CN106318290A - Heat-resistant waterproof adhesive for shoes - Google Patents

Heat-resistant waterproof adhesive for shoes Download PDF

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Publication number
CN106318290A
CN106318290A CN201610696555.3A CN201610696555A CN106318290A CN 106318290 A CN106318290 A CN 106318290A CN 201610696555 A CN201610696555 A CN 201610696555A CN 106318290 A CN106318290 A CN 106318290A
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China
Prior art keywords
parts
emulsion
heat
modified
footwear
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CN201610696555.3A
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Chinese (zh)
Inventor
朱立芳
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ANHUI BIG PINE RESIN Co Ltd
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ANHUI BIG PINE RESIN Co Ltd
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Priority to CN201610696555.3A priority Critical patent/CN106318290A/en
Publication of CN106318290A publication Critical patent/CN106318290A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a heat-resistant waterproof adhesive for shoes. The heat-resistant waterproof adhesive comprises, by weight, 20-50 parts of modified acrylate emulsion, 5-15 parts of polyvinyl acetate emulsion, 2-8 parts of natural latex, 3-5 parts of styrene-butadiene latex, 1-4 parts of neoprene latex, 1-4 parts of polyacrylamide, 3-5 parts of phenolic resin, 2-6 parts of polyurethane, 1-4 parts of polyvinyl butyral, 2-5 parts of carboxymethylcellulose, 2-5 parts of organosilicon boron, 3-6 parts of nano silica, 4-8 parts of organic bentonite, 5-8 parts of light calcium carbonate, 4-9 parts of white clay, 2-5 parts of modified curing agent, 3-6 parts of silane coupling agent KH-550, 1-4 parts of promoter DMP-30, 2-5 parts of polyether polyol and 2-5 parts of antioxidant. The heat-resistant waterproof adhesive has excellent heat-resistant and waterproof performance.

Description

A kind of heat-resisting moisture-proof adhesive of footwear
Technical field
The present invention relates to a kind of adhesive, particularly relate to a kind of heat-resisting moisture-proof adhesive of footwear.
Background technology
China is footwear manufacturing country, country of consumption and exported country maximum in the world, footwear annual production tens pairs, accounts for complete More than the 50% of sneakers production.About more than 20 hundred million pairs, domestic annual consumption footwear, have exceeded the U.S. and have occupied first place in the world.Domestic existing Family more than 20,000 of footwear enterprise, produced footwear 80% are above rubber adhesive shoes, and footwear glue consumption reaches more than 20 ten thousand tons.The use of adhesive is significantly Improve the production efficiency of shoe-making industry.
Heat-resisting and the water resistance of the adhesive that existing shoe-making field uses cannot meet the demand of reality, therefore needs badly and sets A kind of footwear of meter solve demand of the prior art with heat-resisting moisture-proof adhesive.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of heat-resisting moisture-proof adhesive of footwear, has Excellent heat-resisting and water resistance.
The heat-resisting moisture-proof adhesive of a kind of footwear that the present invention proposes, its raw material includes by weight: modification acrylate breast Liquid 20-50 part, polyvinyl acetate emulsion 5-15 part, natural emulsion 2-8 part, styrene-butadiene latex 3-5 part, polychloroprene latex 1-4 part, poly- Acrylamide 1-4 part, phenolic resin 3-5 part, polyurethane 2-6 part, polyvinyl butyral resin 1-4 part, carboxymethyl cellulose 2-5 Part, organic silicon-boron 2-5 part, nano silicon 3-6 part, organobentonite 4-8 part, precipitated calcium carbonate 5-8 part, white clay 4-9 Part, modified firming agent 2-5 part, silane resin acceptor kh-550 3-6 part, altax P-30 1-4 part, polyether polyol 2-5 part, Antioxidant 1010 2-5 part.
Preferably, the raw material of modified acrylate emulsion includes by weight: dodecylbenzene sodium sulfonate 8-16 part, OP- 10 6-12 parts, epoxy resin 12-24 part, butyl acrylate 2-5 part, methyl methacrylate 1-4 part, acrylic acid 3-5 part, mistake Ammonium sulfate 2-6 part, sodium bicarbonate 3-9 part, deionized water 5-15 part.
