CN106393511A - Organic fluoride emulsification release agent for paraffin base - Google Patents
Organic fluoride emulsification release agent for paraffin base Download PDFInfo
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- CN106393511A CN106393511A CN201510463769.1A CN201510463769A CN106393511A CN 106393511 A CN106393511 A CN 106393511A CN 201510463769 A CN201510463769 A CN 201510463769A CN 106393511 A CN106393511 A CN 106393511A
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Abstract
The invention discloses an organic fluoride emulsification release agent for a paraffin base. Metacrylic acid ester, methacrylic acid amide and a fluorinated phenyl and carboxyl acrylate monomer are subjected to a polymerization reaction and are emulsified to be prepared into a fluorinated acrylic ester copolymer emulsion through bi-octyphenol polyoxyethylene ether, alkyl polyglycoside and dialkybenze sulfonate; and paraffin is emulsified to be prepared into a paraffin rough emulsion through sorbitan monolaurate, diethylene glycol monobutyl ether, fatty alcohol polyoxyethylene ether, alkyl polyglucoside, dialkybenze sulfonate and bi-octyphenol polyoxyethylene ether under the heating condition, and the organic fluoride emulsification release agent for the paraffin base is prepared in the manner of homogeneous emulsification dispersing of the paraffin rough emulsion and the fluorinated acrylic ester copolymer emulsion. The purpose that the organic fluoride emulsification release agent for the paraffin base is used for conducting effective mold releasing on mold pressing, laminating and the like is achieved, and the organic fluoride emulsification release agent has the beneficial effects that mold release residues are few, the corrosion inhibition effect is good, and the emulsions are stable.
Description
Technical field
The present invention relates to technical field of mold release, the organic fluoride emulsifying releasing agent of espespecially a kind of paraffinic base.
Background technology
Releasing agent is a kind of functional materials between mould and finished product.Releasing agent is chemically resistant, heat-resisting and stress performance, is not easily decomposed or weares and teares；Releasing agent is adhered to and is not transfer on mould on processed product, other secondary machining operation of without prejudice to.Due to developing rapidly of the techniques such as injection, extrusion, calendering, molding, lamination, the consumption of releasing agent is also significantly increased, although releasing agent industry focuses on environmental protection always, but from the beginning of the nineties, global range inner height payes attention to reducing in the work environment harmful steam, cancels using the fluorochlorohydrocarbon solvent carrier compound having destruction to Ozone in Atmosphere layer.Chlorinated solvents be widely used as releasing agent and molding abluent quick-drying, do not fire solvent carrier.However, novel water-based releasing agent is incorporated in the application of large-scale thermosetting resin etc. many technological requirements, and then reduce the usage amount of organic solvent, be reduced as far as environmental pollution.
Content of the invention、
A kind of organic fluoride emulsifying releasing agent of paraffinic base of the present invention, is characterized in that：Methacrylate, methacrylic and fluorine-containing phenylcarboxy acrylate monomer make fluoro-acrylate copolymer emulsion by polyreaction and by double OPEOs, alkyl polyglucoside, dialkylbenzene disulfonate emulsifying；Paraffin is under conditions of heating and by water sorbitan monolaurate, butyl, fatty alcohol-polyoxyethylene ether, alkyl sugar, dialkylbenzene disulfonate and double OPEO, carry out emulsifying and make the thick emulsion of paraffin, using the thick emulsion of paraffin and the scattered mode of fluoro-acrylate copolymer emulsion emulsifying, the organic fluoride emulsifying releasing agent of prepared paraffinic base, realize the organic fluoride emulsifying releasing agent of the paraffinic base purpose to the effectively demoulding such as molding, lamination, have the characteristics that the demoulding remains less, corrosion mitigating effect is excellent and emulsion-stabilizing.
To achieve these goals, the technical solution of the present invention is：A kind of organic fluoride emulsifying releasing agent of paraffinic base includes the raw material of following mass parts：3～8 parts of fluorine-containing phenylcarboxy acrylate monomer, 40～60 parts of paraffin, 1,3- are double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 4～7 parts of tetramethyl siloxanes, 4～7 parts of fatty alcohol-polyoxyethylene ether, 5～8 parts of double OPEO, 5～9 parts of alkyl polyglucoside, 2～5 parts of dialkylbenzene disulfonate, 2～4 parts of sorbitan mono-laurate, 1～2 part of butyl, 3～6 parts of methacrylic, 3～6 parts of methacrylic acid, 0.1～0.3 part of Ammonium persulfate., 60～75 parts of deionized water.
