CN106366265A - Preparation method of vermilion transparent resin - Google Patents
Preparation method of vermilion transparent resin Download PDFInfo
- Publication number
- CN106366265A CN106366265A CN201610756871.5A CN201610756871A CN106366265A CN 106366265 A CN106366265 A CN 106366265A CN 201610756871 A CN201610756871 A CN 201610756871A CN 106366265 A CN106366265 A CN 106366265A
- Authority
- CN
- China
- Prior art keywords
- parts
- hour
- temperature
- transparent resin
- vermilion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000011347 resin Substances 0.000 title claims abstract description 7
- 229920005989 resin Polymers 0.000 title claims abstract description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 12
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005751 Copper oxide Substances 0.000 claims abstract description 4
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 claims abstract description 4
- 230000008018 melting Effects 0.000 claims abstract description 4
- 239000004312 hexamethylene tetramine Substances 0.000 claims abstract 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract 2
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 abstract description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 229930185605 Bisphenol Natural products 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical group C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
- C08G8/34—Chemically modified polycondensates by natural resins or resin acids, e.g. rosin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
The invention discloses a preparation method of vermilion red transparent resin. The preparation method is characterized by comprising the following steps: according to weight parts, heating 100 parts of rosin at the temperature of 150 to 160DEG C, melting, and adding 20 to 22 parts of copper oxide; performing reaction on 5 to 15 parts of maleic anhydride at the temperature of 180 to 200DEG C for 1.5 to 2 hours; adding 10 to 15 parts of bisphenol A, stirring for 0.3 to 0.5 hour, cooling to be 90 to 100DEG C, adding 12 to 30 parts of formaldehyde and 1 to 3 parts of hexamethylenetetramine as an accelerator , stirring at the temperature of 90 to 100DEG C for 2 to 2.5 hours; adding not less than 80 parts of glycerol, raising the temperature to be180 to 200DEG C, and performing stirring reaction for 2 to 2.5 hours; raising the temperature to be 270 to 280DEG C, and vacuumizing for one hour, thus obtaining a product.
Description
Technical field
The invention belongs to a kind of Colophonium deep working method.
Background technology
Colophonium is the Renewable resource of China's abundant, and annual production reaches more than 60 ten thousand tons, ranks first in the world.It is by a series of
Resinic acid composition, there are chemical constitution and the mulitiple chiral centers of uniqueness, the carboxyl in structure and phenanthrene ring frame can be carried out
A series of chemical modification, is a kind of natural chiral source material.Colophonium can obtain a series of deep processings through chemical modification
Product, the every field being widely applied in daily life, plays very important effect in the national economic development.These are deep
The value ratio raw material Colophonium of converted productss mentions 2-10 times, or even decades of times.
Content of the invention
It is an object of the invention to: for the deficiencies in the prior art, a kind of vermilion transparent resin preparation method is proposed.
The vermilion transparent resin preparation method of the present invention it is characterised in that: by weight, 100 parts of Colophonium, heat 150-
160 DEG C of meltings, add copper oxide 20-22 part；Maleic anhydride 5-15 part, carries out at 180-200 DEG C reacting 1.5-2 hour；
Add bis-phenol a, 10-15 part, stir 0.3-0.5 hour, be cooled to 90-100 DEG C, add formaldehyde 12-30 part, six first of accelerator
Urotropine 1-3 part, 90-100 DEG C of stirring 2-2.5 hour, add glycerol to be no less than 80 parts, 180-200 DEG C of intensification, stirring reaction
2-2.5 hour, is warming up to 270-280 DEG C of evacuation 1 hour；Obtain final product product.
The product of the present invention has lighter color, the features such as softening point is high, should make good use of artware, in paint, ink, synthesis tree
The industrial departments such as fat, adhesive, electronics, chemical industry.
Present invention beneficial effect compared with prior art: rationally, response speed is fast and relaxes it is easy to control for design science
System, product color is shallow, up to more than 185 DEG C of softening point, quality are good, the advantages of production cost reduces.
Specific embodiment
The present invention's is raw materials used available commercially.
The vermilion transparent resin preparation method of the present invention it is characterised in that: by weight, 100 parts of Colophonium, heat 150-
160 DEG C of meltings, add copper oxide 20-22 part；Maleic anhydride 5-15 part, carries out at 180-200 DEG C reacting 1.5-2 hour；
Add bis-phenol a, 10-15 part, stir 0.3-0.5 hour, be cooled to 90-100 DEG C, add formaldehyde 12-30 part, six first of accelerator
Urotropine 1-3 part, 90-100 DEG C of stirring 2-2.5 hour, add glycerol to be no less than 80 parts, 180-200 DEG C of intensification, stirring reaction 2-
2.5 hours, it is warming up to 270-280 DEG C of evacuation 1 hour；Obtain final product product.Products obtained therefrom quality index reaches following index:
Claims (1)
1. a kind of vermilion transparent resin preparation method it is characterised in that: by weight, 100 parts of Colophonium, heat 150-160 DEG C
Melting, adds copper oxide 20-22 part；Maleic anhydride 5-15 part, carries out at 180-200 DEG C reacting 1.5-2 hour；Add double
Phenol a, 10-15 part, stirs 0.3-0.5 hour, is cooled to 90-100 DEG C, adds formaldehyde 12-30 part, accelerator hexamethylenetetramine
1-3 part, 90-100 DEG C of stirring 2-2.5 hour, add glycerol to be no less than 80 parts, 180-200 DEG C of intensification, stirring reaction 2-2.5 is little
When, it is warming up to 270-280 DEG C of evacuation 1 hour；Obtain final product product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756871.5A CN106366265A (en) | 2016-08-24 | 2016-08-24 | Preparation method of vermilion transparent resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756871.5A CN106366265A (en) | 2016-08-24 | 2016-08-24 | Preparation method of vermilion transparent resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106366265A true CN106366265A (en) | 2017-02-01 |
Family
ID=57902528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610756871.5A Pending CN106366265A (en) | 2016-08-24 | 2016-08-24 | Preparation method of vermilion transparent resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106366265A (en) |
-
2016
- 2016-08-24 CN CN201610756871.5A patent/CN106366265A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170201 |