Preferably, modified acrylate emulsion is prepared by following technique: by dodecylbenzene sodium sulfonate, OP-10, ring Epoxy resins, butyl acrylate, methyl methacrylate, acrylic acid and deionized water mix homogeneously, in 12000-14000r/min Emulsion dispersion 25-35min, obtains emulsion, then adds Ammonium persulfate. and sodium bicarbonate mix homogeneously in emulsion, heats up To 75-85 DEG C, it is incubated 1-3h, is cooled to room temperature, filter and backward filtrate adds triethanolamine regulation pH to 7.0-8.0, obtain Modified acrylate emulsion.
Preferably, modified firming agent is prepared by following technique: by the mixing of thiourea, diethylenetriamine and sodium chloride all Even, it is passed through nitrogen, then oil bath is heated to 110-150 DEG C, is incubated 20-40min, is then cooled to 50-60 DEG C, is incubated 0.5- 1.5h, is then cooled to room temperature and obtains modified firming agent.
Preferably, in the preparation technology of modified firming agent, the mol ratio of thiourea, diethylenetriamine and sodium chloride is 0.5- 1.5:1-3:2-5.
Preferably, its raw material includes by weight: modified acrylate emulsion 25-45 part, polyvinyl acetate emulsion 8- 12 parts, natural emulsion 3-7 part, styrene-butadiene latex 3.5-4.5 part, polychloroprene latex 2-3 part, polyacrylamide 2-3 part, phenolic resin 3.5-4.5 part, polyurethane 3-5 part, polyvinyl butyral resin 2-3 part, carboxymethyl cellulose 3-4 part, organic silicon-boron 3-4 part, receive Rice silicon dioxide 4-5 part, organobentonite 5-7 part, precipitated calcium carbonate 6-7 part, white clay 5-8 part, modified firming agent 3-4 part, Silane resin acceptor kh-550 4-5 part, altax P-30 2-3 part, polyether polyol 3-4 part, antioxidant 1010 3-4 part.
Preferably, its raw material includes by weight: modified acrylate emulsion 35 parts, polyvinyl acetate emulsion 10 parts, Natural emulsion 5 parts, styrene-butadiene latex 4 parts, polychloroprene latex 2.5 parts, polyacrylamide 2.5 parts, 4 parts of phenolic resin, polyurethane 4 parts, Polyvinyl butyral resin 2.5 parts, carboxymethyl cellulose 3.5 parts, organic silicon-boron 3.5 parts, nano silicon 4.5 parts, organic bentonite 6 parts of profit soil, precipitated calcium carbonate 6.5 parts, white clay 6.5 parts, modified firming agent 3.5 parts, silane resin acceptor kh-550 4.5 parts, rush Enter agent DMP-302.5 part, polyether polyol 3.5 parts, antioxidant 1010 3.5 parts.
The preparation method of the present invention is as follows: by modified acrylate emulsion, polyvinyl acetate emulsion, natural emulsion, fourth Benzene latex, polychloroprene latex, polyacrylamide, phenolic resin, polyurethane, polyvinyl butyral resin, carboxymethyl cellulose, organosilicon Boron, nano silicon, organobentonite, precipitated calcium carbonate, white clay, modified firming agent, silane resin acceptor kh-550, promotion Agent DMP-30, polyether polyol and antioxidant 1010 mix homogeneously, the speed in 1200r/min stirs 30min and obtains footwear use Heat-resisting moisture-proof adhesive.
