CN106396630A - Crushed stone-type alumina light ceramsite with air purifying function - Google Patents

Crushed stone-type alumina light ceramsite with air purifying function Download PDF

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Publication number
CN106396630A
CN106396630A CN201610831115.4A CN201610831115A CN106396630A CN 106396630 A CN106396630 A CN 106396630A CN 201610831115 A CN201610831115 A CN 201610831115A CN 106396630 A CN106396630 A CN 106396630A
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aluminum oxide
gravel
air purification
purification function
light ceramic
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袁欣
许庆华
焦文涛
金白云
吴青
吴一青
蒋文兰
许盛英
袁长兵
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Abstract

The invention discloses a crushed stone-type alumina light ceramsite with an air purifying function. Ingredients of the ceramsite comprise attapulgite clay powder with an air purifying function, alumina, activated carclazyte residues, white carbon black, sodium aluminate, hollow beads, calcined gypsum powder, sodium dodecyl sulfate and a scrubable alumina photocatalyst spray liquid. Through ingredient stirring, extruded granulation, drying, crushing, screening, roasting, thermal insulation, screening, immersion, drying, screening and sealed packaging, the crushed stone-type alumina light ceramsites with an air purifying function are obtained. The crushed stone-type alumina light ceramsite with an air purifying function has a specific surface area, low bulk density, light weight, high strength, high moisture absorption and excellent adsorption and purification performances, is suitable for being used in a room, a furniture cabinet, a vehicle, a ship or other buildings, has effects of adsorption and degradation of pollutants such as formaldehyde, ammonia, benzene and TVOC and realizes the purpose of purifying the air for a long time.

Description

Gravel has the aluminum oxide light ceramic of air purification function
Technical field
The present invention relates to haydite is and in particular to a kind of gravel has the aluminum oxide light ceramic of air purification function.
Background technology
The air purifying preparation supplied in the market has following several types:Absorbent-type air purifying preparation, covering type taste removal Product and Breakdown type taste removal product.Absorbent-type air purifying preparation is using materials such as activated carbon, bamboo charcoal, molecular sieve, mineral matters The performances such as physical absorption, chemisorbed, catalysis oxidation and reduction remove the purification product of pollutant;Covering type taste removal product is profit Cover the various peculiar smell of in the air with the fragrance of aromatic hydrocarbon, peculiar smell is not in fact removed, simply by a lot of air fresheners With a kind of odor type, peculiar smell is covered;Breakdown type air clearing product is more rare on the market.
Chinese patent Authorization Notice No.:CN 103861421 B, authorized announcement date:On November 18th, 2015, entitled " one Kind of air purifying preparation ", discloses that " a kind of air purifying preparation, its preparing raw material is contained by mass fraction:Diatomite in powder, zeolite powder, Medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder, and adopt and prepare with the following method:1) by diatomite Powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder mixing;2) by step 1) gained mix Compound granulates;3) baking step 2) granulation after gained mixture.The air purifying preparation specific surface that the present invention is obtained is big and uniform, Good to the adsorption-decomposition function effect of in the air harmful substance, it is for interior, the depollution of environment of the closing space such as in-car and various sky The ideal chose material of gas purifier ".
The weak point of above-mentioned patent is:(1) diatomite in powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder and sea Afrodite powder, not through necessary modification, is difficult to really play the effect of its effective purify air.(2) gained mixed powder Granulated using granulating disc after the clear water stirring adding 20-30%, be a kind of circular granular of a diameter of 1.2-1.6mm.Should Mixed powder itself normal moisture content of invention is more than 10%, and the circular granular moisture content after the granulation that adds water will be greater than 30%, and Drying temperature, in the case of less than 100 DEG C, is difficult to dry circular granular in 3 hours.Diatomite, zeolite, medical stone, After tourmaline and sepiolite carry out heat treatment process at 250~450 DEG C, its absorption property is relatively good, and this is the technology of this area Personnel know altogether;The circular granular of this invention is dried in the case of less than 100 DEG C, can not effectively improve the work of purify air With, and the compression strength of circular granular also very little, gently one pinched with hand, circular granular will be crumbed as powdered.