The preparation method of the organic fluoride emulsifying releasing agent of described paraffinic base is：
（1）, the preparation of fluorine-containing phenylcarboxy acrylate monomer：
4～7 parts of hydroxy phenyl carboxylic acids are added in the four-hole boiling flask equipped with agitator, psychrolusia and thermometer（Ⅰ）, 4～7 parts of N,N-dimethylformamide organic solvent and 2～4 parts of perfluoro propyl vinyl ethers（Ⅱ）, after stirring, it is slowly added dropwise 0.5～0.8 part of triethylamine, reacts 4～7 hours at 22～29 DEG C of keeping temperature, steam organic solvent, the aqueous solution of addition sodium hydroxide, continue stirring, dissolving, filter prepared compound（Ⅲ）, under conditions of continuing to be kept stirring for, it is slowly added to the hydrochloric acid that concentration is 20% and washes out white solid, after filtration, obtain filter cake（Ⅳ）, its main chemical reactions is as follows：
In formula ,-RCOOH is the organic carboxy that carbon number including carboxyl, carboxymethyl group, carboxy ethyl, carboxy vinyl is 1～5；
Filter cake after filtration（Ⅳ）It is then added to, equipped with four there-necked flasks of agitator, thermometer and reflux condensate device, add 1～2 part of propenyl（Ⅴ）, 0.1～0.3 part of sulphuric acid, 0.05～0.1 part of hydroquinone and 4～6 parts of dimethylbenzene, it is heated to 115～125 DEG C under conditions of stirring and keeps 7～14 hours, product goes out through vacuum distillation to be rectifying to obtain fluorine-containing phenylcarboxy acrylate monomer after dimethylbenzene again（Ⅵ）, its main chemical reactions is as follows：
In formula ,-RCOOH is the organic carboxy that carbon number including carboxyl, carboxymethyl group, carboxy ethyl, carboxy vinyl is 1～5；
（2）, the preparation of fluoro-acrylate copolymer emulsion：
To equipped with agitator、In the four-hole boiling flask of thermometer and reflux condensate device，Add 8～10 parts of deionized water、0.2～0.4 part of double OPEO、0.3～0.5 part of alkyl polyglucoside、0.1～0.3 part of dialkylbenzene disulfonate、4～6 parts of methacrylic、4～6 parts of methacrylic acid and fluorine-containing phenylcarboxy acrylate monomer，Open stirring，With 1300 revs/min of stirrings of rotating speed，It is passed through nitrogen protection，It is heated to 65～70 DEG C and keep 0.5 hour，Then drip 0.1～0.3 part of the Ammonium persulfate. being dissolved in 1 part of deionized water in 3～4 hours，It is heated to 70～75 DEG C again and keep 2 hours，Stop heating，Cooling，Adjusting emulsion pH value with ammonia is 8～9，Obtain fluoro-acrylate copolymer emulsion with 80 mesh filter-cloth filterings，Standby；
（3）, the preparation of composite fluoride emulsifying releasing agent：Add 40～60 parts of paraffin in the stirring container with heating, heating is melted completely, add 2～4 parts of sorbitan mono-laurate, 1～2 part of butyl, 4～7 parts of fatty alcohol-polyoxyethylene ether, 1,3- double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 4～7 parts of tetramethyl siloxanes, the alkyl polyglucoside of residual mass part, dialkylbenzene disulfonate and double OPEO, it is heated to 80～90 DEG C, be slowly added dropwise deionized water, high-speed stirred is after 2～3 hours, stop heating, make the thick emulsion of paraffin, be eventually adding the fluoro-acrylate copolymer emulsion of preparation and remaining deionized water, mixed liquor is dispersed into the organic fluoride emulsifying releasing agent of paraffinic base with homogenizer under 50MPa pressure condition.
Advantages of the present invention and feature are：Methacrylate, methacrylic and fluorine-containing phenylcarboxy acrylate monomer make fluoro-acrylate copolymer emulsion by polyreaction and by double OPEOs, alkyl polyglucoside, dialkylbenzene disulfonate emulsifying；Paraffin is under conditions of heating and by water sorbitan monolaurate, butyl, fatty alcohol-polyoxyethylene ether, alkyl sugar, dialkylbenzene disulfonate and double OPEO, carry out emulsifying and make the thick emulsion of paraffin, using the thick emulsion of paraffin and the scattered mode of fluoro-acrylate copolymer emulsion emulsifying, the organic fluoride emulsifying releasing agent of prepared paraffinic base, reach the organic fluoride emulsifying releasing agent of the paraffinic base effect to the effectively demoulding such as molding, lamination, have the characteristics that the demoulding remains less, corrosion mitigating effect is excellent and emulsion-stabilizing.