The heat-resisting moisture-proof adhesive of a kind of footwear of the present invention, its raw material includes modified acrylate emulsion, polyvinyl acetate Ester emulsion, natural emulsion, styrene-butadiene latex, polychloroprene latex, polyacrylamide, phenolic resin, polyurethane, polyvinyl butyral resin, Carboxymethyl cellulose, organic silicon-boron, nano silicon, organobentonite, precipitated calcium carbonate, white clay, modified firming agent, silicon Alkane coupling agent KH-550, altax P-30, polyether polyol and antioxidant 1010.With modified acrylate emulsion it is wherein Major ingredient, auxiliary add polyvinyl acetate emulsion, natural emulsion, styrene-butadiene latex, polychloroprene latex, polyacrylamide, phenolic resin, Polyurethane and the reinforcement material that polyvinyl butyral resin is major ingredient, by the proportioning of conservative control Yu major ingredient, impart footwear of the present invention Stick with glue the heat-resisting water resistance that agent is excellent.The carboxymethyl cellulose of interpolation, organic silicon-boron, nano silicon, organic swelling Soil, precipitated calcium carbonate and white clay are filler, impart the toughness that adhesive for shoes of the present invention is excellent, heat-resisting and water resistance Good.The silane resin acceptor kh-550 added carries out effective graft modification to filler so that be connected more between filler with major ingredient Add, impart the waterproof heat resistant performance that adhesive for shoes of the present invention is excellent.Add altax P-30, polyether polyol and Antioxidant 1010, as auxiliary agent, imparts the combination property that adhesive for shoes of the present invention is excellent.The footwear that the present invention prepares Stick with glue agent and there is the heat-resisting and water resistance of excellence.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for this is described Bright rather than be used for limiting the invention, any made on the basis of the present invention amendment, equivalent etc. is all at this In bright protection domain.
In detailed description of the invention, the weight portion of modified acrylate emulsion can be 20 parts, 25 parts, 30 parts, 35 parts, 40 Part, 45 parts, 50 parts；The weight portion of polyvinyl acetate emulsion can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 Part, 13 parts, 14 parts, 15 parts；The weight portion of natural emulsion can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；Styrene-butadiene latex Weight portion can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of polychloroprene latex can be 1 part, 1.5 parts, 2 parts, 2.5 Part, 3 parts, 3.5 parts, 4 parts；The weight portion of polyacrylamide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Phenol The weight portion of urea formaldehyde can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of polyurethane can be 2 parts, 3 parts, 4 parts, 5 Part, 6 parts；The weight portion of polyvinyl butyral resin can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Carboxymethyl is fine The weight portion of dimension element can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of organic silicon-boron can be 2 Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of nano silicon can be 3 parts, 3.5 parts, 4 parts, 4.5 Part, 5 parts, 5.5 parts, 6 parts；Bentonite weight portion can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight of precipitated calcium carbonate Part can be 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The weight portion of white clay can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The weight portion of modified firming agent can be 2 parts, 2.5 parts, 3 Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of silane resin acceptor kh-550 can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of altax P-30 can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Polyethers is many The weight portion of unit's alcohol can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of antioxidant 1010 is permissible It it is 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts.
Embodiment 1
The heat-resisting moisture-proof adhesive of a kind of footwear that the present invention proposes, its raw material includes by weight: modification acrylate breast Liquid 35 parts, polyvinyl acetate emulsion 10 parts, natural emulsion 5 parts, styrene-butadiene latex 4 parts, polychloroprene latex 2.5 parts, polyacrylamide 2.5 parts, 4 parts of phenolic resin, polyurethane 4 parts, polyvinyl butyral resin 2.5 parts, carboxymethyl cellulose 3.5 parts, organic silicon-boron 3.5 Part, nano silicon 4.5 parts, organobentonite 6 parts, precipitated calcium carbonate 6.5 parts, white clay 6.5 parts, modified firming agent 3.5 Part, silane resin acceptor kh-550 4.5 parts, altax P-30 2.5 parts, polyether polyol 3.5 parts, antioxidant 1010 3.5 Part.
Embodiment 2
The heat-resisting moisture-proof adhesive of a kind of footwear that the present invention proposes, its raw material includes by weight: modification acrylate breast Liquid 20 parts, polyvinyl acetate emulsion 15 parts, natural emulsion 2 parts, styrene-butadiene latex 5 parts, polychloroprene latex 1 part, polyacrylamide 4 Part, 3 parts of phenolic resin, polyurethane 6 parts, polyvinyl butyral resin 1 part, carboxymethyl cellulose 5 parts, organic silicon-boron 2 parts, nanometer two Silicon oxide 6 parts, organobentonite 4 parts, precipitated calcium carbonate 8 parts, white clay 4 parts, modified firming agent 5 parts, silane coupler KH- 550 3 parts, altax P-30 4 parts, polyether polyol 2 parts, antioxidant 1010 5 parts.
