CN106366865A - Anti-bacterial water-resistant ultraviolet curing paint - Google Patents
Anti-bacterial water-resistant ultraviolet curing paint Download PDFInfo
- Publication number
- CN106366865A CN106366865A CN201610737120.9A CN201610737120A CN106366865A CN 106366865 A CN106366865 A CN 106366865A CN 201610737120 A CN201610737120 A CN 201610737120A CN 106366865 A CN106366865 A CN 106366865A
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- acrylate
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- 239000003973 paint Substances 0.000 title claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 25
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 37
- 239000011737 fluorine Substances 0.000 claims abstract description 37
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 30
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 claims abstract description 27
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 25
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 22
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 15
- -1 3,3,5-trimethyl cyclohexyl methyl Chemical group 0.000 claims abstract description 13
- 229920000728 polyester Polymers 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 claims abstract description 11
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims abstract description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 9
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims abstract description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 30
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 claims description 26
- 150000002148 esters Chemical class 0.000 claims description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- 239000003822 epoxy resin Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 229920000647 polyepoxide Polymers 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 claims description 11
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims description 11
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 10
- NIWFIJFHALTBRN-UHFFFAOYSA-N 2-methyl-5-propan-2-ylidenecyclopentan-1-one Chemical compound CC1CCC(=C(C)C)C1=O NIWFIJFHALTBRN-UHFFFAOYSA-N 0.000 claims description 10
- 239000013530 defoamer Substances 0.000 claims description 10
- 235000013312 flour Nutrition 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N Vilsmeier-Haack reagent Natural products CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- TXNXVKSSXJDGIR-UHFFFAOYSA-N OC(C)N1CN(CN(C1)O)O Chemical compound OC(C)N1CN(CN(C1)O)O TXNXVKSSXJDGIR-UHFFFAOYSA-N 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 3
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 3
- 229940008099 dimethicone Drugs 0.000 claims description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- UUYQSLQNSVVXCC-UHFFFAOYSA-N CN.C(C=C)(=O)OCCN(C)C Chemical compound CN.C(C=C)(=O)OCCN(C)C UUYQSLQNSVVXCC-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 claims 1
- 125000004494 ethyl ester group Chemical group 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 230000003373 anti-fouling effect Effects 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- VNQXSTWCDUXYEZ-UHFFFAOYSA-N 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2(C)C(=O)C(=O)C1C2(C)C VNQXSTWCDUXYEZ-UHFFFAOYSA-N 0.000 abstract 1
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 abstract 1
- HUHGPYXAVBJSJV-UHFFFAOYSA-N 2-[3,5-bis(2-hydroxyethyl)-1,3,5-triazinan-1-yl]ethanol Chemical compound OCCN1CN(CCO)CN(CCO)C1 HUHGPYXAVBJSJV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 229930006711 bornane-2,3-dione Natural products 0.000 abstract 1
- 239000002041 carbon nanotube Substances 0.000 abstract 1
- 229910021393 carbon nanotube Inorganic materials 0.000 abstract 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 abstract 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 12
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- GBDLBTQHXOOMAV-UHFFFAOYSA-N (2-hexylphenyl)-phenylmethanone Chemical compound C(CCCCC)C1=C(C(=O)C2=CC=CC=C2)C=CC=C1 GBDLBTQHXOOMAV-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 108050008598 Phosphoesterases Proteins 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- OHYINUJIHLYARE-UHFFFAOYSA-N 2-(2H-1,3,5-triazin-1-yl)ethane-1,1,1-triol Chemical compound OC(CN1CN=CN=C1)(O)O OHYINUJIHLYARE-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- PCIRJWTVSRUWCU-UHFFFAOYSA-N (3,3,5-trimethylcyclohexyl)methyl prop-2-enoate Chemical compound CC1CC(COC(=O)C=C)CC(C)(C)C1 PCIRJWTVSRUWCU-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 1
