CN106366852A - Oil paint for air compressor shells and preparation method of oil paint - Google Patents
Oil paint for air compressor shells and preparation method of oil paint Download PDFInfo
- Publication number
- CN106366852A CN106366852A CN201610761709.2A CN201610761709A CN106366852A CN 106366852 A CN106366852 A CN 106366852A CN 201610761709 A CN201610761709 A CN 201610761709A CN 106366852 A CN106366852 A CN 106366852A
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- Prior art keywords
- air compressor
- phenyl ether
- glycol phenyl
- oil paint
- self
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04B—POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
- F04B39/00—Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
- F04B39/12—Casings; Cylinders; Cylinder heads; Fluid connections
- F04B39/121—Casings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses oil paint for air compressor shells and a preparation method of the oil paint. The oil paint comprises, by weight, 52g of waterborne epoxy resin, 12g of tetrabutyl titanate, 8g of phthalic anhydride, 4g of titanium dioxide nanopowder, 6g of N,N'-ethylene hisstearamide, 15g of PAN carbon fibers, 2g of sulfonated lignin, 7g of zinc borate, 3g of dialkyl glycol phenyl ether, 1.5-2.5g of potassium dichromate, 6-10g of calcium bentonite, 2-4g of MgO nanoparticles, 3-5g of diethylene glycol phenyl ether, 1-5g of 1-acetamidine-ethenyl-1.1-bisphosphonate, 0.8-2.2g of self-made pigment, 20-30g of Arabic gum and 80-120g of organic solvent. The oil paint and the preparation method thereof have the advantages that the components are blended reasonably, the preparation method is scientific and convenient to operate, and various performances of the oil paint such as corrosion, weather, water, acid-base, rust, ageing and ultraviolet irradiation resistance are improved; the oil paint is dried quickly, has high adhesive force, and is convenient to apply, safe and environment friendly; the oil paint has excellent performance when being applied to the air compressor shells.
Description
Technical field
The present invention relates to paint fabricating technology field, more particularly, to a kind of air compressor shell paint and its system
Preparation Method.
Background technology
Air compressor is the basic product of the modernization of industry, just has entirely pneumatic containing in the electric and automatization often saying
Justice;And air compressor is exactly to provide source of the gas power, it is the nucleus equipment of pneumatic system, the main body in dynamo-electric bleed source device,
It is the device that the mechanical energy of former dynamic (typically motor or diesel engine) is converted into gas pressure energy, is the gas of compressed air
Pressure generating apparatus.Air compressor is used for vehicle braking, food, pharmaceuticals industry, the starting of big marine diesel engine, wind-tunnel in fact
Test, underpass ventilation, metal smelt, armament systems, produce pressure-air be used for workpiece cooling and be dried etc..
Air compressor shell, plays the effect such as protection and support to compressor.What its working environment had is carried out indoors,
Have is carried out outdoor, and its surface of air compressor is corroded by various mal-conditions, and prior art is entered to it using paint
Row protection.
But existing paint can not meet its resistance to water, anti-corrosive properties, weatherability etc. simultaneously, and safe and environment-friendly, property
The superior effect of energy.
Content of the invention
For overcoming above-mentioned deficiency, the present invention provides a kind of high performance paints being applied to air compressor and its preparation side
Method.
The present invention takes technical scheme below to realize: a kind of air compressor shell paint it is characterised in that
It is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanium dioxide are received
Rice flour end 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycols
Phenyl ether 3g, potassium dichromate 1.5-2.5g, calcium-base bentonite 6-10g, mgo nano-particle 2-4g, diethylene glycol phenyl ether 3-5g,
1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1-5g, self-control pigment 0.8-2.2g, arabic gum 20-30g and organic solvent 80-
120g;
The preparation method of described self-control pigment is: utilizes after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g
Waterproof pulverization is ground into the mixture a of 10-20 m, adds pe pearly-lustre purple master batch 2g and add copper nanoparticle in mixture a
Colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, heating in water bath to 75 DEG C,
And it is dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, be dried at 105 DEG C,
Dry powder moves to Muffle furnace calcining, prepares self-control pigment.
Preferred version as the present invention: it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate
12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation
Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 1.5g, calcium-base bentonite 6g, mgo nano-particle
2g, diethylene glycol phenyl ether 3g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1g, self-control pigment 0.8g, arabic gum 20g and have
Machine solvent 80g.
Preferred version as the present invention: it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate
12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation
Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2g, calcium-base bentonite 8g, mgo nano-particle 3g,
Diethylene glycol phenyl ether 4g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 3g, self-control pigment 1.5g, arabic gum 25g and organic
Solvent 100g.