Specific embodiment
Embodiment 1
A kind of organic fluoride emulsifying releasing agent of paraffinic base includes the raw material of following mass parts：3 parts of fluorine-containing phenylcarboxy acrylate monomer, 40 parts of paraffin, 1,3- are double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 7 parts of tetramethyl siloxanes, 4 parts of fatty alcohol-polyoxyethylene ether, 5 parts of double OPEO, 9 parts of alkyl polyglucoside, 2 parts of dialkylbenzene disulfonate, 2 parts of sorbitan mono-laurate, 1 part of butyl, 5 parts of methacrylic, 3 parts of methacrylic acid, 0.1 part of Ammonium persulfate., 60 parts of deionized water；
Its preparation method is：To equipped with agitator、4 parts of p-hydroxycinnamic acid are added in the four-hole boiling flask of psychrolusia and thermometer、7 parts of N,Dinethylformamide organic solvent and 2 parts of perfluoro propyl vinyl ethers，After stirring，It is slowly added dropwise 0.5 part of triethylamine，React 4～7 hours at 22～29 DEG C of keeping temperature，Steam organic solvent，Add the aqueous solution of sodium hydroxide，Continue stirring、Dissolving、Filter to take filtrate，Under conditions of continuing to be kept stirring for，It is slowly added to the hydrochloric acid that concentration is 20% and wash out white solid，Filter cake after filtration is then added to equipped with agitator、In four there-necked flasks of thermometer and reflux condensate device，Add 1 part of propenyl、0.1 part of sulphuric acid、0.05 part of hydroquinone and 4 parts of dimethylbenzene，It is heated to 115～125 DEG C under conditions of stirring and keep 7～14 hours，Product goes out through vacuum distillation to be rectifying to obtain fluorine-containing phenylcarboxy acrylate monomer after dimethylbenzene again，Standby；To equipped with agitator, in the four-hole boiling flask of thermometer and reflux condensate device, add 8 parts of deionized water, 0.3 part of double OPEO, 0.3 part of alkyl polyglucoside, 0.1 part of dialkylbenzene disulfonate, 5 parts of methacrylic, 3 parts of methacrylic acid and 3 parts of fluorine-containing phenylcarboxy acrylate monomer, open stirring, with 1300 revs/min of stirrings of rotating speed, it is passed through nitrogen protection, it is heated to 65～70 DEG C and keep 0.5 hour, then drip 0.1 part of the Ammonium persulfate. being dissolved in 1 part of deionized water in 3～4 hours, it is heated to 70～75 DEG C again and keep 2 hours, stop heating, cooling, adjusting emulsion pH value with ammonia is 8～9, obtain fluoro-acrylate copolymer emulsion with 80 mesh filter-cloth filterings, standby；Add 40 parts of paraffin in the stirring container with heating, heating is melted completely, add 2 parts of sorbitan mono-laurate, 1 part of butyl, 4 parts of fatty alcohol-polyoxyethylene ether, 1,3- double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 7 parts of tetramethyl siloxanes, the alkyl polyglucoside of residual mass part, dialkylbenzene disulfonate and double OPEO, it is heated to 80～90 DEG C, be slowly added dropwise deionized water, high-speed stirred is after 2～3 hours, stop heating, make the thick emulsion of paraffin, be eventually adding the fluoro-acrylate copolymer emulsion of preparation and remaining deionized water, mixed liquor is dispersed into the organic fluoride emulsifying releasing agent of paraffinic base with homogenizer under 50MPa pressure condition.