- YVKJGLZZMYZTNO-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)ethane-1,1,1-triol Chemical compound OC(O)(O)CC1=NC=NC=N1 YVKJGLZZMYZTNO-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 102100021541 Sodium/nucleoside cotransporter 2 Human genes 0.000 description 1
- 101710123669 Sodium/nucleoside cotransporter 2 Proteins 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical compound Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses anti-bacterial water-resistant ultraviolet curing paint. The anti-bacterial water-resistant ultraviolet curing paint comprises the following raw materials: bisphenol A epoxy acrylate resin, polyester acrylate, tripropylene glycol diacrylate, 1,6-hexanediol diacrylate, 3,3,5-trimethyl cyclohexyl methyl acrylate, propoxylated glyceryl triacrylate, alpha-hydroxyl cyclohexyl benzene ketone, camphorquinone, talcum powder, quartz powder, carclazyte, carbon nano-tubes, nano-vanadium dioxide, nano-zirconium dioxide, (octyl)-trimethoxysilane, fluorine-containing quaternary ammonium salt, hexahydro-1,3,5-tris(hydroxyethyl)-s-triazine, poly dimethyl diallyl ammonium chloride, an antifoaming agent, a levelling agent, a wetting agent and butyl acetate. The anti-bacterial water-resistant ultraviolet curing paint disclosed by the invention has good water resistance, wear resistance and antifouling property, and excellent anti-bacterial performance.
Description
Technical field
The present invention relates to technical field of coatings, more particularly, to a kind of antibacterial resistance to water ultraviolet-cured paint.
Background technology
UV-curing technology has curing rate fast (0.1～10s), low in the pollution of the environment, energy expenditure is low, energy automatization
The advantages of produce, be suitable for use on heat-sensitive substrate material.To divide according to its purposes, mainly to have ultraviolet-curing paint, adhesive, oil
Ink etc..Wherein wide with ultraviolet-curing paint range, produce kind most.Ultraviolet-curing paint is according to its application neck
The different of domain can be divided into again: woodenware ultraviolet-curing paint, plastics ultraviolet-curing paint, metal ultraviolet light polymerization apply
Material, paper ultraviolet-curing paint, optical fiber ultraviolet-curing paint etc..
But the requirement more and more higher with social development and consumer, the performance of coating and appearance requirement are also carrying therewith
Height, for a long time, ultraviolet-curing paint has that hardness is low, chemical resistance is poor, resistance to water and less desirable the lacking of antibiotic property
Fall into.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of antibacterial resistance to water ultraviolet-cured paint, its
Resistance to water, wearability and antifouling property are good, and anti-microbial property is excellent.
A kind of antibacterial resistance to water ultraviolet-cured paint proposed by the present invention, its raw material includes by weight: Bisphenol A Type Epoxy Resin third
Alkene acid ester resin 20-40 part, polyester acrylate 3-15 part, tri (propylene glycol) diacrylate 5-15 part, 1,6-HD
Diacrylate 5-15 part, 3,3,5- 3-methyl cyclohexanol methyl acrylate 6-15 part, propoxylated glycerol triacrylate
3-15 part, Alpha-hydroxy phenylcyclohexyl ketone 1-5 part, camphorone 0.2-1 part, Pulvis Talci 2-10 part, silica flour 1-5 part, hargil 1-5
Part, CNT 1-3.5 part, nano vanadium dioxide 0.5-2 part, nano zirconium dioxide 1-3 part, n-octyl trimethoxy silane 1-
4 parts, fluorine-containing quaternary ammonium salt 3-8 part, hexahydro -1,3,5- trihydroxyethyl s-triazine 0.2-1 part, PDDA 2-
5 parts, defoamer 0.1-0.5 part, levelling agent 0.1-1 part, wetting agent 0.2-1 part, butyl acetate 3-10 part.
Preferably, in its raw material, Bisphenol A Type Epoxy Resin acrylate, the weight of polyester acrylate are than for 25-35:6-
13.