Modified acrylate emulsion is prepared by following technique: by weight by 8 parts of dodecylbenzene sodium sulfonate, 12 parts OP-10,12 parts of epoxy resin, 5 parts of butyl acrylate, 1 part of methyl methacrylate, 5 parts of acrylic acid and 5 parts of deionized water mixing Uniformly, in 14000r/min emulsion dispersion 25min, obtain emulsion, in emulsion, then add 6 parts of Ammonium persulfate .s and 3 parts Sodium bicarbonate mix homogeneously, is warming up to 85 DEG C, is incubated 1h, is cooled to room temperature, filters and adds triethanolamine regulation in backward filtrate PH to 8.0, obtains modified acrylate emulsion.
Modified firming agent is prepared by following technique: by molar part by 0.5 part of thiourea, 3 parts of diethylenetriamines and 2 parts of chlorine Changing sodium mix homogeneously, be passed through nitrogen, then oil bath is heated to 150 DEG C, is incubated 20min, is then cooled to 60 DEG C, is incubated 0.5h, It is then cooled to room temperature and obtains modified firming agent.
Embodiment 3
The heat-resisting moisture-proof adhesive of a kind of footwear that the present invention proposes, its raw material includes by weight: modification acrylate breast Liquid 50 parts, polyvinyl acetate emulsion 5 parts, natural emulsion 8 parts, styrene-butadiene latex 3 parts, polychloroprene latex 4 parts, polyacrylamide 1 part, 5 parts of phenolic resin, polyurethane 2 parts, polyvinyl butyral resin 4 parts, carboxymethyl cellulose 2 parts, organic silicon-boron 5 parts, nano-silica SiClx 3 parts, organobentonite 8 parts, precipitated calcium carbonate 5 parts, white clay 9 parts, modified firming agent 2 parts, silane resin acceptor kh-550 6 parts, altax P-30 1 part, polyether polyol 5 parts, antioxidant 1010 2 parts.
Modified acrylate emulsion is prepared by following technique: by weight by 16 parts of dodecylbenzene sodium sulfonate, 6 parts OP-10,24 parts of epoxy resin, 2 parts of butyl acrylate, 4 parts of methyl methacrylates, 3 parts of acrylic acid and 15 parts of deionized waters mix Close uniformly, in 12000r/min emulsion dispersion 35min, obtain emulsion, in emulsion, then add 2 parts of Ammonium persulfate .s and 9 Part sodium bicarbonate mix homogeneously, is warming up to 75 DEG C, is incubated 3h, is cooled to room temperature, filters and adds triethanolamine tune in backward filtrate Joint pH to 7.0, obtains modified acrylate emulsion.
Modified firming agent is prepared by following technique: by molar part by 1.5 parts of thiourea, 1 part of diethylenetriamine and 5 parts of chlorine Changing sodium mix homogeneously, be passed through nitrogen, then oil bath is heated to 110 DEG C, is incubated 40min, is then cooled to 50 DEG C, is incubated 1.5h, It is then cooled to room temperature and obtains modified firming agent.
Embodiment 4
The heat-resisting moisture-proof adhesive of a kind of footwear that the present invention proposes, its raw material includes by weight: modification acrylate breast Liquid 25 parts, polyvinyl acetate emulsion 12 parts, natural emulsion 3 parts, styrene-butadiene latex 4.5 parts, polychloroprene latex 2 parts, polyacrylamide 3 Part, 3.5 parts of phenolic resin, polyurethane 5 parts, polyvinyl butyral resin 2 parts, carboxymethyl cellulose 4 parts, organic silicon-boron 3 parts, nanometer Silicon dioxide 5 parts, organobentonite 5 parts, precipitated calcium carbonate 7 parts, white clay 5 parts, modified firming agent 4 parts, silane coupler KH- 550 4 parts, altax P-30 3 parts, polyether polyol 3 parts, antioxidant 1010 4 parts.
