CN106367776A - Electrolysis device and gas output equipment used for outputting hydrogen-containing mixed gas and provided with electrolysis device - Google Patents

Electrolysis device and gas output equipment used for outputting hydrogen-containing mixed gas and provided with electrolysis device Download PDF

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Publication number
CN106367776A
CN106367776A CN201611025215.4A CN201611025215A CN106367776A CN 106367776 A CN106367776 A CN 106367776A CN 201611025215 A CN201611025215 A CN 201611025215A CN 106367776 A CN106367776 A CN 106367776A
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China
Prior art keywords
electrode plate
gas
negative electrode
isolation
plate
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CN201611025215.4A
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Chinese (zh)
Inventor
丁卫军
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Shanghai Dingxin Medical Equipment Co Ltd
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Shanghai Dingxin Medical Equipment Co Ltd
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Priority to CN201611025215.4A priority Critical patent/CN106367776A/en
Publication of CN106367776A publication Critical patent/CN106367776A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/10Mixing gases with gases
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention provides an electrolysis device and gas output equipment used for outputting hydrogen-containing mixed gas and provided with the electrolysis device. The electrolysis device comprises positive electrode plates, negative electrode plates, isolating frame plates, first exhaust structures, second exhaust structures and flow guiding structures, wherein the isolating frame plates are arranged between the positive electrode plates and the negative electrode plates, ion films are arranged in frames of the isolating frame plates, a first electrode chamber is formed between each ion film and the corresponding positive electrode plate, and a second electrode chamber is formed between each ion film and the corresponding negative electrode plate; the first exhaust structures penetrate through the first electrode chambers to exhaust electrolyzed first gas from the first electrode chambers; the second exhaust structures penetrate through the second electrode chambers to exhaust electrolyzed second gas from the second electrode chambers; and the flow guiding structures communicate with the first electrode chambers and the second electrode chambers and are used for guiding electrolyte into the first electrode chambers and the second electrode chambers. The gas output equipment used for outputting hydrogen-containing mixed gas comprises the electrolysis device. The electrolysis device is made of plate structures, so that manufacturing and assembling efficiency is effectively improved.

Description

Electrolysis unit and the gas outut device of the output hydrogen gaseous mixture being suitable for
Technical field
The present invention relates to the construction applications of electrolysis unit, more particularly, to a kind of electrolysis unit and the output hydrogen being suitable for The gas outut device of gaseous mixture.
Background technology
Research shows, human body sucks appropriate amount of hydrogen daily, can be good at resisting the attack of oxygen-derived free radicals, makes each cell The state that can automatically keep fit, removing body become rusty, slow down aging, simultaneously to allergic dermatitises, constipation, hypertension, diabetes, Cancer etc. has preventive and therapeutic effect by all kinds of symptoms that free radical causes.For this reason, output is mixed with the air outut device of hydrogen, such as Hydrogen respirator etc., is available for the hydrogen of human body respiration as offer, the health care facility of oxygen arises at the historic moment, and in medical treatment, health care, U.S. Hold industry development rapid.Produce hydrogen using electrolysis bath, be a kind of convenient, inexpensive mode, so, most of hydrogen are exhaled at present In suction machine, hydrogen generating apparatus are electrolysis unit.Traditional water electrolyser, volume is big, complex structure, and the hydrogen of generation and oxygen Gas easily mixes, safety low it is difficult to meet medical, health care, the requirement to water electrolyser for the hydrogen respirator cosmetically.For water power Positive and negative electrode room in electrolysis unit is kept apart in existing hydrogen respirator by the deficiency that solution groove exists, more each electrode bar is pacified It is contained in counter electrode room.Although this kind of mode solves the problems, such as the hydrogen-oxygen mixing of traditional electrolyte groove, yet suffer from tying Structure is complicated, the low problem of assembling capacity.
Content of the invention
The present invention provides the gas outut device of a kind of electrolysis unit and the output hydrogen gaseous mixture being suitable for, for solving The certainly complex structure of electrolysis bath, the low problem of assembling capacity in health care kind equipment.
A first aspect of the present invention, provides a kind of electrolysis unit, comprising: positive electrode plate;Negative electrode plate;Isolation deckle board, if Put between described positive electrode plate and negative electrode plate, described isolation deckle board inframe there is ionic membrane, described ionic membrane with described It is formed with first electrode room between anelectrode;It is formed with second electrode room between described ionic membrane and described negative electrode;First row Depressed structure, first electrode room described in insertion, the first gas of electrolysis are discharged from first electrode room;Second exhaust structure, passes through Lead to described second electrode room, the second gas of electrolysis are discharged from second electrode room;Flow guiding structure, connects described first electrode Room and second electrode room, electrolyte is introduced described first electrode room and second electrode room.
In certain embodiments, the quantity of at least one of described positive electrode plate and negative electrode plate is multiple, and according to just Negative alternately arranged;The quantity of described isolation deckle board is multiple, and described isolation deckle board is spaced described positive electrode plate and negative electrode plate.
In certain embodiments, also include: insulation side plate, clamp described positive electrode plate or negative electrode with described isolation deckle board Plate.
