CN106349943A - Preparing method for maleated lithium rosin - Google Patents
Preparing method for maleated lithium rosin Download PDFInfo
- Publication number
- CN106349943A CN106349943A CN201610756987.9A CN201610756987A CN106349943A CN 106349943 A CN106349943 A CN 106349943A CN 201610756987 A CN201610756987 A CN 201610756987A CN 106349943 A CN106349943 A CN 106349943A
- Authority
- CN
- China
- Prior art keywords
- lithium
- hour
- colophonium
- add
- rosin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 title claims abstract description 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title abstract 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title abstract 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 13
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229930185605 Bisphenol Natural products 0.000 claims abstract description 7
- 239000011261 inert gas Substances 0.000 claims abstract description 4
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 7
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 6
- 235000019256 formaldehyde Nutrition 0.000 abstract 2
- 238000007259 addition reaction Methods 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000007385 chemical modification Methods 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 electronics Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical group C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses a preparing method for maleated lithium rosin. The ratio of maleic anhydride: bisphenol: methanal: pentaerythritol: lithium hydroxide of the rosin is 1:0.3:0.2:0.3:0.3:1. The process comprises the steps of heating the rosin with the presence of inert gases and increasing the temperature to 180-200oC, adding lithium hydroxide and increasing the temperature to 250-260oC, reacting for 30-40min, adding bisphenol A and mixing for 0.3-0.5h, decreasing to 90-100oC, adding methanal, mixing for 2-2.5h at 90-100oC, adding maleic anhydride, performing addition reaction at 180-200oC for 1.5-2h; adding pentaerythritol and increasing to 180-200oC, mixing and reacting for 2-2.5h, increasing to 270-280oC and vacuumizing for 1h to obtain the product.
Description
Technical field
The invention belongs to a kind of Colophonium deep working method.
Background technology
Colophonium is the Renewable resource of China's abundant, and annual production reaches more than 60 ten thousand tons, ranks first in the world.It is by a series of
Resinic acid composition, there are chemical constitution and the mulitiple chiral centers of uniqueness, the carboxyl in structure and phenanthrene ring frame can be carried out
A series of chemical modification, is a kind of natural chiral source material.Colophonium can obtain a series of deep processings through chemical modification
Product, the every field being widely applied in daily life, plays very important effect in the national economic development.These are deep
The value ratio raw material Colophonium of converted productss mentions 2-10 times, or even decades of times.
Content of the invention
It is an object of the invention to: for the deficiencies in the prior art, a kind of Malaysia lithium Colophonium preparation method is proposed.
The Malaysia lithium Colophonium preparation method of the present invention it is characterised in that: material ratio is, Colophonium: maleic anhydride: bis-phenol
: formaldehyde: tetramethylolmethane: the mol ratio of Lithium hydrate is 1: 0.3: 0.2: 0.3: 0.3: 1；Its technique comprises the following steps, by joining
Ratio quantity, Colophonium is heated under an inert gas melting, 180-200 DEG C of intensification, adds Lithium hydrate, be warming up to 250-260 DEG C
Reaction 30-40 minute, adds bis-phenol a, stirs 0.3-0.5 hour, is cooled to 90-100 DEG C, adds formaldehyde, 90-100 DEG C of stirring
2-2.5 hour, adds maleic anhydride, carries out additive reaction 1.5-2 hour at 180-200 DEG C；Add tetramethylolmethane, heat up
180-200 DEG C, stirring reaction 2-2.5 hour, it is warming up to 270-280 DEG C of evacuation 1 hour；Obtain final product product.
The product of the present invention has lighter color, the features such as softening point is high, is applied to paint, ink, synthetic resin, gluing
The industrial departments such as agent, electronics, chemical industry.
Present invention beneficial effect compared with prior art: rationally, response speed is fast and relaxes it is easy to control for design science
System, product color is shallow, up to more than 185 DEG C of softening point, quality are good, the advantages of production cost reduces.
Specific embodiment
The present invention's is raw materials used available commercially.
The Malaysia lithium Colophonium preparation method of the present invention it is characterised in that: material ratio is, Colophonium: maleic anhydride: bis-phenol
: formaldehyde: tetramethylolmethane: the mol ratio of Lithium hydrate is 1: 0.3: 0.2: 0.3: 0.3: 1；Its technique comprises the following steps, by joining
Ratio quantity, Colophonium is heated under an inert gas melting, 180-200 DEG C of intensification, adds Lithium hydrate, be warming up to 250-260 DEG C
Reaction 30-40 minute, adds bis-phenol a, stirs 0.3-0.5 hour, is cooled to 90-100 DEG C, adds formaldehyde, 90-100 DEG C of stirring
2-2.5 hour, adds maleic anhydride, carries out additive reaction 1.5-2 hour at 180-200 DEG C；Add tetramethylolmethane, heat up
180-200 DEG C, stirring reaction 2-2.5 hour, it is warming up to 270-280 DEG C of evacuation 1 hour；Obtain final product product.Products obtained therefrom quality
Index reaches following index:
Claims (1)
1. a kind of Malaysia lithium Colophonium preparation method it is characterised in that: material ratio is, Colophonium: maleic anhydride: bis-phenol: formaldehyde:
Tetramethylolmethane: the mol ratio of Lithium hydrate is 1: 0.3: 0.2: 0.3: 0.3: 1；Its technique comprises the following steps, by stoichiometric amount,
Colophonium is heated under an inert gas melting, 180-200 DEG C of intensification, add Lithium hydrate, be warming up to 250-260 DEG C of reaction 30-
40 minutes, add bis-phenol a, stir 0.3-0.5 hour, be cooled to 90-100 DEG C, add formaldehyde, 90-100 DEG C of stirring 2-2.5 is little
When, add maleic anhydride, at 180-200 DEG C, carry out additive reaction 1.5-2 hour；Add tetramethylolmethane, intensification 180-200
DEG C, stirring reaction 2-2.5 hour, it is warming up to 270-280 DEG C of evacuation 1 hour；Obtain final product product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756987.9A CN106349943A (en) | 2016-08-24 | 2016-08-24 | Preparing method for maleated lithium rosin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756987.9A CN106349943A (en) | 2016-08-24 | 2016-08-24 | Preparing method for maleated lithium rosin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106349943A true CN106349943A (en) | 2017-01-25 |
Family
ID=57857233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610756987.9A Pending CN106349943A (en) | 2016-08-24 | 2016-08-24 | Preparing method for maleated lithium rosin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106349943A (en) |
-
2016
- 2016-08-24 CN CN201610756987.9A patent/CN106349943A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170125 |