CN107446199A - A kind of vulcanized polyethylene resistant tensile cable and its manufacture method - Google Patents
A kind of vulcanized polyethylene resistant tensile cable and its manufacture method Download PDFInfo
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- CN107446199A CN107446199A CN201710763708.6A CN201710763708A CN107446199A CN 107446199 A CN107446199 A CN 107446199A CN 201710763708 A CN201710763708 A CN 201710763708A CN 107446199 A CN107446199 A CN 107446199A
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
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- C08L11/00—Compositions of homopolymers or copolymers of chloroprene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
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- C—CHEMISTRY; METALLURGY
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to cable production art, specifically a kind of vulcanized polyethylene resistant tensile cable and its manufacture method, include according to weight composition point:50 60 parts of rubber, 40 50 parts of vulcanized polyethylene, 6 10 parts of tetrafluoroethene, 20 25 parts of magnesia powder, 15 20 parts of oxide powder and zinc, 15 20 parts of sial charcoal, 10 15 parts of calcium hydroxide, 10 13 parts of sulphur, 8 10 parts of oxidant, 8 10 parts of antioxidant, 8 10 parts of resin, 68 parts of age resistor, it is comprised the following steps that:(1) it is kneaded;(2) carbon black;(3) mix;(4) vulcanize, the oil resistivity of rubber is good, especially nitrile rubber, and a variety of rubber compoundings use, and are complementary to one another long weakness;In order to prevent the inflammable problem of rubber strip, add oxide mineral and serve as fire retardant;In order to which cohesive adds resin well;Carry out vulcanization and reduce the problem of Cracking subsequently brought, reduce subsequent maintenance cost.
Description
Technical field
The present invention relates to cable production art, specifically a kind of vulcanized polyethylene resistant tensile cable and its manufacture method.
Background technology
Used with the large area of cable, for the requirement more and more higher of cable, traditional cable over time and
The change of environment, cuticular breakdown, wearability, oil resistivity are all deteriorated, especially in special dimension, as used in during PETROLEUM PROCESSING
Cable needs to possess very strong oil resistivity, is difficult to accomplish that prolonged oil resistant is wear-resistant in existing cable, it is therefore desirable to proposes new
Cable material fill market.
The content of the invention
In order to solve the above problems, the present invention proposes a kind of vulcanized polyethylene resistant tensile cable and its manufacture method.
A kind of vulcanized polyethylene resistant tensile cable, include according to weight composition point:
Rubber 50-60 parts, vulcanized polyethylene 40-50 parts, tetrafluoroethene 6-10 parts, magnesia powder 20-25 parts, oxide powder and zinc
15-20 parts, sial charcoal 15-20 parts, calcium hydroxide 10-15 parts, sulphur 10-13 parts, oxidant 8-10 parts, antioxidant 8-10 parts,
Resin 8-10 parts, age resistor 6-8 parts.
Described rubber includes natural rubber, butadiene-styrene rubber, butadiene rubber, epoxy natural rubber, fluorubber, silicon rubber
Two kinds in glue, nitrile rubber, ethylene propylene diene rubber, neoprene and two or more arbitrary compositions.
Described resin includes tackifying resin, phenolic resin, epoxy resin, one kind or any combination in organic siliconresin
Thing.
Described age resistor is using ditert-butylhydro quinone.
Described antioxidant is antioxidant 246.
Described oxidant is air, steam, one kind or any combination in hydrogen peroxide.
A kind of manufacture method of vulcanized polyethylene resistant tensile cable, it is comprised the following steps that:
(1) it is kneaded:Integrally, then at high temperature under high pressure rubber, tetrafluoroethene, vulcanized polyethylene are kneaded at high temperature
Magnesia powder, oxide powder and zinc, calcium hydroxide are added, stirred;
(2) carbon black:While step (1) is carried out, by sial charcoal and oxidizing formation silica-alumina carbon black;
(3) mix:Mixture in step (1) is mixed with the silica-alumina carbon black in step (2), at the same add antioxidant,
Resin, age resistor, stir;
(4) vulcanize:Mixture in step (3) is inserted in vulcanization bed, sulphur is added and is vulcanized.
The beneficial effects of the invention are as follows:The oil resistivity of rubber is good, especially nitrile rubber, and a variety of rubber compoundings use, phase
Mutually at supplement length;In order to prevent the inflammable problem of rubber strip, add oxide mineral and serve as fire retardant;In order to which cohesive adds well
Enter resin;Carry out vulcanization and reduce the problem of Cracking subsequently brought, reduce subsequent maintenance cost.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, below it is right
The present invention is expanded on further.
