CN106380084A - Antibacterial structure, refrigerator and processing method of antibacterial toughened glass - Google Patents

Antibacterial structure, refrigerator and processing method of antibacterial toughened glass Download PDF

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Publication number
CN106380084A
CN106380084A CN201610728314.2A CN201610728314A CN106380084A CN 106380084 A CN106380084 A CN 106380084A CN 201610728314 A CN201610728314 A CN 201610728314A CN 106380084 A CN106380084 A CN 106380084A
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CN
China
Prior art keywords
antibacterial
ink
glass
nano
refrigerator
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Pending
Application number
CN201610728314.2A
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Chinese (zh)
Inventor
杨乐庭
鲁俊
沈剑
张永飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Hualing Co Ltd
Midea Group Co Ltd
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Hefei Hualing Co Ltd
Midea Group Co Ltd
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Priority to CN201610728314.2A priority Critical patent/CN106380084A/en
Publication of CN106380084A publication Critical patent/CN106380084A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2201/00Polymeric substrate or laminate
    • B05D2201/02Polymeric substrate

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Belonging to the field of antibacterial technologies of refrigerators, the invention discloses an antibacterial structure. The antibacterial structure comprises an antibacterial layer formed by mixing of ink and a nano-silver antibacterial agent, the antibacterial layer is cured on a substrate, nano-silver particles do not agglomerate or overflow, the antibacterial effectiveness is lasting, also the antibacterial structure does not change in color, and the appear does not change easily. The nano-silver particles are evenly distributed at all parts of the substrate surface, and have good antibacterial and bactericidal effects. The invention relates to a refrigerator, the panel and shelf surface of the refrigerator are composed of the antibacterial structure, so that the refrigerator has antibacterial properties. The nano-silver particles do not agglomerate or overflow easily, the appearance and performance of components do not change, and the long-term antibacterial effect is good. The invention also relates to a processing method of antibacterial toughened glass, and the method consists of: coating the glass substrate surface with the antibacterial layer formed by mixing of ink and the nano-silver antibacterial agent, curing the antibacterial layer and conducting overall toughening treatment. The obtained antibacterial toughened glass has antibacterial properties and good long-term antibacterial effect, does not change in color easily, and has good rigidity.

Description

A kind of antibacterial structure, refrigerator, the processing method of antibacterial safety glass
Technical field
The present invention relates to refrigerater antibiotic technical field, particularly to a kind of antibacterial structure, refrigerator, antibacterial safety glass plus Work method.
Background technology
The sterilizing fresh-keeping function of refrigerator product emerges in an endless stream in the market, the fresh-keeping antibacterial of such as VC, plasma, silver ion Antibacterial etc., such mainly module by adding sterilized antibacterial to play the effect of sterilization, rather than the material of refrigerator Itself there is the function of sterilization, antibacterial.
Each position of refrigerator due to human body, the continuous contact of food and produce bacterium, particularly refrigerator inside glass The outer surface of shelf and refrigerator is the most serious.Therefore in recent years, consumer is also more next for the antibacterial of refrigerator product, sterilized requirement Higher, single interpolation antibacterial module cannot meet the requirement of consumer.
Nowadays heavy metal ion antibacterial also quickly grows, and in heavy metal ion sterilization, the bactericidal effect of silver ion is the brightest Aobvious, also by people use the most extensive, but main a shortcoming of silver ion for sterilization is exactly silver easily oxidation change Color, leads to material variable color, and the outward appearance of impact material even affects the performance of material itself, and has silver in use and overflow The phenomenon going out, affects the long-lasting of material antibacterial.
Content of the invention
(1) technical problem to be solved
The technical problem to be solved in the present invention is:Often connect with people for the indoor shelf of the panel and storage that solve refrigerator Touch, the single mode block in the indoor setting antibacterial mould of storage cannot meet the problem of user's request.
(2) technical scheme
In order to solve above-mentioned technical problem, the invention provides a kind of antibacterial structure, including:Base material and be solidificated in described base The antibiotic layer on material surface, described antibiotic layer is 0.5~1.5 by mass ratio:1000 nano silver antimicrobials and ink mix.