In certain embodiments, described first exhaust structure and second exhaust structure all comprise to be arranged on described isolation deckle board Plate body on air vent.
In certain embodiments, described first exhaust structure includes: the first current path, is arranged on by adjacent described isolation On the plate body of at least part of positive electrode plate of deckle board clamping;And/or, described second exhaust structure includes: the second current path, if Put by the plate body of at least part of negative electrode plate of adjacent described isolation deckle board clamping.
In certain embodiments, described flow guiding structure includes electrolyte inlet port, and described electrolyte inlet port is arranged on institute State on isolation deckle board.
In certain embodiments, described flow guiding structure includes: electrolyte path, is arranged between described isolation deckle board extremely Small part positive electrode plate and on the plate body of negative electrode plate.
In certain embodiments, by all positive electrode plates and negative electrode plate the plate bodys of adjacent described isolation deckle board clamping On be equipped with electrolyte path;Described flow guiding structure also includes: is arranged in the electrolyte inlet port on one of isolation deckle board.
In certain embodiments, described positive electrode plate, negative electrode plate, isolation deckle board and insulation board plate body on be equipped with dress Join area, for assembling.
In certain embodiments, the plate body of described positive electrode plate and negative electrode plate is additionally provided with wire connecting portion, described wire connecting portion It is arranged on outside assembly section.
In certain embodiments, described insulation side plate and isolation deckle board are obtained via same contour mould, and described insulation Side plate integral insulation.
A second aspect of the present invention, also provides a kind of gas outut device of output hydrogen gaseous mixture, comprising: above-mentioned Electrolysis unit, control device, electrolyte input equipment, hydrogen treat device and oxygen treatments applied device;Described control device is provided with Anelectrode interface and negative electrode interface, wherein, described anelectrode interface connects the positive electrode plate in described electrolysis unit, described negative Electrode interface connects the negative electrode plate in described electrolysis unit;First row in described oxygen treatments applied device and described electrolysis unit Depressed structure is connected;Described hydrogen treat device is connected with the second exhaust structure in described electrolysis unit;Described electrolyte input Device is connected with the flow guiding structure in described electrolysis unit.
In certain embodiments, described hydrogen treat device includes: diluted in hydrogen assembly;Described diluted in hydrogen assembly bag Include: air introduction part and gas hydrid component;Described air introduction part is connected with described gas mixing part, and described second Exhaust structure is connected with described gas mixing part;It is outer that the described gas mixing part described air introduction part of mixing is imported The hydrogen that portion's air and described second exhaust structure are exported.
In certain embodiments, described oxygen treatments applied device includes: oxygen discharge member, with described first exhaust structure phase Even, for being discharged into the oxygen being received in air.
In certain embodiments, described oxygen treatments applied device also with described hydrogen treat device in gas mixing part phase Even, hydrogen that described gas mixing part mixing is externally introduced air, described second exhaust structure are exported and described Oxygen.
In certain embodiments, described hydrogen treat device includes: gas filtration part, for by the gaseous mixture of hydrogen Body is filtered.
Electrolysis unit provided by the present invention and the gas outut device of the output hydrogen gaseous mixture being suitable for, due to electricity Solution device adopts full plate structure, and producers need not be docked and assembled one by one, substantially carries so manufacturing and all having with efficiency of assembling High.Simultaneously as to achieving air bound between first electrode room and second electrode room from produced hydrogen or oxygen gas cannot mix Become hazardous gas, effectively increase the use safety of hydrogen.
In addition, setting air vent and electrolyte inlet port are the broad-rulers that make use of isolation deckle board itself on isolation deckle board Very little, effectively reduce the size of electrolysis unit so that described electrolysis unit is easy to be applied in the housed device more simplified.
In addition, setting current path and electrolyte path are it is intended to reduce every further on positive electrode plate and negative electrode plate The making complexity of individual isolation deckle board, further increases the make efficiency of isolation deckle board.
In addition, the unified assembly section arranging on each plate, producer is conducive to carry out overall assembling.
In addition, the connection part side setting of positive electrode plate and negative electrode plate, effectively prevent the interfering with each other of electrode, further Improve efficiency of assembling.
In addition, described gas outut device utilizes the non-oxidizability of hydrogen, hydrogen is mixed with extraneous air, is user Health care and the medical environment of delaying senility are provided.
Brief description
Fig. 1 is electrolysis unit of the present invention structural representation in one embodiment.
Fig. 2 is the structural representation of electrolysis unit of the present invention a-a section in embodiment described in Fig. 1.
Fig. 3 is positive electrode plate structural representation in one embodiment in electrolysis unit of the present invention.
Fig. 4 is negative electrode plate structural representation in one embodiment in electrolysis unit of the present invention.
Fig. 5 is electrolysis unit of the present invention structural representation in another embodiment.
Fig. 6 is electrolysis unit of the present invention structural representation in yet.
Fig. 7 is electrolysis unit of the present invention structural representation in another embodiment.
Fig. 8 is positive electrode plate structural representation in one embodiment in electrolysis unit of the present invention.