Preferably, in its raw material, tri (propylene glycol) diacrylate, 1,6- hexanediyl ester, 3,3,5- tri-
Methylcyclohexylmethyl acrylate, the weight of propoxylated glycerol triacrylate are than for 8-13:6-12:8-13:5-13.
Preferably, its raw material includes by weight: 30 parts of Bisphenol A Type Epoxy Resin acrylate, 12 parts of polyester acrylate,
11 parts of tri (propylene glycol) diacrylate, 10 parts of 1,6 hexanediol diacrylate, 3,3,5- trimethylcyclohexyl methyl-prop
12 parts of olefin(e) acid ester, 10 parts of propoxylated glycerol triacrylate, 3.8 parts of Alpha-hydroxy phenylcyclohexyl ketone, 0.7 part of camphorone, cunning
5 parts of stone powder, 3.2 parts of silica flour, 4 parts of hargil, 2 parts of CNT, 1.6 parts of nano vanadium dioxide, 2.1 parts of nano zirconium dioxide,
3.1 parts of n-octyl trimethoxy silane, 5 parts of fluorine-containing quaternary ammonium salt, 0.6 part of hexahydro -1,3,5- trihydroxyethyl s-triazine, poly dimethyl
3 parts of diallyl ammonium chloride, 0.4 part of defoamer, 0.6 part of levelling agent, 0.7 part of wetting agent, 8 parts of butyl acetate.
Preferably, for mean diameter, the nano vanadium dioxide being 30-80nm, mean diameter are described nano vanadium dioxide
The nano vanadium dioxide of 250-400nm is by weight the mixture for 3-12:2-40.
Preferably, for mean diameter, the nano zirconium dioxide being 300-500nm, mean diameter are described nano zirconium dioxide
2-5 μm of nano zirconium dioxide is by weight the mixture for 5-15:5-30.
In the present invention, for mean diameter, the nano vanadium dioxide being 30-80nm, mean diameter are described nano vanadium dioxide
The nano vanadium dioxide of 250-400nm is by weight the mixture for 3-12:2-40；Described nano zirconium dioxide is mean diameter
Nano zirconium dioxide for 300-500nm, mean diameter are 2-5 μm of nano zirconium dioxide by weight for 5-15:5-30's
Mixture；By controlling the nano vanadium dioxide and nano zirconium dioxide content in system, and its size, so that
Nano vanadium dioxide and nano zirconium dioxide obtain in system and are closely spaced, and improve its bulk density in system,
Obtain and while more preferable mechanical property, improve its pining force in the base, thus improving the anti-wear performance of paint film, hardness and resistance to
Hot.
Preferably, described fluorine-containing quaternary ammonium salt is prepared according to following technique: by weight in 50-80 part dimethyl formyl
Add 8-15 part dimethylaminoethyl methacrylate in amine, be subsequently adding 30-45 part 2,3,4,5,6- five fluorine bromobenzyl and 0.05-
0.5 part of hydroquinone, stirring reaction 3.5-5h at 50-65 DEG C, reaction is cooled to room temperature after terminating, and then sinks through absolute ether
Form sediment, wash, being dried to obtain described fluorine-containing quaternary ammonium salt.
Preferably, described fluorine-containing quaternary ammonium salt is prepared according to following technique: by weight in 65 parts of dimethylformamides
12 parts of dimethylaminoethyl methacrylates of middle addition, are subsequently adding 40 part 2, and 3,4,5,6- five fluorine bromobenzyls and 0.3 part are to benzene two
Phenol, stirring reaction 4.2h at 60 DEG C, reaction is cooled to room temperature after terminating, and then precipitates, washs, is dried to obtain through absolute ether
Described fluorine-containing quaternary ammonium salt.
Preferably, described defoamer is dimethicone.
Preferably, described levelling agent is epoxidized soybean oil fatty acid；Described wetting agent is alkylphenol polyoxyethylene phosphoric acid
The mixture of one of ester, phenethyl phenol polyoxyethylene groups ether phosphate or two kinds.
