CN106431229A - Rubble-shaped molecular sieve lightweight ceramsite with air purification function - Google Patents
Rubble-shaped molecular sieve lightweight ceramsite with air purification function Download PDFInfo
- Publication number
- CN106431229A CN106431229A CN201610831134.7A CN201610831134A CN106431229A CN 106431229 A CN106431229 A CN 106431229A CN 201610831134 A CN201610831134 A CN 201610831134A CN 106431229 A CN106431229 A CN 106431229A
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- Prior art keywords
- molecular sieve
- air purification
- gravel
- purification function
- light ceramic
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Classifications
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- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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Abstract
The invention discloses a rubble-shaped molecular sieve lightweight ceramsite with an air purification function. The technical scheme is characterized in that the ceramsite is prepared from ingredients including attapulgite pottery clay powder with the air purification function, molecular sieves, activated clay waste residues, white carbon black, activated aluminum oxide, sodium aluminate, hollow microspheres, sodium dodecyl sulfate, a scrubbing molecular sieve photocatalyst spraying liquid and the like by stirring, extruding and granulating, drying, crushing, sieving, roasting, standing at the constant temperature, sieving, soaking, drying, sieving, and sealed packaging, and the rubble-shaped molecular sieve lightweight ceramsite with the air purification function is obtained; the rubble-shaped molecular sieve lightweight ceramsite with the air purification function has the characteristics that the specific surface area is large, the bulk density is low, the lightweight strength is good, the moisture rate is high and the adsorption and purification performance is excellent, and is suitable to be placed in houses, furniture, cupboards, vehicles, ships or other buildings for adsorbing and degrading formaldehyde, ammonia, benzene, TVOC and other pollutants to achieve the purpose of long-time air purification.
Description
Technical field
The present invention relates to haydite, and in particular to a kind of gravel has the molecular sieve light ceramic of air purification function.
Background technology
The air purifying preparation that supplies in the market has following several types：Absorbent-type air purifying preparation, covering type taste removal
Product and Breakdown type taste removal product.Absorbent-type air purifying preparation be using materials such as activated carbon, bamboo charcoal, molecular sieve, mineral
The performance such as physical absorption, chemisorbed, catalysis oxidation and reduction removes the purification product of pollutant；Covering type taste removal product is profit
The various abnormal flavour of in the air are covered with the fragrance of aromatic hydrocarbon, abnormal flavour is not in fact removed by a lot of air fresheners, simply
With a kind of odor type, abnormal flavour is covered；Breakdown type air clearing product is more rare on the market.
Chinese patent Authorization Notice No.：103861421 B of CN, authorized announcement date：On November 18th, 2015, entitled " one
Kind of air purifying preparation ", discloses that " a kind of air purifying preparation, its preparing raw material is contained by mass fraction：Diatomite in powder, zeolite powder,
Medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder, and adopt and prepare with the following method：1) by kieselguhr
Powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder, sepiolite powder, titanium dioxide powder mixing；2) by step 1) gained mix
Compound pelletize；3) baking step 2) gained mixture after pelletize.Air purifying preparation specific surface obtained in the present invention is big and uniform,
Good to the adsorption-decomposition function effect of in the air harmful substance, be for interior, the depollution of environment of the closing space such as in-car and various skies
The ideal chose material of gas purifier ".
The weak point of above-mentioned patent is：(1) diatomite in powder, zeolite powder, medical stone powder, tourmaline powder, activated carbon powder and sea
Afrodite powder is not through necessary modification, it is difficult to really play the effect of its effective purify air.(2) gained mixed powder
Granulating disc pelletize is adopted after the clear water stirring for adding 20-30%, be a kind of circular granular of a diameter of 1.2-1.6mm.Should
Itself normal moisture content of the mixed powder of invention is more than 10%, and the circular granular moisture content after the pelletize that adds water will be greater than 30%, and
Drying temperature less than in the case of 100 DEG C, it is difficult to circular granular be dried in 3 hours.Kieselguhr, zeolite, Maifanitum,
After tourmaline and meerschaum carry out heat treatment process at 250～450 DEG C, its absorption property is relatively good, and this is the technology of this area
Personnel know altogether；The circular granular of the invention is dried in the case of less than 100 DEG C, can not effectively improve the work of purify air
With, and the comprcssive strength of circular granular also very little, gently one pinched with handss, circular granular will be crumbed as powdered.