Fig. 9 is negative electrode plate structural representation in one embodiment in electrolysis unit of the present invention.
Figure 10 is electrolysis unit of the present invention structural representation in another embodiment.
Figure 11 is electrolysis unit of the present invention structural representation in another embodiment.
Figure 12 exports the gas outut device structural representation in one embodiment of hydrogen gaseous mixture for the present invention.
Specific embodiment
Below by way of specific instantiation, embodiments of the present invention are described, those skilled in the art can be by this specification Disclosed content understands other advantages and effect of the present invention easily.The present invention can also be by addition different concrete realities The mode of applying is carried out or applies, and the every details in this specification can also be based on different viewpoints and application, without departing from Carry out various modifications and changes under the spirit of the present invention.
It should be noted that structure depicted in this specification institute accompanying drawings, ratio, size etc., all only in order to coordinate Content disclosed in bright book, so that those skilled in the art understands and reads, is not limited to the enforceable limit of the present invention Fixed condition, therefore do not have technical essential meaning, the adjustment of the modification of any structure, the change of proportionate relationship or size, not Under impact present invention effect that can be generated by and the purpose that can reach, all should still fall and obtain in disclosed technology contents In the range of covering.Meanwhile, in this specification cited as " on ", D score, "left", "right", " middle " and " one " etc. Term, be merely convenient to describe understands, and is not used to limit the enforceable scope of the present invention, the change of its relativeness or tune Whole, under no essence change technology contents, when being also considered as the enforceable category of the present invention.
The present invention is in view of that existing electrolysis unit is transplanted to the complex structure that hydrogen respirator brought, equipment installation difficulty is big Deng difficult, a kind of electrolysis unit is proposed, with effectively improve electrolysis unit itself and its place hydrogen respirator peripheral structure can Assembling.Although it should be noted that electrolysis unit of the present invention is more suitable for, hydrogen respirator etc. is medical, health-related set Standby, but be not restricted to this, described electrolysis unit can also individually or coordinate other devices to be arranged on electrolytic chlorine gas etc. such as to be electrolysed In the other equipment of gas.
Embodiment one
Refer to Fig. 1 to Fig. 6, wherein, Fig. 1 is electrolysis unit of the present invention structural representation in one embodiment.This Invent the electrolysis unit shown in this embodiment to include: positive electrode plate 11, negative electrode plate 13, isolation deckle board 12, first Exhaust structure 14, second exhaust structure 15, and flow guiding structure 16.
Wherein, positive electrode plate 11 and negative electrode plate 13 are conductive plate, its available same mould cutting gold of technical staff Belong to plate and obtain.In certain embodiments, a pair of positive electrode plate 11 and negative electrode plate 13 are only set in described electrolysis unit.
Described isolation deckle board 12 is arranged between described positive electrode plate 11 and negative electrode plate 13, the frame of described isolation deckle board 12 Inside there is ionic membrane 121, between described ionic membrane 121 and described positive electrode plate 11, be formed with first electrode room 19;Described ion It is formed with second electrode room 18 between film 121 and described negative electrode plate 13.Wherein, described first electrode room 19 and second electrode room 18 structural representation is as shown in Figure 2.
Specifically, described isolation deckle board 12 is insulant.On described isolation deckle board 12, one or more sashes can be set, There is in each sash ionic membrane 121.Wherein, described ionic membrane 121 can be ion exchange resin material, its can be sun from Proton exchange or anion exchange membrane.In some embodiments, electrolyte can pass through ionic membrane 121 in first electrode room 19 He Flow between second electrode room 18.Wherein, described isolation deckle board 12 thickness be more than ionic membrane 121 thickness so that described from Form first electrode room 19 between sub- film 121 and anelectrode, between described ionic membrane 121 and described negative electrode, be formed with the second electricity Pole room 18.For ease of assembling, the ionic membrane 121 on each isolation deckle board 12 is obtained by same material, same template, and seal It is embedded in the sash of described isolation deckle board 12, not only improve single electric charge with electrolyte movement to be formed, be effectively isolated electricity again The structure of solution gas.
Described positive electrode plate 11, isolation deckle board 12 and negative electrode plate 13 the formed electrolysis unit that is assembled together are integrally close Envelope, and first electrode room 19 therein and second electrode room 18 each other air bound from.For this reason, described isolation deckle board 12 preferably has concurrently Hardness and the insulation board of airtight demand, for example, described isolation deckle board 12 is epoxy insulating board, insulation resin sheet etc..
Described first electrode room 19 is through with first exhaust structure 14.Described first exhaust structure 14 is by first electrode The first gas of room 19 Inner electrolysis are discharged.
Described second electrode room 18 is through with second exhaust structure 15.Described second exhaust structure 15 is by second electrode The second gas of room 18 Inner electrolysis are discharged.
Here, described first exhaust structure 14 and second exhaust structure 15 can have identical structure.For example, described first row Depressed structure 14 and second exhaust structure 15 all comprise: be arranged on the air vent on the plate body of described isolation deckle board 12.Wherein, described Isolate the first hole in deckle board 12 framework described in air vent insertion and be located at the exhaustor on described first hole.For example, described Isolation deckle board 12 is located on two side frame bodies of isolating membrane and respectively arranges first hole and the airtight row being plugged on each first hole Trachea.
