CN105671586A - PEM membrane low-voltage hydrogen electrolysis and ozone generation system - Google Patents
PEM membrane low-voltage hydrogen electrolysis and ozone generation system Download PDFInfo
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- CN105671586A CN105671586A CN201610234948.2A CN201610234948A CN105671586A CN 105671586 A CN105671586 A CN 105671586A CN 201610234948 A CN201610234948 A CN 201610234948A CN 105671586 A CN105671586 A CN 105671586A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/13—Ozone
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Abstract
The invention discloses a PEM membrane low-voltage hydrogen electrolysis and ozone generation system which comprises a cathode water storage tank, an anode water storage tank, an electrolysis module and a constant-current switching power supply. The electrolysis module is communicated with the cathode water storage tank and the anode water storage tank respectively through a pipe and comprises a cathode electrolysis module and an anode electrolysis module, the constant-current switching power supply is connected with the cathode electrolysis module and the anode electrolysis module of the electrolysis module respectively through a lead, and both the cathode water storage tank and the anode water storage tank are located above the electrolysis module. The PEM membrane low-voltage hydrogen electrolysis and ozone generation system is simple in structure, can produce hydrogen-rich water and ozone water according to different demands, feeds hydrogen and ozone from the bottoms of the water storage tanks, improves the mixing effect, uses pure water and deionized water as raw materials and is good in safety performance, ozone does not contain by-product cancerogen and the like, and the comprehensive using cost is low. In addition, the water serves as a cooling medium itself, the electrolysis module does not need an additional cooling device, and a cathode catalyst and an anode catalyst which are prepared by adopting a unique process improve the hydrogen and ozone generation efficiency.
Description
Technical field
The invention belongs to technical field of electrochemistry, particularly relate to a kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system.
Background technology
Hydrogen molecule can remove human free radical, and the acute and chronic diseases that old and feeble and multiple reason free radical is caused has good therapeutical effect. " modern medicine thinks that the corruption of material is the process of acidifying (oxidation), Smoking And Drinking, environmental pollution etc. all can time human body in produce a large amount of peroxy radicals, its meeting vandalism cell tissue, cause genopathy and body aging, internal free radical can effectively be dispelled by reactive hydrogen, hydrogen rich water has and exceedes vitamin C, carotene, the non-oxidizability of the polyphenoils that all mankind such as lecithin are known, to allergic dermatitis, constipation, hypertension, diabetes, all kinds of symptoms that cancer etc. are caused by free radical have powerful protective action, often drink hydrogen rich water, can be good at enhancing metabolism, make the state that each cell can be kept fit, dispel body rust, slow down aging ".
Ozone has broad-spectrum sterilization, easy to use, feature without any residual and instantaneously sterilising, and completely avoid the harm that chemosterilant brings to environment, it it is a kind of desirably sterilization material, being widely used in public water system, food pharmaceutical, industrial processes, health care in the U.S., Japan, European many countries in recent years, particularly agricultural product produce, process and have fairly large application in storage and transport process.
Existing ozone generating-device there is also that to include carcinogen etc., the low operating environment requirements of ozone concentration containing by-product in produced ozone high, comprehensive use cost is high, there is the shortcomings such as potential safety hazard, and yet there are no the relevant report of generating means that can simultaneously produce hydrogen, ozone.
Summary of the invention
The technical problem to be solved is to provide a kind of simple in construction, efficiency is high, cost is low PEM membrane low-voltage electrolysis hydrogen, ozone generation system.
For solving above-mentioned technical problem, the invention provides a kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system, including negative electrode storage tank, anode storage tank, electrolytic module and constant-current switch power source, described electrolytic module is connected with described negative electrode storage tank and anode storage tank respectively by pipeline, described electrolytic module includes catholyte assembly and anode electrolysis assembly, described constant-current switch power source is connected with the catholyte assembly of electrolytic module and anode electrolysis assembly respectively by wire, described negative electrode storage tank and anode storage tank are respectively positioned on above described electrolytic module, the hydrogen that electrolysis produces is directly entered negative electrode storage tank, the ozone that electrolysis produces is directly entered anode storage tank, high-concentration ozone water can be produced, the ozone concentration of output is up to 25% (accounting for ozone and the percentage ratio of oxygen gross weight).