Embodiment 2,
A kind of organic fluoride emulsifying releasing agent of paraffinic base includes the raw material of following mass parts：5 parts of fluorine-containing phenylcarboxy acrylate monomer, 50 parts of paraffin, 1,3- are double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 5 parts of tetramethyl siloxanes, 6 parts of fatty alcohol-polyoxyethylene ether, 7 parts of double OPEO, 5 parts of alkyl polyglucoside, 4 parts of dialkylbenzene disulfonate, 3 parts of sorbitan mono-laurate, 1.5 parts of butyl, 6 parts of methacrylic, 4 parts of methacrylic acid, 0.2 part of Ammonium persulfate., 70 parts of deionized water；
Its preparation method is：To equipped with agitator、5 parts of m-hydroxybenzoic acids are added in the four-hole boiling flask of psychrolusia and thermometer、6 parts of N,Dinethylformamide organic solvent and 3 parts of perfluoro propyl vinyl ethers，After stirring，It is slowly added dropwise 0.6 part of triethylamine，React 4～7 hours at 22～29 DEG C of keeping temperature，Steam organic solvent，Add the aqueous solution of sodium hydroxide，Continue stirring、Dissolving、Filter to take filtrate，Under conditions of continuing to be kept stirring for，It is slowly added to the hydrochloric acid that concentration is 20% and wash out white solid，Filter cake after filtration is then added to equipped with agitator、In four there-necked flasks of thermometer and reflux condensate device，Add 1.5 parts of propenyls、0.2 part of sulphuric acid、0.07 part of hydroquinone and 5 parts of dimethylbenzene，It is heated to 115～125 DEG C under conditions of stirring and keep 7～14 hours，Product goes out through vacuum distillation to be rectifying to obtain fluorine-containing phenylcarboxy acrylate monomer after dimethylbenzene again，Standby；To equipped with agitator, in the four-hole boiling flask of thermometer and reflux condensate device, add 9 parts of deionized water, 0.4 part of double OPEO, 0.5 part of alkyl polyglucoside, 0.2 part of dialkylbenzene disulfonate, 6 parts of methacrylic, 4 parts of methacrylic acid and 5 parts of fluorine-containing phenylcarboxy acrylate monomer, open stirring, with 1300 revs/min of stirrings of rotating speed, it is passed through nitrogen protection, it is heated to 65～70 DEG C and keep 0.5 hour, then drip 0.2 part of the Ammonium persulfate. being dissolved in 1 part of deionized water in 3～4 hours, it is heated to 70～75 DEG C again and keep 2 hours, stop heating, cooling, adjusting emulsion pH value with ammonia is 8～9, obtain fluoro-acrylate copolymer emulsion with 80 mesh filter-cloth filterings, standby；Add 50 parts of paraffin in the stirring container with heating, heating is melted completely, add 3 parts of sorbitan mono-laurate, 1.5 parts of butyl, 6 parts of fatty alcohol-polyoxyethylene ether, 1,3- double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 5 parts of tetramethyl siloxanes, the alkyl polyglucoside of residual mass part, dialkylbenzene disulfonate and double OPEO, it is heated to 80～90 DEG C, be slowly added dropwise deionized water, high-speed stirred is after 2～3 hours, stop heating, make the thick emulsion of paraffin, be eventually adding the fluoro-acrylate copolymer emulsion of preparation and remaining deionized water, mixed liquor is dispersed into the organic fluoride emulsifying releasing agent of paraffinic base with homogenizer under 50MPa pressure condition.
Embodiment 3
A kind of organic fluoride emulsifying releasing agent of paraffinic base includes the raw material of following mass parts：8 parts of fluorine-containing phenylcarboxy acrylate monomer, 60 parts of paraffin, 1,3- are double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 4 parts of tetramethyl siloxanes, 7 parts of fatty alcohol-polyoxyethylene ether, 8 parts of double OPEO, 7 parts of alkyl polyglucoside, 5 parts of dialkylbenzene disulfonate, 4 parts of sorbitan mono-laurate, 2 parts of butyl, 3 parts of methacrylic, 6 parts of methacrylic acid, 0.3 part of Ammonium persulfate., 75 parts of deionized water；