For the ease of being introduced into electrolyte in each electrode chamber of described electrolysis unit, described electrolysis unit also includes drain knot Structure 16.
Specifically, described flow guiding structure 16 connects described first electrode room 19 and second electrode room 18, and electrolyte is drawn Enter described first electrode room 19 and second electrode room 18.
Here, described flow guiding structure 16 may be provided between described positive electrode plate 11 and isolation deckle board 12, it is arranged on described Between negative electrode plate 13 and isolation deckle board 12.In certain embodiments, described flow guiding structure 16 is arranged on described isolation deckle board 12 Framework on.Specifically, described flow guiding structure 16 includes electrolyte inlet port, and described electrolyte inlet port is arranged on described isolation On deckle board 12.For example, described electrolyte inlet port includes: isolates deckle board 12 described in insertion and for electrolyte is introduced first Electrode chamber and the second hole of second electrode room, and it is inserted in the drainage tube in described second hole.
In order to avoid the short circuit of positive-negative electrode plate 13 and external circuit in described electrolysis unit, on the side of described electrolysis unit Side is additionally provided with insulation side plate 17.Described insulation side plate 17 clamps corresponding positive electrode plate 11 or negative electrode plate 13 to isolation deckle board 12. Described insulation side plate 17 can be pasted on clamped battery lead plate.In some embodiments, for the ease of assembling, described insulation Side plate 17 adopts same sheet material with isolation deckle board 12, and is made by same contour mould.Different from described isolation deckle board 12 , described insulation side plate 17 is integral insulation and need not be processed further the frame structure for arranging ionic membrane.
For the ease of the assembling of each plate, each plate body edge is provided with assembly section 111 (131), the assembly section 111 (131) of each plate It is configured with unified pilot hole, so that producer is according to insulation side plate 17, positive electrode plate 11, isolation deckle board 12, negative electrode plate 13 and insulation side plate 17 distributing order assembled.For the ease of positive electrode plate 11 and the external counter electrode of negative electrode plate 13, Wire connecting portion 112 (132), described wire connecting portion 112 (132) setting are additionally provided with the plate body of described positive electrode plate 11 and negative electrode plate 13 Outside assembly section 111 (131).Wherein, described wire connecting portion 112 (132) can be binding post or patch panel.In order to ensure dress Each electrode chamber after joining and external environment condition seal, and described wire connecting portion 112 (132) is preferably plate body and extends the part, and in institute Extend the part setting via.For example, as shown in Figures 3 and 4, described positive electrode plate 11 and negative electrode plate 13 are for unification is tailored Become, there is same shape, wherein, the edge of described positive electrode plate 11 and negative electrode plate 13 is provided with assembly section 111 (131) (in figure Dotted line institute's frame region), extend the wire connecting portion 112 (132) with via along plate body side for bottom.In certain embodiments, institute The assembly section 111 (131) stating positive electrode plate 11 and negative electrode plate 13 is in substantially axial symmetry, positive electrode plate 11 and negative electrode plate 13 Wire connecting portion 112 (132) extends along plate body side.In certain embodiments, positive and negative electrode external for convenience no touches each other, As shown in figure 5, in assembling, described positive electrode plate 11 wire connecting portion 112 and the wire connecting portion 113 of described negative electrode plate 13 set up separately In described electrolysis unit both sides, the wire connecting portion 112 (or 132) of homonymy connects identical electrodes.
Gas-liquid in order to prevent assembly section 111 (131) is revealed, sheathed close in the upper each pilot hole in described assembly section 111 (131) Tube sealing, to increase the seal of first electrode room and second electrode room.Wherein, described seal pipe citing is pv pipe.
In order to prevent described electrolysis unit from touching with the electricity of external circuit, as shown in fig. 6, described electrolysis unit is by two absolutely Rim plate 17 is side board, the positive electrode plate 11 of middle clamping sequential, isolation deckle board 12 and negative electrode plate 13.
Embodiment two
On the basis of the various embodiments described above, as shown in fig. 7, when the described positive electrode plate 11 in described electrolysis unit and bearing When the quantity of at least one of battery lead plate 13 is multiple, each positive electrode plate 11 and negative electrode plate 13 are staggered according to positive and negative. For example, when positive and negative electrode plate is multiple, such as positive electrode plate is the three: first positive electrode plate, the second positive electrode plate, the 3rd Positive electrode plate, such as negative electrode plate are the three: first negative electrode plate, the second negative electrode plate, the 3rd negative electrode plate, then aforesaid each Positive electrode plate and negative electrode plate according to positive and negative staggered order are then: the first positive electrode plate, the first negative electrode plate, second just Battery lead plate, the second negative electrode plate, the 3rd positive electrode plate, the 3rd negative electrode plate.
Need in described electrolysis unit to arrange multipair positive electrode plate 11 and negative electrode plate 13, and be staggered according to positive and negative.Institute State isolation deckle board 12 and be spaced each described positive electrode plate 11 and negative electrode plate 13, to be formed by some adjacent first electrode rooms by institute State positive electrode plate 11 to separate, some adjacent second electrode rooms are separated by described negative electricity pole room.