Wherein, the thickness of described antibiotic layer is 15-20 μm.
Wherein, the particle diameter of the Nano Silver in described nano silver antimicrobials is 15-300nm.
Wherein, described ink is transparent ink.
Wherein, described base material is glass.
Wherein, described base material is plastics.
The present invention also disclosed a kind of refrigerator, and the panel of at least described refrigerator and/or the surface of storeroom shelf are by above-mentioned Antibacterial structure forms.
The present invention also disclosed a kind of processing method of antibacterial safety glass, comprises the following steps:
S1, prepare antibacterial ink:By nano silver antimicrobials with ink with mass ratio for 0.5~1.5:1000 ratio mixing And stir;
S2, choose be cut to specified size, without tempering process, cleaning glass baseplate;
S3, the nano silver antimicrobials that step S1 is obtained and the mixed material of ink are coated in the glass base described in step S2 Material surface;
S4, to step S3 process after glass baseplate carry out curing process;
S5, to step S4 process after glass baseplate carry out tempering process.
Wherein, in described step S1, mixing time is 2 hours, not higher than 60 DEG C of whipping temp.
Wherein, in described step S3, described antibacterial ink is coated in described glass baseplate table by silk-screen printing technique Face.
Wherein, the coating thickness of described antibacterial ink is 15-20 μm.
Wherein, described in described step S4, the condition of curing process is:Solidify 7-8 minute in the environment of 150 DEG C -180 DEG C.
Wherein, described in described step S5, the condition of tempering process is:Tempering 7-8 in 600 DEG C -650 DEG C High temperature tempered stoves Minute.
(3) beneficial effect
Technique scheme has the advantage that:A kind of antibacterial structure of the present invention, had by ink by antibacterial structure and The antibiotic layer that nano silver antimicrobials are mixed into, antibiotic layer is solidificated on base material, and nano-Ag particles are not in reunite or overflow now As, antimicrobial long-acting is good, and antibacterial structure will not variable color, outward appearance be not susceptible to change;Nano-Ag particles are evenly distributed on base material Everywhere, antibacterial, bactericidal effect are good on surface.
A kind of refrigerator of the present invention, the panel of refrigerator, the surface of shelf are made up of above-mentioned antibacterial structure, make refrigerator the most easily with The part of people's contact has antibiotic and sterilizing performance, and nano-Ag particles are difficult to reunite or overflow it is ensured that the outward appearance of original part and property Can not change, antimicrobial long-acting is preferable.
A kind of processing method of present invention antibacterial safety glass, is to be resisted by ink and Nano Silver in glass substrate surface coating Antibiotic layer that microbial inoculum mixes simultaneously is solidified and is carried out overall steel process;The antibacterial safety glass obtaining has antibacterial Performance, antimicrobial long-acting is good, not easy to change, and rigidity preferably, can be used to make the panel of refrigerator or shelf, improves the anti-of refrigerator Bacterium bactericidal property, protects user health.
Brief description
Fig. 1 is the structural representation of antibacterial structure of the present invention.
Wherein, 1, base material;2nd, Nano Silver;3rd, antibiotic layer.
Specific embodiment
With reference to the accompanying drawings and examples, the specific embodiment of the present invention is described in further detail.Hereinafter implement Example is used for the present invention is described, but is not limited to the scope of the present invention.
In describing the invention, it should be noted that unless otherwise stated, " multiple " be meant that two or two with On;Term " on ", D score, "left", "right", " interior ", " outward ", " front end ", " rear end ", " head ", the orientation of the instruction such as " afterbody " Or position relationship is based on orientation shown in the drawings or position relationship, it is for only for ease of the description present invention and simplifies description, and It is not instruction or the hint device of indication or element must have specific orientation, with specific azimuth configuration and operation, therefore It is not considered as limiting the invention.Additionally, term " first ", " second ", " the 3rd " etc. are only used for describing purpose, and can not It is interpreted as indicating or imply relative importance.