Its preparation method is：To equipped with agitator、7 parts of p-hydroxyphenylaceticacids are added in the four-hole boiling flask of psychrolusia and thermometer、7 parts of N,Dinethylformamide organic solvent and 4 parts of perfluoro propyl vinyl ethers，After stirring，It is slowly added dropwise 0.8 part of triethylamine，React 4～7 hours at 22～29 DEG C of keeping temperature，Steam organic solvent，Add the aqueous solution of sodium hydroxide，Continue stirring、Dissolving、Filter to take filtrate，Under conditions of continuing to be kept stirring for，It is slowly added to the hydrochloric acid that concentration is 20% and wash out white solid，Filter cake after filtration is then added to equipped with agitator、In four there-necked flasks of thermometer and reflux condensate device，Add 2 parts of propenyls、0.3 part of sulphuric acid、0.1 part of hydroquinone and 6 parts of dimethylbenzene，It is heated to 115～125 DEG C under conditions of stirring and keep 7～14 hours，Product goes out through vacuum distillation to be rectifying to obtain fluorine-containing phenylcarboxy acrylate monomer after dimethylbenzene again，Standby；To in the four-hole boiling flask equipped with agitator, thermometer and reflux condensate device, add 10 parts of deionized water, 0.2 part of double OPEO, 0.4 part of alkyl polyglucoside, 0.3 part of dialkylbenzene disulfonate、3 parts of methacrylic, 6 parts of methacrylic acid and 8 parts of fluorine-containing phenylcarboxy acrylate monomer; open stirring; with 1300 revs/min of stirrings of rotating speed; it is passed through nitrogen protection; it is heated to 65～70 DEG C and keep 0.5 hour; then drip 0.3 part of the Ammonium persulfate. being dissolved in 1 part of deionized water in 3～4 hours; it is heated to 70～75 DEG C again and keep 2 hours; stop heating; cooling; adjusting emulsion pH value with ammonia is 8～9, obtains fluoro-acrylate copolymer emulsion with 80 mesh filter-cloth filterings, standby；Add 60 parts of paraffin in the stirring container with heating, heating is melted completely, add 4 parts of sorbitan mono-laurate, 2 parts of butyl, 7 parts of fatty alcohol-polyoxyethylene ether, 1,3- double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 4 parts of tetramethyl siloxanes, the alkyl polyglucoside of residual mass part, dialkylbenzene disulfonate and double OPEO, it is heated to 80～90 DEG C, be slowly added dropwise deionized water, high-speed stirred is after 2～3 hours, stop heating, make the thick emulsion of paraffin, be eventually adding the fluoro-acrylate copolymer emulsion of preparation and remaining deionized water, mixed liquor is dispersed into the organic fluoride emulsifying releasing agent of paraffinic base with homogenizer under 50MPa pressure condition.
The above; the unit of the mass parts in embodiment 1～3 is kilogram; embodiment is only that the preferred embodiment of the present invention is described; not the scope of the present invention is defined; on the premise of the spirit without departing from the technology of the present invention; various modifications and improvement that this area engineers and technicians make to technical scheme, all should fall in the protection domain of claims of the present invention determination.
Claims (2)
1. a kind of organic fluoride emulsifying releasing agent of paraffinic base, is characterized in that：The organic fluoride emulsifying releasing agent of described paraffinic base includes the raw material of following mass parts：3～8 parts of fluorine-containing phenylcarboxy acrylate monomer, 40～60 parts of paraffin, 1,3- are double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 4～7 parts of tetramethyl siloxanes, 4～7 parts of fatty alcohol-polyoxyethylene ether, 5～8 parts of double OPEO, 5～9 parts of alkyl polyglucoside, 2～5 parts of dialkylbenzene disulfonate, 2～4 parts of sorbitan mono-laurate, 1～2 part of butyl, 3～6 parts of methacrylic, 3～6 parts of methacrylic acid, 0.1～0.3 part of Ammonium persulfate., 60～75 parts of deionized water；
The preparation method of the organic fluoride emulsifying releasing agent of described paraffinic base includes the preparation of the preparation, the preparation of fluoro-acrylate copolymer emulsion and composite fluoride emulsifying releasing agent of fluorine-containing phenylcarboxy acrylate monomer, specifically：
（1）, the preparation of fluorine-containing phenylcarboxy acrylate monomer：
4～7 parts of hydroxy phenyl carboxylic acids, 4～7 parts of N are added in the four-hole boiling flask equipped with agitator, psychrolusia and thermometer, dinethylformamide organic solvent and 2～4 parts of perfluoro propyl vinyl ethers, after stirring, it is slowly added dropwise 0.5～0.8 part of triethylamine, react 4～7 hours at 22～29 DEG C of keeping temperature, steam organic solvent, add the aqueous solution of sodium hydroxide, continue stirring, dissolving, filter prepared compound, under conditions of continuing to be kept stirring for, it is slowly added to the hydrochloric acid that concentration is 20% and washes out white solid, after filtration, obtain filter cake；Filter cake after filtration is then added to equipped with four there-necked flasks of agitator, thermometer and reflux condensate device, add 1～2 part of propenyl, 0.1～0.3 part of sulphuric acid, 0.05～0.1 part of hydroquinone and 4～6 parts of dimethylbenzene, it is heated to 115～125 DEG C under conditions of stirring and keeps 7～14 hours, product goes out through vacuum distillation to be rectifying to obtain fluorine-containing phenylcarboxy acrylate monomer after dimethylbenzene again；