On market, the spheroidal air purifying preparation of supply, molecular sieve, drier or other spherical granules, were granulating It is first powdery dispensing to be processed into the bead that a kind of diameter is less than 0.5 millimeter in journey, then by the vaporific aqueous solution preparing, spray Spill in the bead in on-stream comminutor, then powdery dispensing is trickled down on the surface of moistening bead, through being repeated several times Spray the vaporific aqueous solution and trickle down on the surface of moistening bead by powdery dispensing, through the parcel of layer upon layer, bead Volume constantly increase, be finally completed the overall process of granulation, be prepared into a kind of spherical granules, due to spherical granules internal junction Structure is very closely knit, greatly reduces the effective specific surface area of spherical granules, the proportion of spherical granules and bulk density all than Larger, directly influence the absorption purifying effect of spherical granules.
Content of the invention
The purpose of the present invention is to overcome weak point in prior art, provides a kind of gravel to have air purification function Aluminum oxide light ceramic.
Gravel has the dispensing of the aluminum oxide light ceramic of air purification function by having the concavo-convex of air purification function Excellent potter's clay powder, aluminum oxide, active white clay waste slag, white carbon, precipitated calcium carbonate, light magnesium oxide, sodium aluminate, cenosphere, ripe Land plaster, expanded perlite, lauryl sodium sulfate and washable aluminum oxide photocatalytic spray liquid composition.
Gravel has the production method of the aluminum oxide light ceramic of air purification function:Gravel had purify air The dispensing of the aluminum oxide light ceramic semi-finished product of function is stirred, extruder grain, drying, broken, screening, roasting, insulation, sieve Divide, soak, drying, sieving, packing the aluminum oxide light ceramic for gravel with air purification function.
The concave convex rod potter's clay powder with air purification function is by high viscous Concave-convex clay rod, attapulite constant humidity amendment, sky So mineral adsorption filtering agent, cacumen biotae, aluminium silicate fiber peacekeeping polyacrylamide composition, has preferable caking property, plasticity, touches Denaturation, fire resistance and heat endurance, can effectively adsorb the harmful substances such as formaldehyde in air, ammonia and benzene, environmental protection and enhancement People's is healthy, and the present invention is from grain fineness≤0.074 millimeter of the concave convex rod potter's clay powder with air purification function.
Aluminum oxide is a kind of white-amorphous powder, and it is extremely hard that aluminum oxide is insoluble in water, odorless, tasteless, matter, the easy moisture absorption and Not deliquescence, has strong absorption affinity and catalysis activity, has selection adsorptivity to the moisture of gas, vapor and some liquid, this Invention is from grain fineness≤0.074 millimeter of aluminum oxide.
Atlapulgite is a kind of odorless, tasteless, nontoxic white or cream-coloured powder or particle, and the activity after decolouring is white Soil loses activity and becomes active white clay waste slag, some oily factories all by these active white clay waste slags abandon, if cannot and When process, produces after the organic fermentation of lipid in active white clay waste slag and goes mouldy and stench, the not only wasting of resources, pollute environment and Groundwater quality, and fire hazardous, will cause certain loss to society and enterprise;The present invention selects active white clay waste slag Grain fineness≤0.149 millimeter.
White carbon is a kind of ultra tiny inorganic porous property material, due to its particle diameter very little, has that specific surface area is big, surface is inhaled Attached power is strong, chemical purity is high, dispersive property is good, superior stability, reinforcing, thickening property, adhesive force and thixotropy etc. are special Performance.
Precipitated calcium carbonate fine particles, surface are rougher, and specific surface area is big, and precipitated calcium carbonate also has and do not settle, easily point Dissipate, the characteristic such as good luster, the present invention selects grain fineness≤0.074 millimeter of precipitated calcium carbonate.
Light magnesium oxide is the white loose unformed powder of lightweight, odorless, tasteless, and nontoxic, volume shared by light magnesium oxide is about About the three times of heavy-burned magnesia, there are extremely fireproof heat-insulating property, reinforcing agent, adhesive, the present invention selects light magnesium oxide Grain fineness≤0.074 millimeter.
Sodium aluminate also known as sodium metaaluminate, are a kind of general chemical article, white, odorless, tasteless, in alkaline solid, Easily absorb moisture content and carbon dioxide in atmosphere, the present invention selects grain fineness≤0.074 millimeter of sodium aluminate.
