CN106380719B - A kind of preparation method of antibacterial PVC terylene cladding wire - Google Patents
A kind of preparation method of antibacterial PVC terylene cladding wire Download PDFInfo
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- CN106380719B CN106380719B CN201610732458.5A CN201610732458A CN106380719B CN 106380719 B CN106380719 B CN 106380719B CN 201610732458 A CN201610732458 A CN 201610732458A CN 106380719 B CN106380719 B CN 106380719B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/04—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
- D01F11/08—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/04—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
- D10B2321/041—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polyvinyl chloride or polyvinylidene chloride
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Abstract
The present invention relates to a kind of preparation method of antibacterial PVC terylene cladding wire, 1), Masterbatch preparation：Weigh the raw material of following components；Each component raw material is put into super mixer and carries out mixed at high speed；Stirring is transferred to hopper after being cooled to 50 degree, hopper is sent into host bucket through conveying device；Particle, i.e. Masterbatch are cut by pelleter；2) it, coats：Polyester filament is put into long guide frame, penetrates mold through tensioner positioning device, mold is packed into current divider；Hopper is added in Masterbatch, by host motor control to current divider after heating plasticizing；Polyester filament is driven to be coated through current divider by sheave；It is cooling through cooling water, it enters back into transfer matic and is wound after detecting.Using polyvinyl chloride as the vector resin of Masterbatch, antimicrobial nano material is added, had not only made terylene wire coloring, but also assign its good antibiotic property；The stiffening feel of dacron thread is enhanced, other application stiffening agent arranging process during terylene window decorations product following process is eliminated.
Description
Technical field
The present invention relates to a kind of preparation methods of antibacterial PVC terylene cladding wire, belong to the cladding wire neck of filament of synthetic fibre
Domain.
Background technique
Currently, China's polyester fiber yield surpasses ten million ton, wherein one third is needed to colour and be used, dyeing method,
40,000,000 tons of coloured sewage will be discharged every year, and the items fastness such as light fastness, washing, sweat stain, distillation of dyeing is all far below
Coloring before spinning has been not suitable with the needs of social development and people's living standard raising.Coloring is that Masterbatch is melted before terylene is spun
Or be dispersed in Direct-spinning of PET Fiber stoste and carry out melt spinning, the new process of colored polyester fiber is directly made, is to save terylene dye
The most effective approach of color.
With the improvement of people's living standards, the antibiotic property of people's pay attention to day by day clothes, duvets.Currently, curtain
Production dacron thread adds single antibacterial when needing anti-microbial property by coating colorant on its surface to reach coloring purpose
The disadvantages of master batch endowing antibacterial energy causes the component of processing more, complex process.
Summary of the invention
The object of the present invention is to provide a kind of preparation methods of antibacterial PVC terylene cladding wire, by improving raw material components,
Dacron thread surface coats PVC mixture, excellent antibiotic property is coloured and assign on dacron thread surface, to meet wanting for window decorations product
It asks.
To achieve the above object, the technical scheme is that：
A kind of preparation method of antibacterial PVC terylene cladding wire, includes the following steps：
1), prepared by Masterbatch
A, in terms of mass parts, the raw material of following components is weighed
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersing agent, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide connect
8 parts of powder of branch；
B, each component raw material is put into super mixer and carries out mixed at high speed；
C, stirring is transferred to hopper after being cooled to 50 degree, and hopper is sent into host bucket through conveying device；
D, particle, i.e. Masterbatch are cut by pelleter；
2) it, coats
A, polyester filament is put into long guide frame, penetrates mold through tensioner positioning device, mold is packed into current divider
B, hopper is added in Masterbatch, by host motor control to current divider after heating plasticizing；
C, polyester filament is driven to be coated through current divider by sheave；
D, cooling through cooling water, it enters back into transfer matic and is wound after detecting.