Modified acrylate emulsion is prepared by following technique: by weight by 9 parts of dodecylbenzene sodium sulfonate, 11 parts OP-10,14 parts of epoxy resin, 4 parts of butyl acrylate, 2 parts of methyl methacrylates, 4.5 parts of acrylic acid and 8 parts of deionized waters mix Close uniformly, in 13500r/min emulsion dispersion 28min, obtain emulsion, in emulsion, then add 5 parts of Ammonium persulfate .s and 4 Part sodium bicarbonate mix homogeneously, is warming up to 82 DEG C, is incubated 1.5h, is cooled to room temperature, filters addition triethanolamine in backward filtrate Regulation pH to 7.8, obtains modified acrylate emulsion.
Modified firming agent is prepared by following technique: by molar part by 0.8 part of thiourea, 2.5 parts of diethylenetriamines and 3 parts Sodium chloride mix homogeneously, is passed through nitrogen, and then oil bath is heated to 140 DEG C, is incubated 25min, is then cooled to 58 DEG C, insulation 0.8h, is then cooled to room temperature and obtains modified firming agent.
Embodiment 5
The heat-resisting moisture-proof adhesive of a kind of footwear that the present invention proposes, its raw material includes by weight: modification acrylate breast Liquid 45 parts, polyvinyl acetate emulsion 8 parts, natural emulsion 7 parts, styrene-butadiene latex 3.5 parts, polychloroprene latex 3 parts, polyacrylamide 2 Part, 4.5 parts of phenolic resin, polyurethane 3 parts, polyvinyl butyral resin 3 parts, carboxymethyl cellulose 3 parts, organic silicon-boron 4 parts, nanometer Silicon dioxide 4 parts, organobentonite 7 parts, precipitated calcium carbonate 6 parts, white clay 8 parts, modified firming agent 3 parts, silane coupler KH- 550 5 parts, altax P-30 2 parts, polyether polyol 4 parts, antioxidant 1010 3 parts.
Modified acrylate emulsion is prepared by following technique: by weight by 15 parts of dodecylbenzene sodium sulfonate, 7 parts OP-10,22 parts of epoxy resin, 3 parts of butyl acrylate, 3 parts of methyl methacrylates, 3.5 parts of acrylic acid and 12 parts of deionized waters Mix homogeneously, in 12500r/min emulsion dispersion 32min, obtains emulsion, then add in emulsion 3 parts of Ammonium persulfate .s and 8 parts of sodium bicarbonate mix homogeneously, are warming up to 78 DEG C, are incubated 2.5h, are cooled to room temperature, filter addition triethanolamine in backward filtrate Regulation pH to 7.2, obtains modified acrylate emulsion.
Modified firming agent is prepared by following technique: by molar part by 1.2 parts of thiourea, 1.5 parts of diethylenetriamines and 4 parts Sodium chloride mix homogeneously, is passed through nitrogen, and then oil bath is heated to 120 DEG C, is incubated 35min, is then cooled to 52 DEG C, insulation 1.2h, is then cooled to room temperature and obtains modified firming agent.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (7)

1. the heat-resisting moisture-proof adhesive of footwear, it is characterised in that its raw material includes by weight: modified acrylate emulsion 20-50 part, polyvinyl acetate emulsion 5-15 part, natural emulsion 2-8 part, styrene-butadiene latex 3-5 part, polychloroprene latex 1-4 part, poly-third Acrylamide 1-4 part, phenolic resin 3-5 part, polyurethane 2-6 part, polyvinyl butyral resin 1-4 part, carboxymethyl cellulose 2-5 part, Organic silicon-boron 2-5 part, nano silicon 3-6 part, organobentonite 4-8 part, precipitated calcium carbonate 5-8 part, white clay 4-9 part, Modified firming agent 2-5 part, silane resin acceptor kh-550 3-6 part, altax P-30 1-4 part, polyether polyol 2-5 part, anti- Oxidant 1010 2-5 part.
The heat-resisting moisture-proof adhesive of footwear the most according to claim 1, it is characterised in that the raw material of modified acrylate emulsion Include by weight: dodecylbenzene sodium sulfonate 8-16 part, OP-10 6-12 part, epoxy resin 12-24 part, butyl acrylate 2- 5 parts, methyl methacrylate 1-4 part, acrylic acid 3-5 part, Ammonium persulfate. 2-6 part, sodium bicarbonate 3-9 part, deionized water 5-15 Part.