Antibacterial resistance to water ultraviolet-cured paint of the present invention can be according to conventional ultraviolet-curing paint preparation technology
It is prepared from.
Bisphenol A Type Epoxy Resin acrylate has laser curing velocity hardness that is fast, solidifying caudacoria and glossiness is high, thermostability
Well, the advantages of resistance to chemical corrosion is excellent, in the present invention, is main performed polymer with Bisphenol A Type Epoxy Resin acrylate, and
Cooperation adds appropriate polyester acrylate, so that both performances is worked in coordination with, and coordinates specific light trigger Alpha-hydroxy hexamethylene
Base benzophenone and camphorone, are keeping Bisphenol A Type Epoxy Resin acrylate laser curing velocity hardness that is fast, solidifying caudacoria and gloss
Degree height, thermostability and resistance to chemical corrosion improve toughness and the weatherability of system while good；With tripropylene glycol two
Acrylate, 1,6 hexanediol diacrylate, 3,3,5- 3-methyl cyclohexanol methyl acrylate, propoxylated glycerol 3 third
Olefin(e) acid ester coordinates the reactive diluent as system, improves the viscosity of system, simultaneously participates in the solidification of system, improve further
Prevent paint film wrinkling while the toughness of paint film, improve hardness and the adhesive force of system simultaneously；Pulvis Talci, silica flour,
In hargil, CNT, nano vanadium dioxide, nano zirconium dioxide addition system, in n-octyl trimethoxy silane, fluorine-containing season
It is uniformly dispersed in system in the presence of ammonium salt, PDDA, significantly improve hardness, the toughness of paint film
And wearability；Fluorine-containing quaternary ammonium salt, hexahydro -1,3,5- trihydroxyethyl s-triazine, PDDA add system
In there is Synergistic antimicrobial, improve the hygroscopicity of paint film simultaneously, give paint film excellent resistance to water；In optimal way, institute
State fluorine-containing quaternary ammonium salt with dimethylaminoethyl methacrylate, 2,3,4,5,6- five fluorine bromobenzyls for raw material, thus by metering system
Sour dimethylaminoethyl and 2,3,4,5,6- five fluorine bromobenzyls are combined as a whole, obtain have high surface, high heat-resistant stability,
The fluorine-containing quaternary ammonium salt of the property such as high chemical stability and water and oil repellence, in addition system, on the one hand, with hexahydro -1,3,5-
Trihydroxyethyl s-triazine and PDDA cooperation give paint film excellent antibiotic property, on the other hand, and just
Octyl group trimethoxy silane coordinates, and improves the compatibility of system, improves the resistance to water of paint film.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of antibacterial resistance to water ultraviolet-cured paint proposed by the present invention, its raw material includes by weight: Bisphenol A Type Epoxy Resin third
40 parts of alkene acid ester resin, 3 parts of polyester acrylate, 15 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
5 parts of ester, 15 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 3 parts of propoxylated glycerol triacrylate, Alpha-hydroxy hexamethylene
5 parts of base benzophenone, 0.2 part of camphorone, 10 parts of Pulvis Talci, 1 part of silica flour, 5 parts of hargil, 1 part of CNT, nano vanadium dioxide
2 parts, 1 part of nano zirconium dioxide, 4 parts of n-octyl trimethoxy silane, 3 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,5- trihydroxyethyl equal
1 part of triazine, 2 parts of PDDA, 0.5 part of defoamer, 0.1 part of levelling agent, 1 part of wetting agent, butyl acetate 3
Part.