The surface of nanometer zinc oxide graft powder is prepared by the following method：
A, 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl trimethoxy silane are taken, 120 parts of ethyl alcohol are added；Water=4
: in the aqueous solution of 1 dehydrated alcohol, Hydrolysis At Room Temperature 1h；The nano zine oxide of 14 parts 120 DEG C dry 12h is weighed simultaneously, is added 30
Part ethyl alcohol；Water=4: the aqueous solution of 1 dehydrated alcohol, ultrasonic disperse 30min；Then the two is mixed and pours into flask, be warming up to
80 DEG C are stirred simultaneously, react 12h；It is cooled to room temperature after reaction, reactant is centrifugated 20min with 4000r/min, and
It is washed repeatedly with dehydrated alcohol and removes unreacted coupling agent；Vacuum dried case is put into drier after sufficiently drying, and obtains surface
Modified nano zinc oxide white powder；
B, 10 parts of Modified Nano-ZnO powder are taken, 84 parts of dehydrated alcohol, ultrasonic disperse 30min is added；Then
Suspension is transferred in reactor, stir and is warming up to 70 DEG C, a small amount of 0.3 part of initiator azodiisobutyronitrile is added and is passed through simultaneously
N2；7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 are added dropwise after azodiisobutyronitrile is completely dissolved
The mixed solution of part vinyl chloride, reacts 6h；After reaction, cooling, centrifuge separation is simultaneously washed with dehydrated alcohol repeatedly, is removed not
The monomer of reaction；Vacuum dried case is put into drier after sufficiently drying, and obtains surface of nanometer zinc oxide graft powder.
The pigment be phthalocyanine color, titanium dioxide, carbon black, ultramarine pigment, titanium yellow pigment, azo pigments, Heterocyclics Pigments,
One of miscellany pigment or multiple combinations.
The dispersing agent be one of polyethylene wax, polypropylene wax, oleamide, calcium stearate, zinc stearate or
It is a variety of.
The antioxidant is four (2,4- di-tert-butyl-phenyl -4,4 '-xenyls) bisphosphonates (abbreviation：It is anti-oxidant
Agent P-EPQ) and bis- (2,4- di-tert-butyl-phenyl) pentaerythritol diphosphites are (referred to as：Antioxidant 626) in it is any one
Kind.
The fire retardant is decabromodiphenylethane and hydroxy phenyl phosphinylidyne propionic acid, hydroxy phenyl phosphonoacetic acid, tricresyl phosphate
One of phenyl ester.
The preparation method of antibacterial PVC terylene cladding wire of the present invention, using polyvinyl chloride as the vector resin of Masterbatch, addition is anti-
Bacterium nano material had not only made terylene wire coloring, but also assigned its good antibiotic property；Polyvinyl chloride is coated on dacron thread surface, enhancing
The stiffening feel of dacron thread eliminates and in addition applies stiffening agent arranging process during terylene window decorations product following process, shortens
Process time, energy resources are saved.
Specific embodiment
Following embodiment, is merely illustrative of, and is not only, so, all within the scope of the present invention or make with
The similar change of the present invention is both contained within the present invention.
The invention discloses a kind of preparation methods of antibacterial PVC terylene cladding wire, mainly include Masterbatch preparation and terylene
Silk cladding the two steps of Masterbatch.
The preparation of Masterbatch includes the following steps：
A, in terms of mass parts, each component raw material is weighed；
B, each component raw material is put into super mixer and carries out mixed at high speed；
C, stirring is transferred to hopper after being cooled to 50 degree, and hopper is sent into host bucket through conveying device；
D, particle, i.e. Masterbatch are cut by pelleter.
The revolving speed of mixed at high speed is 700-800 revs/min.
Dacron thread coat Masterbatch the step of be：
A, long filament is put into long guide frame, penetrates mold through tensioner positioning device, mold is packed into current divider
B, hopper is added in Masterbatch, by host motor control to current divider after heating plasticizing；
C, polyester filament is driven to be coated through current divider by sheave；
D, cooling through cooling water, it enters back into transfer matic and is wound after detecting.
In terms of mass parts, Masterbatch is made of the raw material of following components：
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersing agent, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide connect
8 parts of powder of branch.
The polyvinyl chloride is the vector resin of Masterbatch, and there is no particular restriction for selection, is gathered for commonly used in the art
Vinyl chloride resin.
The no particular/special requirement of the selection of pigment, pigment commonly used in the art can be used.It is preferred that phthalocyanine color, titanium dioxide, charcoal
One of black, ultramarine pigment, titanium yellow pigment, azo pigments, Heterocyclics Pigments, miscellany pigment or multiple combinations.
The dispersing agent does not have particular/special requirement, is dispersing agent commonly used in the art.It is preferred that polyethylene wax, polypropylene wax,
One of oleamide, calcium stearate, zinc stearate are a variety of.