Natural dihydrate gypsum is also called gypsum, through calcining, levigate obtain gesso, the plaster of paris has more micropore Structure, is allowed to have excellent sound insulation, heat-insulated and fire protecting performance, and the present invention selects grain fineness≤0.074 millimeter of gesso.
Cenosphere outward appearance is canescence, is a kind of loose, good fluidity powder body material, cenosphere proportion is little, table Face is smooth, intensity is big, easily disperse, the present invention select the grain fineness of cenosphere≤≤ 0.149 millimeter.
Perlite is expanded and becomes a kind of lightweight, multifunctional novel shaped material, have that apparent density is light, thermal conductivity factor is low, The features such as chemical stability is good, the present invention selects grain fineness≤0.074 millimeter of expanded perlite.
Lauryl sodium sulfate is white or faint yellow powdery, is dissolved in water, insensitive to alkali and hard water, has decontamination, breast Change and excellent foaming power, be a kind of nontoxic anion surfactant.
Washable aluminum oxide photocatalytic spray liquid is sprayed on building or decorative material surface, under the irradiation of light, permissible Continual absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene,toluene,xylene, TVOC, and there is extremely strong sterilization, remove Smelly, mould proof, anti-fouling and self-cleaning and the function of purify air.
The technical scheme is that:
1st, gravel has the dispensing of the aluminum oxide light ceramic of air purification function and is made up of following component by weight percentage: Gravel has the aluminum oxide light ceramic semi-finished product 55~95% of air purification function and washable aluminum oxide photocatalytic spray Liquid 5~45%.
2nd, gravel has the production method of the aluminum oxide light ceramic of air purification function:(1) first by washable aluminum oxide Photocatalytic spray liquid is put in fermentation vat, then by gravel have air purification function aluminum oxide light ceramic semi-finished product slow Add in the washable aluminum oxide photocatalytic spray liquid in fermentation vat, gravel has the aluminum oxide Lightweight ceramic of air purification function Micropore inside and outside grain semi-finished product, constantly sucks washable aluminum oxide photocatalytic spray liquid, until in saturation state;(2) from immersion Take out in pond and be filled the gravel of washable aluminum oxide photocatalytic spray liquid there is the aluminum oxide light ceramic of air purification function, It is transported in low temperature rotary drying oven and is dried, drying temperature controls at 150~180 DEG C, and drying time controls 1~3 Hour;(3) the aluminum oxide light ceramic gravel after low temperature drying being had air purification function is transported in vibratory sieve and carries out Screening, weeds out the powder less than 0.25 millimeter, packs the aluminum oxide Lightweight ceramic for gravel with air purification function The finished product of grain.
3rd, gravel have the dispensing of the aluminum oxide light ceramic semi-finished product of air purification function by weight percentage by under Row group is grouped into:There is the concave convex rod potter's clay powder 10~45% of air purification function, aluminum oxide 5~25%, active white clay waste slag 2 ~10%, white carbon 1~8%, precipitated calcium carbonate 1~5%, light magnesium oxide 1~5%, sodium aluminate 0.5~5%, cenosphere 0.5~5%, gesso 0.5~5%, expanded perlite 0.5~5%, lauryl sodium sulfate 0.5~5% and water 10~ 40%.
4th, gravel has the production method of the aluminum oxide light ceramic semi-finished product of air purification function:(1) gravel is had In the stirring mixer that the dispensing input having the aluminum oxide light ceramic semi-finished product of air purification function has operated, stirring mixing There is the mixture of the aluminum oxide light ceramic of air purification function for gravel;(2) gravel had air purification function The mixture of aluminum oxide light ceramic is transported in Squeezinggranulator, and extruder grain is a kind of cylindrical particle, (3) by cylinder Particle is transported in swinging drying oven and is dried, and drying temperature controls at 200~250 DEG C, and drying time controls 1~4 Hour;(4) the cylindrical particle after drying is transported in disintegrating machine and is crushed, it is irregular broken for carrying out screening after crushing Stone shape particle, the grain fineness of gravel particle controls at 0.5~6 millimeter;(5) by the irregular gravel particle after screening Input swinging roasting kiln roasting, at 650~750 DEG C, roasting time controlled at 1~3 hour the temperature control of combustion chamber;⑹ To be incubated in irregular gravel particle input stainless steel cylinder storehouse after roasting, temperature retention time controlled at 8~24 hours;⑺ Irregular gravel particle after insulation cooling is transported in vibratory sieve and is sieved, weed out the powdery less than 0.25 millimeter After thing, it is the aluminum oxide light ceramic semi-finished product that gravel has air purification function.