In describing the invention in addition it is also necessary to explanation, unless otherwise clearly defined and limited, term " installation ", " being connected ", " connection " should be interpreted broadly, for example, it may be being fixedly connected or being detachably connected, or integratedly connect Connect;Can be to be mechanically connected or electrically connect;Can be to be joined directly together it is also possible to be indirectly connected to by intermediary.Right For those of ordinary skill in the art, visual concrete condition understands above-mentioned term concrete meaning in the present invention.
Embodiment one:
As shown in figure 1, the invention discloses a kind of antibacterial structure, including:Base material 1 and be solidificated in described base material 1 surface Antibiotic layer 3, described antibiotic layer 3 is 0.5~1.5 by mass ratio:1000 nano silver antimicrobials and ink mix.The present invention Described nano silver antimicrobials are a kind of conventional antiseptics, can directly purchase, the content of wherein Nano Silver 2 typically constitutes from Nano Silver The 2% of antiseptic gross weight;By mixing existing nano silver antimicrobials by a certain percentage with ink, make antibiotic layer 3, so Afterwards this antibiotic layer 3 is coated and be solidificated in base material 1 surface;During nano silver antimicrobials and the blended curing process of ink, Intercalation can be produced, nano silver antimicrobials pass through the intercalation of mineral crystal interlayer, by Nano Silver 2 in crystal interlayer in situ Synthesis, then nano-Ag particles are fettered by the Van der Waals force between crystal, hinder nano-Ag particles to reunite or overflow, be finally reached Durable antibiotic effect;Because nano silver antimicrobials proportion is less, along with being sufficiently mixed of nano silver antimicrobials and ink, Color thus without impact ink itself.This antibacterial structure had the fungi-proofing performance of good antibacterial;Nano-Ag particles quilt It is solidificated in ink, in the presence of intermolecular force, nano-Ag particles cannot depart from situ, is not in nano-Ag particles The phenomenon reunited or even overflow, is not in the phenomenon of antibacterial structure variable color, the antibacterial functions duration is long simultaneously, has long-acting The function of antibacterial.When the mass ratio of nano silver antimicrobials and ink is 0.5:When 1000, Nano Silver 2 total amount is less, antibacterial effect Relatively poor;When the mass ratio of nano silver antimicrobials and ink is 1.5:When 1000, Nano Silver 2 total amount is relatively many, and antibacterial is imitated Fruit is relatively preferable, then the color that at most can disturb ink;Suitable ratio can be selected during manufacture as needed to be mixed.
Specifically, the thickness of described antibiotic layer 3 is 15-20 μm.The thickness of antibiotic layer 3 should not be excessively thin, otherwise can affect it Anti-microbial property is it is impossible to realize the fungi-proofing function of effective antibacterial;But also unsuitable blocked up, antibiotic layer 3 is blocked up may to affect solidification effect, Affect the antimicrobial long-acting of this antibacterial structure.Will antibiotic layer 3 thickness to be taken at 15-20 μm of scope be a preferred scope, Within the range, this antibacterial structure had both enabled the fungi-proofing effect of good antibacterial, and can obtain preferable solidification effect, antibiotic layer When 3 thickness take 15 μm, solidification effect is preferable, but antibacterial effect is slightly poor;And antibiotic layer 3 thickness is when taking 20 μm, solidification effect is poor, But antibacterial effect is preferable;So suitable antibiotic layer 3 thickness can be chosen as needed within the range.
Preferably, the particle diameter of the Nano Silver 2 in described nano silver antimicrobials is 15-300nm.
Preferably, described ink is transparent ink.The color of base material 1 can be shown have with transparent ink again Preferably aesthetic property.Colored ink can certainly be adopted to require to meet different appearance designs.
Preferably, described base material 1 is glass.Glass properties is stable and has certain rigidity, and this antibacterial structure is permissible It is arranged on the surface of the parts such as panel, the shelf of refrigerator, both enabled to support, there is good anti-microbial property again.