Further, described negative electrode storage tank upper end is provided with the first gas outlet, and lower end is provided with the first connecting tube and the second connecting tube; Described anode storage tank upper end is provided with the second gas outlet, and lower end is provided with the 3rd connecting tube and the 4th connecting tube.
Further, described catholyte assembly includes negative electrode water tank and the minus plate being arranged in negative electrode water tank, described minus plate side is provided with negative pole connecting portion, described negative pole connecting portion is connected with described constant-current switch power source by wire, described first connecting tube is connected with the hydrogen air vent of negative electrode water tank upper end, and described second connecting tube is connected with the negative electrode water inlet of negative electrode water tank lower end; Described anode electrolysis assembly includes anode water tank and the positive plate being arranged in anode water tank, and described positive plate side is provided with positive pole connecting portion, and described positive pole connecting portion is connected with described constant-current switch power source by wire; Being noble metal electrode room between described minus plate and positive plate, described 3rd connecting tube is connected with the ozone air vent of anode water tank upper end, and described 4th connecting tube is connected with the anode water inlet of anode water tank lower end.
Further, described minus plate includes negative electrode clamping plate, and described negative electrode clamping plate one side surface is disposed with cathode micro porous plate, cathode catalyst layer, negative electrode silica gel tetrafluoro cushion and negative electrode, anode intermediate material proton exchange from inside to outside; Described positive plate includes anode clamp, and described anode clamp one side surface is disposed with anode micro porous plate, anode catalyst layer, anode gel tetrafluoro cushion and negative electrode, anode intermediate material proton exchange from inside to outside; Described minus plate and positive plate relative spacing certain distance are arranged, and are electrode chamber between the two. It is on-consumable type, it is only necessary to ensureing that the electrical conductivity of electrolyte (pure water or deionized water) meets the requirements, equipment can be stabilized operation during the core component operation work of electrolytic module. Described minus plate and positive plate share same negative electrode, anode intermediate material proton exchange, in its both sides respectively added with silica gel tetrafluoro cushion, to guarantee that negative electrode, anode intermediate material proton exchange do not damage.
Further, the composition of described cathode catalyst layer comprises following raw material: chloroplatinic acid 0.02-3.1 part, activated carbon 0.07-11 part and isopropanol 2-22 part, and manufacture method is by formula mix and blend by each for cathod catalyst component, obtains mixture; 40-100 DEG C of pure water sucking filtration is used to clean described mixture; Dry the described mixture after sucking filtration; Described mixture after the system of rolling or compacting drying, to obtain final product.
Further, the composition of described anode catalyst layer comprises following raw material by weight percentage: plumbi nitras 190-600 part, copper nitrate 7-42 part, nitric acid 1-17 part, sodium fluoride 0.08-1.7 part, chlorization high tin 0.07-8 part, Butter of antimony. 0.06-10 part, hydrochloric acid 0.6-13 part and butanol 5-49 part, manufacture method for carrying out anti-Passivation Treatment by chlorization high tin, Butter of antimony., hydrochloric acid and butanol, afterwards with plumbi nitras, copper nitrate, nitric acid and sodium fluoride mix and blend, in the melting pan of 50-100 DEG C, then carry out electrolysis, adopt the unidirectional current of 30A-40A; By the material after electrolysis 70 DEG C drying, grind and get final product.
Further, between the described wire between positive pole connecting portion and described constant-current switch power source, it is provided with relay, to ensure that closing power work switch timer is completely in off-position.
Further, the connecting tube that described the first connecting tube, the second connecting tube, the 3rd connecting tube and the 4th connecting tube are all made up of high acrylonitrile NBR/PVC oil resistant, resistance to ozone material, it is prevented that corrosive pipeline.
Further, described cathode micro porous plate and anode micro porous plate are POROUS TITANIUM PLATE.
Beneficial effect: a kind of PEM membrane low-voltage electrolysis hydrogen of the present invention, ozone generation system simple in construction, can need to produce hydrogen rich water and Ozone Water according to difference, hydrogen and ozone enter bottom storage tank, improve mixed effect, the luminous efficiency of hydrogen and ozone is high, use pure water or deionized water as raw material, security performance is good, ozone does not contain by-product carcinogen etc., comprehensive use cost is low, and water itself is as cooling medium, electrolytic module is without other cooling device, the cathod catalyst of employing Particular craft manufacture and anode catalyst improve the luminous efficiency of hydrogen and ozone.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the structural representation of electrolytic module of the present invention;
Fig. 3 is the structural representation of minus plate of the present invention;
Fig. 4 is the structural representation of positive plate of the present invention.