Spheroidal air purifying preparation, molecular sieve, desiccant or the other spherical granules that supplies on market, in pelletize
It is first powdery dispensing to be processed into a kind of bead of diameter less than 0.5 millimeter, then by the vaporific aqueous solution for preparing, spray in journey
Spill in the bead in comminutor in operation, then powdery dispensing is trickled down the surface of the bead in moistening, through being repeated several times
The vaporific aqueous solution of sprinkling and powdery dispensing is trickled down the surface of the bead in moistening, through the parcel of layer upon layer, bead
Volume constantly increase, be finally completed the overall process of pelletize, be prepared into a kind of spherical granules, due to spherical granules internal junction
Structure is very closely knit, greatly reduces the effective specific surface area of spherical granules, the proportion of spherical granules and bulk density all than
Larger, directly influence the absorption purifying effect of spherical granules.
Content of the invention
The purpose of the present invention is to overcome weak point in prior art, provides a kind of gravel and has air purification function
Molecular sieve light ceramic.
Gravel has the dispensing of the molecular sieve light ceramic of air purification function by with the concavo-convex of air purification function
Rod potter's clay powder, molecular sieve, active white clay waste slag, white carbon, precipitated calcium carbonate, light magnesium oxide, activated alumina, sodium aluminate,
Cenosphere, gesso, expanded perlite, sodium lauryl sulphate and washable molecular sieve photocatalytic spray liquid composition.
Gravel has the production method of the molecular sieve light ceramic of air purification function：Gravel had purify air
The dispensing of the molecular sieve light ceramic semi-finished product of function is stirred, extruder grain, drying, broken, screening, roasting, insulation, sieve
Divide, soak, drying, sieving, packing the molecular sieve light ceramic that there is air purification function for gravel.
Attapulgite potter's clay powder with air purification function is by high viscous Concave-convex clay rod, attapulite constant humidity amendment, day
So mineral adsorption filtering agent, Cacumen Platycladi, aluminium silicate fiber peacekeeping polyacrylamide composition, with preferable caking property, plasticity, touch
Degeneration, fire resistance and heat stability, can effectively adsorb harmful substance, environmental protection and the enhancements such as formaldehyde in air, ammonia and benzene
People's is healthy, and the present invention selects fineness of the particles≤0.074 millimeter of the attapulgite potter's clay powder with air purification function.
Molecular sieve has uniform microcellular structure, and its hole diameter is uniform, and these holes can be less than its diameter
Molecular Adsorption to the inside of vestibule, and to polar molecule and unsaturated molecule, there is Preferential adsorption ability, thus can be polarity
Degree difference, degree of saturation difference, the different molecule of the different and boiling point of molecular size is separated, that is, have " screening " molecule
Effect, therefore claim molecular sieve, molecular sieve derives from physical absorption to the absorption of material（Van der Waals force）, have very inside its crystal hole
Strong polarity and Coulombian field, to polar molecule（As water）Go out strong absorbability with unsaturated molecule displays, molecular sieve is powder
Last shape crystal, has metallic luster, hardness be 3～5, relative density be 2～2.8, the present invention from molecular sieve fineness of the particles≤
0.074 millimeter.
Active hargil is a kind of odorless, tasteless, nontoxic white or cream-coloured powder or granule, and the activity after decolourizing is white
Soil loses activity and becomes active white clay waste slag, and these active white clay waste slags are all abandoned by some oily factories, if cannot and
When process, produces after the fermentation of lipid organic matter in active white clay waste slag and goes mouldy and stench, the not only wasting of resources, pollute environment and
Groundwater quality, and fire hazardous, will cause certain loss to society and enterprise；The present invention is from active white clay waste slag
Fineness of the particles≤0.149 millimeter.
White carbon is a kind of ultra tiny inorganic porous property material, due to its particle diameter very little, with specific surface area is big, surface is inhaled
Attached power is strong, chemical purity is high, dispersive property is good, superior stability, reinforcing, thickening property, adhesive force and thixotropy etc. are special
Performance.
Precipitated calcium carbonate fine particles, surface are rougher, and specific surface area is big, and precipitated calcium carbonate easily divides also with not settling
Dissipate, the characteristic such as good luster, the present invention is from fineness of the particles≤0.074 millimeter of precipitated calcium carbonate.
Light magnesium oxide is the loose unformed powder of white lightweight, odorless, tasteless, and nontoxic, volume shared by light magnesium oxide is about
Three times for heavy-burned magnesia or so, have an extremely fireproof heat-insulating property, reinforcing agent, adhesive, and the present invention selects light magnesium oxide
Fineness of the particles≤0.074 millimeter.