The heat-resisting moisture-proof adhesive of footwear the most according to claim 1 and 2, it is characterised in that modified acrylate emulsion is pressed Following technique is prepared: by dodecylbenzene sodium sulfonate, OP-10, epoxy resin, butyl acrylate, methyl methacrylate, Acrylic acid and deionized water mix homogeneously, in 12000-14000r/min emulsion dispersion 25-35min, obtain emulsion, then to Emulsion adds Ammonium persulfate. and sodium bicarbonate mix homogeneously, is warming up to 75-85 DEG C, be incubated 1-3h, be cooled to room temperature, filter Backward filtrate adds triethanolamine regulation pH to 7.0-8.0, obtains modified acrylate emulsion.
4. according to the heat-resisting moisture-proof adhesive of footwear described in any one of claim 1-3, it is characterised in that modified firming agent is by such as Lower technique is prepared: by thiourea, diethylenetriamine and sodium chloride mix homogeneously, being passed through nitrogen, then oil bath is heated to 110- 150 DEG C, be incubated 20-40min, be then cooled to 50-60 DEG C, be incubated 0.5-1.5h, be then cooled to room temperature obtain modified solidified Agent.
5. according to the heat-resisting moisture-proof adhesive of footwear described in any one of claim 1-4, it is characterised in that the system of modified firming agent In standby technique, the mol ratio of thiourea, diethylenetriamine and sodium chloride is 0.5-1.5:1-3:2-5.
6. according to the heat-resisting moisture-proof adhesive of footwear described in any one of claim 1-5, it is characterised in that its raw material is by weight Including: modified acrylate emulsion 25-45 part, polyvinyl acetate emulsion 8-12 part, natural emulsion 3-7 part, styrene-butadiene latex 3.5-4.5 part, polychloroprene latex 2-3 part, polyacrylamide 2-3 part, phenolic resin 3.5-4.5 part, polyurethane 3-5 part, polyethylene Butyral 2-3 part, carboxymethyl cellulose 3-4 part, organic silicon-boron 3-4 part, nano silicon 4-5 part, organobentonite 5-7 Part, precipitated calcium carbonate 6-7 part, white clay 5-8 part, modified firming agent 3-4 part, silane resin acceptor kh-550 4-5 part, accelerator DMP-30 2-3 part, polyether polyol 3-4 part, antioxidant 1010 3-4 part.
7. according to the heat-resisting moisture-proof adhesive of footwear described in any one of claim 1-6, it is characterised in that its raw material is by weight Including: modified acrylate emulsion 35 parts, polyvinyl acetate emulsion 10 parts, natural emulsion 5 parts, styrene-butadiene latex 4 parts, neoprene Breast 2.5 parts, polyacrylamide 2.5 parts, 4 parts of phenolic resin, polyurethane 4 parts, polyvinyl butyral resin 2.5 parts, carboxymethyl cellulose Element 3.5 parts, organic silicon-boron 3.5 parts, nano silicon 4.5 parts, organobentonite 6 parts, precipitated calcium carbonate 6.5 parts, white clay 6.5 parts, modified firming agent 3.5 parts, silane resin acceptor kh-550 4.5 parts, altax P-30 2.5 parts, polyether polyol 3.5 Part, antioxidant 1010 3.5 parts.