In figure, 1, negative electrode storage tank, 101, first connecting tube, 102, second connecting tube, 103, first gas outlet, 2, anode storage tank, 201, 3rd connecting tube, 202, 4th connecting tube, 203, second gas outlet, 3, electrolytic module, 301, negative electrode water tank, 3011, negative pole connecting portion, 3012, minus plate, 3012a, negative electrode clamping plate, 3012b, cathode micro porous plate, 3012c, cathode catalyst layer, 3012d, negative electrode silica gel tetrafluoro cushion, 3012e, negative electrode, anode intermediate material proton exchange, 3013, hydrogen air vent, 3014, negative electrode water inlet, 302, anode water tank, 3021, positive pole connecting portion, 3022, positive plate, 3022a, negative electrode clamping plate, 3022b, anode micro porous plate, 3022c, anode catalyst layer, 3022d, anode gel tetrafluoro cushion, 303, electrode chamber, 4, constant-current switch power source, 5, relay.
Detailed description of the invention
As employed some vocabulary in the middle of description and claim to censure specific components. Those skilled in the art are it is to be appreciated that hardware manufacturer may call same assembly with different nouns. This specification and claims are not used as distinguishing in the way of assembly by the difference of title, but are used as the criterion distinguished with assembly difference functionally. " including " as mentioned in the middle of description and claim in the whole text is an open language, therefore should be construed to " including but not limited to ". Description subsequent descriptions is implement the better embodiment of the present invention, and right described description is for the purpose of the rule so that the present invention to be described, is not limited to the scope of the present invention. Protection scope of the present invention is when being as the criterion depending on the defined person of claims.
Below in conjunction with accompanying drawing, the present invention is described in further detail, but not as a limitation of the invention.
A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system, including negative electrode storage tank 1, anode storage tank 2, electrolytic module 3 and constant-current switch power source 4, described electrolytic module 3 is connected with described negative electrode storage tank 1 and anode storage tank 2 respectively by pipeline, described electrolytic module 3 includes catholyte assembly and anode electrolysis assembly, described constant-current switch power source 4 is connected with the catholyte assembly of electrolytic module 3 and anode electrolysis assembly respectively by wire, and described negative electrode storage tank 1 and anode storage tank 2 are respectively positioned on above described electrolytic module 3.
Particularly preferred, described negative electrode storage tank 1 upper end is provided with the first gas outlet 103, and lower end is provided with the first connecting tube 101 and the second connecting tube 102;Described anode storage tank 2 upper end is provided with the second gas outlet 203, and lower end is provided with the 3rd connecting tube 201 and the 4th connecting tube 202.
Particularly preferred, described catholyte assembly includes negative electrode water tank 301 and the minus plate 3012 being arranged in negative electrode water tank 301, described minus plate 3012 side is provided with negative pole connecting portion 3011, described negative pole connecting portion 3011 is connected with described constant-current switch power source 4 by wire, described first connecting tube 101 is connected with the hydrogen air vent 3013 of negative electrode water tank 301 upper end, and described second connecting tube 102 is connected with the negative electrode water inlet 3014 of negative electrode water tank 301 lower end; Described anode electrolysis assembly includes anode water tank 302 and the positive plate 3022 being arranged in anode water tank 302, described positive plate 3022 side is provided with positive pole connecting portion 3021, and described positive pole connecting portion 3021 is connected with described constant-current switch power source 4 by wire; Being electrode chamber 303 between described minus plate 3012 and positive plate 3022, described 3rd connecting tube 201 is connected with the ozone air vent 3023 of anode water tank 302 upper end, and described 4th connecting tube 202 is connected with the anode water inlet 3024 of anode water tank 302 lower end. As it is further preferred that negative electrode storage tank 1 and/or anode storage tank 2 also can be set to two each independent respectively water tanks, it is connected with water inlet, gas outlet respectively. As it is further preferred that can also directly use pure water to pass through electrolytic module 3 produce hydrogen rich water and Ozone Water without arranging negative electrode storage tank 1 and anode storage tank 2.
