CN106366533A - Optical lens with low thermal conductivity - Google Patents

Optical lens with low thermal conductivity Download PDF

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Publication number
CN106366533A
CN106366533A CN201610759771.8A CN201610759771A CN106366533A CN 106366533 A CN106366533 A CN 106366533A CN 201610759771 A CN201610759771 A CN 201610759771A CN 106366533 A CN106366533 A CN 106366533A
Authority
CN
China
Prior art keywords
parts
coupling agent
heat conductivity
low heat
perlite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610759771.8A
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Chinese (zh)
Inventor
刘德兴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd
Original Assignee
DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd filed Critical DONGXING HUAHONG OPTICAL TECHNOLOGY Co Ltd
Priority to CN201610759771.8A priority Critical patent/CN106366533A/en
Publication of CN106366533A publication Critical patent/CN106366533A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5415Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041Lenses
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

Abstract

The invention provides an optical lens with the low thermal conductivity. The optical lens is prepared from, by weight, 25-39 parts of acrylic materials, 12-19 parts of sepiolite, 8-13 parts of perlite, 6-9 parts of tribasic lead sulfate, 6-10 parts of acetone, 3-5 parts of an antioxygen and 2-5 parts of a coupling agent. According to the optical lens with the low thermal conductivity, the sepiolite, the perlite, the tribasic lead sulfate and the acetone are added into the raw materials, and made optical lens has the low thermal conductivity accordingly; as the coupling agent is added, bonding performance of glass fibers and resin can be improved, and the strength performance, the waterproof performance, the anti-weather performance and the like of the glass fiber reinforced composition are greatly improved.

Description

There is the optical glass of low heat conductivity
Technical field
The present invention relates to optical glass technical field is and in particular to a kind of optical glass with low heat conductivity.
Background technology
Low heat conductivity is the important indicator weighing optical glass quality, but the low heat conductivity of existing optical glass is universal Typically.
Content of the invention
For the variety of problems facing described in background technology, it is an object of the invention to provide a kind of have low heat conductivity Optical frames eyeglass.
For reaching above-mentioned purpose, the technical solution adopted in the present invention is: a kind of optical glass with low heat conductivity, bag Include each component of following weight portion: acrylate materials 25-39 part, meerschaum 12-19 part, perlite 8-13 part, three alkali formulas Lead sulfate 6-9 part, acetone 6-10 part, antioxidant 3-5 part, coupling agent 2-5 part.
Further, acrylate materials are allylation cyclohexyldimethacrylate, ethoxylation trihydroxy methyl Propane trimethyl acrylic ester and the mixture of isodecyl acrylate.
Further, including each component of following weight portion: 25 parts of acrylate materials, 12 parts of meerschaum, perlite 8 Part, 6 parts of tribasic lead sulfate, 6 parts of acetone, 3 parts of antioxidant, 2 parts of coupling agent.
Further, including each component of following weight portion: 39 parts of acrylate materials, 15 parts of meerschaum, perlite 13 parts, 7 parts of tribasic lead sulfate, 8 parts of acetone, 4 parts of antioxidant, 3 parts of coupling agent.
Further, including each component of following weight portion: 28 parts of acrylate materials, 19 parts of meerschaum, perlite 10 parts, 9 parts of tribasic lead sulfate, 10 parts of acetone, 5 parts of antioxidant, 5 parts of coupling agent.
Further, coupling agent is one of isobutyl ethyl triethoxy silicane and silane coupler.
The method have the advantages that
1. the present invention adds meerschaum, perlite, tribasic lead sulfate and acetone in the feed so that the optical frames made Piece has low heat conductivity.
2. the present invention is added with coupling agent, can improve the bond propertiess of glass fibre and resin, greatly improve glass fibre The performances such as the intensity of enhancing composite, water resistant, anti-weather.
Specific embodiment
It is described further with reference to the optical glass that specific embodiment has low heat conductivity to the present invention.
Embodiment 1
The present invention has the optical glass of low heat conductivity, including each component of following weight portion: 25 parts of acrylate materials, sea 12 parts of afrodite, 8 parts of perlite, 6 parts of tribasic lead sulfate, 6 parts of acetone, 3 parts of antioxidant, 2 parts of coupling agent.Wherein, acrylate Class material is allylation cyclohexyldimethacrylate, ethoxylated trimethylolpropane trimethyl acrylic ester and isodecyl The mixture of acrylate, coupling agent is one of isobutyl ethyl triethoxy silicane and silane coupler.
Embodiment 2
The present invention has the optical glass of low heat conductivity, including each component of following weight portion: 39 parts of acrylate materials, sea 15 parts of afrodite, 13 parts of perlite, 7 parts of tribasic lead sulfate, 8 parts of acetone, 4 parts of antioxidant, 3 parts of coupling agent.Wherein, acrylate Class material is allylation cyclohexyldimethacrylate, ethoxylated trimethylolpropane trimethyl acrylic ester and isodecyl The mixture of acrylate, coupling agent is one of isobutyl ethyl triethoxy silicane and silane coupler.
Embodiment 3
The present invention has the optical glass of low heat conductivity, including each component of following weight portion: 28 parts of acrylate materials, sea 19 parts of afrodite, 10 parts of perlite, 9 parts of tribasic lead sulfate, 10 parts of acetone, 5 parts of antioxidant, 5 parts of coupling agent.Wherein, acrylic acid Esters material is allylation cyclohexyldimethacrylate, ethoxylated trimethylolpropane trimethyl acrylic ester and isodecyl The mixture of base acrylate, coupling agent is one of isobutyl ethyl triethoxy silicane and silane coupler.
In sum, the method have the advantages that
1. the present invention adds meerschaum, perlite, tribasic lead sulfate and acetone in the feed so that the optical frames made Piece has low heat conductivity.
2. the present invention is added with coupling agent, can improve the bond propertiess of glass fibre and resin, greatly improve glass fibre The performances such as the intensity of enhancing composite, water resistant, anti-weather.