Activated alumina is the solid material of a kind of porous, high degree of dispersion, has very big surface area, its micropore surface tool
Standby characteristic required by catalytic action, such as absorption property, surface activity, excellent heat stability etc., so be widely used as
The catalyst of chemical reaction and catalyst carrier, the present invention is from fineness of the particles≤0.074 millimeter of activated alumina.
Sodium aluminate also known as sodium metaaluminate, are a kind of general chemical articles, white, odorless, tasteless, in alkaline solid,
Moisture content and carbon dioxide are easily absorbed in atmosphere, the present invention is from fineness of the particles≤0.074 millimeter of sodium aluminate.
Natural dihydrate gypsum is also called Gypsum Fibrosum, through calcining, levigate obtain gesso, Gypsum Fibrosum preparata has more micropore
Structure, is allowed to have excellent sound insulation, heat-insulated and fire protecting performance, and the present invention is from fineness of the particles≤0.074 millimeter of gesso.
Cenosphere outward appearance is canescence, is a kind of loose, powder body material of good fluidity, and cenosphere proportion is little, table
Face is smooth, intensity is big, easily disperse, the present invention from cenosphere fineness of the particles≤≤ 0.149 millimeter.
Perlite is expanded and becomes a kind of lightweight, multifunctional novel shaped material, with apparent density light, heat conductivity is low,
The features such as chemical stability is good, the present invention is from fineness of the particles≤0.074 millimeter of expanded perlite.
Sodium lauryl sulphate is white or faint yellow powdery, is dissolved in water, insensitive to alkali and hard water, with decontamination, breast
Change and excellent foaming power, be a kind of nontoxic anion surfactant.
Washable molecular sieve photocatalytic spray liquid is sprayed on building or decorative material surface, under the irradiation of light, permissible
Continual absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene,toluene,xylene, TVOC, and with extremely strong sterilization, remove
Smelly, mould proof, anti-fouling and self-cleaning and the function of purify air.
The technical scheme is that：
1st, the dispensing that gravel has the molecular sieve light ceramic of air purification function is made up of following component by weight percentage：
Gravel has the molecular sieve light ceramic semi-finished product 55～95% of air purification function and washable molecular sieve photocatalytic spray
Liquid 5～45%.
2nd, gravel has the production method of the molecular sieve light ceramic of air purification function：(1) first by washable molecular sieve
Photocatalytic spray liquid is put in fermentation vat, then by gravel have air purification function molecular sieve light ceramic semi-finished product slow
Add in the washable molecular sieve photocatalytic spray liquid in fermentation vat, gravel has the molecular sieve Lightweight ceramic of air purification function
Micropore inside and outside grain semi-finished product, constantly sucks washable molecular sieve photocatalytic spray liquid, until being in saturation；(2) from immersion
Take out in pond and be filled the gravel of washable molecular sieve photocatalytic spray liquid there is the molecular sieve light ceramic of air purification function,
It is transported in low temperature rotary drying oven and is dried, drying temperature control is at 150～180 DEG C, and drying time controls 1～3
Hour；(3) the molecular sieve light ceramic for the gravel after oven drying at low temperature being had air purification function is transported in vibrosieve and carries out
Screening, weeds out the powder less than 0.25 millimeter, packs the molecular sieve Lightweight ceramic for having air purification function for gravel
The finished product of grain.
3rd, gravel have the dispensing of the molecular sieve light ceramic semi-finished product of air purification function by weight percentage by under
Row group is grouped into：Attapulgite potter's clay powder 10～45%, molecular sieve 5～25% with air purification function, active white clay waste slag 2
～10%, white carbon 1～8%, precipitated calcium carbonate 1～5%, light magnesium oxide 1～5%, activated alumina 1～5%, sodium aluminate
0.5～5%, cenosphere 0.5～5%, gesso 0.5～5%, expanded perlite 0.5～5%, sodium lauryl sulphate
0.5～5% and water 10～40%.