Preferred version as the present invention: it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate
12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation
Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2.5g, calcium-base bentonite 10g, mgo nano-particle
4g, diethylene glycol phenyl ether 5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 5g, self-control pigment 2.2g, arabic gum 30g and have
Machine solvent 120g.
The present invention also provides a kind of preparation method of air compressor shell paint, comprises the following steps:
1) it is ground into after remaining component mixing in addition to arabic gum, self-control pigment and organic solvent using waterproof pulverization
The mixture a of 10-20 m;
2) mixture a is transferred in large beaker, is placed on magnetic stirring apparatuss, to 65 DEG C, constant temperature stirs 35min to heating in water bath,
Naturally cool to room temperature;
3) heating in water bath adds after arabic gum, organic solvent high-speed stirred 60min to 85 DEG C, is cooled to 55 DEG C and adds self-control
Pigment, high-speed stirred 45min, then carry out supersound process 20min at such a temperature, ultrasonic power is 1000w, is down to room temperature and obtains final product
A kind of air compressor shell paint.
In sum the method have the advantages that the present invention provide a kind of air compressor shell to paint and its
Preparation method, group assignment system is reasonable, and preparation method science is easy to operate, improves the various aspects of performance of paint, such as: anticorrosion
Property, weatherability, resistance to water, stability, acid and alkali-resistance, antirust, freeze thawing resistance stability, aging resistance, ultraviolet resistance according to etc. performance, and dry
Dry quick, adhesive force is good, easy construction, safety and environmental protection, through test, the present invention applies on air compressor shell performance extremely
Superior.
Specific embodiment
Technological means, creation characteristic, reached purpose and effect for making the present invention realize are easy to understand, with reference to
Specific embodiment, is expanded on further the present invention.
Embodiment 1
A kind of air compressor shell paint, it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate
12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation
Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 1.5g, calcium-base bentonite 6g, mgo nano-particle
2g, diethylene glycol phenyl ether 3g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1g, self-control pigment 0.8g, arabic gum 20g and have
Machine solvent 80g.
The preparation method of described self-control pigment is: after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g
It is ground into the mixture a of 10-20 m using waterproof pulverization, add pe pearly-lustre purple master batch 2g in mixture a and add nanometer
Copper powder colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, and heating in water bath is extremely
75 DEG C, and be dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, at 105 DEG C
It is dried, dry powder moves to Muffle furnace calcining, prepares self-control pigment.
The present invention also provides a kind of preparation method of air compressor shell paint, comprises the following steps:
1) it is ground into after remaining component mixing in addition to arabic gum, self-control pigment and organic solvent using waterproof pulverization
The mixture a of 10-20 m;
2) mixture a is transferred in large beaker, is placed on magnetic stirring apparatuss, to 65 DEG C, constant temperature stirs 35min to heating in water bath,
Naturally cool to room temperature;
3) heating in water bath adds after arabic gum, organic solvent high-speed stirred 60min to 85 DEG C, is cooled to 55 DEG C and adds self-control
Pigment, high-speed stirred 45min, then carry out supersound process 20min at such a temperature, ultrasonic power is 1000w, is down to room temperature and obtains final product
A kind of air compressor shell paint.
Embodiment 2
A kind of air compressor shell paint, it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate
12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation
Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2g, calcium-base bentonite 8g, mgo nano-particle 3g,
Diethylene glycol phenyl ether 4g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 3g, self-control pigment 1.5g, arabic gum 25g and organic
Solvent 100g.
The preparation method of described self-control pigment is: after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g
It is ground into the mixture a of 10-20 m using waterproof pulverization, add pe pearly-lustre purple master batch 2g in mixture a and add nanometer
Copper powder colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, and heating in water bath is extremely
75 DEG C, and be dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, at 105 DEG C
It is dried, dry powder moves to Muffle furnace calcining, prepares self-control pigment.
The preparation method of the present invention is with the preparation method of embodiment 1.
Embodiment 3
A kind of air compressor shell paint, it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate
12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation
Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2.5g, calcium-base bentonite 10g, mgo nano-particle
4g, diethylene glycol phenyl ether 5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 5g, self-control pigment 2.2g, arabic gum 30g and have
Machine solvent 120g.
The preparation method of described self-control pigment is: utilizes after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g
Waterproof pulverization is ground into the mixture a of 10-20 m, adds pe pearly-lustre purple master batch 2g and add copper nanoparticle in mixture a
Colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, heating in water bath to 75 DEG C,
And it is dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, be dried at 105 DEG C,
Dry powder moves to Muffle furnace calcining, prepares self-control pigment.
