CN106366852A - Oil paint for air compressor shells and preparation method of oil paint - Google Patents

Oil paint for air compressor shells and preparation method of oil paint Download PDF

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Publication number
CN106366852A
CN106366852A CN201610761709.2A CN201610761709A CN106366852A CN 106366852 A CN106366852 A CN 106366852A CN 201610761709 A CN201610761709 A CN 201610761709A CN 106366852 A CN106366852 A CN 106366852A
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China
Prior art keywords
air compressor
phenyl ether
glycol phenyl
oil paint
self
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Pending
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CN201610761709.2A
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Chinese (zh)
Inventor
林勇
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ANHUI RUITIAN MACHINERY Co Ltd
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ANHUI RUITIAN MACHINERY Co Ltd
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Priority to CN201610761709.2A priority Critical patent/CN106366852A/en
Publication of CN106366852A publication Critical patent/CN106366852A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B39/00Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
    • F04B39/12Casings; Cylinders; Cylinder heads; Fluid connections
    • F04B39/121Casings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses oil paint for air compressor shells and a preparation method of the oil paint. The oil paint comprises, by weight, 52g of waterborne epoxy resin, 12g of tetrabutyl titanate, 8g of phthalic anhydride, 4g of titanium dioxide nanopowder, 6g of N,N'-ethylene hisstearamide, 15g of PAN carbon fibers, 2g of sulfonated lignin, 7g of zinc borate, 3g of dialkyl glycol phenyl ether, 1.5-2.5g of potassium dichromate, 6-10g of calcium bentonite, 2-4g of MgO nanoparticles, 3-5g of diethylene glycol phenyl ether, 1-5g of 1-acetamidine-ethenyl-1.1-bisphosphonate, 0.8-2.2g of self-made pigment, 20-30g of Arabic gum and 80-120g of organic solvent. The oil paint and the preparation method thereof have the advantages that the components are blended reasonably, the preparation method is scientific and convenient to operate, and various performances of the oil paint such as corrosion, weather, water, acid-base, rust, ageing and ultraviolet irradiation resistance are improved; the oil paint is dried quickly, has high adhesive force, and is convenient to apply, safe and environment friendly; the oil paint has excellent performance when being applied to the air compressor shells.

