CN106396557B - ceramic tile adhesive mortar and preparation method thereof - Google Patents

ceramic tile adhesive mortar and preparation method thereof Download PDF

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Publication number
CN106396557B
CN106396557B CN201610827772.1A CN201610827772A CN106396557B CN 106396557 B CN106396557 B CN 106396557B CN 201610827772 A CN201610827772 A CN 201610827772A CN 106396557 B CN106396557 B CN 106396557B
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Prior art keywords
parts
ceramic tile
adhesive mortar
tile adhesive
neopelex
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Expired - Fee Related
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CN201610827772.1A
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Chinese (zh)
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CN106396557A (en
Inventor
刘小燕
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Guangxi Tianpin Technology Co ltd
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Guangxi Palm Garden Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008Obtaining or using nanotechnology related materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/94Products characterised by their shape
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/95Products characterised by their size, e.g. microceramics

Abstract

The invention discloses a kind of ceramic tile adhesive mortar, the ceramic tile adhesive mortar is made by weight of following material:50 100 parts of modified epoxy, 50 100 parts of nano zine oxide, 30 55 parts of hydroxylated cellulose, 20 50 parts of sodium methyl silicate, 10 20 parts of neopelex, 20 50 parts of xanthans, 15 30 parts of vitamin C, 35 55 parts of castor oil polyoxyethylene ether, 100 200 parts of ethylene glycol, 50 100 parts of nano ceramics grain, 22 38 parts of wooden sodium sulfonate, 100 150 parts of fine sand, 400 800 parts of portland cement, 200 400 parts of water;Modified epoxy, nano zine oxide, xanthans, vitamin C can penetrate into ceramic tile veneer surface layer and other materials one layer of fine and close net structure of formation of the present invention by solvent interaction in the present invention, intensity is high, caking property is lasting so that ceramic tile is not easy to fall off.