The preparation method of the present invention is with the preparation method of embodiment 1.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of the spirit or essential attributes of the present invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment only wraps
Containing an independent technical scheme, only for clarity, those skilled in the art should for this narrating mode of description
Using description as an entirety, the technical scheme in each embodiment can also form those skilled in the art through appropriately combined
Understandable other embodiment.
Claims (5)
1. a kind of air compressor shell paints it is characterised in that it is made up of following raw material: aqueous epoxy resins
52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base
Carbon fiber 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 1.5-2.5g, calcio are swollen
Native 6-10g, mgo nano-particle 2-4g of profit, diethylene glycol phenyl ether 3-5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1-5g, from
Pigment 0.8-2.2g processed, arabic gum 20-30g and organic solvent 80-120g;
The preparation method of described self-control pigment is: utilizes after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g
Waterproof pulverization is ground into the mixture a of 10-20 m, adds pe pearly-lustre purple master batch 2g and add copper nanoparticle in mixture a
Colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, heating in water bath to 75 DEG C,
And it is dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, be dried at 105 DEG C,
Dry powder moves to Muffle furnace calcining, prepares self-control pigment.
2. a kind of air compressor shell paint according to claim 1 it is characterised in that: it is by following raw material
Composition: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebis
Stearmide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate
1.5g, calcium-base bentonite 6g, mgo nano-particle 2g, diethylene glycol phenyl ether 3g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1g,
Self-control pigment 0.8g, arabic gum 20g and organic solvent 80g.
3. a kind of air compressor shell paint according to claim 1 it is characterised in that: it is by following raw material
Composition: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebis
Stearmide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate
2g, calcium-base bentonite 8g, mgo nano-particle 3g, diethylene glycol phenyl ether 4g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 3g, from
Pigment 1.5g processed, arabic gum 25g and organic solvent 100g.
4. a kind of air compressor shell paint according to claim 1 it is characterised in that: it is by following raw material
Composition: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebis
Stearmide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate
2.5g, calcium-base bentonite 10g, mgo nano-particle 4g, diethylene glycol phenyl ether 5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 5g,
Self-control pigment 2.2g, arabic gum 30g and organic solvent 120g.
5. a kind of air compressor shell paint according to claim 1 preparation method it is characterised in that: include with
Lower step:
1) it is ground into after remaining component mixing in addition to arabic gum, self-control pigment and organic solvent using waterproof pulverization
The mixture a of 10-20 m;
2) mixture a is transferred in large beaker, is placed on magnetic stirring apparatuss, to 65 DEG C, constant temperature stirs 35min to heating in water bath,
Naturally cool to room temperature;
3) heating in water bath adds after arabic gum, organic solvent high-speed stirred 60min to 85 DEG C, is cooled to 55 DEG C and adds self-control
Pigment, high-speed stirred 45min, then carry out supersound process 20min at such a temperature, ultrasonic power is 1000w, is down to room temperature and obtains final product
A kind of air compressor shell paint.
Priority Applications (1)
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CN201610761709.2A CN106366852A (en) | 2016-08-31 | 2016-08-31 | Oil paint for air compressor shells and preparation method of oil paint |
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CN201610761709.2A CN106366852A (en) | 2016-08-31 | 2016-08-31 | Oil paint for air compressor shells and preparation method of oil paint |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108485518A (en) * | 2018-03-14 | 2018-09-04 | 合肥尚涵装饰工程有限公司 | A kind of environment-friendly type paint of metal door and window and preparation method thereof |
CN108504243A (en) * | 2018-03-01 | 2018-09-07 | 合肥康之恒机械科技有限公司 | A kind of preparation method of environment protection oil paint for mechanical equipment |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101041760A (en) * | 2007-04-25 | 2007-09-26 | 沈阳市航达科技有限责任公司 | Water-based anticorrosive paint and preparation method thereof |
CN104479497A (en) * | 2014-12-17 | 2015-04-01 | 常熟市恒仕达电器有限公司 | Solar all-mains refrigerator |
-
2016
- 2016-08-31 CN CN201610761709.2A patent/CN106366852A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101041760A (en) * | 2007-04-25 | 2007-09-26 | 沈阳市航达科技有限责任公司 | Water-based anticorrosive paint and preparation method thereof |
CN104479497A (en) * | 2014-12-17 | 2015-04-01 | 常熟市恒仕达电器有限公司 | Solar all-mains refrigerator |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108504243A (en) * | 2018-03-01 | 2018-09-07 | 合肥康之恒机械科技有限公司 | A kind of preparation method of environment protection oil paint for mechanical equipment |
CN108485518A (en) * | 2018-03-14 | 2018-09-04 | 合肥尚涵装饰工程有限公司 | A kind of environment-friendly type paint of metal door and window and preparation method thereof |
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Application publication date: 20170201 |