Description

A kind of air compressor shell paint and preparation method thereof
Technical field
The present invention relates to paint fabricating technology field, more particularly, to a kind of air compressor shell paint and its system Preparation Method.
Background technology
Air compressor is the basic product of the modernization of industry, just has entirely pneumatic containing in the electric and automatization often saying Justice;And air compressor is exactly to provide source of the gas power, it is the nucleus equipment of pneumatic system, the main body in dynamo-electric bleed source device, It is the device that the mechanical energy of former dynamic (typically motor or diesel engine) is converted into gas pressure energy, is the gas of compressed air Pressure generating apparatus.Air compressor is used for vehicle braking, food, pharmaceuticals industry, the starting of big marine diesel engine, wind-tunnel in fact Test, underpass ventilation, metal smelt, armament systems, produce pressure-air be used for workpiece cooling and be dried etc..
Air compressor shell, plays the effect such as protection and support to compressor.What its working environment had is carried out indoors, Have is carried out outdoor, and its surface of air compressor is corroded by various mal-conditions, and prior art is entered to it using paint Row protection.
But existing paint can not meet its resistance to water, anti-corrosive properties, weatherability etc. simultaneously, and safe and environment-friendly, property The superior effect of energy.
Content of the invention
For overcoming above-mentioned deficiency, the present invention provides a kind of high performance paints being applied to air compressor and its preparation side Method.
The present invention takes technical scheme below to realize: a kind of air compressor shell paint it is characterised in that It is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanium dioxide are received Rice flour end 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycols Phenyl ether 3g, potassium dichromate 1.5-2.5g, calcium-base bentonite 6-10g, mgo nano-particle 2-4g, diethylene glycol phenyl ether 3-5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1-5g, self-control pigment 0.8-2.2g, arabic gum 20-30g and organic solvent 80- 120g;
The preparation method of described self-control pigment is: utilizes after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g Waterproof pulverization is ground into the mixture a of 10-20 m, adds pe pearly-lustre purple master batch 2g and add copper nanoparticle in mixture a Colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, heating in water bath to 75 DEG C, And it is dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, be dried at 105 DEG C, Dry powder moves to Muffle furnace calcining, prepares self-control pigment.
Preferred version as the present invention: it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 1.5g, calcium-base bentonite 6g, mgo nano-particle 2g, diethylene glycol phenyl ether 3g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1g, self-control pigment 0.8g, arabic gum 20g and have Machine solvent 80g.
Preferred version as the present invention: it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2g, calcium-base bentonite 8g, mgo nano-particle 3g, Diethylene glycol phenyl ether 4g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 3g, self-control pigment 1.5g, arabic gum 25g and organic Solvent 100g.
Preferred version as the present invention: it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2.5g, calcium-base bentonite 10g, mgo nano-particle 4g, diethylene glycol phenyl ether 5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 5g, self-control pigment 2.2g, arabic gum 30g and have Machine solvent 120g.
The present invention also provides a kind of preparation method of air compressor shell paint, comprises the following steps:
1) it is ground into after remaining component mixing in addition to arabic gum, self-control pigment and organic solvent using waterproof pulverization The mixture a of 10-20 m;
2) mixture a is transferred in large beaker, is placed on magnetic stirring apparatuss, to 65 DEG C, constant temperature stirs 35min to heating in water bath, Naturally cool to room temperature;
3) heating in water bath adds after arabic gum, organic solvent high-speed stirred 60min to 85 DEG C, is cooled to 55 DEG C and adds self-control Pigment, high-speed stirred 45min, then carry out supersound process 20min at such a temperature, ultrasonic power is 1000w, is down to room temperature and obtains final product A kind of air compressor shell paint.
In sum the method have the advantages that the present invention provide a kind of air compressor shell to paint and its Preparation method, group assignment system is reasonable, and preparation method science is easy to operate, improves the various aspects of performance of paint, such as: anticorrosion Property, weatherability, resistance to water, stability, acid and alkali-resistance, antirust, freeze thawing resistance stability, aging resistance, ultraviolet resistance according to etc. performance, and dry Dry quick, adhesive force is good, easy construction, safety and environmental protection, through test, the present invention applies on air compressor shell performance extremely Superior.
Specific embodiment
Technological means, creation characteristic, reached purpose and effect for making the present invention realize are easy to understand, with reference to Specific embodiment, is expanded on further the present invention.
Embodiment 1
A kind of air compressor shell paint, it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 1.5g, calcium-base bentonite 6g, mgo nano-particle 2g, diethylene glycol phenyl ether 3g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1g, self-control pigment 0.8g, arabic gum 20g and have Machine solvent 80g.
The preparation method of described self-control pigment is: after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g It is ground into the mixture a of 10-20 m using waterproof pulverization, add pe pearly-lustre purple master batch 2g in mixture a and add nanometer Copper powder colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, and heating in water bath is extremely 75 DEG C, and be dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, at 105 DEG C It is dried, dry powder moves to Muffle furnace calcining, prepares self-control pigment.
The present invention also provides a kind of preparation method of air compressor shell paint, comprises the following steps:
1) it is ground into after remaining component mixing in addition to arabic gum, self-control pigment and organic solvent using waterproof pulverization The mixture a of 10-20 m;
2) mixture a is transferred in large beaker, is placed on magnetic stirring apparatuss, to 65 DEG C, constant temperature stirs 35min to heating in water bath, Naturally cool to room temperature;
3) heating in water bath adds after arabic gum, organic solvent high-speed stirred 60min to 85 DEG C, is cooled to 55 DEG C and adds self-control Pigment, high-speed stirred 45min, then carry out supersound process 20min at such a temperature, ultrasonic power is 1000w, is down to room temperature and obtains final product A kind of air compressor shell paint.
Embodiment 2
A kind of air compressor shell paint, it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2g, calcium-base bentonite 8g, mgo nano-particle 3g, Diethylene glycol phenyl ether 4g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 3g, self-control pigment 1.5g, arabic gum 25g and organic Solvent 100g.
The preparation method of described self-control pigment is: after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g It is ground into the mixture a of 10-20 m using waterproof pulverization, add pe pearly-lustre purple master batch 2g in mixture a and add nanometer Copper powder colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, and heating in water bath is extremely 75 DEG C, and be dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, at 105 DEG C It is dried, dry powder moves to Muffle furnace calcining, prepares self-control pigment.
The preparation method of the present invention is with the preparation method of embodiment 1.
Embodiment 3
A kind of air compressor shell paint, it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base carbon fibre 15g, sulfonation Lignin 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2.5g, calcium-base bentonite 10g, mgo nano-particle 4g, diethylene glycol phenyl ether 5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 5g, self-control pigment 2.2g, arabic gum 30g and have Machine solvent 120g.
The preparation method of described self-control pigment is: utilizes after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g Waterproof pulverization is ground into the mixture a of 10-20 m, adds pe pearly-lustre purple master batch 2g and add copper nanoparticle in mixture a Colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, heating in water bath to 75 DEG C, And it is dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, be dried at 105 DEG C, Dry powder moves to Muffle furnace calcining, prepares self-control pigment.
The preparation method of the present invention is with the preparation method of embodiment 1.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of the spirit or essential attributes of the present invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment only wraps Containing an independent technical scheme, only for clarity, those skilled in the art should for this narrating mode of description Using description as an entirety, the technical scheme in each embodiment can also form those skilled in the art through appropriately combined Understandable other embodiment.