Embodiment 2
A kind of antibacterial resistance to water ultraviolet-cured paint proposed by the present invention, its raw material includes by weight: Bisphenol A Type Epoxy Resin third
20 parts of alkene acid ester resin, 15 parts of polyester acrylate, 5 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
15 parts of ester, 6 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 15 parts of propoxylated glycerol triacrylate, Alpha-hydroxy ring
1 part of hexyl benzophenone, 1 part of camphorone, 2 parts of Pulvis Talci, 5 parts of silica flour, 1 part of hargil, 3.5 parts of CNT, nanometer titanium dioxide
0.5 part of vanadium, 3 parts of nano zirconium dioxide, 1 part of n-octyl trimethoxy silane, 8 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,5- three hydroxyl second
0.2 part of base s-triazine, 5 parts of PDDA, 0.1 part of defoamer, 1 part of levelling agent, 0.2 part of wetting agent, vinegar
10 parts of acid butyl ester.
Embodiment 3
A kind of antibacterial resistance to water ultraviolet-cured paint proposed by the present invention, its raw material includes by weight: Bisphenol A Type Epoxy Resin third
35 parts of alkene acid ester resin, 6 parts of polyester acrylate, 13 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
6 parts of ester, 13 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 5 parts of propoxylated glycerol triacrylate, Alpha-hydroxy hexamethylene
3.8 parts of base benzophenone, 0.5 part of camphorone, 8 parts of Pulvis Talci, 3.1 parts of silica flour, 3.6 parts of hargil, CNT 2.7 part, nanometer
1.7 parts of vanadium dioxide, 2 parts of nano zirconium dioxide, 3 parts of n-octyl trimethoxy silane, 4.8 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,
0.8 part of 5- trihydroxyethyl s-triazine, 3.8 parts of PDDA, 0.4 part of defoamer, 0.5 part of levelling agent, profit
0.75 part of humectant, 5.8 parts of butyl acetate；
Wherein, the nano vanadium dioxide that described nano vanadium dioxide is 30nm for mean diameter, mean diameter are 400nm's
Nano vanadium dioxide is by weight the mixture for 3:40；
Described nano zirconium dioxide for mean diameter be the nano zirconium dioxide of 300nm, mean diameter be 5 μm of nanometer two
Zirconium oxide is by weight the mixture for 5:30；
Described fluorine-containing quaternary ammonium salt is prepared according to following technique: adds 15 by weight in 50 parts of dimethylformamides
Part dimethylaminoethyl methacrylate, is subsequently adding 30 part 2,3,4,5,6- five fluorine bromobenzyls and 0.5 part of hydroquinone, at 50 DEG C
Lower stirring reaction 5h, reaction is cooled to room temperature after terminating, and then precipitates, washs through absolute ether, being dried to obtain described fluorine-containing season
Ammonium salt.
Embodiment 4
A kind of antibacterial resistance to water ultraviolet-cured paint proposed by the present invention, its raw material includes by weight: Bisphenol A Type Epoxy Resin third
25 parts of alkene acid ester resin, 13 parts of polyester acrylate, 8 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
12 parts of ester, 8 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 13 parts of propoxylated glycerol triacrylate, Alpha-hydroxy ring
2 parts of hexyl benzophenone, 0.8 part of camphorone, 5.8 parts of Pulvis Talci, 4 parts of silica flour, 3 parts of hargil, CNT 3.2 part, nanometer two
1 part of vanadium oxide, 2.5 parts of nano zirconium dioxide, 2.3 parts of n-octyl trimethoxy silane, 6 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,5-
0.55 part of trihydroxyethyl s-triazine, 4.3 parts of PDDA, 0.28 part of defoamer, 0.8 part of levelling agent, alkane
Base phenol polyethenoxy ether phosphoesterase 30 .2 part, phenethyl phenol polyoxyethylene ether phosphoesterase 30 .3 part, 8 parts of butyl acetate；
Wherein, the nano vanadium dioxide that described nano vanadium dioxide is 80nm for mean diameter, mean diameter are 250nm's
Nano vanadium dioxide is by weight the mixture for 12:2；
Described nano zirconium dioxide for mean diameter be the nano zirconium dioxide of 500nm, mean diameter be 2 μm of nanometer two
Zirconium oxide is by weight the mixture for 15:5；
Described fluorine-containing quaternary ammonium salt is prepared according to following technique: adds 8 by weight in 80 parts of dimethylformamides
Part dimethylaminoethyl methacrylate, is subsequently adding 45 part 2,3,4,5,6- five fluorine bromobenzyls and 0.05 part of hydroquinone, 65
Stirring reaction 3.5h at DEG C, reaction terminate after be cooled to room temperature, then through absolute ether precipitate, wash, being dried to obtain described in contain
Fluorine quaternary ammonium salt.