4th, gravel has the production method of the molecular sieve light ceramic semi-finished product of air purification function：(1) gravel is had
In the stirring mixer that the dispensing input for having the molecular sieve light ceramic semi-finished product of air purification function has operated, stirring mixing
There is the mixture of the molecular sieve light ceramic of air purification function for gravel；(2) gravel had air purification function
The mixture of molecular sieve light ceramic is transported in Squeezinggranulator, and extruder grain is a kind of cylindrical particle, (3) by cylinder
Granule is transported in swinging drying oven and is dried, and drying temperature control is at 200～250 DEG C, and drying time controls 1～4
Hour；(4) the cylindrical particle after drying being transported in disintegrating machine and being crushed, it is irregular broken that screening is carried out after crushing
Stone shape granule, the fineness of the particles of gravel granule controls at 0.5～6 millimeter；(5) by the irregular gravel granule after screening
Input swinging roasting kiln roasting, the temperature control of combustor is at 650～750 DEG C, and roasting time controlled at 1～3 hour；⑹
To be incubated in irregular gravel granule input rustless steel cylinder storehouse after roasting, temperature retention time controlled at 8～24 hours；⑺
Irregular gravel granule after insulation cooling is transported in vibrosieve and is sieved, weed out the powdery less than 0.25 millimeter
After thing, it is molecular sieve light ceramic semi-finished product that gravel has air purification function.
5th, the production method of the attapulgite potter's clay powder with air purification function is：(1) by with the recessed of air purification function
It is input in pulverizer after the dispensing mixing of convex rod potter's clay powder and is crushed, the compound particles fineness after crushing is less than 0.5 millimeter；
(2) pulverulent mixture is added and soak that to be carried out in old pond soaking old process with water be semi-finished product, soak old time control and exist
7～30 days；(3) semi-finished product are input in vacuum-extruder and cylindrical bar is squeezed into, the diameter control of cylindrical bar exists
2～10 millimeters；(4) cylindrical bar being input to cement threshing ground carries out dry in the sun, and the cylindrical bar water content after dry in the sun is little
In 15%；(5) pulverizing will be carried out for powder in the cylindrical bar input grinding machine after dry in the sun, the fineness of the particles of powder is little
In 0.074 millimeter.
The dispensing of the attapulgite potter's clay powder with air purification function is made up of following component by weight percentage：High viscous recessed
Convex rod stone clay 35～60%, attapulite constant humidity amendment 10～35%, natural-minerals adsorptive filter medium 5～20%, Cacumen Platycladi 2
～15%, alumina silicate fibre 1～5% and polyacrylamide 0.1～3%.
Attapulgite potter's clay powder with air purification function is using being applied on 2 25th, 2011 by the present inventor
" the attapulgite potter's clay powder with air purification function ", Chinese patent Authorization Notice No. is：102173743 B of CN, Granted publication
Day：On July 25th, 2012.
High viscous Concave-convex clay rod is glued using the attapulgite of the processing technique production for improving viscosity of attapulgite clay
Soil, from the attapulgite clay of mining area exploitation, needs the weathering through 30～120 days；Modification processing method is：With weight
Percentage ratio is calculated, and is taken the attapulgite clay after weathering 94～98%, is uniformly added into 2～6% sodium carbonate, common input leaching
In bubble pond, clear water is added to carry out immersion ageing, soak time is 72～120 hours；Take the attapulgite clay after soaking, input
Being stirred in blender, and by the attapulgite clay after stirring, thin slice being extruded into through extruder, its THICKNESS CONTROL is 0.5～2
Millimeter, attapulgite clay thin slice carries out dry in the sun, the attapulgite clay thin slice after dry in the sun, its water content≤15%；Dispensing
Calculated in weight percent：Attapulgite clay 94～98%, High hydrophilous resin 0.5～5% after dry in the sun and cellulose 0.5～
3%, above-mentioned dispensing is stirred, after stirring, in input grinding machine, carries out pulverizing, fineness of the particles≤0.074 millimeter；
Above-mentioned production technology is " to improve viscosity of attapulgite clay using filed in 20 days June in 2005 of the present inventor
Processing technique ", Chinese patent Authorization Notice No. is：CN 1317067C, authorized announcement date：On May 23rd, 2007.
The detection method of high viscous Concave-convex clay rod：28.0g attapulgite clay powder sample is taken, adds homogenizer
In suspension cup, 372g water is added, suspension cup is placed on homogenizer, stir under 11000 revs/min of rotating speed
20 minutes, then by the beaker that high-speed stirred sample suspension pours 250mL into, tested using NDJ-1 type rotating cylinder viscometer
The viscosity of suspension, tested viscosity value >=2200 mPa s is high viscous Concave-convex clay rod.