The production method the 5th, with the concave convex rod potter's clay powder of air purification function is:(1) will there is the recessed of air purification function Pulverized in input pulverizer after the dispensing mixing of convex rod potter's clay powder, the compound particles fineness after pulverizing is less than 0.5 millimeter; (2) pulverulent mixture is added and soak in old pond that to carry out soaking old process with water be semi-finished product, soak old time control and exist 7~30 days;(3) semi-finished product are inputted in vacuum-extruder and be squeezed into cylindrical bar, the diameter control of cylindrical bar exists 2~10 millimeters;(4) cylindrical bar is input to cement threshing ground and carries out airing, the cylindrical bar water content after airing is little In 15%;(5) abrasive dust will be carried out for powder in the cylindrical bar input grinding machine after airing, the grain fineness of powder is little In 0.074 millimeter.
The dispensing with the concave convex rod potter's clay powder of air purification function is made up of following component by weight percentage:High viscous recessed Convex rod stone clay 35~60%, attapulite constant humidity amendment 10~35%, natural-minerals adsorptive filter medium 5~20%, cacumen biotae 2 ~15%, alumina silicate fibre 1~5% and polyacrylamide 0.1~3%.
The concave convex rod potter's clay powder with air purification function is applied on 2 25th, 2011 using by the present inventor " having the concave convex rod potter's clay powder of air purification function ", Chinese patent Authorization Notice No. is:CN 102173743 B, Granted publication Day:On July 25th, 2012.
High viscous Concave-convex clay rod is to be glued using the attapulgite that the processing technology improving viscosity of attapulgite clay produces Soil, from the Concave-convex clay rod of mining area exploitation, needs the weathering through 30~120 days;Modification processing method is:With weight Percentage calculates, and takes the Concave-convex clay rod after weathering 94~98%, is uniformly added into 2~6% sodium carbonate, common input leaching In bubble pond, clear water is added to carry out soaking ageing, soak time is 72~120 hours;Take the Concave-convex clay rod after immersion, input It is stirred in mixer, and by the Concave-convex clay rod after stirring, is extruded into thin slice through extruder, its THICKNESS CONTROL is 0.5~2 Millimeter, Concave-convex clay rod thin slice carries out airing, the Concave-convex clay rod thin slice after airing, its water content≤15%;Dispensing Calculated in weight percent:Concave-convex clay rod 94~98% after airing, high hydroscopic resin 0.5~5% and cellulose 0.5~ 3%, above-mentioned dispensing is stirred, after stirring, in input grinding machine, carries out abrasive dust, grain fineness≤0.074 millimeter;
Above-mentioned production technology is " to improve viscosity of attapulgite clay using filed in 20 days June in 2005 of the present inventor Processing technology ", Chinese patent Authorization Notice No. is:CN 1317067C, authorized announcement date:On May 23rd, 2007.
The detection method of high viscous Concave-convex clay rod:Take 28.0g Concave-convex clay rod powder sample, add homogenizer In suspension cup, add 372g water, suspension cup is placed on homogenizer, stir under 11000 revs/min of rotating speed 20 minutes, then by the beaker that high-speed stirred sample suspension pours 250mL into, tested using NDJ-1 type rotation viscometer The viscosity of suspension, tested viscosity value >=2200 mPa s is high viscous Concave-convex clay rod.
6th, the dispensing of washable aluminum oxide photocatalytic spray liquid is made up of following component by weight percentage:Aluminum oxide 5~ 12%th, the Concave-convex clay rod 4~10% after being acidified, high viscous Concave-convex clay rod 2~8%, nano titanium oxide 1~5%, white Carbon black 1~5%, nano silver-supported antibacterial powder 0.5~5%, nano magnesia 0.5~5%, nano zirconium dioxide 0~5%, nanometer Zinc oxide 0~5%, polyvinyl alcohol 0.5~5%, polyethylene glycol 0.1~3%, dimethyl silicone polymer 0.1~2% and deionization Water 50~82%;
The production method of washable aluminum oxide photocatalytic spray liquid:(1) the dispensing of washable aluminum oxide photocatalytic spray liquid is inputted Carry out strong stirring, dispersion and emulsification in the high speed dispersor having operated, be then ground to erasable in input three-roll grinder Wash the semi-finished product of aluminum oxide photocatalytic spray liquid;(2) the semi-finished product of washable aluminum oxide photocatalytic spray liquid are inputted colloid mill In, carry out again disperseing, emulsify, pulverize, homogeneous, froth breaking and grinding;(3) the washable aluminum oxide photocatalytic spray liquid after grinding Granularity≤0.01 millimeter of middle solid particle, canned for washable aluminum oxide photocatalytic spray liquid.