Particularly preferred, described minus plate 3012 includes negative electrode clamping plate 3012a, and described negative electrode clamping plate 3012a mono-example surface is disposed with cathode micro porous plate 3012b, cathode catalyst layer 3012c, negative electrode silica gel tetrafluoro cushion 3012d and negative electrode, anode intermediate material proton exchange 3012e from inside to outside; Described positive plate 3022 includes anode clamp 3022a, and described anode clamp 3022a mono-side surface is disposed with anode micro porous plate 3022b, anode catalyst layer 3022c, anode gel tetrafluoro cushion 3022d and negative electrode, anode intermediate material proton exchange 3012e from inside to outside; Described minus plate 3012 and positive plate 3022 relative spacing certain distance are arranged, and are electrode chamber 303 between the two.
Particularly preferred, the composition of described cathode catalyst layer 3012c comprises following raw material: chloroplatinic acid 0.02-3.1 part, activated carbon 0.07-11 part and isopropanol 2-22 part, and manufacture method is by formula mix and blend by each for cathod catalyst component, obtains mixture; 40-100 DEG C of pure water sucking filtration is used to clean described mixture; Dry the described mixture after sucking filtration; Described mixture after the system of rolling or compacting drying, to obtain final product.
Particularly preferred, the composition of described anode catalyst layer 3022c comprises following raw material by weight percentage: plumbi nitras 190-600 part, copper nitrate 7-42 part, nitric acid 1-17 part, sodium fluoride 0.08-1.7 part, chlorization high tin 0.07-8 part, Butter of antimony. 0.06-10 part, hydrochloric acid 0.6-13 part and butanol 5-49 part, manufacture method is by chlorization high tin, Butter of antimony., hydrochloric acid and butanol carry out anti-Passivation Treatment, afterwards and plumbi nitras, copper nitrate, nitric acid and sodium fluoride mix and blend, then in the melting pan of 50-100 DEG C, carry out electrolysis, adopt the unidirectional current of 30A-40A, by the material after electrolysis 70 DEG C drying, grind and get final product.
Particularly preferred, it is provided with relay 5 between the wire between described positive pole connecting portion 3021 and described constant-current switch power source 4.
Particularly preferred, that first described connecting tube the 101, second connecting tube the 102, the 3rd connecting tube 201 and the 4th connecting tube 202 are all made up of high acrylonitrile NBR/PVC oil resistant, resistance to ozone material connecting tube.
Particularly preferred, described cathode micro porous plate 3012b and anode micro porous plate 3022b is POROUS TITANIUM PLATE.
PEM low tension solution generation systems can produce hydrogen and two kinds of materials of ozone simultaneously, hydrogen rich water and Ozone Water can be obtained, principle is adopt negative and positive the two poles of the earth electrolysis deionized water of low-voltage DC conductive polymers membrane electrode, water form with proton exchange on solution interface is separated by electrolysis, hydrogen directly discharges from cathode solution interface and generates hydrogen, oxygen molecule obtains energy because of the electron excitation of high-density current generation in anodic interface, and aggregates into ozone molecule.
A kind of PEM membrane low-voltage electrolysis hydrogen of the present invention, ozone generation system simple in construction, can need to produce hydrogen rich water and Ozone Water according to difference, hydrogen and ozone enter bottom storage tank, improve mixed effect, the luminous efficiency of hydrogen and ozone is high, use pure water or deionized water as raw material, security performance is good, ozone does not contain by-product carcinogen etc., comprehensive use cost is low, and water itself is as cooling medium, electrolytic module is without other cooling device, the cathod catalyst of employing Particular craft manufacture and anode catalyst improve the luminous efficiency of hydrogen and ozone.
Described above illustrate and describes some preferred embodiments of the present invention, but as previously mentioned, it is to be understood that the present invention is not limited to form disclosed herein, it is not to be taken as the eliminating to other embodiments, and can be used for other combinations various, amendment and environment, and in invention contemplated scope described herein, can be modified by the technology of above-mentioned instruction or association area or knowledge. And the change that those skilled in the art carry out and change are without departing from the spirit and scope of the present invention, then all should in the protection domain of claims of the present invention.