6th, the dispensing of washable molecular sieve photocatalytic spray liquid is made up of following component by weight percentage：Molecular sieve 5～
12%th, attapulgite clay after the acidify 4～10%, high viscous Concave-convex clay rod 2～8%, nano titanium oxide 1～5%, white
White carbon black 1～5%, nano silver-supported antibacterial powder 0.5～5%, nano magnesia 0.5～5%, nano zirconium dioxide 0～5%, nanometer
Aluminium oxide 0～5%, nano zine oxide 0～5%, polyvinyl alcohol 0.5～5%, Polyethylene Glycol 0.1～3%, polydimethylsiloxanes
Alkane 0.1～2% and deionized water 50～82%；
The production method of washable molecular sieve photocatalytic spray liquid：(1) the dispensing of washable molecular sieve photocatalytic spray liquid is input into
Strong stirring, dispersion and emulsifying is carried out in the high speed dispersor for having operated, and is then ground in input three-roll grinder erasable
Wash the semi-finished product of molecular sieve photocatalytic spray liquid；(2) the semi-finished product of washable molecular sieve photocatalytic spray liquid are input into colloid mill
In, carry out again disperseing, emulsifying, crushing, homogenizing, froth breaking and grinding；(3) the washable molecular sieve photocatalytic spray liquid after grinding
Granularity≤0.01 millimeter of middle solid particle, canned for washable molecular sieve photocatalytic spray liquid.
Washable molecular sieve photocatalytic spray liquid be using by " washable filed in the applicant on 07 29th, 2016
Molecular sieve photocatalytic spray liquid ", Chinese Patent Application No. is：201610612095.1.
Heretofore described PCm is weight percentage.
There are substantial amounts of micropore and activated carbon in the attapulgite potter's clay powder with air purification function in the present invention, with relatively
Good caking property, plasticity, thixotropy, fire resistance and heat stability, can effectively adsorb formaldehyde in air, ammonia and benzene etc. harmful
Material.
It is primary raw material using the attapulgite potter's clay powder with air purification function, production gravel has purify air work(
The molecular sieve light ceramic of energy, has given full play to the effective efficiency of the attapulgite potter's clay powder with air purification function.
Molecular sieve has Preferential adsorption ability to polar molecule and unsaturated molecule, substantially increases gravel and has purification
The absorption of the molecular sieve light ceramic of air function and clean-up effect.
Active white clay waste slag is in roasting process, and the lipid in active white clay waste slag and organic matter participate in gravel tool jointly
Have the roasting of the molecular sieve light ceramic of air purification function, improve the heat of combustion-gas flow, not only can save energy, also
The inside beneficial to gravel with the molecular sieve light ceramic of air purification function can be grilled thoroughly completely, increase gravel and have purification
Porosity inside the molecular sieve light ceramic of air function.
White carbon, light magnesium oxide, activated alumina and sodium aluminate can improve gravel and have dividing for air purification function
The absorbability of son sieve light ceramic and increase gravel have the granule strength of the molecular sieve light ceramic of air purification function.
Gravel has using lauryl sulphate acid in the dispensing of the molecular sieve light ceramic semi-finished product of air purification function
Sodium, is conducive to produce substantial amounts of foam in stirring mixed process, to increase the molecule that gravel has air purification function
Micropore inside sieve light ceramic.
Precipitated calcium carbonate, gesso, cenosphere and expanded perlite can reduce gravel and have air purification function
Molecular sieve light ceramic bulk density, increase gravel there is the hole inside the molecular sieve light ceramic of air purification function
Gap rate.
The gravel for sucking washable molecular sieve photocatalytic spray liquid has the molecular sieve light ceramic of air purification function
Semi-finished product, the molecular sieve light ceramic for gravel after drying with air purification function, under the irradiation of light, gravel
Molecular sieve light ceramic with air purification function can continual absorption and the dirt such as degradation of formaldehyde, ammonia, benzene and TVOC
Dye thing, and the function with extremely strong sterilization, deodorization, mould proof, anti-fouling and self-cleaning and purify air.
The molecular sieve light ceramic cylindrical particle moisture content that gravel after extruder grain has air purification function is big
In 30%, swinging roaster high temperature roasting is delivered directly to, in high-temperature calcination process, the surface of cylindrical particle is first opened
Beginning sintering curing, and the water vapour of inside is difficult rapid evaporation out, cylindrical particle will produce explosion, nor can be by
Grill thoroughly inside cylindrical particle.
The present invention is first transported to cylindrical particle in swinging drying oven and slowly carries out prebake, and drying temperature control exists
150～250 DEG C, then the cylindrical particle after drying is transported in disintegrating machine is crushed, broken after carry out screening for not advising
Irregular gravel granule after screening is finally input into swinging roasting kiln roasting, combustor by gravel granule then
Temperature control at 650～750 DEG C, it can be ensured that in roasting process, irregular gravel granule is grilled thoroughly, and can also
Save more than 25% fuel.