Washable aluminum oxide photocatalytic spray liquid is using by " washable filed in the applicant on 07 29th, 2016 Aluminum oxide photocatalytic spray liquid ", Chinese Patent Application No. is:201610613139.2.
Heretofore described PCm is weight percentage.
Having in the concave convex rod potter's clay powder of air purification function in the present invention has substantial amounts of micropore and activated carbon, has relatively Caking property well, plasticity, thixotropy, fire resistance and heat endurance, can effectively adsorb formaldehyde in air, ammonia and benzene etc. and be harmful to Material.
It is primary raw material using the concave convex rod potter's clay powder with air purification function, produce gravel and there is purify air work( The aluminum oxide light ceramic of energy, has given full play to the effective efficiency of the concave convex rod potter's clay powder with air purification function.
Aluminum oxide has strong absorption affinity and catalysis activity, has selection absorption to the moisture of gas, vapor and some liquid Ability, can improve the absorption property of aluminum oxide light ceramic and the granule strength that gravel has air purification function.
In roasting process, the lipid in active white clay waste slag and organic common gravel of participating in have active white clay waste slag Have the roasting of the aluminum oxide light ceramic of air purification function, improve the heat of combustion-gas flow, not only can save energy, also The inside beneficial to gravel with the aluminum oxide light ceramic of air purification function can be grilled thoroughly completely, increase gravel and have purification The porosity within aluminum oxide light ceramic of air function.
White carbon, light magnesium oxide and sodium aluminate can improve the aluminum oxide light ceramic that gravel has air purification function Adsorption capacity and increase gravel have air purification function aluminum oxide light ceramic granule strength.
Gravel has in the dispensing of aluminum oxide light ceramic semi-finished product of air purification function and adopts dodecyl sulphate Sodium, is conducive to produce substantial amounts of foam in stirring mixed process, to increase the oxidation that gravel has air purification function Micropore within aluminium light ceramic.
Precipitated calcium carbonate, gesso, cenosphere and expanded perlite can reduce gravel and have air purification function Aluminum oxide light ceramic bulk density, increase gravel and there is the hole within aluminum oxide light ceramic of air purification function Gap rate.
The gravel sucking washable aluminum oxide photocatalytic spray liquid has the aluminum oxide light ceramic of air purification function Semi-finished product, have the aluminum oxide light ceramic of air purification function, under the irradiation of light, gravel after drying for gravel The aluminum oxide light ceramic with air purification function can continual absorption and the dirt such as degradation of formaldehyde, ammonia, benzene and TVOC Dye thing, and there is the function of extremely strong sterilized, deodorant, mould proof, anti-fouling and self-cleaning and purify air.
The aluminum oxide light ceramic cylindrical particle moisture content that gravel after extruder grain has air purification function is big In 30%, it is delivered directly to swinging roaster high temperature roasting, in high-temperature calcination process, the surface of cylindrical particle is first opened Beginning sintering curing, and the water vapour of inside is difficult to rapid evaporation out, cylindrical particle will produce explosion, nor can be by Grill thoroughly inside cylindrical particle.
The present invention first cylindrical particle is transported in swinging drying oven and slowly carries out prebake, and drying temperature controls 150~250 DEG C, then the cylindrical particle after drying is transported in disintegrating machine and is crushed, broken after carry out screening for not advising Gravel particle then, finally by the irregular gravel particle input swinging roasting kiln roasting after screening, combustion chamber Temperature control at 650~750 DEG C it can be ensured that irregular gravel particle is grilled thoroughly in roasting process, and can also Save more than 25% fuel.