In certain embodiments, described first exhaust structure 14 includes: the first current path 141, is arranged on by adjacent institute State on the plate body of at least part of positive electrode plate 11 of isolation deckle board 12 clamping.
As shown in figure 8, institute is got through on the plate body of partial electrode plate in battery lead plate obtained by making according to uniform template State the first current path 141, and using the battery lead plate being provided with described first current path 141 as positive electrode plate 11, will not set Positive-negative electrode plate as negative electrode plate 13, then, in assembling, can be replaced and arrange by the battery lead plate being equipped with described first current path 141 Cloth, and clamped by each described isolation deckle board 12.
In certain embodiments, described second exhaust structure 15 includes: the second current path 151, is arranged on by adjacent institute State on the plate body of at least part of negative electrode plate 13 of isolation deckle board 12 clamping.
As shown in figure 9, institute is got through on the plate body of partial electrode plate in battery lead plate obtained by making according to uniform template State the second current path 151, and using the battery lead plate being provided with described second current path 151 as negative electrode plate 13, will not set Positive-negative electrode plate as positive electrode plate 11, then, in assembling, can be replaced and arrange by the battery lead plate being equipped with described second current path 151 Cloth, and clamped by each described isolation deckle board 12.
In certain embodiments, described first exhaust structure 14 includes: the first current path 141, is arranged on by adjacent institute State on the plate body of at least part of positive electrode plate 11 of isolation deckle board 12 clamping;And described second exhaust structure 15 includes: second Current path 151, is arranged on the plate body of at least part of negative electrode plate 13 being clamped by adjacent described isolation deckle board 12.
As shown in FIG. 8 and 9, due to positive electrode plate 11 and negative electrode plate 13 separately two with electrode electrode chamber 18 (19), Then can by arrange on the plate body with the battery lead plate 11 (13) of electrodes room 18 (19) for the interval corresponding first current path 141 or Second current path 151.The shape of this two kinds of current path 141 (151) is not limited, and can be circular, cylindrical, rectangle Deng.The size of this two kinds of current path 141 (151) can identical or according to the corresponding gas flow being electrolysed out depending on.Two with electricity Gas of the same race produced by the electrode chamber of pole can pass through corresponding current path 141 (151) appointing from this two electrode chamber 18 (19) One exhaust structure is discharged.For example, the first gas warp of the be electrolysed generation in two first electrode rooms 19 being spaced by positive electrode plate 11 By institute's insertion on described positive electrode plate 11 the first current path 141 from this two first electrodes room 19 arbitrary first exhaust structure 14 discharges.The second gas of the be electrolysed generation in two second electrode rooms 18 being spaced by negative electrode plate 13 are via described negative electrode plate On 13, the second current path 151 of institute's insertion arbitrary second exhaust structure 15 from this two second electrodes room 18 is discharged.
Because the quantity of first electrode room 19 and second electrode room 18 is multiple, then corresponding first exhaust structure 14 He The quantity of second exhaust structure 15 is also multiple.It is connected with the gas of electrolysis unit for the ease of external device (ED), described first row Depressed structure 14 and second exhaust structure 15 also each include: trachea linker (is unillustrated).Wherein, described first exhaust structure Air vent on each isolation deckle board 12 in 14 connects via wherein one trachea linker, respectively isolates in described second exhaust structure 15 Air vent on deckle board 12 connects via another trachea linker.Each described trachea linker selects many imports according to actual needs The communicating pipe of one outlet or the communicating pipe of many imports multiple exit.
In certain embodiments, in order to deckle board 12 is isolated in easier manufacture, each isolation deckle board 12 only sets described the One exhaust structure 14 or second exhaust structure 15.As shown in Figure 10, all positive electricity clamped by adjacent described isolation deckle board 12 Be equipped with current path on pole plate 11 and negative electrode plate 13 plate body, each described isolation deckle board 12 and be located at ionic membrane 121 Exhaust structure is arranged on the framework of homonymy.Aerofluxuss after each plate body is assembled into electrolysis unit, in first electrode room 19 Structure is first exhaust structure 14, and the exhaust structure in second electrode room 18 is second exhaust structure 15, and, adjacent the The current path on the plate body of positive electrode plate 11 between one electrode chamber be the first current path 141, adjacent second electrode room it Between the plate body of negative electrode plate 13 on current path be the second current path 151.
In assembling, described electrolysis unit is side board by two insulation side plates 17, the positive electricity of middle clamping sequential Pole plate 11, isolation deckle board 12, negative electrode plate 13, isolation deckle board 12, positive electrode plate 11, isolation deckle board 12, negative electrode plate 13 ..., Positive electrode plate 11, isolation deckle board 12, the structure of negative electrode plate 13, and carry out each plate body using the pilot hole of setting unified on each plate Overall assembling, to obtain by the electrolysis unit of each plate body crush seal.In described electrolysis unit, first electrode room and second electricity Pole room is gas communication between multiple and adjacent electrode chambers of same electrode, and during electrolysis, produced gas of the same race can be by setting The gas discharge structure put on the isolation deckle board 12 of ionic membrane 121 homonymy is discharged.