Description

Ceramic tile adhesive mortar and preparation method thereof
Technical field
The present invention relates to building fields, and in particular to a kind of ceramic tile adhesive mortar and preparation method thereof.
Background technology
Mortar is common construction material, is generally used for building by laying bricks or stones and plastering engineering.Mortar is by cementitious material (cement, stone Ash, clay etc.) and fine aggregate (sand) plus water mix form.According to composition material, can be divided into:1. lime mortar:By lime paste, sand Be made according to a certain ratio with water, be generally used for intensity requirement it is not high, from moist masonry and coat of plaster;2. cement mortar:By Cement, Sha Heshui are made according to a certain ratio, masonry, metope or the ground etc. being generally used in wet environment or water;3. mixed sand Slurry:Appropriate admixture such as flyash, diatomite etc. are filled in cement or lime mortar to be made, and are used with saving cement or lime Amount, and improve the workability of mortar, common mixed mortar has cement-lime mortar, cement clay mortar and lime clay mortar Deng.It is divided by purposes difference:Masonry mortar, decorative mortar (including decoration mortar, waterproof mortar), adhesive mortar etc..It is and ceramic Brick adhesive mortar is high for caking property requirement, and particularly exterior wall Ceramic Tiles adhesive mortar caking property is extremely good, and Current Ceramic Tiles are poor with adhesive mortar caking property persistence, come off so as to cause ceramic tile.
The content of the invention
It is an object of the invention in view of the above-mentioned problems, providing a kind of ceramic tile adhesive mortar, caking property of the present invention is held Long property is good, prevents ceramic tile from coming off.
Technical solution provided by the invention is:
A kind of ceramic tile adhesive mortar, the ceramic tile adhesive mortar are made by weight of following material:Modified ring 50-100 parts of oxygen resin, 50-100 parts of nano zine oxide, 30-55 parts of hydroxylated cellulose, 20-50 parts of sodium methyl silicate, dodecane 10-20 parts of base benzene sulfonic acid sodium salt, 20-50 parts of xanthans, 15-30 parts of vitamin C, 35-55 parts of castor oil polyoxyethylene ether, second two 100-200 parts of alcohol, 50-100 parts of nano ceramics grain, wooden sodium sulfonate 22-38 parts, 100-150 parts of fine sand, portland cement 400- 800 parts, 200-400 parts of water.
Preferably, the ceramic tile adhesive mortar is made by weight of following material:85 parts of modified epoxy, 65 parts of nano zine oxide, 45 parts of hydroxylated cellulose, 35 parts of sodium methyl silicate, 13 parts of neopelex, 35 parts of xanthans, 22 parts of vitamin C, 45 parts of castor oil polyoxyethylene ether, 165 parts of ethylene glycol, 78 parts of nano ceramics grain, 32 parts of wooden sodium sulfonate, 128 parts of fine sand, 655 parts of portland cement, 300 parts of water.
Preferably, the nano ceramics grain is made of following parts by weight material:100-200 parts of kaolin, montmorillonite 50- 100 parts, 45-55 parts of aluminium oxide, 30-50 parts of attapulgite, 8-15 parts of neopelex, polyethylene glycol 400 100-200 Part, 150-300 parts of water;The nano ceramics grain is made of following methods:By kaolin, montmorillonite, aluminium oxide, attapulgite powder After when broken 500 mesh sieve of mistake, obtained powder and neopelex, polyethylene glycol 400, water mixing 1-2 small, spraying Be dried to obtain solid particle, solid particle is sintered at 800-1000 DEG C 4-6 it is small when, after cooling, be crushed to less than 100 nanometers Obtain the nano ceramics grain.
Preferably, the nano ceramics grain is made of following parts by weight material:150 parts of kaolin, 60 parts of montmorillonite, oxygen Change 48 parts of aluminium, 38 parts of attapulgite, 12 parts of neopelex, 160 parts of polyethylene glycol 400,220 parts of water.
Preferably, the grain size of the fine sand is 300-500 mesh.
A kind of preparation method of the ceramic tile adhesive mortar, the preparation method of the ceramic tile adhesive mortar include The following steps:
I heats water to 60 DEG C of constant temperature, adds in xanthans and vitamin C, and stirring obtains solution A to after dissolving;
II disperses modified epoxy, castor oil polyoxyethylene ether, ethylene glycol using emulsion dispersion machine, until solution is transparent Until, obtain solution B;
III by solution A, solution B, nano zine oxide, hydroxylated cellulose, sodium methyl silicate, neopelex with Wooden sodium sulfonate using emulsion dispersion machine disperse 0.5-1 it is small when, vacuumize to obtain mixing liquid C;