It is still up to more than 600 DEG C in temperature in irregular gravel particle after roasting, will be irregular after roasting Gravel particle input stainless steel cylinder storehouse in be incubated, it is possible to use the waste heat of itself, continue to irregular gravel Grain uniformly heats, not only can ensure that will grill thoroughly completely inside irregular gravel particle moreover it is possible to play uniformly dispersing heat and The effect of slow cooling, to improve the inherent quality that gravel has the aluminum oxide light ceramic semi-finished product of air purification function.
The aluminum oxide light ceramic semi-finished product that gravel has air purification function are a kind of irregular gravel particles, There is substantial amounts of micropore surface and inside, and are a kind of open pores, open pore not only each other insertion also communicate with the external world, increased The effective ratio area of haydite, intensity and reduce bulk density, and the absorption of haydite and net can be greatly improved in actual use Change the effect of air.
The aluminum oxide light ceramic that gravel has air purification function has that specific surface area is big, bulk density is low, lightweight Intensity is good, hydroscopicity is high, absorption and the superior feature of purifying property, and gravel has the aluminum oxide Lightweight ceramic of air purification function Grain does not have dust in the dry state, can adsorb the pollutants such as the substantial amounts of formaldehyde of in the air, ammonia, benzene and TVOC, soak all the year round Also disintegration will not be produced in water.
The gravel sucking washable aluminum oxide photocatalytic spray liquid has the aluminum oxide light ceramic of air purification function, It is to be degraded on the basis of absorption, improve the aluminum oxide light ceramic absorption that gravel has air purification function comprehensively Ability with purify air.
The aluminum oxide light ceramic that gravel has air purification function uses through long, adsorbs a certain amount of dirt After dye thing, aluminum oxide photocatalyst degradation capability begins to decline, and can present saturation state, using 90~100 DEG C of hot water, by The aluminum oxide light ceramic that gravel through being in saturation state has air purification function is backwashed, and cleaning sticks to broken Stone shape has aluminum oxide photo-catalyst film or the particulate inside and outside the aluminum oxide light ceramic of air purification function, after cleaning up, By the new washable aluminum oxide photocatalytic spray liquid prepared, spray or be dipped into the aluminum oxide that gravel has air purification function Inside and outside light ceramic, and dried or dried, can continue to play the aluminum oxide lightweight that gravel has air purification function The effect of haydite purify air.
The particulate waste residue washing down can be used for planting bracketplant, aloe, sansevieria trifasciata, pocket coconut, ivy and epipremnum aureum In green plants, the interior thing that stays not decomposed of particulate waste residue slowly will be adsorbed by green plantss such as bracketplant, aloe, sansevieria trifasciatas Decompose, new pollution will not be produced.
Gravel have air purification function aluminum oxide light ceramic be applied to placement indoors, furniture cabinet, vehicle, In aircraft, ship, subway, tunnel, highway sound panel, military installations, ornament materials, public place or other building, Carry out absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene, TVOC, to reach the purpose of long-time purify air.
Specific embodiment
With reference to embodiment, the invention will be further described:
1st, gravel has the dispensing of the aluminum oxide light ceramic of air purification function and is made up of following component by weight percentage: Gravel has the aluminum oxide light ceramic semi-finished product 88% of air purification function and washable aluminum oxide photocatalytic spray liquid 12%.
2nd, gravel has the production method of the aluminum oxide light ceramic of air purification function:(1) first by washable aluminum oxide Photocatalytic spray liquid is put in fermentation vat, then by gravel have air purification function aluminum oxide light ceramic semi-finished product slow Add in the washable aluminum oxide photocatalytic spray liquid in fermentation vat, gravel has the aluminum oxide Lightweight ceramic of air purification function Micropore inside and outside grain semi-finished product, constantly sucks washable aluminum oxide photocatalytic spray liquid, until in saturation state;(2) from immersion Take out in pond and be filled the gravel of washable aluminum oxide photocatalytic spray liquid there is the aluminum oxide light ceramic of air purification function, It is transported in low temperature rotary drying oven and is dried, drying temperature controls at 160~170 DEG C, and drying time controls little 2 When;(3) the aluminum oxide light ceramic gravel after low temperature drying being had air purification function is transported in vibratory sieve and is sieved Point, weed out the powder less than 0.25 millimeter, pack the aluminum oxide light ceramic for gravel with air purification function Finished product.