Embodiment one:
A kind of vulcanized polyethylene resistant tensile cable, include according to weight composition point:
60 parts of rubber, 45 parts of vulcanized polyethylene, 6 parts of tetrafluoroethene, 25 parts of magnesia powder, 18 parts of oxide powder and zinc, sial charcoal
15 parts, 15 parts of calcium hydroxide, 12 parts of sulphur, 8 parts of oxidant, 10 parts of antioxidant, 9 parts of resin, 6 parts of age resistor.
Described rubber includes natural rubber, butadiene-styrene rubber, butadiene rubber, epoxy natural rubber, fluorubber, silicon rubber
Two kinds in glue, nitrile rubber, ethylene propylene diene rubber, neoprene and two or more arbitrary compositions.
Described resin includes tackifying resin, phenolic resin, epoxy resin, one kind or any combination in organic siliconresin
Thing.
Described age resistor is using ditert-butylhydro quinone.
Described antioxidant is antioxidant 246.
Described oxidant is air, steam, one kind or any combination in hydrogen peroxide.
A kind of manufacture method of vulcanized polyethylene resistant tensile cable, it is comprised the following steps that:
(1) it is kneaded:Integrally, then at high temperature under high pressure rubber, tetrafluoroethene, vulcanized polyethylene are kneaded at high temperature
Magnesia powder, oxide powder and zinc, calcium hydroxide are added, stirred;
(2) carbon black:While step (1) is carried out, by sial charcoal and oxidizing formation silica-alumina carbon black;
(3) mix:Mixture in step (1) is mixed with the silica-alumina carbon black in step (2), at the same add antioxidant,
Resin, age resistor, stir;
(4) vulcanize:Mixture in step (3) is inserted in vulcanization bed, sulphur is added and is vulcanized.
Embodiment two:
A kind of vulcanized polyethylene resistant tensile cable, include according to weight composition point:
55 parts of rubber, 50 parts of vulcanized polyethylene, 10 parts of tetrafluoroethene, 23 parts of magnesia powder, 20 parts of oxide powder and zinc, sial charcoal
15 parts, 13 parts of calcium hydroxide, 13 parts of sulphur, 8 parts of oxidant, 9 parts of antioxidant, 10 parts of resin, 6 parts of age resistor.
Described rubber includes natural rubber, butadiene-styrene rubber, butadiene rubber, epoxy natural rubber, fluorubber, silicon rubber
Two kinds in glue, nitrile rubber, ethylene propylene diene rubber, neoprene and two or more arbitrary compositions.
Described resin includes tackifying resin, phenolic resin, epoxy resin, one kind or any combination in organic siliconresin
Thing.
Described age resistor is using ditert-butylhydro quinone.
Described antioxidant is antioxidant 246.
Described oxidant is air, steam, one kind or any combination in hydrogen peroxide.
A kind of manufacture method of vulcanized polyethylene resistant tensile cable, it is comprised the following steps that:
(1) it is kneaded:Integrally, then at high temperature under high pressure rubber, tetrafluoroethene, vulcanized polyethylene are kneaded at high temperature
Magnesia powder, oxide powder and zinc, calcium hydroxide are added, stirred;
(2) carbon black:While step (1) is carried out, by sial charcoal and oxidizing formation silica-alumina carbon black;
(3) mix:Mixture in step (1) is mixed with the silica-alumina carbon black in step (2), at the same add antioxidant,
Resin, age resistor, stir;
(4) vulcanize:Mixture in step (3) is inserted in vulcanization bed, sulphur is added and is vulcanized.
Embodiment three:
A kind of vulcanized polyethylene resistant tensile cable, include according to weight composition point:
50 parts of rubber, 50 parts of vulcanized polyethylene, 8 parts of tetrafluoroethene, 20 parts of magnesia powder, 20 parts of oxide powder and zinc, sial charcoal
18 parts, 10 parts of calcium hydroxide, 13 parts of sulphur, 9 parts of oxidant, 8 parts of antioxidant, 10 parts of resin, 7 parts of age resistor.
Described rubber includes natural rubber, butadiene-styrene rubber, butadiene rubber, epoxy natural rubber, fluorubber, silicon rubber
Two kinds in glue, nitrile rubber, ethylene propylene diene rubber, neoprene and two or more arbitrary compositions.
Described resin includes tackifying resin, phenolic resin, epoxy resin, one kind or any combination in organic siliconresin
Thing.
Described age resistor is using ditert-butylhydro quinone.
Described antioxidant is antioxidant 246.
Described oxidant is air, steam, one kind or any combination in hydrogen peroxide.