Claims (9)
1. a PEM membrane low-voltage electrolysis hydrogen, ozone generation system, it is characterized in that: include negative electrode storage tank (1), anode storage tank (2), electrolytic module (3) and constant-current switch power source (4), described electrolytic module (3) is connected with described negative electrode storage tank (1) and anode storage tank (2) respectively by pipeline, described electrolytic module (3) includes catholyte assembly and anode electrolysis assembly, described constant-current switch power source (4) is connected with the catholyte assembly of electrolytic module (3) and anode electrolysis assembly respectively by wire, described negative electrode storage tank (1) and anode storage tank (2) are respectively positioned on described electrolytic module (3) top.
2. PEM membrane low-voltage electrolysis hydrogen according to claim 1, ozone generation system, it is characterized in that: described negative electrode storage tank (1) upper end is provided with the first gas outlet (103), lower end is provided with the first connecting tube (101) and the second connecting tube (102); Described anode storage tank (2) upper end is provided with the second gas outlet (203), and lower end is provided with the 3rd connecting tube (201) and the 4th connecting tube (202).
3. PEM membrane low-voltage electrolysis hydrogen according to claim 2, ozone generation system, it is characterized in that: described catholyte assembly includes negative electrode water tank (301) and the minus plate (3012) being arranged in negative electrode water tank (301), described minus plate (3012) side is provided with negative pole connecting portion (3011), described negative pole connecting portion (3011) is connected with described constant-current switch power source (4) by wire, described first connecting tube (101) is connected with the hydrogen air vent (3013) of negative electrode water tank (301) upper end, described second connecting tube (102) is connected with the negative electrode water inlet (3014) of negative electrode water tank (301) lower end,Described anode electrolysis assembly includes anode water tank (302) and the positive plate (3022) being arranged in anode water tank (302), described positive plate (3022) side is provided with positive pole connecting portion (3021), and described positive pole connecting portion (3021) is connected with described constant-current switch power source (4) by wire; It is electrode chamber (303) between described minus plate (3012) and positive plate (3022), described 3rd connecting tube (201) is connected with the ozone air vent (3023) of anode water tank (302) upper end, and described 4th connecting tube (202) is connected with the anode water inlet (3024) of anode water tank (302) lower end.
4. PEM membrane low-voltage electrolysis hydrogen according to claim 3, ozone generation system, it is characterized in that: described minus plate (3012) includes negative electrode clamping plate (3012a), and described negative electrode clamping plate (3012a) side surface is disposed with cathode micro porous plate (3012b), cathode catalyst layer (3012c), negative electrode silica gel tetrafluoro cushion (3012d) and negative electrode, anode intermediate material proton exchange (3012e) from inside to outside; Described positive plate (3022) includes anode clamp (3022a), and described anode clamp (3022a) side surface is disposed with anode micro porous plate (3022b), anode catalyst layer (3022c), anode gel tetrafluoro cushion (3022d) and negative electrode, anode intermediate material proton exchange (3012e) from inside to outside; Described minus plate (3012) and positive plate (3022) relative spacing certain distance are arranged, and are electrode chamber (303) between the two.
5. PEM membrane low-voltage electrolysis hydrogen according to claim 4, ozone generation system, it is characterized in that, the composition of described cathode catalyst layer (3012c) comprises following raw material: chloroplatinic acid 0.02-3.1 part, activated carbon 0.07-11 part and isopropanol 2-22 part.
6. PEM membrane low-voltage electrolysis hydrogen according to claim 4, ozone generation system, it is characterized in that: the composition of described anode catalyst layer (3022c) comprises following raw material by weight percentage: plumbi nitras 190-600 part, copper nitrate 7-42 part, nitric acid 1-17 part, sodium fluoride 0.08-1.7 part, chlorization high tin 0.07-8 part, Butter of antimony. 0.06-10 part, hydrochloric acid 0.6-13 part and butanol 5-49 part.
7. PEM membrane low-voltage electrolysis hydrogen according to claim 3, ozone generation system, it is characterised in that: be provided with relay (5) between the wire between described positive pole connecting portion (3021) and described constant-current switch power source (4).
8. PEM membrane low-voltage electrolysis hydrogen according to claim 3, ozone generation system, it is characterised in that: the connecting tube that described the first connecting tube (101), the second connecting tube (102), the 3rd connecting tube (201) and the 4th connecting tube (202) are all made up of high acrylonitrile NBR/PVC oil resistant, resistance to ozone material.