The antioxidant be antioxidant commonly used in the art, preferably four (2,4- di-tert-butyl-phenyl -4,
4 '-xenyls) bisphosphonate is (referred to as：Antioxidant P-EPQ) and bis- (2,4- di-tert-butyl-phenyl) pentaerythrite diphosphorous acids
Any one in ester.
The fire retardant selects fire retardant commonly used in the art, preferably decabromodiphenylethane and hydroxy phenyl phosphinylidyne third
One of acid, hydroxy phenyl phosphonoacetic acid, triphenyl phosphate.
Nano zine oxide is a kind of new inorganic material of multifunctionality, and granular size is about at 1~100 nanometer.Due to
The imperceptibility of crystal grain, Electronic Structure and crystal structure change, and produce the surface effect that macro object does not have
It answers, bulk effect, quantum size effect and macroscopical tunnel-effect and the features such as the high grade of transparency, polymolecularity, there is common oxygen
Change particularity and purposes that zinc can not compare, nano zine oxide can be used for anti-biotic material in field of textiles.
Since nano zine oxide has the characteristics that large specific surface area and specific surface energy are big, itself is easy to reunite；On the other hand, it receives
Rice zinc oxide surface polarity is stronger, is not easy in organic media evenly dispersed, this just significantly limits the hair of its nano effect
It waves.Therefore dispersion is carried out to nanometer Zinc oxide powder and surface is modified as Application of micron necessary place before terylene spinning
Reason means.
The present invention is first modified surface of nanometer zinc oxide with coupling agent, then particle surface grafting after modification is organic
Fluorine, quaternary ammonium salt and vinyl chloride.On the one hand, Organic fluoride can promote surface of nanometer zinc oxide graft powder in PVC base uniformly,
Stable dispersion；On the other hand, the quaternary ammonium salt with antibacterial functions can form antibacterial synergistic effect with nano zine oxide, further mention
The anti-microbial property of high terylene color silk.
Since fluorine has lower surface tension, ten trifluoro octyl trimethoxy silane of silicon fluoride coupling agent is to nano-silica
It is modified to change titanium progress surface, so that the surface of nano-titania particle is reduced, is conducive to the stabilization of nanoparticle, and promote
It is evenly dispersed in dispersion.
The surface of nanometer zinc oxide graft powder is prepared by the following method：
A, 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl trimethoxy silane are taken, 120 parts of ethyl alcohol are added；Water=4
: in the aqueous solution of 1 dehydrated alcohol, Hydrolysis At Room Temperature 1h；The nano zine oxide of 14 parts 120 DEG C dry 12h is weighed simultaneously, is added 30
Part ethyl alcohol；Water=4: the aqueous solution of 1 dehydrated alcohol, ultrasonic disperse 30min；Then the two is mixed and pours into flask, be warming up to
80 DEG C are stirred simultaneously, react 12h；It is cooled to room temperature after reaction, reactant is centrifugated 20min with 4000r/min, and
It is washed repeatedly with dehydrated alcohol and removes unreacted coupling agent；Vacuum dried case is put into drier after sufficiently drying, and obtains surface
Modified nano zinc oxide white powder；
B, 10 parts of Modified Nano-ZnO powder are taken, 84 parts of dehydrated alcohol, ultrasonic disperse 30min is added；Then
Suspension is transferred in reactor, stir and is warming up to 70 DEG C, a small amount of 0.3 part of initiator azodiisobutyronitrile is added and is passed through simultaneously
N2；7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 are added dropwise after azodiisobutyronitrile is completely dissolved
The mixed solution of part vinyl chloride, reacts 6h；After reaction, cooling, centrifuge separation is simultaneously washed with dehydrated alcohol repeatedly, is removed not
The monomer of reaction；Vacuum dried case is put into drier after sufficiently drying, and obtains surface of nanometer zinc oxide graft powder.
Embodiment 1：
A kind of preparation method of antibacterial PVC terylene cladding wire, includes the following steps：
1), prepared by Masterbatch
A, in terms of mass parts, the raw material of following components is weighed
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersing agent, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide connect
8 parts of powder of branch；
B, each component raw material is put into super mixer and carries out mixed at high speed；
C, stirring is transferred to hopper after being cooled to 50 degree, and hopper is sent into host bucket through conveying device；
D, particle, i.e. Masterbatch are cut by pelleter；
2) it, coats
A, long filament is put into long guide frame, penetrates mold through tensioner positioning device, mold is packed into current divider
B, hopper is added in Masterbatch, by host motor control to current divider after heating plasticizing；
C, polyester filament is driven to be coated through current divider by sheave；
D, cooling through cooling water, it enters back into transfer matic and is wound after detecting.
