CN106380719A - Preparation method of antibacterial PVC polyester coated filament - Google Patents
Preparation method of antibacterial PVC polyester coated filament Download PDFInfo
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- CN106380719A CN106380719A CN201610732458.5A CN201610732458A CN106380719A CN 106380719 A CN106380719 A CN 106380719A CN 201610732458 A CN201610732458 A CN 201610732458A CN 106380719 A CN106380719 A CN 106380719A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/04—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
- D01F11/08—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/04—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
- D10B2321/041—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polyvinyl chloride or polyvinylidene chloride
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a preparation method of an antibacterial PVC polyester coated filament. The method consists of: 1) color masterbatch preparation: weighing the following raw materials; putting the raw materials into a high-speed mixer to conduct high speed mixing; carrying out stirring cooling to 50DEG C, then transferring the mixture into a hopper, and sending the hopper into a host hopper by a conveying device; cutting the mixture into particles by a pelletizer, thus obtaining color masterbatch; 2) coating: putting polyester filament into a filament rack, penetrating a mold by a tensioner positioning device, and mounting the mold into a diverter; adding the color masterbatch into a hopper, carrying out heating plasticizing, then bringing the color masterbatch to the diverter by a host motor; letting a traction disc drive the polyester filament to perform coating through the diverter; and conducting cooling with cooling water, then bringing the filament into an automation line, performing detection, and then conducting rolling-up. The carrier resin with polyvinyl chloride as the color masterbatch is added with an antibacterial nano material, the polyester filament is colored, and is also endowed with good antibacterial properties. The stiffness handfeel of the polyester filament is enhanced, and the finishing process of additional application of a stiffening agent in a follow-up processing process of polyester window decorations can be eliminated.
Description
Technical field
The present invention relates to a kind of preparation method of antibacterial PVC terylene cladding wire, belong to the cladding wire neck of filament of synthetic fibre
Domain.
Background technology
At present, China's polyester fiber yield surpasses ten million ton, and wherein 1/3rd need coloring to use, dyeing method,
The annual coloured sewage that will discharge 40,000,000 tons, every fastness such as the light fastness of dyeing, washing, sweat stain, distillation is all far below
Coloring before spinning, has been not suitable with the needs that social development and people's living standard improve.Coloring before terylene spins is that Masterbatch is melted
Or be dispersed in Direct-spinning of PET Fiber stoste and carry out melt spinning, the new technology of colored polyester fiber is directly obtained, is to leave out terylene dye
The maximally effective approach of color.
With the raising of living standards of the people, people's pay attention to day by day clothes, the antibiotic property of duvets.At present, curtain
Production dacron thread passes through to reach coloring purpose in its Surface coating colouring agent, adds single antibacterial when needing anti-microbial property
Master batch endowing antibacterial energy, causes the component processed many, the shortcomings of complex process.
Content of the invention
It is an object of the invention to provide a kind of preparation method of antibacterial PVC terylene cladding wire, by improving raw material components,
Dacron thread Surface coating PVC mixture, colours on dacron thread surface and gives excellent antibiotic property, to meet wanting of window decorations product
Ask.
For achieving the above object, the technical scheme is that：
A kind of preparation method of antibacterial PVC terylene cladding wire, comprises the following steps：
1), Masterbatch preparation
A, in terms of mass parts, weigh the raw material of following components
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersant, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide connect
8 parts of powder of branch；
B, by each component raw material put into super mixer in carry out mixed at high speed；
C, stirring are transferred to hopper after being cooled to 50 degree, and hopper sends into main frame bucket through conveying device；
D, it is cut into particle by pelleter, i.e. Masterbatch；
2), coat
Long guide frame put into by a, polyester filament, penetrates mould through tensioner positioner, and mould loads current divider
B, Masterbatch is added hopper, by main frame motor control to current divider after heating plasticizing；
C, by sheave drive polyester filament coated through current divider；
D, cooled water cooling, enter back into transfer matic and wind afterwards after testing.