More than 600 DEG C are still up in temperature in irregular gravel granule after roasting, will be irregular after roasting
Gravel granule input rustless steel cylinder storehouse in be incubated, it is possible to use the waste heat of itself, continue to irregular gravel
Grain is uniform to be heated, and not only can ensure that and will be grilled thoroughly inside irregular gravel granule completely, moreover it is possible to play uniformly dispersing heat and
The effect of slow cooling, to improve the inherent quality that gravel has the molecular sieve light ceramic semi-finished product of air purification function.
It is a kind of irregular gravel granule that gravel has the molecular sieve light ceramic semi-finished product of air purification function,
There is substantial amounts of micropore surface and inside, and are a kind of open pores, open pore not only each other insertion also communicate with the external world, increased
The effective ratio area of haydite, intensity and reduce bulk density, and the absorption of haydite and net can be greatly improved in actual use
Change the effect of air.
Gravel has the molecular sieve light ceramic of air purification function and has that specific surface area is big, bulk density is low, lightweight
The feature that intensity is good, hydroscopicity is high, absorption and purifying property are superior, gravel has the molecular sieve Lightweight ceramic of air purification function
Grain can adsorb the pollutant such as the substantial amounts of formaldehyde of in the air, ammonia, benzene and TVOC, soak all the year round in the dry state without dust
Disintegrate will not be also produced in water.
The gravel for sucking washable molecular sieve photocatalytic spray liquid has the molecular sieve light ceramic of air purification function,
It is to be degraded on the basis of absorption, improves the molecular sieve light ceramic absorption that gravel has air purification function comprehensively
Ability with purify air.
The molecular sieve light ceramic that gravel has air purification function is used through prolonged, adsorbs a certain amount of dirt
After dye thing, molecular sieve photocatalyst degradation capability begins to decline, and can present saturation, using 90～100 DEG C of hot water, by
The molecular sieve light ceramic for having air purification function through the gravel in saturation carries out backwash, and cleaning sticks to broken
Stone shape has molecular sieve photo-catalyst film or the microgranule inside and outside the molecular sieve light ceramic of air purification function, after cleaning up,
By the new washable molecular sieve photocatalytic spray liquid for preparing, spray or be dipped into the molecular sieve that gravel has air purification function
Inside and outside light ceramic, and dried or dried, can continue to play the molecular sieve lightweight that gravel has air purification function
The effect of haydite purify air.
The microgranule waste residue for washing down can be used for planting bracketplant, Aloe, Folium Sansevieriae Trifasclatae, pocket Cortex cocois radiciss, Caulis Hederae Sinensiies and Epipremnum aureum (Linde et Andre) (Bunting.)
In green plantss, the interior thing that stays not decomposed of microgranule waste residue will slowly be adsorbed by green plantss such as bracketplant, Aloe, Folium Sansevieriae Trifasclataes
Decompose, new pollution will not be produced.
Gravel have air purification function molecular sieve light ceramic be applied to place indoors, furniture cabinet, vehicle,
In aircraft, ship, subway, tunnel, highway baffle, military installations, ornament materials, public place or other buildings,
Absorption and the pollutant such as degradation of formaldehyde, ammonia, benzene, TVOC are carried out, to reach the purpose of long-time purify air.
Specific embodiment
With reference to embodiment, the invention will be further described：
1st, the dispensing that gravel has the molecular sieve light ceramic of air purification function is made up of following component by weight percentage：
Gravel has the molecular sieve light ceramic semi-finished product 85% of air purification function and washable molecular sieve photocatalytic spray liquid
15%.
2nd, gravel has the production method of the molecular sieve light ceramic of air purification function：(1) first by washable molecular sieve
Photocatalytic spray liquid is put in fermentation vat, then by gravel have air purification function molecular sieve light ceramic semi-finished product slow
Add in the washable molecular sieve photocatalytic spray liquid in fermentation vat, gravel has the molecular sieve Lightweight ceramic of air purification function
Micropore inside and outside grain semi-finished product, constantly sucks washable molecular sieve photocatalytic spray liquid, until being in saturation；(2) from immersion
Take out in pond and be filled the gravel of washable molecular sieve photocatalytic spray liquid there is the molecular sieve light ceramic of air purification function,
It is transported in low temperature rotary drying oven and is dried, drying temperature control is at 160～170 DEG C, and drying time control is little 2
When；(3) the molecular sieve light ceramic for the gravel after oven drying at low temperature being had air purification function is transported in vibrosieve and is sieved
Point, the powder less than 0.25 millimeter is weeded out, packs the molecular sieve light ceramic that there is air purification function for gravel
Finished product.