Claims (6)

1. a kind of optical glass with low heat conductivity is it is characterised in that include each component of following weight portion: esters of acrylic acid Material 25-39 part, meerschaum 12-19 part, perlite 8-13 part, tribasic lead sulfate 6-9 part, acetone 6-10 part, antioxidant 3-5 Part, coupling agent 2-5 part.
2. the optical glass with low heat conductivity according to claim 1 it is characterised in that: acrylate materials be alkene Propylated cyclohexyldimethacrylate, ethoxylated trimethylolpropane trimethyl acrylic ester and isodecyl acrylate Mixture.
3. the optical glass with low heat conductivity according to claim 1 is it is characterised in that include each of following weight portion Component: 25 parts of acrylate materials, 12 parts of meerschaum, 8 parts of perlite, 6 parts of tribasic lead sulfate, 6 parts of acetone, antioxidant 3 Part, 2 parts of coupling agent.
4. the optical glass with low heat conductivity according to claim 1 is it is characterised in that include each of following weight portion Component: 39 parts of acrylate materials, 15 parts of meerschaum, 13 parts of perlite, 7 parts of tribasic lead sulfate, 8 parts of acetone, antioxidant 4 Part, 3 parts of coupling agent.
5. the optical glass with low heat conductivity according to claim 1 is it is characterised in that include each of following weight portion Component: 28 parts of acrylate materials, 19 parts of meerschaum, 10 parts of perlite, 9 parts of tribasic lead sulfate, 10 parts of acetone, antioxidant 5 parts, 5 parts of coupling agent.
6. the optical glass with low heat conductivity according to claim 1 it is characterised in that: coupling agent be isobutyl group three second One of epoxide silicon and silane coupler.
CN201610759771.8A 2016-08-30 2016-08-30 Optical lens with low thermal conductivity Pending CN106366533A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610759771.8A CN106366533A (en) 2016-08-30 2016-08-30 Optical lens with low thermal conductivity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610759771.8A CN106366533A (en) 2016-08-30 2016-08-30 Optical lens with low thermal conductivity

Publications (1)

Publication Number Publication Date
CN106366533A true CN106366533A (en) 2017-02-01

Family

ID=57901249

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610759771.8A Pending CN106366533A (en) 2016-08-30 2016-08-30 Optical lens with low thermal conductivity

Country Status (1)

Country Link
CN (1) CN106366533A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109705381A (en) * 2018-11-27 2019-05-03 新野旭润光电科技有限公司 Low heat conductivity optical mirror slip

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220200A (en) * 2007-12-20 2008-07-16 上海交通大学 Transparent organic polymer material and method for producing the same
CN105074506A (en) * 2013-03-15 2015-11-18 庄臣及庄臣视力保护公司 Silicone-containing contact lens having clay treatment applied thereto
CN105623223A (en) * 2014-11-04 2016-06-01 刘和超 Optical glass with low thermal conductivity
CN111440402A (en) * 2020-05-11 2020-07-24 江苏可奥熙光学材料科技有限公司 Nano composite infrared-resistant lens monomer with refractive index of 1.60

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220200A (en) * 2007-12-20 2008-07-16 上海交通大学 Transparent organic polymer material and method for producing the same
CN105074506A (en) * 2013-03-15 2015-11-18 庄臣及庄臣视力保护公司 Silicone-containing contact lens having clay treatment applied thereto
CN105623223A (en) * 2014-11-04 2016-06-01 刘和超 Optical glass with low thermal conductivity
CN111440402A (en) * 2020-05-11 2020-07-24 江苏可奥熙光学材料科技有限公司 Nano composite infrared-resistant lens monomer with refractive index of 1.60

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109705381A (en) * 2018-11-27 2019-05-03 新野旭润光电科技有限公司 Low heat conductivity optical mirror slip

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Application publication date: 20170201