Described surface of nanometer zinc oxide graft powder is prepared by the following method：
A, take 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl group trimethoxy silane, add 120 parts of ethanol；Water=4
: in the aqueous solution of 1 absolute ethyl alcohol, Hydrolysis At Room Temperature 1h；Weigh the 14 parts 120 DEG C nano zine oxides that 12h is dried simultaneously, add 30
Part ethanol；Water=4: the aqueous solution of 1 absolute ethyl alcohol, ultrasonic disperse 30min；Then the two mixing is poured into flask, be warming up to
80 DEG C are stirred simultaneously, react 12h；Reaction is cooled to room temperature after terminating, by reactant with 4000r/min centrifugation 20min, and
Remove unreacted coupling agent with absolute ethyl alcohol cyclic washing；Vacuum dried case puts into drier after being fully dried, and obtains surface
Modified nano zinc oxide white powder；
B, take 10 parts of Modified Nano-ZnO powder, add 84 parts of absolute ethyl alcohol, ultrasonic disperse 30min；Then
Suspension is proceeded in reactor, stirs and be warming up to 70 DEG C, add a small amount of 0.3 part of initiator azodiisobutyronitrile to be passed through simultaneously
N2；7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 are dripped after azodiisobutyronitrile is completely dissolved
The mixed solution of part vinyl chloride, reacts 6h；After reaction terminates, cooling, centrifugation simultaneously use absolute ethyl alcohol cyclic washing, remove not
The monomer of reaction；Vacuum dried case puts into drier after being fully dried, and obtains surface of nanometer zinc oxide graft powder.
Described pigment be phthalocyanine color, titanium dioxide, carbon black, ultramarine pigment, titanium yellow pigment, AZOpigments, Heterocyclics Pigments,
One or more of miscellany pigment combines.
Described dispersant be one of Tissuemat E, polypropylene wax, oleamide, calcium stearate, zinc stearate or
Multiple.
Described antioxidant is that bisphosphonate is (referred to as four (2,4- di-tert-butyl-phenyl -4,4 '-xenyls)：Anti-oxidant
Agent P-EPQ) and double (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites are (referred to as：Antioxidant 626) in any one
Kind.
Described fire retardant is TDE and hydroxy phenyl phosphinylidyne propionic acid, hydroxy phenyl phosphonoacetic acid, tricresyl phosphate
One of phenyl ester.
The preparation method of antibacterial PVC terylene cladding wire of the present invention, the vector resin with polyvinyl chloride as Masterbatch, adds anti-
Bacterium nano material, had both made terylene wire coloring, gave its good antibiotic property again；Polyvinyl chloride is coated on dacron thread surface, strengthens
The stiffening feel of dacron thread, in addition applies stiffening agent arranging process during eliminating terylene window decorations product following process, shortens
Process time, energy resources are saved.
Specific embodiment
Following embodiment, is merely illustrative of, and is not only, so, all within the scope of the present invention or make with
The similar change of the present invention is both contained within the present invention.
The invention discloses a kind of preparation method of antibacterial PVC terylene cladding wire, main inclusion Masterbatch preparation and terylene
Silk cladding this two steps of Masterbatch.
The preparation of Masterbatch comprises the following steps：
A, in terms of mass parts, weigh each component raw material；
B, by each component raw material put into super mixer in carry out mixed at high speed；
C, stirring are transferred to hopper after being cooled to 50 degree, and hopper sends into main frame bucket through conveying device；
D, it is cut into particle by pelleter, i.e. Masterbatch.
The rotating speed of mixed at high speed is 700-800 rev/min.
Dacron thread coat Masterbatch step be：
Long guide frame put into by a, long filament, penetrates mould through tensioner positioner, and mould loads current divider
B, Masterbatch is added hopper, by main frame motor control to current divider after heating plasticizing；
C, by sheave drive polyester filament coated through current divider；
D, cooled water cooling, enter back into transfer matic and wind afterwards after testing.
In terms of mass parts, Masterbatch is made up of the raw material of following components：
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersant, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide connect
8 parts of powder of branch.
Described polyvinyl chloride is the vector resin of Masterbatch, and it is commonly used in the art gathering from there is no particular restriction
Vinyl chloride resin.