3rd, gravel have the dispensing of the molecular sieve light ceramic semi-finished product of air purification function by weight percentage by under
Row group is grouped into：Attapulgite potter's clay powder 36%, molecular sieve 12% with air purification function, active white clay waste slag 4%, Linesless charcoal
Black 3%, precipitated calcium carbonate 3%, light magnesium oxide 2%, activated alumina 2%, sodium aluminate 2%, cenosphere 2%, Gypsum Fibrosum preparata
Powder 1%, expanded perlite 1%, sodium lauryl sulphate 2% and water 30%.
4th, gravel has the production method of the molecular sieve light ceramic semi-finished product of air purification function：(1) gravel is had
In the stirring mixer that the dispensing input for having the molecular sieve light ceramic semi-finished product of air purification function has operated, stirring mixing
There is the mixture of the molecular sieve light ceramic of air purification function for gravel；(2) gravel had air purification function
The mixture of molecular sieve light ceramic is transported in Squeezinggranulator, and extruder grain is a kind of cylindrical particle, (3) by cylinder
Granule is transported in swinging drying oven and is dried, and drying temperature control is at 220～230 DEG C, and drying time control is little 1
When；(4) the cylindrical particle after drying being transported in disintegrating machine and crushed, screening is carried out after crushing for irregular rubble
Shape granule, the fineness of the particles of gravel granule controls at 0.5～5 millimeter；(5) will be defeated for irregular gravel granule after screening
Enter swinging roasting kiln roasting, the temperature control of combustor at 650～660 DEG C, roasting time control at 1 hour；(6) will roasting
It is incubated in irregular gravel granule input rustless steel cylinder storehouse after burning, temperature retention time controlled at 16 hours；(7) will insulation
Irregular gravel granule after cooling is transported in vibrosieve and is sieved, after weeding out the powder less than 0.25 millimeter,
There are the molecular sieve light ceramic semi-finished product of air purification function for gravel.
Claims (3)
1. a kind of gravel has the molecular sieve light ceramic of air purification function, it is characterised in that it is empty that gravel has purification
The dispensing of the molecular sieve light ceramic of airway dysfunction is made up of following component by weight percentage：Gravel has air purification function
Molecular sieve light ceramic semi-finished product 55～95% and washable molecular sieve photocatalytic spray liquid 5～45%；
The gravel has the dispensing of the molecular sieve light ceramic semi-finished product of air purification function by weight percentage by following
Group is grouped into：Attapulgite potter's clay powder 10～45%, molecular sieve 5～25% with air purification function, active white clay waste slag 2～
10%th, white carbon 1～8%, precipitated calcium carbonate 1～5%, light magnesium oxide 1～5%, activated alumina 1～5%, sodium aluminate
0.5～5%, cenosphere 0.5～5%, gesso 0.5～5%, expanded perlite 0.5～5%, sodium lauryl sulphate
0.5～5% and water 10～40%；
Gravel has the production method of the molecular sieve light ceramic semi-finished product of air purification function：(1) gravel is had and purify
In the stirring mixer that the dispensing input of the molecular sieve light ceramic semi-finished product of air function has operated, stirring is mixed into rubble
Shape has the mixture of the molecular sieve light ceramic of air purification function；(2) gravel is had the molecular sieve of air purification function
The mixture of light ceramic is transported in Squeezinggranulator, and extruder grain is a kind of cylindrical particle, (3) that cylindrical particle is defeated
It is sent in swinging drying oven and is dried, drying temperature control is at 200～250 DEG C, and drying time controlled at 1～4 hour；⑷
Cylindrical particle after drying being transported in disintegrating machine and is crushed, screening is carried out after crushing for irregular gravel
Grain, the fineness of the particles of gravel granule controls at 0.5～6 millimeter；(5) the irregular gravel granule after screening is input into back
Rotatable roasting kiln roasting, the temperature control of combustor is at 650～750 DEG C, and roasting time controlled at 1～3 hour；(6) by roasting
It is incubated in irregular gravel granule input rustless steel cylinder storehouse afterwards, temperature retention time controlled at 8～24 hours；(7) will insulation
Irregular gravel granule after cooling is transported in vibrosieve and is sieved, after weeding out the powder less than 0.25 millimeter,
There are the molecular sieve light ceramic semi-finished product of air purification function for gravel；