Embodiment 5
A kind of antibacterial resistance to water ultraviolet-cured paint proposed by the present invention, its raw material includes by weight: Bisphenol A Type Epoxy Resin third
30 parts of alkene acid ester resin, 12 parts of polyester acrylate, 11 parts of tri (propylene glycol) diacrylate, 1,6-HD diacrylate
10 parts of ester, 12 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, 10 parts of propoxylated glycerol triacrylate, Alpha-hydroxy ring
3.8 parts of hexyl benzophenone, 0.7 part of camphorone, 5 parts of Pulvis Talci, 3.2 parts of silica flour, 4 parts of hargil, CNT 2 part, nanometer two
1.6 parts of vanadium oxide, 2.1 parts of nano zirconium dioxide, 3.1 parts of n-octyl trimethoxy silane, 5 parts of fluorine-containing quaternary ammonium salt, hexahydro -1,3,
0.6 part of 5- trihydroxyethyl s-triazine, 3 parts of PDDA, 0.4 part of dimethicone, epoxidized soybean oil fat
0.6 part of fat acid, alkylphenol polyoxyethylene phosphoesterase 30 .7 part, 8 parts of butyl acetate；
Wherein, the nano vanadium dioxide that described nano vanadium dioxide is 60nm for mean diameter, mean diameter are 300nm's
Nano vanadium dioxide is by weight the mixture for 6:21；
Described nano zirconium dioxide for mean diameter be the nano zirconium dioxide of 400nm, mean diameter be 3.8 μm of nanometer
Zirconium dioxide is by weight the mixture for 12:17；
Described fluorine-containing quaternary ammonium salt is prepared according to following technique: adds 12 by weight in 65 parts of dimethylformamides
Part dimethylaminoethyl methacrylate, is subsequently adding 40 part 2,3,4,5,6- five fluorine bromobenzyls and 0.3 part of hydroquinone, at 60 DEG C
Lower stirring reaction 4.2h, reaction terminate after be cooled to room temperature, then precipitate, wash through absolute ether, be dried to obtain described fluorine-containing
Quaternary ammonium salt.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (10)
1. a kind of antibacterial resistance to water ultraviolet-cured paint is it is characterised in that its raw material includes by weight: Bisphenol A Type Epoxy Resin propylene
Acid ester resin 20-40 part, polyester acrylate 3-15 part, tri (propylene glycol) diacrylate 5-15 part, 1,6-HD two
Acrylate 5-15 part, 3,3,5- 3-methyl cyclohexanol methyl acrylate 6-15 part, propoxylated glycerol triacrylate 3-
15 parts, Alpha-hydroxy phenylcyclohexyl ketone 1-5 part, camphorone 0.2-1 part, Pulvis Talci 2-10 part, silica flour 1-5 part, hargil 1-5
Part, CNT 1-3.5 part, nano vanadium dioxide 0.5-2 part, nano zirconium dioxide 1-3 part, n-octyl trimethoxy silane 1-
4 parts, fluorine-containing quaternary ammonium salt 3-8 part, hexahydro -1,3,5- trihydroxyethyl s-triazine 0.2-1 part, PDDA 2-
5 parts, defoamer 0.1-0.5 part, levelling agent 0.1-1 part, wetting agent 0.2-1 part, butyl acetate 3-10 part.
2. according to claim 1 antibacterial resistance to water ultraviolet-cured paint it is characterised in that in its raw material, Bisphenol A Type Epoxy Resin third
Alkene acid ester resin, the weight of polyester acrylate are than for 25-35:6-13.