The selection of pigment does not have particular/special requirement, and pigment commonly used in the art all can use.Preferably phthalocyanine color, titanium dioxide, charcoal
Black, one or more of ultramarine pigment, titanium yellow pigment, AZOpigments, Heterocyclics Pigments, miscellany pigment combination.
Described dispersant does not have particular/special requirement, is dispersant commonly used in the art.Preferably Tissuemat E, polypropylene wax,
One or more of oleamide, calcium stearate, zinc stearate.
Described antioxidant is antioxidant commonly used in the art, preferably four (2,4- di-tert-butyl-phenyl -4,
4 '-xenyl) bisphosphonate is (referred to as：Antioxidant P-EPQ) and double (2,4- di-tert-butyl-phenyl) pentaerythrite diphosphorous acid
Any one in ester.
Described fire retardant selects fire retardant commonly used in the art, preferably TDE and hydroxy phenyl phosphinylidyne third
Acid, one of hydroxy phenyl phosphonoacetic acid, triphenyl phosphate.
Nano zine oxide is a kind of polyfunctional new inorganic material, and its granular size is about at 1～100 nanometer.Due to
The granular of crystal grain, its Electronic Structure and crystal structure change, and create the surface effect that macro object does not have
Should, bulk effect, quantum size effect and the features such as macroscopical tunnel-effect and the high grade of transparency, polymolecularity, there is common oxygen
Change particularity and the purposes that zinc cannot compare, nano zine oxide can be used for anti-biotic material in field of textiles.
Because nano zine oxide has, specific surface area is big and the features such as specific surface energy is big, and itself easily reunites；On the other hand, receive
Rice zinc oxide surface polarity is stronger, is difficult dispersed in organic media, and this just significantly limit sending out of its nano effect
Wave.Therefore nanometer Zinc oxide powder is disperseed and surface modification is become Application of micron necessary place before terylene spinning
Reason means.
The present invention is first modified to surface of nanometer zinc oxide with coupling agent, then particle surface grafting after modification is organic
Fluorine, quaternary ammonium salt and vinyl chloride.On the one hand, Organic fluoride can promote surface of nanometer zinc oxide graft powder in PVC base uniformly,
Stable dispersion；On the other hand, the quaternary ammonium salt with antibacterial functions can form antibacterial cooperative effect with nano zine oxide, carries further
The anti-microbial property of high terylene color silk.
Because fluorine has relatively low surface tension, silicon fluoride coupling agent ten trifluoro octyl group trimethoxy silane is to nano-silica
After change titanium carries out surface modification, so that the surface energy of nano-titania particle is reduced, be conducive to stablizing of nano-particle, and promote
It is dispersed in dispersion.
Described surface of nanometer zinc oxide graft powder is prepared by the following method：
A, take 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl group trimethoxy silane, add 120 parts of ethanol；Water=4
: in the aqueous solution of 1 absolute ethyl alcohol, Hydrolysis At Room Temperature 1h；Weigh the 14 parts 120 DEG C nano zine oxides that 12h is dried simultaneously, add 30
Part ethanol；Water=4: the aqueous solution of 1 absolute ethyl alcohol, ultrasonic disperse 30min；Then the two mixing is poured into flask, be warming up to
80 DEG C are stirred simultaneously, react 12h；Reaction is cooled to room temperature after terminating, by reactant with 4000r/min centrifugation 20min, and
Remove unreacted coupling agent with absolute ethyl alcohol cyclic washing；Vacuum dried case puts into drier after being fully dried, and obtains surface
Modified nano zinc oxide white powder；
B, take 10 parts of Modified Nano-ZnO powder, add 84 parts of absolute ethyl alcohol, ultrasonic disperse 30min；Then
Suspension is proceeded in reactor, stirs and be warming up to 70 DEG C, add a small amount of 0.3 part of initiator azodiisobutyronitrile to be passed through simultaneously
N2；7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 are dripped after azodiisobutyronitrile is completely dissolved
The mixed solution of part vinyl chloride, reacts 6h；After reaction terminates, cooling, centrifugation simultaneously use absolute ethyl alcohol cyclic washing, remove not
The monomer of reaction；Vacuum dried case puts into drier after being fully dried, and obtains surface of nanometer zinc oxide graft powder.