IV is uniformly mixed mixing liquid C with nano ceramics grain, fine sand, portland cement up to the Ceramic Tiles binding sand Slurry.
Preferably, emulsion dispersion machine rate of dispersion is 2000-3000rmp in step II, when jitter time 0.5 is small.
Preferably, emulsion dispersion machine rate of dispersion is 500-1000rmp in step III, and the vacuum degree vacuumized is 0.8-0.9Mpa。
Beneficial effects of the present invention are as follows:
Modified epoxy, nano zine oxide, xanthans, vitamin C can be penetrated by solvent interaction in the present invention The other materials of Ceramic Tiles veneer surface layer and the present invention form one layer of fine and close net structure, and intensity is high, and caking property is lasting so that Ceramic Tiles are not easy to fall off, and wherein sodium methyl silicate, which plays waterproof action, can improve the water resistance of mortar so as to play mortar not It is corroded, improves the service life of mortar, nano-ceramic particle is by materials such as kaolin, montmorillonite, aluminium oxide, attapulgites in the present invention Material is made, and can significantly improve the tensile strength and compression strength of mortar of the present invention;Caking property of the present invention is good in summary, intensity Height, waterproof ability is strong, prevents Ceramic Tiles from coming off.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, those skilled in the art's reference to be made to say Bright book word can be implemented according to this.
Embodiment 1:
A kind of ceramic tile adhesive mortar is made by weight of following material:It is 50 parts of modified epoxy, nano oxidized 50 parts of zinc, 30 parts of hydroxylated cellulose, 20 parts of sodium methyl silicate, 10 parts of neopelex, 20 parts of xanthans, vitamin C 15 parts, 35 parts of castor oil polyoxyethylene ether, 100 parts of ethylene glycol, 50 parts of nano ceramics grain, 22 parts of wooden sodium sulfonate, fine sand 100 Part, 400 parts of portland cement, 200 parts of water.
The preparation method of the ceramic tile adhesive mortar, comprises the following steps:
I heats water to 60 DEG C of constant temperature, adds in xanthans and vitamin, and stirring obtains solution A to after dissolving;
II disperses modified epoxy, castor oil polyoxyethylene ether, ethylene glycol using emulsion dispersion machine, until solution is transparent Until, obtain solution B;
III by solution A, solution B, nano zine oxide, hydroxylated cellulose, sodium methyl silicate, neopelex with Wooden sodium sulfonate using emulsion dispersion machine disperse 0.5 it is small when, vacuumize to obtain mixing liquid C;
IV is uniformly mixed mixing liquid C with nano ceramics grain, fine sand, portland cement up to the Ceramic Tiles binding sand Slurry.
Embodiment 2
A kind of ceramic tile adhesive mortar is made by weight of following material:100 parts of modified epoxy, nano oxygen Change 100 parts of zinc, 55 parts of hydroxylated cellulose, 50 parts of sodium methyl silicate, 20 parts of neopelex, 50 parts of xanthans, dimension life Plain 30 parts of C, 55 parts of castor oil polyoxyethylene ether, 200 parts of ethylene glycol, 100 parts of nano ceramics grain, 38 parts of wooden sodium sulfonate, fine sand 150 parts, 800 parts of portland cement, 400 parts of water;The nano ceramics grain is made of following parts by weight material:100 parts of kaolin, 50 parts of montmorillonite, 45 parts of aluminium oxide, 30 parts of attapulgite, 8 parts of neopelex, 100 parts of polyethylene glycol 400, water 150 Part;The nano ceramics grain is made of following methods:Kaolin, montmorillonite, aluminium oxide, attapulgite were crushed into 500 mesh sieves, After when obtained powder and small neopelex, polyethylene glycol 400, water mixing 1, spray drying obtains solid Grain, solid particle is sintered at 800 DEG C 4 it is small when, after cooling, be crushed to less than 100 nanometers and obtain the nano ceramics grain.
The preparation method of the ceramic tile adhesive mortar, comprises the following steps:
I heats water to 60 DEG C of constant temperature, adds in xanthans and vitamin, and stirring obtains solution A to after dissolving;
II disperses modified epoxy, castor oil polyoxyethylene ether, ethylene glycol using emulsion dispersion machine, until solution is transparent Until, solution B is obtained, emulsion dispersion machine rate of dispersion is 2000rmp, when jitter time 0.5 is small;
III by solution A, solution B, nano zine oxide, hydroxylated cellulose, sodium methyl silicate, neopelex with Wooden sodium sulfonate using emulsion dispersion machine disperse 1 it is small when, vacuumize to obtain mixing liquid C, emulsion dispersion machine rate of dispersion is 500rmp, the vacuum degree vacuumized are 0.8Mpa;
IV is uniformly mixed mixing liquid C with nano ceramics grain, fine sand, portland cement up to the Ceramic Tiles binding sand Slurry.