3. antibacterial resistance to water ultraviolet-cured paint according to claim 1 or claim 2 is it is characterised in that in its raw material, two contractings 3 third
Omega-diol diacrylate, 1,6 hexanediol diacrylate, 3,3,5- 3-methyl cyclohexanol methyl acrylate, propoxylation are sweet
The weight of oily triacrylate is than for 8-13:6-12:8-13:5-13.
4. according to any one of claim 1-3 antibacterial resistance to water ultraviolet-cured paint it is characterised in that its raw material press weight
Amount part includes: 30 parts of Bisphenol A Type Epoxy Resin acrylate, 12 parts of polyester acrylate, tri (propylene glycol) diacrylate 11
Part, 10 parts of 1,6 hexanediol diacrylate, 12 parts of 3,3,5- 3-methyl cyclohexanol methyl acrylate, propoxylated glycerol three
10 parts of acrylate, 3.8 parts of Alpha-hydroxy phenylcyclohexyl ketone, 0.7 part of camphorone, 5 parts of Pulvis Talci, 3.2 parts of silica flour, hargil 4
Part, 2 parts of CNT, 1.6 parts of nano vanadium dioxide, 2.1 parts of nano zirconium dioxide, 3.1 parts of n-octyl trimethoxy silane, contain
5 parts of fluorine quaternary ammonium salt, 0.6 part of hexahydro -1,3,5- trihydroxyethyl s-triazine, 3 parts of PDDA, defoamer
0.4 part, 0.6 part of levelling agent, 0.7 part of wetting agent, 8 parts of butyl acetate.
5. according to any one of claim 1-4 antibacterial resistance to water ultraviolet-cured paint it is characterised in that described nanometer two
The nano vanadium dioxide that vanadium oxide is 30-80nm for mean diameter, mean diameter are the nano vanadium dioxide of 250-400nm by weight
Amount is than the mixture for 3-12:2-40.
6. according to any one of claim 1-5 antibacterial resistance to water ultraviolet-cured paint it is characterised in that described nanometer two
Zirconium oxide for mean diameter be the nano zirconium dioxide of 300-500nm, mean diameter be 2-5 μm nano zirconium dioxide by weight
Than the mixture for 5-15:5-30.
7. according to any one of claim 1-6 antibacterial resistance to water ultraviolet-cured paint it is characterised in that described fluorine-containing season
Ammonium salt is prepared according to following technique: adds 8-15 part methacrylic acid by weight in 50-80 part dimethylformamide
Dimethylaminoethyl, is subsequently adding 30-45 part 2,3,4,5,6- five fluorine bromobenzyl and 0.05-0.5 part hydroquinone, at 50-65 DEG C
Lower stirring reaction 3.5-5h, reaction terminate after be cooled to room temperature, then through absolute ether precipitate, wash, being dried to obtain described in contain
Fluorine quaternary ammonium salt.
8. according to any one of claim 1-7 antibacterial resistance to water ultraviolet-cured paint it is characterised in that described fluorine-containing season
Ammonium salt is prepared according to following technique: adds 12 parts of dimethylaminoethyl acrylate methyl ammonia by weight in 65 parts of dimethylformamides
Base ethyl ester, is subsequently adding 40 part 2,3,4,5,6- five fluorine bromobenzyls and 0.3 part of hydroquinone, stirring reaction 4.2h at 60 DEG C, instead
Room temperature should be cooled to after terminating, then precipitate, wash through absolute ether, being dried to obtain described fluorine-containing quaternary ammonium salt.
9. according to any one of claim 1-8 antibacterial resistance to water ultraviolet-cured paint it is characterised in that described defoamer
For dimethicone.
10. according to any one of claim 1-9 antibacterial resistance to water ultraviolet-cured paint it is characterised in that described levelling
Agent is epoxidized soybean oil fatty acid；Described wetting agent is alkylphenol polyoxyethylene phosphate ester, phenethyl phenol polyoxyethylene ether
The mixture of one of phosphate ester or two kinds.
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