Preferably, described base material 1 is plastics.In use, its surface can touch various germs to mobile phone, But there is long-time and human contact, there is certain healthy hidden danger;Curable product is then more easily accessible to germ;When base material 1 is During plastics, this antibacterial structure can be arranged on phone housing or curable product, so that phone housing or curable product was both had There is the fungi-proofing function of antibacterial, and lighter in weight, use for a long time and also will not feel very tried.
Embodiment two:
The present invention also disclosed a kind of refrigerator, and the panel of at least described refrigerator and/or the surface of storeroom shelf are by above-mentioned Antibacterial structure forms.
In use, panel and shelf are the easiest and human contact two positions to refrigerator, are that germ is easiest to grow Place that is raw and propagating, the antibacterial structure described in embodiment one is arranged on panel surface or shelf surfaces is made with antibacterial work( The panel of energy and shelf, then the germ being effectively reduced on refrigerator grows quantity, protects user health.Simultaneously because Nano Silver Grain is cured in ink, and nano-Ag particles cannot be reunited under the influence of intermolecular force or be overflowed, it is possible to achieve long-acting The fungi-proofing purpose of antibacterial;Nano-Ag particles cannot be reunited, and antibacterial structure will not occur variable color, and that is, panel or shelf surfaces also will not Metachromatism occurs it is ensured that the aesthetic property of panel or shelf because silver nanoparticle Argent grain is reunited;Antibacterial structure be distributed in panel or The surface of shelf, panel, shelf there is antibiotic property everywhere, the side relatively antibacterial module being somewhere set with existing Formula, the antibacterial functions of the present embodiment are more comprehensive, antibacterial effect greatly promotes.Either manufacture shelf or panel, base material 1 is all From glass;When manufacturing shelf, ink is preferably transparent ink, and shelf color is difficult to obscure with food materials, easy to use, improves and uses The comfort at family;When manufacturing panel, ink is preferably colored ink to lift the aesthetic property of panel.
Embodiment three:
The present invention also disclosed a kind of processing method of antibacterial safety glass, comprises the following steps:
S1, prepare antibacterial ink:By nano silver antimicrobials with ink with mass ratio for 0.5~1.5:1000 ratio mixing And stir;This ratio is a preferred scope, and nano silver antimicrobials are 0.5 with the mass ratio of ink:When 1000, nanometer Silver antibacterial agent is less, and antibacterial effect is slightly poor;Nano silver antimicrobials are 1.5 with the mass ratio of ink:When 1000, nano silver antimicrobials More, antibacterial effect is preferable.It is nano silver antimicrobials gross weight that described nano silver antimicrobials generally refer to nano-Ag particles content The 2% of amount, if it is also possible to pass through to adjust nanometer silver antimicrobial when in nano silver antimicrobials, the content of nano-Ag particles is higher or low The mode of the ratio of agent and ink adjusts the content of nano-Ag particles in whole antibiotic layer 3, to ensure antibacterial effect;
S2, choose be cut to specified size, without tempering process, cleaning glass baseplate;Can not after glass tempering Cut, so directly selecting the glass baseplate being cut to given size before coating and being cleaned clean, waited to be coated Antibiotic layer 3;
S3, the nano silver antimicrobials that step S1 is obtained and the mixed material of ink are coated in the glass base described in step S2 Material surface;Coating procedure should ensure that and coats uniformly everywhere so that glass baseplate nano-Ag particles are evenly distributed it is ensured that glass everywhere Base material antibacterial effect everywhere;
S4, to step S3 process after glass baseplate carry out curing process;After coating, glass baseplate is solidified with antibiotic layer 3 Together, so that antibiotic layer 3 and glass baseplate is fastenedly connected, the ink being also simultaneously is cured, make the nano-Ag particles in ink It is fixed in certain scope and cannot move, nano-Ag particles are reunited or the phenomenon overflowed is it is ensured that this antibacterial steel to avoid the occurrence of Change the anti-microbial property of glass;Nano-Ag particles will not be reunited, antibacterial safety glass will not variable color it is ensured that aesthetic property;
S5, to step S4 process after glass baseplate carry out tempering process.Tempering is processed can be hard with reinforcing glass base material Degree, strengthens its bearing capacity, reduces the damage probability of this antibacterial safety glass.