3rd, gravel have the dispensing of the aluminum oxide light ceramic semi-finished product of air purification function by weight percentage by under Row group is grouped into:There is the concave convex rod potter's clay powder 38% of air purification function, aluminum oxide 12%, active white clay waste slag 4%, hard charcoal Black 4%, precipitated calcium carbonate 3%, light magnesium oxide 2%, sodium aluminate 2%, cenosphere 1%, gesso 1%, expanded pearlite Rock 1%, lauryl sodium sulfate 2% and water 30%.
4th, gravel has the production method of the aluminum oxide light ceramic semi-finished product of air purification function:(1) gravel is had In the stirring mixer that the dispensing input having the aluminum oxide light ceramic semi-finished product of air purification function has operated, stirring mixing There is the mixture of the aluminum oxide light ceramic of air purification function for gravel;(2) gravel had air purification function The mixture of aluminum oxide light ceramic is transported in Squeezinggranulator, and extruder grain is a kind of cylindrical particle, (3) by cylinder Particle is transported in swinging drying oven and is dried, and drying temperature controls at 220~230 DEG C, and drying time controls little 1 When;(4) the cylindrical particle after drying is transported in disintegrating machine and is crushed, carrying out screening after crushing is irregular rubble Shape particle, the grain fineness of gravel particle controls at 0.5~5 millimeter;(5) will be defeated for the irregular gravel particle after screening Enter swinging roasting kiln roasting, the temperature control of combustion chamber at 650~660 DEG C, roasting time controlled at 1 hour;(6) will roast It is incubated in irregular gravel particle input stainless steel cylinder storehouse after burning, temperature retention time controlled at 16 hours;(7) will be incubated Irregular gravel particle after cooling is transported in vibratory sieve and is sieved, after weeding out the powder less than 0.25 millimeter, There are the aluminum oxide light ceramic semi-finished product of air purification function for gravel.

Claims (3)

1. a kind of gravel has the aluminum oxide light ceramic of air purification function it is characterised in that gravel has purification sky The dispensing of the aluminum oxide light ceramic of airway dysfunction is made up of following component by weight percentage:Gravel has air purification function Aluminum oxide light ceramic semi-finished product 55~95% and washable aluminum oxide photocatalytic spray liquid 5~45%;
Described gravel has the dispensing of the aluminum oxide light ceramic semi-finished product of air purification function by weight percentage by following Group is grouped into:Have the concave convex rod potter's clay powder 10~45% of air purification function, aluminum oxide 5~25%, active white clay waste slag 2~ 10%th, white carbon 1~8%, precipitated calcium carbonate 1~5%, light magnesium oxide 1~5%, sodium aluminate 0.5~5%, cenosphere 0.5~5%, gesso 0.5~5%, expanded perlite 0.5~5%, lauryl sodium sulfate 0.5~5% and water 10~ 40%;
Gravel has the production method of the aluminum oxide light ceramic semi-finished product of air purification function:(1) gravel had purification In the stirring mixer that the dispensing input of the aluminum oxide light ceramic semi-finished product of air function has operated, stirring is mixed into rubble Shape has the mixture of the aluminum oxide light ceramic of air purification function;(2) gravel had the aluminum oxide of air purification function The mixture of light ceramic is transported in Squeezinggranulator, and extruder grain is a kind of cylindrical particle, (3) that cylindrical particle is defeated Deliver in swinging drying oven and dried, drying temperature controls at 200~250 DEG C, and drying time controlled at 1~4 hour;⑷ Cylindrical particle after drying is transported in disintegrating machine and is crushed, carrying out screening after crushing is irregular gravel Grain, the grain fineness of gravel particle controls at 0.5~6 millimeter;(5) the irregular gravel particle after screening is inputted back Rotatable roasting kiln roasting, at 650~750 DEG C, roasting time controlled at 1~3 hour the temperature control of combustion chamber;(6) by roasting It is incubated in irregular gravel particle input stainless steel cylinder storehouse afterwards, temperature retention time controlled at 8~24 hours;(7) will be incubated Irregular gravel particle after cooling is transported in vibratory sieve and is sieved, after weeding out the powder less than 0.25 millimeter, There are the aluminum oxide light ceramic semi-finished product of air purification function for gravel;