9. PEM membrane low-voltage electrolysis hydrogen according to claim 4, ozone generation system, it is characterised in that: described cathode micro porous plate (3012b) and anode micro porous plate (3022b) are POROUS TITANIUM PLATE.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106235499A (en) * | 2016-09-30 | 2016-12-21 | 福州品行科技发展有限公司 | A kind of antioxidation sterilizing shoe and foot healthcare method |
| CN106264236A (en) * | 2016-09-30 | 2017-01-04 | 福州品行科技发展有限公司 | A kind of washbowl and using method thereof |
| CN106389181A (en) * | 2016-11-30 | 2017-02-15 | 福州品行科技发展有限公司 | Facial mask machine and use method thereof |
| CN106390696A (en) * | 2016-11-30 | 2017-02-15 | 福州品行科技发展有限公司 | Refrigerator moisture absorption and deodorization device and refrigerator adopting same |
| CN109023418A (en) * | 2018-08-23 | 2018-12-18 | 西安富阳环境科技有限公司 | A kind of preparation method of Pt/ carbon fiber Ti electrode |
| CN109699675A (en) * | 2019-01-24 | 2019-05-03 | 贾臻 | A method of Ozone Water being made with water and replaces pesticide and is replaced with Pipe spraying manually spraying |
| CN113522206A (en) * | 2021-08-03 | 2021-10-22 | 湖南新欧源环保科技有限公司 | Multi-ion hydrolysis blue oxygen generator assembly |
| CN114381744A (en) * | 2022-01-06 | 2022-04-22 | 钱靖 | Electrolytic ozone generator |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1900367A (en) * | 2005-07-20 | 2007-01-24 | 徐名勇 | Anode structure of electrolytic ozone generator |
| CN102899685A (en) * | 2012-09-12 | 2013-01-30 | 金华市广源环保科技有限公司 | Cathode and anode catalyst for low-voltage electrolytic ozone generator module and preparation method thereof |
| CN205856615U (en) * | 2016-04-07 | 2017-01-04 | 金华市润达环保科技有限公司 | A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system |
-
2016
- 2016-04-07 CN CN201610234948.2A patent/CN105671586A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1900367A (en) * | 2005-07-20 | 2007-01-24 | 徐名勇 | Anode structure of electrolytic ozone generator |
| CN102899685A (en) * | 2012-09-12 | 2013-01-30 | 金华市广源环保科技有限公司 | Cathode and anode catalyst for low-voltage electrolytic ozone generator module and preparation method thereof |
| CN205856615U (en) * | 2016-04-07 | 2017-01-04 | 金华市润达环保科技有限公司 | A kind of PEM membrane low-voltage electrolysis hydrogen, ozone generation system |
Non-Patent Citations (1)
| Title |
|---|
| 魏征: "电解法臭氧发生装置的制备与性能研究", 《中国优秀硕士学位论文全文数据库工程科技Ⅱ辑》 * |
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| CN106235499A (en) * | 2016-09-30 | 2016-12-21 | 福州品行科技发展有限公司 | A kind of antioxidation sterilizing shoe and foot healthcare method |
| CN106264236A (en) * | 2016-09-30 | 2017-01-04 | 福州品行科技发展有限公司 | A kind of washbowl and using method thereof |
| CN106235499B (en) * | 2016-09-30 | 2018-06-29 | 福州品行科技发展有限公司 | A kind of anti-oxidant sterilizing shoe and foot healthcare method |
| CN106389181A (en) * | 2016-11-30 | 2017-02-15 | 福州品行科技发展有限公司 | Facial mask machine and use method thereof |
| CN106390696A (en) * | 2016-11-30 | 2017-02-15 | 福州品行科技发展有限公司 | Refrigerator moisture absorption and deodorization device and refrigerator adopting same |
| CN106389181B (en) * | 2016-11-30 | 2021-02-23 | 福州品行科技发展有限公司 | Mask machine and using method thereof |
| CN109023418A (en) * | 2018-08-23 | 2018-12-18 | 西安富阳环境科技有限公司 | A kind of preparation method of Pt/ carbon fiber Ti electrode |
| CN109699675A (en) * | 2019-01-24 | 2019-05-03 | 贾臻 | A method of Ozone Water being made with water and replaces pesticide and is replaced with Pipe spraying manually spraying |
| CN113522206A (en) * | 2021-08-03 | 2021-10-22 | 湖南新欧源环保科技有限公司 | Multi-ion hydrolysis blue oxygen generator assembly |
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