This antibacterial safety glass with glass for base material 1 can be made the panel of refrigerator, shelf etc. and often connect with human body Touch the part of easily dead endophytic bacteria, improve the anti-microbial property of refrigerator;Nano-Ag particles will not be reunited or be overflowed, and antimicrobial long-acting is relatively Good and will not variable color;Do not change original component capabilities and outward appearance while realizing antibacterial functions;Improve the antibacterial of part Bactericidal property.
Specifically, in described step S1, mixing time is 2 hours, not higher than 60 DEG C of whipping temp.Mixing time is long, Nano silver antimicrobials can be made to be sufficiently mixed with ink;Whipping temp is low, nano-Ag particles can be avoided to reunite, make Nano Silver Grain is uniformly distributed in humour.
In described step S3, described antibacterial ink is coated in described glass substrate surface by silk-screen printing technique.Institute The coating thickness stating antibacterial ink is 15-20 μm.Silk-screen printing technique can make antibiotic layer 3 be coated in glass uniformly, securely Substrate surface it is ensured that everywhere antibiotic layer 3 thickness distribution uniform;The thickness of antibiotic layer 3 can be selected according to actual conditions, preferably For 15-20 μm, to realize antibacterial, on the premise of fungi-proofing, sterilizing function, to facilitate the solidification of antibiotic layer 3, it is to avoid nanometer occurs The phenomenon that Argent grain is reunited or overflowed.
Preferably, described in described step S4, the condition of curing process is:In the environment of 150 DEG C -180 DEG C, solidification 7-8 divides Clock.Using hot setting, nano silver antimicrobials will not be destroyed with ink structure it is ensured that nano-Ag particles are uniformly distributed and do not go out Existing agglomeration.
Preferably, described in described step S5, the condition of tempering process is:Tempering 7- in 600 DEG C -650 DEG C High temperature tempered stoves 8 minutes.Tempering conditions can require flexibly to select according to hardness to product etc., tempering parameters here be one preferably real Apply scope.
The above is only the preferred embodiment of the present invention it is noted that ordinary skill people for the art For member, on the premise of without departing from the technology of the present invention principle, some improvement can also be made and replace, these improve and replace Also should be regarded as protection scope of the present invention.

Claims (13)

1. a kind of antibacterial structure is it is characterised in that include:Base material and the antibiotic layer being solidificated in described substrate surface, described antibacterial Layer is 0.5~1.5 by mass ratio:1000 nano silver antimicrobials and ink mix.
2. antibacterial structure as claimed in claim 1 is it is characterised in that the thickness of described antibiotic layer is 15-20 μm.
3. antibacterial structure as claimed in claim 1 is it is characterised in that the particle diameter of Nano Silver in described nano silver antimicrobials is 15-300nm.
4. antibacterial structure as claimed in claim 1 is it is characterised in that described ink is transparent ink.
5. the antibacterial structure as described in any one of claim 1-4 is it is characterised in that described base material is glass.
6. the antibacterial structure as described in any one of claim 1-4 is it is characterised in that described base material is plastics.
7. a kind of refrigerator is it is characterised in that the panel of at least described refrigerator and/or the surface of storeroom shelf are by claim 1- Antibacterial structure composition described in 6 any one.
8. a kind of processing method of antibacterial safety glass is it is characterised in that comprise the following steps:
S1, prepare antibacterial ink:By nano silver antimicrobials with ink with mass ratio for 0.5~1.5:1000 ratio mixes and stirs Mix uniformly;
S2, choose be cut to specified size, without tempering process, cleaning glass baseplate;
S3, the nano silver antimicrobials that step S1 is obtained and the mixed material of ink are coated in the glass baseplate table described in step S2 Face;
S4, to step S3 process after glass baseplate carry out curing process;
S5, to step S4 process after glass baseplate carry out tempering process.