Embodiment 2：
The preparation of surface of nanometer zinc oxide graft powder：
A, 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl trimethoxy silane are taken, 120 parts of ethyl alcohol are added；Water=4
: in the aqueous solution of 1 dehydrated alcohol, Hydrolysis At Room Temperature 1h；The nano zine oxide of 14 parts 120 DEG C dry 12h is weighed simultaneously, is added 30
Part ethyl alcohol；Water=4: the aqueous solution of 1 dehydrated alcohol, ultrasonic disperse 30min；Then the two is mixed and pours into flask, be warming up to
80 DEG C are stirred simultaneously, react 12h；It is cooled to room temperature after reaction, reactant is centrifugated 20min with 4000r/min, and
It is washed repeatedly with dehydrated alcohol and removes unreacted coupling agent；Vacuum dried case is put into drier after sufficiently drying, and obtains surface
Modified nano zinc oxide white powder；
B, 10 parts of Modified Nano-ZnO powder are taken, 84 parts of dehydrated alcohol, ultrasonic disperse 30min is added；Then
Suspension is transferred in reactor, stir and is warming up to 70 DEG C, a small amount of 0.3 part of initiator azodiisobutyronitrile is added and is passed through simultaneously
N2；7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 are added dropwise after azodiisobutyronitrile is completely dissolved
The mixed solution of part vinyl chloride, reacts 6h；After reaction, cooling, centrifuge separation is simultaneously washed with dehydrated alcohol repeatedly, is removed not
The monomer of reaction；Vacuum dried case is put into drier after sufficiently drying, and obtains surface of nanometer zinc oxide graft powder.
According to GB/T 20944.3-2008《The evaluation third portion of antibacterial textile performance：Succusion》Test method is right
The terylene cladding wire of the embodiment of the present invention 1 carries out anti-microbial property test, as a result surface, to Escherichia coli, Staphylococcus aureus
Antibiotic rate is up to 98.6%.
Claims (5)
1. a kind of preparation method of antibacterial PVC cladding wire, which is characterized in that include the following steps：
1), prepared by Masterbatch
A, in terms of mass parts, the raw material of following components is weighed
69 parts of polyvinyl chloride, 6 parts of pigment, 8 parts of dispersing agent, 4 parts of antioxidant, 5 parts of fire retardant, surface of nanometer zinc oxide are grafted powder
8 parts of end；
B, each component raw material is put into super mixer and carries out mixed at high speed；
C, stirring is transferred to hopper after being cooled to 50 DEG C, and hopper is sent into host bucket through conveying device；
D, particle, i.e. Masterbatch are cut by pelleter；
2) it, coats
A, long filament is put into long guide frame, penetrates mold through tensioner positioning device, mold is packed into current divider
B, hopper is added in Masterbatch, by host motor control to current divider after heating plasticizing；
C, polyester filament is driven to be coated through current divider by sheave；
D, cooling through cooling water, it enters back into automatic inspection line and is wound after detecting；
The surface of nanometer zinc oxide graft powder is prepared by the following method：
A, 3 parts of Silane coupling reagent KH-570s, 4 part of ten trifluoro octyl trimethoxy silane are taken, 120 parts of ethyl alcohol are added；Water=4: 1
In the aqueous solution of dehydrated alcohol, Hydrolysis At Room Temperature 1h；The nano zine oxide for weighing 14 parts 120 DEG C dry 12h simultaneously, is added 30 parts of second
Alcohol；Water=4: the aqueous solution of 1 dehydrated alcohol, ultrasonic disperse 30min；Then the two is mixed and pours into flask, be warming up to 80 DEG C
It stirs simultaneously, reacts 12h；It is cooled to room temperature after reaction, reactant is centrifugated 20min with 4000r/min, and use nothing
Water-ethanol washs repeatedly removes unreacted coupling agent；Vacuum dried case is put into drier after sufficiently drying, and it is modified to obtain surface
Nano zine oxide white powder；
B, 10 parts of Modified Nano-ZnO powder are taken, 84 parts of dehydrated alcohol, ultrasonic disperse 30min is added；Then it will hang
Supernatant liquid is transferred in reactor, is stirred and is warming up to 70 DEG C, 0.3 part of initiator azodiisobutyronitrile is added while being passed through N2；To idol
7 parts of dimethyl diallyl ammonium chlorides, 8 parts of hexafluorobutyl acrylates and 11 parts of vinyl chloride are added dropwise after being completely dissolved in nitrogen bis-isobutyronitrile
Mixed solution, react 6h；After reaction, cooling, centrifuge separation is simultaneously washed with dehydrated alcohol repeatedly, removes unreacted list
Body；Vacuum dried case is put into drier after sufficiently drying, and obtains surface of nanometer zinc oxide graft powder.