（2）, the preparation of fluoro-acrylate copolymer emulsion：
To equipped with agitator、In the four-hole boiling flask of thermometer and reflux condensate device，Add 8～10 parts of deionized water、0.2～0.4 part of double OPEO、0.3～0.5 part of alkyl polyglucoside、0.1～0.3 part of dialkylbenzene disulfonate、4～6 parts of methacrylic、4～6 parts of methacrylic acid and fluorine-containing phenylcarboxy acrylate monomer，Open stirring，With 1300 revs/min of stirrings of rotating speed，It is passed through nitrogen protection，It is heated to 65～70 DEG C and keep 0.5 hour，Then drip 0.1～0.3 part of the Ammonium persulfate. being dissolved in 1 part of deionized water in 3～4 hours，It is heated to 70～75 DEG C again and keep 2 hours，Stop heating，Cooling，Adjusting emulsion pH value with ammonia is 8～9，Obtain fluoro-acrylate copolymer emulsion with 80 mesh filter-cloth filterings，Standby；
（3）, the preparation of composite fluoride emulsifying releasing agent：Add 40～60 parts of paraffin in the stirring container with heating, heating is melted completely, add 2～4 parts of sorbitan mono-laurate, 1～2 part of butyl, 4～7 parts of fatty alcohol-polyoxyethylene ether, 1,3- double（Adjacent dilute propyl group Phenoxymethyl）- 1,1,3,3- 4～7 parts of tetramethyl siloxanes, the alkyl polyglucoside of residual mass part, dialkylbenzene disulfonate and double OPEO, it is heated to 80～90 DEG C, be slowly added dropwise deionized water, high-speed stirred is after 2～3 hours, stop heating, make the thick emulsion of paraffin, be eventually adding the fluoro-acrylate copolymer emulsion of preparation and remaining deionized water, mixed liquor is dispersed into the organic fluoride emulsifying releasing agent of paraffinic base with homogenizer under 50MPa pressure condition.
2. a kind of organic fluoride emulsifying releasing agent of paraffinic base according to claim 1, is characterized in that：Described fluorophenyl carboxy acrylic ester monomer is that have the compound of following chemical structure of general formula：
In formula ,-RCOOH is the organic carboxy that carbon number including carboxyl, carboxymethyl group, carboxy ethyl, carboxy vinyl is 1～5.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510463769.1A CN106393511A (en) | 2015-08-03 | 2015-08-03 | Organic fluoride emulsification release agent for paraffin base |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510463769.1A CN106393511A (en) | 2015-08-03 | 2015-08-03 | Organic fluoride emulsification release agent for paraffin base |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108326228A (en) * | 2018-02-07 | 2018-07-27 | 广州采润化工有限公司 | A kind of aqueous release agent preparation method for anodized aluminum alloy die casting thin pieces and corresponding aqueous release agent |
| CN117186410A (en) * | 2023-09-06 | 2023-12-08 | 广东杰果新材料有限公司 | Heavy release agent with stable release force |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010018038A (en) * | 2009-10-27 | 2010-01-28 | Agc Seimi Chemical Co Ltd | Mold releasing agent composition |
| CN102782075A (en) * | 2010-02-15 | 2012-11-14 | 旭硝子株式会社 | Release agent composition |
-
2015
- 2015-08-03 CN CN201510463769.1A patent/CN106393511A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010018038A (en) * | 2009-10-27 | 2010-01-28 | Agc Seimi Chemical Co Ltd | Mold releasing agent composition |
| CN102782075A (en) * | 2010-02-15 | 2012-11-14 | 旭硝子株式会社 | Release agent composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108326228A (en) * | 2018-02-07 | 2018-07-27 | 广州采润化工有限公司 | A kind of aqueous release agent preparation method for anodized aluminum alloy die casting thin pieces and corresponding aqueous release agent |
| CN108326228B (en) * | 2018-02-07 | 2019-11-29 | 广州采润新材料有限公司 | Aqueous release agent and preparation method thereof for anodized aluminum alloy die casting thin pieces |
| CN117186410A (en) * | 2023-09-06 | 2023-12-08 | 广东杰果新材料有限公司 | Heavy release agent with stable release force |
| CN117186410B (en) * | 2023-09-06 | 2024-02-13 | 广东杰果新材料有限公司 | Heavy release agent with stable release force |
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Application publication date: 20170215 |