9. the processing method of antibacterial safety glass as claimed in claim 8 is it is characterised in that in described step S1, stir Time is 2 hours, not higher than 60 DEG C of whipping temp.
10. the processing method of antibacterial safety glass as claimed in claim 8 is it is characterised in that in described step S3, described Antibacterial ink is coated in described glass substrate surface by silk-screen printing technique.
The processing method of 11. antibacterial safety glass as claimed in claim 8 is it is characterised in that the coating of described antibacterial ink Thickness is 15-20 μm.
The processing method of 12. antibacterial safety glass as claimed in claim 8 is it is characterised in that solidify described in described step S4 Process condition be:Solidify 7-8 minute in the environment of 150 DEG C -180 DEG C.
The processing method of 13. antibacterial safety glass as claimed in claim 8 is it is characterised in that tempering described in described step S5 Process condition be:Tempering 7-8 minute in 600 DEG C -650 DEG C High temperature tempered stoves.
CN201610728314.2A 2016-08-25 2016-08-25 Antibacterial structure, refrigerator and processing method of antibacterial toughened glass Pending CN106380084A (en)

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CN107327103A (en) * 2017-07-17 2017-11-07 佛山科学技术学院 A kind of antibacterial devitrified glass composite brick
CN108397973A (en) * 2018-04-24 2018-08-14 唐山启明星玻璃深加工有限公司 Application process of the antibiotic glass in antibacterial household electrical appliances
CN109574483A (en) * 2019-01-04 2019-04-05 唐山佐仑环保科技有限公司 A kind of processing technology of antibacterial tempered glass
CN111807710A (en) * 2020-07-23 2020-10-23 长虹美菱股份有限公司 Front touch layer glass for refrigerator and production process thereof
CN111807712A (en) * 2020-07-23 2020-10-23 长虹美菱股份有限公司 Self-cleaning glass panel of refrigerator and preparation process thereof
CN112344631A (en) * 2020-11-06 2021-02-09 长虹美菱股份有限公司 Refrigerator antibacterial steel plate door body
CN113372011A (en) * 2021-06-10 2021-09-10 深圳市秉兴光电技术有限公司 Production process of toughened antibacterial glass
CN113562984A (en) * 2021-08-17 2021-10-29 长虹美菱股份有限公司 Preparation method of touch display antibacterial layer of refrigerator glass
CN116143418A (en) * 2023-04-21 2023-05-23 山东孟友新材料科技有限责任公司 Antibacterial toughened glass and preparation method thereof

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107327103A (en) * 2017-07-17 2017-11-07 佛山科学技术学院 A kind of antibacterial devitrified glass composite brick
CN108397973A (en) * 2018-04-24 2018-08-14 唐山启明星玻璃深加工有限公司 Application process of the antibiotic glass in antibacterial household electrical appliances
CN109574483A (en) * 2019-01-04 2019-04-05 唐山佐仑环保科技有限公司 A kind of processing technology of antibacterial tempered glass
CN111807710A (en) * 2020-07-23 2020-10-23 长虹美菱股份有限公司 Front touch layer glass for refrigerator and production process thereof
CN111807712A (en) * 2020-07-23 2020-10-23 长虹美菱股份有限公司 Self-cleaning glass panel of refrigerator and preparation process thereof
CN112344631A (en) * 2020-11-06 2021-02-09 长虹美菱股份有限公司 Refrigerator antibacterial steel plate door body
CN113372011A (en) * 2021-06-10 2021-09-10 深圳市秉兴光电技术有限公司 Production process of toughened antibacterial glass
CN113562984A (en) * 2021-08-17 2021-10-29 长虹美菱股份有限公司 Preparation method of touch display antibacterial layer of refrigerator glass
CN116143418A (en) * 2023-04-21 2023-05-23 山东孟友新材料科技有限责任公司 Antibacterial toughened glass and preparation method thereof
CN116143418B (en) * 2023-04-21 2023-08-18 山东孟友新材料科技有限责任公司 Antibacterial toughened glass and preparation method thereof

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