Claims (5)

1. a kind of air compressor shell paints it is characterised in that it is made up of following raw material: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebisstearamide 6g, pan base Carbon fiber 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 1.5-2.5g, calcio are swollen Native 6-10g, mgo nano-particle 2-4g of profit, diethylene glycol phenyl ether 3-5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1-5g, from Pigment 0.8-2.2g processed, arabic gum 20-30g and organic solvent 80-120g;
The preparation method of described self-control pigment is: utilizes after mica powder 22g is mixed with natural jade powder 8g, blanc fixe 6g Waterproof pulverization is ground into the mixture a of 10-20 m, adds pe pearly-lustre purple master batch 2g and add copper nanoparticle in mixture a Colloid solution 30g is adjusted to serosity b, and serosity b is transferred in large beaker, is placed on magnetic stirring apparatuss, heating in water bath to 75 DEG C, And it is dividedly in some parts carbamide 3g, isothermal reaction 40min, naturally cool to room temperature, sucking filtration, wash to neutrality, be dried at 105 DEG C, Dry powder moves to Muffle furnace calcining, prepares self-control pigment.
2. a kind of air compressor shell paint according to claim 1 it is characterised in that: it is by following raw material Composition: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebis Stearmide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 1.5g, calcium-base bentonite 6g, mgo nano-particle 2g, diethylene glycol phenyl ether 3g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 1g, Self-control pigment 0.8g, arabic gum 20g and organic solvent 80g.
3. a kind of air compressor shell paint according to claim 1 it is characterised in that: it is by following raw material Composition: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebis Stearmide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2g, calcium-base bentonite 8g, mgo nano-particle 3g, diethylene glycol phenyl ether 4g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 3g, from Pigment 1.5g processed, arabic gum 25g and organic solvent 100g.
4. a kind of air compressor shell paint according to claim 1 it is characterised in that: it is by following raw material Composition: aqueous epoxy resins 52g, butyl titanate 12g, phthalic anhydride 8g, titanic oxide nano powder 4g, ethylenebis Stearmide 6g, pan base carbon fibre 15g, lignosulfonate 2g, Firebrake ZB 7g, two aklylene glycol phenyl ether 3g, potassium dichromate 2.5g, calcium-base bentonite 10g, mgo nano-particle 4g, diethylene glycol phenyl ether 5g, 1- ethanamidine base-second river -1.1- di 2 ethylhexyl phosphonic acid 5g, Self-control pigment 2.2g, arabic gum 30g and organic solvent 120g.
5. a kind of air compressor shell paint according to claim 1 preparation method it is characterised in that: include with Lower step:
1) it is ground into after remaining component mixing in addition to arabic gum, self-control pigment and organic solvent using waterproof pulverization The mixture a of 10-20 m;
2) mixture a is transferred in large beaker, is placed on magnetic stirring apparatuss, to 65 DEG C, constant temperature stirs 35min to heating in water bath, Naturally cool to room temperature;
3) heating in water bath adds after arabic gum, organic solvent high-speed stirred 60min to 85 DEG C, is cooled to 55 DEG C and adds self-control Pigment, high-speed stirred 45min, then carry out supersound process 20min at such a temperature, ultrasonic power is 1000w, is down to room temperature and obtains final product A kind of air compressor shell paint.
CN201610761709.2A 2016-08-31 2016-08-31 Oil paint for air compressor shells and preparation method of oil paint Pending CN106366852A (en)

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Application Number Priority Date Filing Date Title
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CN201610761709.2A CN106366852A (en) 2016-08-31 2016-08-31 Oil paint for air compressor shells and preparation method of oil paint

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108485518A (en) * 2018-03-14 2018-09-04 合肥尚涵装饰工程有限公司 A kind of environment-friendly type paint of metal door and window and preparation method thereof
CN108504243A (en) * 2018-03-01 2018-09-07 合肥康之恒机械科技有限公司 A kind of preparation method of environment protection oil paint for mechanical equipment

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041760A (en) * 2007-04-25 2007-09-26 沈阳市航达科技有限责任公司 Water-based anticorrosive paint and preparation method thereof
CN104479497A (en) * 2014-12-17 2015-04-01 常熟市恒仕达电器有限公司 Solar all-mains refrigerator

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041760A (en) * 2007-04-25 2007-09-26 沈阳市航达科技有限责任公司 Water-based anticorrosive paint and preparation method thereof
CN104479497A (en) * 2014-12-17 2015-04-01 常熟市恒仕达电器有限公司 Solar all-mains refrigerator

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108504243A (en) * 2018-03-01 2018-09-07 合肥康之恒机械科技有限公司 A kind of preparation method of environment protection oil paint for mechanical equipment
CN108485518A (en) * 2018-03-14 2018-09-04 合肥尚涵装饰工程有限公司 A kind of environment-friendly type paint of metal door and window and preparation method thereof

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Application publication date: 20170201