The dispensing of described washable aluminum oxide photocatalytic spray liquid is made up of following component by weight percentage:Aluminum oxide 5~ 12%th, the Concave-convex clay rod 4~10% after being acidified, high viscous Concave-convex clay rod 2~8%, nano titanium oxide 1~5%, white Carbon black 1~5%, nano silver-supported antibacterial powder 0.5~5%, nano magnesia 0.5~5%, nano zirconium dioxide 0~5%, nanometer Zinc oxide 0~5%, polyvinyl alcohol 0.5~5%, polyethylene glycol 0.1~3%, dimethyl silicone polymer 0.1~2% and deionization Water 50~82%;
The production method of washable aluminum oxide photocatalytic spray liquid:(1) the dispensing of washable aluminum oxide photocatalytic spray liquid is inputted Carry out strong stirring, dispersion and emulsification in the high speed dispersor having operated, be then ground to erasable in input three-roll grinder Wash the semi-finished product of aluminum oxide photocatalytic spray liquid;(2) the semi-finished product of washable aluminum oxide photocatalytic spray liquid are inputted colloid mill In, carry out again disperseing, emulsify, pulverize, homogeneous, froth breaking and grinding;(3) the washable aluminum oxide photocatalytic spray liquid after grinding Granularity≤0.01 millimeter of middle solid particle, canned for washable aluminum oxide photocatalytic spray liquid.
2. gravel according to claim 1 has the aluminum oxide light ceramic of air purification function it is characterised in that having There are grain fineness≤0.074 millimeter of the concave convex rod potter's clay powder of air purification function, grain fineness≤0.074 milli of aluminum oxide Rice, grain fineness≤0.149 millimeter of active white clay waste slag, grain fineness≤0.074 millimeter of precipitated calcium carbonate, lightweight aoxidizes Grain fineness≤0.074 millimeter of magnesium, grain fineness≤0.074 millimeter of sodium aluminate, grain fineness≤0.149 of cenosphere Millimeter, grain fineness≤0.074 millimeter of gesso, grain fineness≤0.074 millimeter of expanded perlite.
3. gravel according to claim 1 has the aluminum oxide light ceramic of air purification function it is characterised in that broken Stone shape has the production method of the aluminum oxide light ceramic of air purification function:(1) first by washable aluminum oxide photocatalytic spray liquid Put in fermentation vat, then the aluminum oxide light ceramic semi-finished product that gravel is had air purification function are slowly added in fermentation vat Washable aluminum oxide photocatalytic spray liquid in, gravel has inside and outside the aluminum oxide light ceramic semi-finished product of air purification function Micropore, constantly suck washable aluminum oxide photocatalytic spray liquid, until in saturation state;(2) take out from fermentation vat and be filled The gravel of washable aluminum oxide photocatalytic spray liquid has the aluminum oxide light ceramic of air purification function, is transported to low temperature and returns Dried in rotatable drying oven, drying temperature controls at 150~180 DEG C, and drying time controlled at 1~3 hour;(3) by low temperature The aluminum oxide light ceramic that gravel after drying has air purification function is transported in vibratory sieve and is sieved, and weeds out and is less than 0.25 millimeter of powder, packs the finished product of the aluminum oxide light ceramic for gravel with air purification function.
CN201610831115.4A 2016-09-19 2016-09-19 Crushed stone-type alumina light ceramsite with air purifying function Withdrawn CN106396630A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110026060A (en) * 2019-03-19 2019-07-19 甘肃省科学院生物研究所 A kind of biomaterial and its making and use method of degradation of formaldehyde

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Publication number Priority date Publication date Assignee Title
CN102515786A (en) * 2011-11-10 2012-06-27 许庆华 Gravel-shaped attapulgite fireproof ceramsite
CN105413629A (en) * 2015-12-31 2016-03-23 湖北格林森新型建材科技有限公司 Alga-calcium-mineral air purification medium and preparation method and application thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102515786A (en) * 2011-11-10 2012-06-27 许庆华 Gravel-shaped attapulgite fireproof ceramsite
CN105413629A (en) * 2015-12-31 2016-03-23 湖北格林森新型建材科技有限公司 Alga-calcium-mineral air purification medium and preparation method and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110026060A (en) * 2019-03-19 2019-07-19 甘肃省科学院生物研究所 A kind of biomaterial and its making and use method of degradation of formaldehyde

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