Described flow guiding structure 16 can individually configure and to be assembled into by positive electrode plate 11, isolation deckle board 12 and negative electrode plate 13 Every group of first electrode room and second electrode room.Each described flow guiding structure 16 includes electrolyte inlet port, and described electrolyte enters Mouth is arranged in the framework of described isolation deckle board 12.Wherein, described electrolyte inlet port includes penetrating described isolation deckle board 12 The second hole in framework and be inserted in the drainage tube on described second hole.
In order to simplify described flow guiding structure 16, it also includes: electrolyte path, is arranged between described isolation deckle board 12 At least partly on the plate body with negative electrode plate 13 of positive electrode plate 11.As shown in figure 11.
Specifically, the shape of described electrolyte path is not limited, and can be circle, cylinder, rectangle etc..Each battery lead plate On the size of electrolyte path can be identical.For the ease of the flowing of electrolyte, described electrolyte path is located in battery lead plate Bottom.In some embodiments, all positive electrode plates 11 and negative electrode plate being clamped by adjacent described isolation deckle board 12 It is equipped with electrolyte path on 13 plate body;Described flow guiding structure 16 also includes: is arranged on one of isolation deckle board 12 Electrolyte inlet port.
For example, as shown in figure 11, when manufacturing described electrolysis unit, multiple positive electrode plates 11 and multiple negative electrode plate 13 are by same One conductive sheet metal forms via the first same template cutting, and wherein, described first template leaves the wire connecting portion 112 of battery lead plate (132).Punched respectively in the bottom of part positive electrode plate 11 and part negative electrode plate 13 and top using perforating apparatus, position Constitute described electrolyte path in the hole of positive electrode plate 11 and negative electrode plate 13 bottom, positioned at positive electrode plate 11 and negative electrode plate 13 The hole at top constitutes corresponding first current path 141 and the second current path 151.The assembly section 111 of each described battery lead plate (131) pilot hole is worn by unified assembling punch device.
Multiple isolation deckle boards 12 and multiple insulation side plate 17 are formed via the second template cutting by same insulating sheet material, and profit Wear pilot hole with described assembling punch device in the assembly section 111 (131) of each isolation deckle board 12 and each insulation side plate 17.Its In, each described isolation deckle board 12 also carries out the cutting of sash after the cutting based on the second template, in sash sealing be embedded from Sub- film 121, and each described isolation deckle board 12 framework top and be located at ionic membrane 121 one side wear exhaust structure.Its In, obtain quantity for manufactured electrolysis unit, wear electrolyte in the framework bottom of the isolation deckle board 12 of respective amount and enter Mouthful.
In assembling, as shown in figure 11, described electrolysis unit is side board by two insulation side plates 17, and middle clamping is sequentially The positive electrode plate 11 (11 ') of arrangement, isolation deckle board 12, negative electrode plate 13 (13 '), isolation deckle board 12, positive electrode plate 11, isolation frame Plate 12, negative electrode plate 13 ..., positive electrode plate 11, isolation deckle board 12, the structure of negative electrode plate 13.Wherein, the positive electrode plate of punching 11 ' and negative electrode plate 13 ' be clamped between adjacent isolation deckle board 12, the positive electrode plate 11 not punched and negative electrode plate 13 quilt It is assemblied in insulation side plate 17 side.Wherein, comprise the isolation deckle board 12 with electrolyte inlet port in each described isolation deckle board 12.Raw Bolt and seal pipe are located in the assembling in the hole of each plate by product personnel, and the nut by fastening and bolt cooperation will be airtight for each plate Clamping.Form first electrode room between each described positive electrode plate 11 (11 ') and ionic membrane 121, respectively in the electrolysis unit being constituted Form second electrode room, the positive electrode plate between adjacent first electrode room between described negative electrode plate 13 (13 ') and ionic membrane 121 Hole on 11 ' is the first gas channel 141, described first gas channel 141 and air vent 142 structure communicating with first electrode room Become described first exhaust structure 14;The hole on negative electrode plate 13 ' between adjacent second electrode room is the second gas channel 151, The air vent 152 that described first gas channel 151 is communicated with second electrode room constitutes second exhaust structure 15.
In some embodiments, for the ease of concentrating external counter electrode, described positive electrode plate 11 and negative electrode plate 13 Wire connecting portion 112 (132) is located at described electrolysis unit both sides in the assembling time-division, and the wire connecting portion 112 (132) of homonymy connects identical electrodes. As shown in Figure 9.The wire connecting portion 112 (132) of homonymy can be utilized electric conductor to wear mode, and the battery lead plate of each same electrode is same with outside One electrode is unified to be connected.
Embodiment three
On the basis of the various embodiments described above, the application also provides a kind of gas output of output hydrogen gaseous mixture to set Standby.Described gas outut device can refer to arbitrarily provide the medical or health-related gas outut device of hydrogen gaseous mixture for live body, Its citing includes: oxy-hydrogen breathing machine, and the equipment containing plurality of health care functions such as body shaping, fat reducing, antioxidation etc..