Embodiment 3
A kind of ceramic tile adhesive mortar is made by weight of following material:It is 85 parts of modified epoxy, nano oxidized 65 parts of zinc, 45 parts of hydroxylated cellulose, 35 parts of sodium methyl silicate, 13 parts of neopelex, 35 parts of xanthans, vitamin C 22 parts, 45 parts of castor oil polyoxyethylene ether, 165 parts of ethylene glycol, 78 parts of nano ceramics grain, 32 parts of wooden sodium sulfonate, fine sand 128 Part, 655 parts of portland cement, 300 parts of water;The nano ceramics grain is made of following parts by weight material:200 parts of kaolin covers De- 100 parts of stone, 55 parts of aluminium oxide, 50 parts of attapulgite, 15 parts of neopelex, 200 parts of polyethylene glycol 400, water 300 Part;The nano ceramics grain is made of following methods:Kaolin, montmorillonite, aluminium oxide, attapulgite were crushed into 500 mesh sieves, After when obtained powder and small neopelex, polyethylene glycol 400, water mixing 2, spray drying obtains solid Grain, solid particle is sintered at 1000 DEG C 6 it is small when, after cooling, be crushed to less than 100 nanometers and obtain the nano ceramics grain; The grain size of the fine sand is 300-500 mesh.
The preparation method of the ceramic tile adhesive mortar, comprises the following steps:
I heats water to 60 DEG C of constant temperature, adds in xanthans and vitamin, and stirring obtains solution A to after dissolving;
II disperses modified epoxy, castor oil polyoxyethylene ether, ethylene glycol using emulsion dispersion machine, until solution is transparent Until, solution B is obtained, emulsion dispersion machine rate of dispersion is 3000rmp, when jitter time 0.5 is small;
III by solution A, solution B, nano zine oxide, hydroxylated cellulose, sodium methyl silicate, neopelex with Wooden sodium sulfonate using emulsion dispersion machine disperse 1 it is small when, vacuumize to obtain mixing liquid c, emulsion dispersion machine rate of dispersion is 1000rmp, the vacuum degree vacuumized are 0.9Mpa;
IV is uniformly mixed mixing liquid C with nano ceramics grain, fine sand, portland cement up to the Ceramic Tiles binding sand Slurry.
Embodiment 4
A kind of ceramic tile adhesive mortar is made by weight of following material:It is 85 parts of modified epoxy, nano oxidized 65 parts of zinc, 45 parts of hydroxylated cellulose, 35 parts of sodium methyl silicate, 13 parts of neopelex, 35 parts of xanthans, vitamin C 22 parts, 45 parts of castor oil polyoxyethylene ether, 165 parts of ethylene glycol, 78 parts of nano ceramics grain, 32 parts of wooden sodium sulfonate, fine sand 128 Part, 655 parts of portland cement, 300 parts of water;The nano ceramics grain is made of following parts by weight material:The nano ceramics grain It is made of following parts by weight material:150 parts of kaolin, 60 parts of montmorillonite, 48 parts of aluminium oxide, 38 parts of attapulgite, dodecyl 12 parts of benzene sulfonic acid sodium salt, 160 parts of polyethylene glycol 400,220 parts of water;The nano ceramics grain is made of following methods:By kaolin, Montmorillonite, aluminium oxide, attapulgite crushed 500 mesh sieves, obtained powder and neopelex, polyethylene glycol 400, Water be mixed 2 it is small when after, spray drying obtains solid particle, solid particle is sintered at 900 DEG C 5 it is small when, after cooling, powder It is broken to less than 100 nanometers and obtains the nano ceramics grain;The grain size of the fine sand is 300-500 mesh.
The preparation method of the ceramic tile adhesive mortar, comprises the following steps:
I heats water to 60 DEG C of constant temperature, adds in xanthans and vitamin, and stirring obtains solution A to after dissolving;
II disperses modified epoxy, castor oil polyoxyethylene ether, ethylene glycol using emulsion dispersion machine, until solution is transparent Until, solution B is obtained, emulsion dispersion machine rate of dispersion is 3000rmp, when jitter time 0.5 is small;
III by solution A, solution B, nano zine oxide, hydroxylated cellulose, sodium methyl silicate, neopelex with Wooden sodium sulfonate using emulsion dispersion machine disperse 0.5 it is small when, vacuumize to obtain mixing liquid C, emulsion dispersion machine rate of dispersion is 800rmp, the vacuum degree vacuumized are 0.9Mpa;
IV is uniformly mixed mixing liquid C with nano ceramics grain, fine sand, portland cement up to the Ceramic Tiles binding sand Slurry.
Although the embodiments of the present invention have been disclosed as above, but its be not restricted in specification and embodiment it is listed With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, it is of the invention and unlimited In specific details and shown here as the embodiment with description.