The dispensing of the washable molecular sieve photocatalytic spray liquid is made up of following component by weight percentage：Molecular sieve 5～
12%th, attapulgite clay after the acidify 4～10%, high viscous Concave-convex clay rod 2～8%, nano titanium oxide 1～5%, white
White carbon black 1～5%, nano silver-supported antibacterial powder 0.5～5%, nano magnesia 0.5～5%, nano zirconium dioxide 0～5%, nanometer
Aluminium oxide 0～5%, nano zine oxide 0～5%, polyvinyl alcohol 0.5～5%, Polyethylene Glycol 0.1～3%, polydimethylsiloxanes
Alkane 0.1～2% and deionized water 50～82%；
The production method of washable molecular sieve photocatalytic spray liquid：(1) the dispensing of washable molecular sieve photocatalytic spray liquid is input into
Strong stirring, dispersion and emulsifying is carried out in the high speed dispersor for having operated, and is then ground in input three-roll grinder erasable
Wash the semi-finished product of molecular sieve photocatalytic spray liquid；(2) the semi-finished product of washable molecular sieve photocatalytic spray liquid are input into colloid mill
In, carry out again disperseing, emulsifying, crushing, homogenizing, froth breaking and grinding；(3) the washable molecular sieve photocatalytic spray liquid after grinding
Granularity≤0.01 millimeter of middle solid particle, canned for washable molecular sieve photocatalytic spray liquid.
2. gravel according to claim 1 has the molecular sieve light ceramic of air purification function, it is characterised in that tool
There are fineness of the particles≤0.074 millimeter of the attapulgite potter's clay powder of air purification function, fineness of the particles≤0.074 milli of molecular sieve
Rice, fineness of the particles≤0.149 millimeter of active white clay waste slag, fineness of the particles≤0.074 millimeter of precipitated calcium carbonate, lightweight is aoxidized
Fineness of the particles≤0.074 millimeter of magnesium, fineness of the particles≤0.074 millimeter of activated alumina, the fineness of the particles of sodium aluminate≤
0.074 millimeter, fineness of the particles≤0.149 millimeter of cenosphere, fineness of the particles≤0.074 millimeter of gesso, expansion is precious
Fineness of the particles≤0.074 millimeter of Zhu Yan.
3. gravel according to claim 1 has the molecular sieve light ceramic of air purification function, it is characterised in that broken
Stone shape has the production method of the molecular sieve light ceramic of air purification function：(1) first by washable molecular sieve photocatalytic spray liquid
It is put in fermentation vat, then the molecular sieve light ceramic semi-finished product that gravel is had air purification function is slowly added in fermentation vat
Washable molecular sieve photocatalytic spray liquid in, gravel has inside and outside the molecular sieve light ceramic semi-finished product of air purification function
Micropore, constantly suck washable molecular sieve photocatalytic spray liquid, until be in saturation；(2) take out from fermentation vat and be filled
The gravel of washable molecular sieve photocatalytic spray liquid has the molecular sieve light ceramic of air purification function, is transported to low temperature and returns
Dried in rotatable drying oven, drying temperature control is at 150～180 DEG C, and drying time controlled at 1～3 hour；(3) by low temperature
Gravel after drying has the molecular sieve light ceramic of air purification function and is transported in vibrosieve and sieved, and weeds out and is less than
0.25 millimeter of powder, packs the finished product of the molecular sieve light ceramic for having air purification function for gravel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610831134.7A CN106431229A (en) | 2016-09-19 | 2016-09-19 | Rubble-shaped molecular sieve lightweight ceramsite with air purification function |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610831134.7A CN106431229A (en) | 2016-09-19 | 2016-09-19 | Rubble-shaped molecular sieve lightweight ceramsite with air purification function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106431229A true CN106431229A (en) | 2017-02-22 |
Family
ID=58165591
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114163255A (en) * | 2021-11-30 | 2022-03-11 | 光合生物科技(深圳)有限公司 | Surfacing stone for potted plants and preparation method thereof |
-
2016
- 2016-09-19 CN CN201610831134.7A patent/CN106431229A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114163255A (en) * | 2021-11-30 | 2022-03-11 | 光合生物科技(深圳)有限公司 | Surfacing stone for potted plants and preparation method thereof |
| CN114163255B (en) * | 2021-11-30 | 2023-05-12 | 光合生物科技(深圳)有限公司 | Paving stone for potted plant and preparation method thereof |
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Application publication date: 20170222 |