As shown in figure 12, described gas outut device includes: the as above electrolysis unit 1 described in any embodiment, control Device 2, electrolyte input equipment 3, hydrogen treat device 4 and oxygen treatments applied device 5.
Wherein, described control device 2 is provided with anelectrode interface and negative electrode interface, and wherein, described anelectrode interface connects Positive electrode plate in described electrolysis unit 1, described negative electrode interface connects the negative electrode plate in described electrolysis unit 1;Described electricity Solution liquid input equipment 3 is connected with the flow guiding structure in described electrolysis unit 1;Described oxygen treatments applied device 5 and described electrolysis unit 1 In first exhaust structure be connected;Described hydrogen treat device 4 is connected with the second exhaust structure in described electrolysis unit 1.
Wherein, described control device 2 be used for control electrolysis unit 1 conduct with electrically disconnected.In certain embodiments, institute State control device 2 and can external switch be set, so that operator carry out being electrolysed control.Described control device 2 is main electric by controlling Road is constituted, and described control circuit is connected with external power source (as civil power), and has the circuit structures such as transformation, rectification.
Described electrolyte input equipment 3 be used for by water or be mixed with catalyst water input electrolysis unit 1 in.Described electrolyte Input equipment 3 is exemplified as the funnel with flexible pipe, and described flexible pipe one end is connected with funnel bottom, the other end and described electrolysis unit Flow guiding structure in 1 connects.Operator can be poured into electrolyte in electrolysis unit 1 by funnel.
Described hydrogen treat device 4 is used for for hydrogen produced by electrolysis being mixed in the air, and is supplied to using this gas The object of outut device.
Specifically, described hydrogen treat device 4 includes diluted in hydrogen assembly.Wherein, described diluted in hydrogen assembly includes: empty Gas introduction part and gas hydrid component;Wherein, described air introduction part is connected with described gas mixing part, and described second Exhaust structure is connected with described gas mixing part;It is outer that the described gas mixing part described air introduction part of mixing is imported The hydrogen that portion's air and described second exhaust structure are exported.
Here, described air introduction part includes air pump, extraneous air is introduced gas mixing part by described air pump In.Described gas mixing part can be the container holding mixed gas, and connects soft between described container and air pump Pipe.Described gas mixing part is also connected with described second exhaust structure.So, produced hydrogen and air in electrolysis unit 1 The introduced extraneous air of introduction part mixes in described gas mixing part, and described gas mixing part can be blended with hydrogen The gas of gas is supplied to user.
Described oxygen treatments applied device 5 is used for for the oxygen being electrolysed out being directly discharged into air.In certain embodiments, in order to give User provides environment rich, and the oxygen being electrolysed out will be discharged as unnecessary gas.
Specifically, described oxygen treatments applied device 5 includes: oxygen discharge member, is connected with described first exhaust structure, is used for The oxygen being received is discharged in air.For example, described oxygen discharge member includes being drawn by electrolysis unit 1 first exhaust structure The gas eduction tube going out.
In other some embodiments, in order to balance the hydrogen-oxygen content in mixed gas, described oxygen discharge member is also It is connected with the gas mixing part in described hydrogen treat device 4, air that the mixing of described gas mixing part is externally introduced, Hydrogen and described oxygen that described second exhaust structure is exported.For example, described oxygen discharge member is by first exhaust structure The oxygen part being exported is discharged into air, and another part is transported in gas mixing part, in order to balance mixed gas Hydrogen-oxygen ratio;Again mixed gas are supplied to by user by described gas mixing part.
In order to provide a user with the Gas Mixtures Containing Hydrogen of more cleaning, described hydrogen treat device 4 also includes: gas filtration portion Part (is unillustrated), for being filtered the mixed gas of hydrogen.
Here, described gas filtration part can be the filter flask that at least one holds water, each filter flask concatenation, so as to mixing Gas carries out multiple times of filtration, and the mixed gas after filtering are supplied to user.
Described gas outut device is exemplified below using the work process of above-mentioned each device:
The water that operator are blended with catalyst is imported in electrolysis unit 1 by electrolyte input equipment 3, and water is via institute State the flow guiding structure in electrolysis unit 1 and introduce the water into each electrode chamber.Then, operator or user open described control device 2 On switch so that positive electrode plate in electrolysis unit 1 connects anelectrode, negative electrode plate connects negative electrode, and start to be electrolysed water, Thus, each first electrode room produces oxygen, each second electrode room produces hydrogen.Oxygen and hydrogen are respectively via first exhaust structure Corresponding with second exhaust structure it is transported to hydrogen treat device 4 and oxygen treatments applied device 5.Wherein, oxygen treatments applied device 5 can be by All oxygen are discharged in air.The hydrogen being received is mixed by hydrogen treat device 4 with the outside air introducing, and passes through Filter is supplied to user.