2. a kind of preparation method of antibacterial PVC cladding wire according to claim 1, it is characterised in that：The dispersing agent
For one of polyethylene wax, polypropylene wax, oleamide, calcium stearate, zinc stearate or a variety of.
3. a kind of preparation method of antibacterial PVC cladding wire according to claim 1, it is characterised in that：Described is anti-oxidant
Agent is four (2,4- di-tert-butyl-phenyl -4,4 '-xenyls) bis-phosphites (abbreviation：Antioxidant P-EPQ) and bis- (2,4- bis-
Tert-butyl-phenyl) any one in pentaerythritol diphosphites.
4. a kind of preparation method of antibacterial PVC cladding wire according to claim 1, it is characterised in that：The fire retardant
For one of decabromodiphenylethane and hydroxy phenyl phosphinylidyne propionic acid, hydroxy phenyl phosphonoacetic acid, triphenyl phosphate.
5. a kind of preparation method of antibacterial PVC cladding wire according to claim 1, it is characterised in that：The pigment is
One of phthalocyanine color, titanium dioxide, carbon black, ultramarine pigment, titanium yellow pigment, azo pigments, Heterocyclics Pigments or multiple combinations.
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| CN107641268A (en) * | 2017-10-16 | 2018-01-30 | 苏州宏泉高压电容器有限公司 | A kind of preparation method of anti-aging antibacterial PVC Masterbatch |
| CN109337239A (en) * | 2018-09-11 | 2019-02-15 | 浙江西大门新材料股份有限公司 | A kind of preparation method of antibacterial PVC Masterbatch and antibacterial fabric |
| CN109763225A (en) * | 2019-01-11 | 2019-05-17 | 山东玉马遮阳技术有限公司 | A kind of thermoplastic elastomer of polyvinyl-chloride yarn and preparation method thereof |
| CN110685046B (en) * | 2019-08-19 | 2022-04-22 | 浙江海洋大学 | Anti-fouling and anti-fatigue multi-strand monofilament mixed-twisted net wire and preparation method thereof |
| CN110904683A (en) * | 2019-12-10 | 2020-03-24 | 山东玉马遮阳科技股份有限公司 | Functional PVC polyester coated yarn for sun-shading fabric and preparation method thereof |
| CN110951187A (en) * | 2019-12-10 | 2020-04-03 | 山东玉马遮阳科技股份有限公司 | Anion PVC polyester coated yarn for sun-shading material and production process thereof |
| CN114318639A (en) * | 2021-12-22 | 2022-04-12 | 宁波狮丹努针织有限公司 | Zinc ion antibacterial knitted fabric and preparation process thereof |
| CN115012215A (en) * | 2022-06-09 | 2022-09-06 | 吴江罗太化纤有限公司 | Preparation method of antibacterial PVC polyester coated yarn |
| CN115368691A (en) * | 2022-09-19 | 2022-11-22 | 山东诺森塑胶有限公司 | Preparation process of high-speed extruded PVC (polyvinyl chloride) coated yarn color master batch formula |
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| JPH083965B2 (en) * | 1988-06-08 | 1996-01-17 | 住友ベークライト株式会社 | High impact resilience matte curl cord |
| CN102094328B (en) * | 2009-12-15 | 2012-12-19 | 银禧工程塑料（东莞）有限公司 | Thermoplastic elastomer material for replacing PVC coated polyester yarns and preparation method thereof |
| CN103627114A (en) * | 2013-11-15 | 2014-03-12 | 温多利遮阳科技（德州）有限公司 | High-stability PVC (polyvinyl chloride) coating wire |
| CN104086855A (en) * | 2014-06-19 | 2014-10-08 | 山东春潮集团有限公司 | Energy-saving cooling toughening filling master batch and preparation method thereof |
| CN104452011B (en) * | 2014-12-25 | 2016-11-02 | 浙江三星特种纺织股份有限公司 | A kind of PVC cladding wire for making vamps of sport shoes and production technology thereof |
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