CN201610696555.3A 2016-08-22 2016-08-22 Heat-resistant waterproof adhesive for shoes Pending CN106318290A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107384280A (en) * 2017-08-31 2017-11-24 成都卡美奇鞋业有限公司 A kind of adhesive for shoe-making process
CN107434965A (en) * 2017-08-31 2017-12-05 成都卡美奇鞋业有限公司 Based on the adhesive for improving adhesive effect
CN107459958A (en) * 2017-07-28 2017-12-12 安徽安大华泰新材料有限公司 A kind of adhesive of waterproof high shelf-life for paper product processing and preparation method thereof
CN107474764A (en) * 2017-08-31 2017-12-15 成都卡美奇鞋业有限公司 A kind of adhesive for being used for connected shoe soles and upper of a shoe
CN107541164A (en) * 2017-07-28 2018-01-05 安徽安大华泰新材料有限公司 A kind of water-repellent modified adhesive for furniture finishing and preparation method thereof
CN107556926A (en) * 2017-07-28 2018-01-09 安徽安大华泰新材料有限公司 A kind of high anticreep water proofing property modified adhesive for electrostatic flocking technology
CN107700250A (en) * 2017-10-19 2018-02-16 无为县荣华鬃刷制品有限公司 A kind of antiultraviolet dyestuff for the printing and dyeing of pig hair
CN108285759A (en) * 2018-02-05 2018-07-17 合肥梵腾环保科技有限公司 Antibacterial high viscous waterproof white glue with vinyl of a kind of environment friendly mildew resistant and preparation method thereof
CN108949043A (en) * 2018-07-16 2018-12-07 广州昱辰元创节能环保科技有限公司 A kind of building board marine glue and its preparation method and application
CN110093126A (en) * 2019-03-27 2019-08-06 广州市永添生物科技有限公司 A kind of preparation method of medical aqueous multiple emulsion paper-plastic lamination adhesive
CN110964466A (en) * 2019-11-25 2020-04-07 深圳市佳鑫一帆科技有限公司 Glue preparation method
CN113100540A (en) * 2021-03-29 2021-07-13 温州职业技术学院 Double-layer waterproof canvas shoes

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CN103409090A (en) * 2013-06-05 2013-11-27 武汉市科达云石护理材料有限公司 Epoxy caulk compound used in humid environment
CN104031580A (en) * 2014-06-17 2014-09-10 毛林涛 Leather adhesive

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CN1237609A (en) * 1999-05-31 1999-12-08 陈锦荣 Emulsion glue and its non-toxic application in shoe-making industry
CN101058704A (en) * 2007-05-29 2007-10-24 林润强 Multifunctional aqueous adhesive and preparation method thereof
CN102181042A (en) * 2011-04-06 2011-09-14 无锡贝拉克新材料科技有限公司 Method for preparing epoxy resin curing agent
CN102876267A (en) * 2012-09-21 2013-01-16 海南必凯水性涂料有限公司 Bi-component waterborne acrylic acid adhesive and preparation method thereof
CN103409090A (en) * 2013-06-05 2013-11-27 武汉市科达云石护理材料有限公司 Epoxy caulk compound used in humid environment
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107459958A (en) * 2017-07-28 2017-12-12 安徽安大华泰新材料有限公司 A kind of adhesive of waterproof high shelf-life for paper product processing and preparation method thereof
CN107541164A (en) * 2017-07-28 2018-01-05 安徽安大华泰新材料有限公司 A kind of water-repellent modified adhesive for furniture finishing and preparation method thereof
CN107556926A (en) * 2017-07-28 2018-01-09 安徽安大华泰新材料有限公司 A kind of high anticreep water proofing property modified adhesive for electrostatic flocking technology
CN107384280A (en) * 2017-08-31 2017-11-24 成都卡美奇鞋业有限公司 A kind of adhesive for shoe-making process
CN107434965A (en) * 2017-08-31 2017-12-05 成都卡美奇鞋业有限公司 Based on the adhesive for improving adhesive effect
CN107474764A (en) * 2017-08-31 2017-12-15 成都卡美奇鞋业有限公司 A kind of adhesive for being used for connected shoe soles and upper of a shoe
CN107700250A (en) * 2017-10-19 2018-02-16 无为县荣华鬃刷制品有限公司 A kind of antiultraviolet dyestuff for the printing and dyeing of pig hair
CN108285759A (en) * 2018-02-05 2018-07-17 合肥梵腾环保科技有限公司 Antibacterial high viscous waterproof white glue with vinyl of a kind of environment friendly mildew resistant and preparation method thereof
CN108949043A (en) * 2018-07-16 2018-12-07 广州昱辰元创节能环保科技有限公司 A kind of building board marine glue and its preparation method and application
CN110093126A (en) * 2019-03-27 2019-08-06 广州市永添生物科技有限公司 A kind of preparation method of medical aqueous multiple emulsion paper-plastic lamination adhesive
CN110964466A (en) * 2019-11-25 2020-04-07 深圳市佳鑫一帆科技有限公司 Glue preparation method
CN113100540A (en) * 2021-03-29 2021-07-13 温州职业技术学院 Double-layer waterproof canvas shoes

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