Although the present invention is open as above with preferred embodiment, it is not for limiting the present invention, any this area Without departing from the spirit and scope of the present invention, the methods and techniques content that may be by the disclosure above is to this for technical staff Bright technical scheme makes possible variation and modification, and therefore, every content without departing from technical solution of the present invention, according to the present invention Technical spirit any simple modification, equivalent variations and modification that above example is made, belong to technical solution of the present invention Protection domain.

Claims (14)

1. a kind of electrolysis unit is it is characterised in that include:
Positive electrode plate;
Negative electrode plate;
Isolation deckle board, is arranged between described positive electrode plate and negative electrode plate, and the inframe of described isolation deckle board has ionic membrane, institute State and between ionic membrane and described anelectrode, be formed with first electrode room;It is formed with second between described ionic membrane and described negative electrode Electrode chamber;
First exhaust structure, first electrode room described in insertion, the first gas of electrolysis are discharged from first electrode room;
Second exhaust structure, second electrode room described in insertion, the second gas of electrolysis are discharged from second electrode room;And
Flow guiding structure, connects described first electrode room and second electrode room, and electrolyte is introduced described first electrode room and the Two electrode chambers.
2. electrolysis unit according to claim 1 is it is characterised in that at least one of described positive electrode plate and negative electrode plate Quantity be multiple, and according to positive and negative alternately arranged;The quantity of described isolation deckle board is multiple, and described isolation deckle board interval is described Positive electrode plate and negative electrode plate.
3. electrolysis unit according to claim 1 and 2 is it is characterised in that also include: insulation side plate, with described isolation frame Plate clamps described positive electrode plate or negative electrode plate.
4. electrolysis unit according to claim 1 and 2 is it is characterised in that described first exhaust structure and second row are depressed Structure all comprises the air vent being arranged on the plate body of described isolation deckle board.
5. electrolysis unit according to claim 2 is it is characterised in that described first exhaust structure includes: the first air-flow leads to Road, is arranged on by the plate body of at least part of positive electrode plate of adjacent described isolation deckle board clamping;
And/or, described second exhaust structure includes: the second current path, is arranged on and is clamped extremely by adjacent described isolation deckle board On the plate body of small part negative electrode plate.
6. electrolysis unit according to claim 1 and 2 is it is characterised in that described flow guiding structure includes electrolyte inlet port, Described electrolyte inlet port is arranged on described isolation deckle board.
7. electrolysis unit according to claim 6 is it is characterised in that described flow guiding structure includes: electrolyte path, setting In described isolation deckle board between at least part of positive electrode plate and on the plate body of negative electrode plate.
8. the electrolysis unit according to claim 6 or 7 is it is characterised in that all by adjacent described isolation deckle board clamping Positive electrode plate and electrolyte path is equipped with the plate body of negative electrode plate;Described flow guiding structure also includes: is arranged in wherein one Electrolyte inlet port on individual isolation deckle board.
9. electrolysis unit according to claim 3 is it is characterised in that described insulation side plate and isolation deckle board are via same wheel Wide template is obtained, and described insulation side plate integral insulation.
10. a kind of gas outut device of output hydrogen gaseous mixture is it is characterised in that include:
As described electrolysis unit arbitrary in claim 1-9, control device, electrolyte input equipment, hydrogen treat device and Oxygen treatments applied device;
Described control device is provided with anelectrode interface and negative electrode interface, and wherein, described anelectrode interface connects described electrolysis dress Positive electrode plate in putting, described negative electrode interface connects the negative electrode plate in described electrolysis unit;
Described oxygen treatments applied device is connected with the first exhaust structure in described electrolysis unit;
Described hydrogen treat device is connected with the second exhaust structure in described electrolysis unit;
Described electrolyte input equipment is connected with the flow guiding structure in described electrolysis unit.
The gas outut devices of 11. output hydrogen gaseous mixtures according to claim 10 are it is characterised in that described hydrogen Processing meanss include: diluted in hydrogen assembly;
Described diluted in hydrogen assembly includes: air introduction part and gas hydrid component;Described air introduction part and described gas Body hydrid component is connected, and described second exhaust structure is connected with described gas mixing part;Described gas mixing part mixes institute State the extraneous air that air introduction part imported and the hydrogen that described second exhaust structure is exported.
The gas outut devices of 12. output hydrogen gaseous mixtures according to claim 10 are it is characterised in that described oxygen Processing meanss include: oxygen discharge member, are connected with described first exhaust structure, for the oxygen being received is discharged into air In.
The gas outut device of the 13. output hydrogen gaseous mixtures according to claim 10 or 12 is it is characterised in that described Oxygen treatments applied device is also connected with the gas mixing part in described hydrogen treat device, and described gas mixing part mixes from outer Hydrogen and described oxygen that the air of portion's importing, described second exhaust structure are exported.
The gas outut devices of 14. output hydrogen gaseous mixtures according to claim 10 are it is characterised in that described hydrogen Processing meanss include: gas filtration part, for being filtered the mixed gas of hydrogen.
CN201611025215.4A 2016-11-18 2016-11-18 Electrolysis device and gas output equipment used for outputting hydrogen-containing mixed gas and provided with electrolysis device Pending CN106367776A (en)

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Application publication date: 20170201