Embodiment 1：
A kind of preparation method of antibacterial PVC terylene cladding wire, comprises the following steps：
1), Masterbatch preparation
A, in terms of mass parts, weigh the raw material of following components
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersant, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide connect
8 parts of powder of branch；
B, by each component raw material put into super mixer in carry out mixed at high speed；
C, stirring are transferred to hopper after being cooled to 50 degree, and hopper sends into main frame bucket through conveying device；
D, it is cut into particle by pelleter, i.e. Masterbatch；
2), coat
Long guide frame put into by a, long filament, penetrates mould through tensioner positioner, and mould loads current divider
B, Masterbatch is added hopper, by main frame motor control to current divider after heating plasticizing；
C, by sheave drive polyester filament coated through current divider；
D, cooled water cooling, enter back into transfer matic and wind afterwards after testing.
Embodiment 2：
The preparation of surface of nanometer zinc oxide graft powder：
A, take 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl group trimethoxy silane, add 120 parts of ethanol；Water=4
: in the aqueous solution of 1 absolute ethyl alcohol, Hydrolysis At Room Temperature 1h；Weigh the 14 parts 120 DEG C nano zine oxides that 12h is dried simultaneously, add 30
Part ethanol；Water=4: the aqueous solution of 1 absolute ethyl alcohol, ultrasonic disperse 30min；Then the two mixing is poured into flask, be warming up to
80 DEG C are stirred simultaneously, react 12h；Reaction is cooled to room temperature after terminating, by reactant with 4000r/min centrifugation 20min, and
Remove unreacted coupling agent with absolute ethyl alcohol cyclic washing；Vacuum dried case puts into drier after being fully dried, and obtains surface
Modified nano zinc oxide white powder；
B, take 10 parts of Modified Nano-ZnO powder, add 84 parts of absolute ethyl alcohol, ultrasonic disperse 30min；Then
Suspension is proceeded in reactor, stirs and be warming up to 70 DEG C, add a small amount of 0.3 part of initiator azodiisobutyronitrile to be passed through simultaneously
N2；7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 are dripped after azodiisobutyronitrile is completely dissolved
The mixed solution of part vinyl chloride, reacts 6h；After reaction terminates, cooling, centrifugation simultaneously use absolute ethyl alcohol cyclic washing, remove not
The monomer of reaction；Vacuum dried case puts into drier after being fully dried, and obtains surface of nanometer zinc oxide graft powder.
According to GB/T 20944.3-2008《The evaluation third portion of antibacterial textile performance：Succusion》Method of testing is right
The terylene cladding wire of the embodiment of the present invention 1 carries out anti-microbial property test, result surface, to Escherichia coli, Staphylococcus aureus
Antibiotic rate reaches 98.6%.
Claims (6)
1. a kind of preparation method of antibacterial PVC cladding wire is it is characterised in that comprise the following steps：
1), Masterbatch preparation
A, in terms of mass parts, weigh the raw material of following components
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersant, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide grafting powder
8 parts of end；
B, by each component raw material put into super mixer in carry out mixed at high speed；
C, stirring are transferred to hopper after being cooled to 50 degree, and hopper sends into main frame bucket through conveying device；
D, it is cut into particle by pelleter, i.e. Masterbatch；
2), coat
Long guide frame put into by a, long filament, penetrates mould through tensioner positioner, and mould loads current divider
B, Masterbatch is added hopper, by main frame motor control to current divider after heating plasticizing；
C, by sheave drive polyester filament coated through current divider；
D, cooled water cooling, enter back into transfer matic and wind afterwards after testing.
