into triangle bag to triangle bag again, 4 times repeatedly, makes sulphur Agent mixes in sizing material, and mill opens recirculated water and prevents that mill bowl temperature is too high to make rubber vulcanization, and temperature is 30~40 DEG C, the sizing material kneading is put into slicer and is cut into slices, talcum powder is coated on the sizing material surface after section prevents sizing material Adhesion, finally obtains final product described high intensity cold-resistant flexible rubber sheath material.
In order to prove the actual effect of the present invention, the application spy is tested, the performance such as following table of test:
General principle, principal character and the advantages of the present invention of the present invention have been shown and described above.The technology of the industry The simply present invention it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and specification for the personnel Principle, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these change and Improvement both falls within claimed invention.Claimed scope is by appending claims and its equivalent circle. Fixed.

Claims (1)

1. a kind of high intensity cold-resistant flexible rubber sheath material it is characterised in that:It is made up of the raw material of following weight parts:
CN201610794871.4A 2016-08-31 2016-08-31 A kind of high intensity cold-resistant flexible rubber sheath material Active CN106397857B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610794871.4A CN106397857B (en) 2016-08-31 2016-08-31 A kind of high intensity cold-resistant flexible rubber sheath material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610794871.4A CN106397857B (en) 2016-08-31 2016-08-31 A kind of high intensity cold-resistant flexible rubber sheath material

Publications (2)

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CN106397857A true CN106397857A (en) 2017-02-15
CN106397857B CN106397857B (en) 2018-12-21

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107086061A (en) * 2017-05-03 2017-08-22 安徽凌宇电缆科技有限公司 A kind of new harbour corrosion-resistant midium voltage cable that blocks water
CN107151353A (en) * 2017-06-08 2017-09-12 合肥帧讯低温科技有限公司 A kind of high-toughness and low-temperature insulation material and its preparation technology
CN107286396A (en) * 2017-06-30 2017-10-24 上海蓝昊电气江苏有限公司 A kind of super low-temperature resistant oil resistant flame retardant jacket materials and its preparation technology
CN107286406A (en) * 2017-06-30 2017-10-24 上海蓝昊电气有限公司 A kind of super low-temperature resistant cable semiconductive material
CN108192158A (en) * 2018-01-19 2018-06-22 广西厚思品牌策划顾问有限公司 A kind of arctic rubber and preparation method thereof
CN108665995A (en) * 2018-06-08 2018-10-16 安徽华星电缆集团有限公司 A kind of anti-interference type warship canon cable and preparation method thereof
CN109306092A (en) * 2018-09-27 2019-02-05 安徽龙川橡塑科技有限公司 A kind of heatproof elastic buffering pad material and its preparation process
CN109503906A (en) * 2018-11-22 2019-03-22 安徽明福电缆有限公司 A kind of powerful permanent seal cooling flame-proof power cable sheath and preparation method thereof
CN112831106A (en) * 2020-12-30 2021-05-25 安徽宏源特种电缆股份有限公司 High-strength flexible sheath material for nuclear-resistant electromagnetic cable and preparation method thereof
CN117285754A (en) * 2023-11-24 2023-12-26 德州市宏祥鞋业有限责任公司 Insulating glove and manufacturing method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102757582A (en) * 2012-07-28 2012-10-31 江西联创电缆科技有限公司 Rubber-sheathed cable environment friendly antibacterial sheath composition for radio device
CN103059352A (en) * 2011-10-24 2013-04-24 远东电缆有限公司 Sheath rubber for rubber sheath flexible cables
CN104072824A (en) * 2014-07-15 2014-10-01 安徽国电电缆集团有限公司 Special cable material for styrene-butadiene rubber sleeved field detection cable and preparation method of special cable material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103059352A (en) * 2011-10-24 2013-04-24 远东电缆有限公司 Sheath rubber for rubber sheath flexible cables
CN102757582A (en) * 2012-07-28 2012-10-31 江西联创电缆科技有限公司 Rubber-sheathed cable environment friendly antibacterial sheath composition for radio device
CN104072824A (en) * 2014-07-15 2014-10-01 安徽国电电缆集团有限公司 Special cable material for styrene-butadiene rubber sleeved field detection cable and preparation method of special cable material

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107086061A (en) * 2017-05-03 2017-08-22 安徽凌宇电缆科技有限公司 A kind of new harbour corrosion-resistant midium voltage cable that blocks water
CN107151353A (en) * 2017-06-08 2017-09-12 合肥帧讯低温科技有限公司 A kind of high-toughness and low-temperature insulation material and its preparation technology
CN107286396A (en) * 2017-06-30 2017-10-24 上海蓝昊电气江苏有限公司 A kind of super low-temperature resistant oil resistant flame retardant jacket materials and its preparation technology
CN107286406A (en) * 2017-06-30 2017-10-24 上海蓝昊电气有限公司 A kind of super low-temperature resistant cable semiconductive material
CN108192158A (en) * 2018-01-19 2018-06-22 广西厚思品牌策划顾问有限公司 A kind of arctic rubber and preparation method thereof
CN108665995A (en) * 2018-06-08 2018-10-16 安徽华星电缆集团有限公司 A kind of anti-interference type warship canon cable and preparation method thereof
CN109306092A (en) * 2018-09-27 2019-02-05 安徽龙川橡塑科技有限公司 A kind of heatproof elastic buffering pad material and its preparation process
CN109503906A (en) * 2018-11-22 2019-03-22 安徽明福电缆有限公司 A kind of powerful permanent seal cooling flame-proof power cable sheath and preparation method thereof
CN112831106A (en) * 2020-12-30 2021-05-25 安徽宏源特种电缆股份有限公司 High-strength flexible sheath material for nuclear-resistant electromagnetic cable and preparation method thereof
CN117285754A (en) * 2023-11-24 2023-12-26 德州市宏祥鞋业有限责任公司 Insulating glove and manufacturing method thereof
CN117285754B (en) * 2023-11-24 2024-02-23 德州市宏祥鞋业有限责任公司 Insulating glove and manufacturing method thereof

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