A kind of manufacture method of vulcanized polyethylene resistant tensile cable, it is comprised the following steps that:
(1) it is kneaded:Integrally, then at high temperature under high pressure rubber, tetrafluoroethene, vulcanized polyethylene are kneaded at high temperature
Magnesia powder, oxide powder and zinc, calcium hydroxide are added, stirred;
(2) carbon black:While step (1) is carried out, by sial charcoal and oxidizing formation silica-alumina carbon black;
(3) mix:Mixture in step (1) is mixed with the silica-alumina carbon black in step (2), at the same add antioxidant,
Resin, age resistor, stir;
(4) vulcanize:Mixture in step (3) is inserted in vulcanization bed, sulphur is added and is vulcanized.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
For personnel it should be appreciated that the present invention is not limited to the above embodiments, that described in above-described embodiment and specification is the present invention
Principle, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these change and
Improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its equivalent
Thing defines.
Claims (7)
- A kind of 1. vulcanized polyethylene resistant tensile cable, it is characterised in that:Include according to weight composition point:Rubber 50-60 parts, sulphur Change polyethylene 40-50 parts, tetrafluoroethene 6-10 parts, magnesia powder 20-25 parts, oxide powder and zinc 15-20 parts, sial charcoal 15-20 parts, Calcium hydroxide 10-15 parts, sulphur 10-13 parts, antioxidant 8-10 parts, resin 8-10 parts, oxidant 6-8 parts, age resistor 6-8 parts.
- A kind of 2. vulcanized polyethylene resistant tensile cable according to claim 1, it is characterised in that:Described rubber includes Natural rubber, butadiene-styrene rubber, butadiene rubber, epoxy natural rubber, fluorubber, silicon rubber, nitrile rubber, ethylene-propylene-diene monomer Two kinds in glue, neoprene and two or more arbitrary compositions.
- A kind of 3. vulcanized polyethylene resistant tensile cable according to claim 1, it is characterised in that:Described resin includes One kind or arbitrary composition in tackifying resin, phenolic resin, epoxy resin, organic siliconresin.
- A kind of 4. vulcanized polyethylene resistant tensile cable according to claim 1, it is characterised in that:Described age resistor is adopted It is ditert-butylhydro quinone.
- A kind of 5. vulcanized polyethylene resistant tensile cable according to claim 1, it is characterised in that:Described antioxidant is Antioxidant 246.
- A kind of 6. vulcanized polyethylene resistant tensile cable according to claim 1, it is characterised in that:Described oxidant is One kind or any combination in air, steam, hydrogen peroxide.
- 7. using a kind of manufacture method of vulcanized polyethylene resistant tensile cable any one of claim 1 to 6, it is special Sign is:It is comprised the following steps that:(1) it is kneaded:Rubber, tetrafluoroethene, vulcanized polyethylene are kneaded integrally, then at high temperature under high pressure by oxygen at high temperature Change magnesium powder, oxide powder and zinc, calcium hydroxide to add, stir;(2) carbon black:While step (1) is carried out, by sial charcoal and oxidizing formation silica-alumina carbon black;(3) mix:Mixture in step (1) is mixed with the silica-alumina carbon black in step (2), at the same add antioxidant, resin, Age resistor, stir;(4) vulcanize:Mixture in step (3) is inserted in vulcanization bed, sulphur is added and is vulcanized.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107987359A (en) * | 2017-12-18 | 2018-05-04 | 安徽明福电缆有限公司 | A kind of preparation method of anticracking high temperature resistant twisted polyethylene cable sheath |
CN108314807A (en) * | 2018-03-12 | 2018-07-24 | 合肥铭佑高温技术有限公司 | A kind of fire resistant rubber material and preparation method thereof |
Citations (2)
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CN103360661A (en) * | 2013-06-05 | 2013-10-23 | 安徽荣玖光纤通信科技有限公司 | Oil-resistant cable sheath material |
CN103539981A (en) * | 2013-10-25 | 2014-01-29 | 安徽文峰电子科技集团有限公司 | Multi-rubber blended ozone-resistant oil-resistant cable material |
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2017
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Publication number | Priority date | Publication date | Assignee | Title |
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CN103360661A (en) * | 2013-06-05 | 2013-10-23 | 安徽荣玖光纤通信科技有限公司 | Oil-resistant cable sheath material |
CN103539981A (en) * | 2013-10-25 | 2014-01-29 | 安徽文峰电子科技集团有限公司 | Multi-rubber blended ozone-resistant oil-resistant cable material |
Non-Patent Citations (1)
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107987359A (en) * | 2017-12-18 | 2018-05-04 | 安徽明福电缆有限公司 | A kind of preparation method of anticracking high temperature resistant twisted polyethylene cable sheath |
CN107987359B (en) * | 2017-12-18 | 2020-09-29 | 安徽明福电缆有限公司 | Preparation method of anti-cracking high-temperature-resistant cross-linked polyethylene cable sheath |
CN108314807A (en) * | 2018-03-12 | 2018-07-24 | 合肥铭佑高温技术有限公司 | A kind of fire resistant rubber material and preparation method thereof |
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