2. a kind of antibacterial PVC cladding wire according to claim 1 preparation method it is characterised in that：Described nano oxygen
Change zinc surface graft powder to prepare by the following method：
A, take 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl group trimethoxy silane, add 120 parts of ethanol；Water=4: 1
In the aqueous solution of absolute ethyl alcohol, Hydrolysis At Room Temperature 1h；Weigh the 14 parts 120 DEG C nano zine oxides that 12h is dried simultaneously, add 30 parts of second
Alcohol；Water=4: the aqueous solution of 1 absolute ethyl alcohol, ultrasonic disperse 30min；Then the two mixing is poured into flask, be warming up to 80 DEG C
Stir simultaneously, react 12h；Reaction is cooled to room temperature after terminating, by reactant with 4000r/min centrifugation 20min, and with no
Water-ethanol cyclic washing removes unreacted coupling agent；Vacuum dried case puts into drier after being fully dried, and obtains surface modification
Nano zine oxide white powder；
B, take 10 parts of Modified Nano-ZnO powder, add 84 parts of absolute ethyl alcohol, ultrasonic disperse 30min；Then will hang
Supernatant liquid proceeds in reactor, stirs and be warming up to 70 DEG C, adds a small amount of 0.3 part of initiator azodiisobutyronitrile to be passed through N simultaneously2；
7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 parts of chlorine are dripped after azodiisobutyronitrile is completely dissolved
The mixed solution of ethene, reacts 6h；After reaction terminates, cooling, centrifugation simultaneously use absolute ethyl alcohol cyclic washing, remove unreacted
Monomer；Vacuum dried case puts into drier after being fully dried, and obtains surface of nanometer zinc oxide graft powder.
3. a kind of antibacterial PVC cladding wire according to claim 1 preparation method it is characterised in that：Described dispersant
For one or more of Tissuemat E, polypropylene wax, oleamide, calcium stearate, zinc stearate.
4. a kind of antibacterial PVC cladding wire according to claim 1 preparation method it is characterised in that：Described is anti-oxidant
Agent is that bisphosphonate is (referred to as four (2,4- di-tert-butyl-phenyl -4,4 '-xenyls)：Antioxidant P-EPQ) and double (2,4- bis- uncles
Butyl phenyl) any one in pentaerythritol diphosphites.
5. a kind of antibacterial PVC cladding wire according to claim 1 preparation method it is characterised in that：Described fire retardant
For one of TDE and hydroxy phenyl phosphinylidyne propionic acid, hydroxy phenyl phosphonoacetic acid, triphenyl phosphate.
6. a kind of antibacterial PVC cladding wire according to claim 1 preparation method it is characterised in that：Described pigment is
One of phthalocyanine color, titanium dioxide, carbon black, ultramarine pigment, titanium yellow pigment, AZOpigments, Heterocyclics Pigments, miscellany pigment or many
Plant combination.
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| CN201610732458.5A CN106380719B (en) | 2016-08-22 | 2016-08-22 | A kind of preparation method of antibacterial PVC terylene cladding wire |
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| CN201610732458.5A CN106380719B (en) | 2016-08-22 | 2016-08-22 | A kind of preparation method of antibacterial PVC terylene cladding wire |
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| CN107641268A (en) * | 2017-10-16 | 2018-01-30 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of anti-aging antibacterial PVC Masterbatch |
| CN109337239A (en) * | 2018-09-11 | 2019-02-15 | 浙江西大门新材料股份有限公司 | A kind of preparation method of antibacterial PVC Masterbatch and antibacterial fabric |
| CN109763225A (en) * | 2019-01-11 | 2019-05-17 | 山东玉马遮阳技术有限公司 | A kind of thermoplastic elastomer of polyvinyl-chloride yarn and preparation method thereof |
| CN110685046A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Anti-fouling and anti-fatigue multi-strand monofilament mixed-twisted net wire and preparation method thereof |