Claims (7)

1. a kind of ceramic tile adhesive mortar, which is characterized in that the ceramic tile adhesive mortar is by weight by following material system Into:50-100 parts of modified epoxy, 50-100 parts of nano zine oxide, 30-55 parts of hydroxylated cellulose, sodium methyl silicate 20-50 Part, 10-20 parts of neopelex, 20-50 parts of xanthans, 15-30 parts of vitamin C, castor oil polyoxyethylene ether 35- 55 parts, 100-200 parts of ethylene glycol, 50-100 parts of nano ceramics grain, wooden sodium sulfonate 22-38 parts, 100-150 parts of fine sand, silicic acid 400-800 parts of salt cement, 200-400 parts of water;Wherein, the nano ceramics grain is made of following parts by weight material:Kaolin 100-200 parts, 50-100 parts of montmorillonite, 45-55 parts of aluminium oxide, 30-50 parts of attapulgite, neopelex 8-15 Part, 100-200 parts of polyethylene glycol 400,150-300 parts of water;The nano ceramics grain is made of following methods:By kaolin, cover De- stone, aluminium oxide, attapulgite crushed 500 mesh sieves, obtained powder and neopelex, polyethylene glycol 400, water Be mixed 1-2 it is small when after, spray drying obtains solid particle, solid particle is sintered at 800-1000 DEG C 4-6 it is small when, it is cold But after, less than 100 nanometers is crushed to and obtains the nano ceramics grain.
2. ceramic tile adhesive mortar as described in claim 1, which is characterized in that the ceramic tile adhesive mortar is by weight It is made of following material:85 parts of modified epoxy, 65 parts of nano zine oxide, 45 parts of hydroxylated cellulose, 35 parts of sodium methyl silicate, 13 parts of neopelex, 35 parts of xanthans, 22 parts of vitamin C, 45 parts of castor oil polyoxyethylene ether, ethylene glycol 165 Part, 78 parts of nano ceramics grain, 32 parts of wooden sodium sulfonate, 128 parts of fine sand, 655 parts of portland cement, 300 parts of water.
3. ceramic tile adhesive mortar as described in claim 1, which is characterized in that the nano ceramics grain is by following parts by weight material Material is made:It is 150 parts of kaolin, 60 parts of montmorillonite, 48 parts of aluminium oxide, 38 parts of attapulgite, 12 parts of neopelex, poly- 400160 parts of ethylene glycol, 220 parts of water.
4. ceramic tile adhesive mortar as described in claim 1, which is characterized in that the grain size of the fine sand is 300-500 mesh.
5. the preparation method of the ceramic tile adhesive mortar as described in any in claim 1-4, which is characterized in that the ceramics The preparation method of brick adhesive mortar comprises the following steps:
I heats water to 60 DEG C of constant temperature, adds in xanthans and vitamin C, and stirring obtains solution A to after dissolving;
II disperses modified epoxy, castor oil polyoxyethylene ether, ethylene glycol using emulsion dispersion machine, until solution is transparent is Only, solution B is obtained;
III by solution A, solution B, nano zine oxide, hydroxylated cellulose, sodium methyl silicate, neopelex and wooden sulphur Sour sodium using emulsion dispersion machine disperse 0.5-1 it is small when, vacuumize to obtain mixing liquid C;
IV is uniformly mixed mixing liquid C with nano ceramics grain, fine sand, portland cement up to the ceramic tile adhesive mortar.
6. the preparation method of ceramic tile adhesive mortar as claimed in claim 5, which is characterized in that emulsion dispersion machine in step II Rate of dispersion is 2000-3000rmp, when jitter time 0.5 is small.
7. the preparation method of ceramic tile adhesive mortar as claimed in claim 5, which is characterized in that emulsion dispersion machine in step III Rate of dispersion is 500-1000rmp, and the vacuum degree vacuumized is 0.8-0.9MPa.
CN201610827772.1A 2016-09-18 2016-09-18 ceramic tile adhesive mortar and preparation method thereof Expired - Fee Related CN106396557B (en)

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CN108585667B (en) * 2018-02-26 2020-09-29 上海牛元工贸有限公司 Adhesive for high-adhesion ceramic tiles and preparation method thereof
CN108328997A (en) * 2018-04-04 2018-07-27 合肥月煌新型装饰材料有限公司 A kind of tile paste adhesive and preparation method thereof
CN109053074B (en) * 2018-08-23 2021-03-23 安徽万博材料科技有限公司 Attapulgite tile bonding mortar and preparation method thereof
CN108975819B (en) * 2018-08-23 2021-03-23 安徽万博材料科技有限公司 Attapulgite exterior wall thermal insulation anti-crack mortar and preparation method thereof
CN110683794B (en) * 2019-11-30 2022-02-22 江苏省苏安能节能建材科技有限公司 Adhesive mortar and preparation method thereof

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