| CN110904683A (en) * | 2019-12-10 | 2020-03-24 | 山东玉马遮阳科技股份有限公司 | Functional PVC polyester coated yarn for sun-shading fabric and preparation method thereof |
| CN110951187A (en) * | 2019-12-10 | 2020-04-03 | 山东玉马遮阳科技股份有限公司 | Anion PVC polyester coated yarn for sun-shading material and production process thereof |
| CN114318639A (en) * | 2021-12-22 | 2022-04-12 | 宁波狮丹努针织有限公司 | Zinc ion antibacterial knitted fabric and preparation process thereof |
| CN115012215A (en) * | 2022-06-09 | 2022-09-06 | 吴江罗太化纤有限公司 | Preparation method of antibacterial PVC polyester coated yarn |
| CN115368691A (en) * | 2022-09-19 | 2022-11-22 | 山东诺森塑胶有限公司 | Preparation process of high-speed extruded PVC (polyvinyl chloride) coated yarn color master batch formula |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0456823A1 (en) * | 1988-06-08 | 1991-11-21 | Sumitomo Bakelite Company Limited | Vinyl chloride resin composition |
| CN102094328A (en) * | 2009-12-15 | 2011-06-15 | 银禧工程塑料（东莞）有限公司 | Thermoplastic elastomer material for replacing PVC coated polyester yarns and preparation method thereof |
| CN103627114A (en) * | 2013-11-15 | 2014-03-12 | 温多利遮阳科技（德州）有限公司 | High-stability PVC (polyvinyl chloride) coating wire |
| CN104086855A (en) * | 2014-06-19 | 2014-10-08 | 山东春潮集团有限公司 | Energy-saving cooling toughening filling master batch and preparation method thereof |
| CN104452011A (en) * | 2014-12-25 | 2015-03-25 | 浙江三星特种纺织股份有限公司 | PVC covered yarn for manufacturing sneaker upper and production technology thereof |
-
2016
- 2016-08-22 CN CN201610732458.5A patent/CN106380719B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0456823A1 (en) * | 1988-06-08 | 1991-11-21 | Sumitomo Bakelite Company Limited | Vinyl chloride resin composition |
| CN102094328A (en) * | 2009-12-15 | 2011-06-15 | 银禧工程塑料（东莞）有限公司 | Thermoplastic elastomer material for replacing PVC coated polyester yarns and preparation method thereof |
| CN103627114A (en) * | 2013-11-15 | 2014-03-12 | 温多利遮阳科技（德州）有限公司 | High-stability PVC (polyvinyl chloride) coating wire |
| CN104086855A (en) * | 2014-06-19 | 2014-10-08 | 山东春潮集团有限公司 | Energy-saving cooling toughening filling master batch and preparation method thereof |
| CN104452011A (en) * | 2014-12-25 | 2015-03-25 | 浙江三星特种纺织股份有限公司 | PVC covered yarn for manufacturing sneaker upper and production technology thereof |
Cited By (9)
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|---|---|---|---|---|
| CN107641268A (en) * | 2017-10-16 | 2018-01-30 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of anti-aging antibacterial PVC Masterbatch |
| CN109337239A (en) * | 2018-09-11 | 2019-02-15 | 浙江西大门新材料股份有限公司 | A kind of preparation method of antibacterial PVC Masterbatch and antibacterial fabric |
| CN109763225A (en) * | 2019-01-11 | 2019-05-17 | 山东玉马遮阳技术有限公司 | A kind of thermoplastic elastomer of polyvinyl-chloride yarn and preparation method thereof |
| CN110685046A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Anti-fouling and anti-fatigue multi-strand monofilament mixed-twisted net wire and preparation method thereof |
| CN110904683A (en) * | 2019-12-10 | 2020-03-24 | 山东玉马遮阳科技股份有限公司 | Functional PVC polyester coated yarn for sun-shading fabric and preparation method thereof |
| CN110951187A (en) * | 2019-12-10 | 2020-04-03 | 山东玉马遮阳科技股份有限公司 | Anion PVC polyester coated yarn for sun-shading material and production process thereof |
| CN114318639A (en) * | 2021-12-22 | 2022-04-12 | 宁波狮丹努针织有限公司 | Zinc ion antibacterial knitted fabric and preparation process thereof |
| CN115012215A (en) * | 2022-06-09 | 2022-09-06 | 吴江罗太化纤有限公司 | Preparation method of antibacterial PVC polyester coated yarn |
| CN115368691A (en) * | 2022-09-19 | 2022-11-22 | 山东诺森塑胶有限公司 | Preparation process of high-speed extruded PVC (polyvinyl chloride) coated yarn color master batch formula |
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