CN106363937A - Silica aerogel penetrating A-class fireproof heat retaining panel and manufacturing method thereof - Google Patents

Silica aerogel penetrating A-class fireproof heat retaining panel and manufacturing method thereof Download PDF

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Publication number
CN106363937A
CN106363937A CN201610844226.9A CN201610844226A CN106363937A CN 106363937 A CN106363937 A CN 106363937A CN 201610844226 A CN201610844226 A CN 201610844226A CN 106363937 A CN106363937 A CN 106363937A
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CN
China
Prior art keywords
silica aerogel
water
penetrating
heated board
heat retaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610844226.9A
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Chinese (zh)
Inventor
李国忠
赵训
曹笃霞
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University of Jinan
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University of Jinan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Jinan filed Critical University of Jinan
Priority to CN201610844226.9A priority Critical patent/CN106363937A/en
Publication of CN106363937A publication Critical patent/CN106363937A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
    • C04B14/064Silica aerogel
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/762Exterior insulation of exterior walls
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • E04B1/80Heat insulating elements slab-shaped
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B1/94Protection against other undesired influences or dangers against fire
    • E04B1/941Building elements specially adapted therefor
    • E04B1/942Building elements specially adapted therefor slab-shaped
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/242Slab shaped vacuum insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/10Insulation, e.g. vacuum or aerogel insulation

Abstract

The invention belongs to the field of external thermal insulation of building outer walls and relates to a silica aerogel penetrating A-class fireproof heat retaining panel and a manufacturing method thereof. A loose type molding polystyrene plate serves as a base plate, silica aerogel, silicate cement, a polycarboxylate water reducing agent, a water-soluble organic silicon waterproof agent and water are mixed and stirred to prepare silica aerogel composite material slurry, cement polymer slurry is permeated into the base plate through vacuum pressure, redundant silica aerogel composite material slurry is removed, maintenance is conducted, and thus the silica aerogel penetrating A-class fireproof heat retaining panel is obtained. The silica aerogel penetrating A-class fireproof heat retaining panel is low in product weight, high in strength and low in heat conductivity coefficient, the combustion performance belongs to the A class, all the performance indexes meet the current national building energy-saving design standard requirements and fire prevention code requirements, and the silica aerogel penetrating A-class fireproof heat retaining panel can be widely applied to the field of external thermal insulation of the building outer walls.

Description

A kind of silica aerogel osmosis type a level fireproof heated board and preparation method thereof
Technical field
The present invention relates to a kind of a level fireproof heated board, more specifically to a kind of silica aerogel osmosis type a level fire prevention guarantor Warm plate, the manufacture method also relating to this silica aerogel osmosis type a level fireproof heated board.This silica aerogel osmosis type a level is prevented Fiery warming plate property indices meet national Current Building ' energy saving igniter requirement and the requirement of fire safety rules, can extensively answer For external wall external thermal insulation field.
Background technology
The enforcement come with Building Energy Conservation Policy of energy crisis, has promoted the fast development of wall heat insulation material.At present, The insulation material that skin adopts mainly has two big class, and a class is polystyrene foam plastics, rigid polyurethane fat foam plastic The organic insulation materials such as material, have the advantages that light weight, good effect of heat insulation.But, this kind of insulation material easy firing, and Produce with a large amount of poisones and flue gas, tend not to meet the requirement of existing National Fire specification.Another kind of be cement board, The inorganic heat insulation materials such as expanded pearlite rock beam, this kind of insulation material has intensity height, combustibility is that a level incombustible material etc. is excellent Point.But its heat conductivity is higher, typically the 1.5 ~ 2 of organic insulation material times, with progressively carrying of China's building energy conservation requirement Height, tends not to meet Current Building ' energy saving igniter requirement.Aeroge has nano-porous structure, and its porosity is high, close Degree is low, specific surface area is big, the low property of heat conductivity is so as to the application in external wall external thermal insulation field has very big diving Power.But the shortcoming of its low intensity, poor toughness is so as to cannot function as single block materials for insulation engineering.Therefore, With aeroge and organic and inorganic insulation material as primary raw material, design and produce a kind of lightweight, do not fire, thermal and insulating performance excellent, The external wall outer insulation material meeting the requirement of the design standard for energy efficiency of buildings requirement of existing country and fire safety rules is very necessary.
Content of the invention
It is an object of the invention to overcoming the deficiencies in the prior art, provide a kind of good heat insulating, combustibility a level, matter Gently, high silica aerogel osmosis type a level fireproof heated board of intensity and preparation method thereof, the silicon airsetting being produced by this manufacture method Glue penetration type a level fireproof heated board, property indices meet the design standard for energy efficiency of buildings requirement of existing country and fire safety rules Requirement, can be widely applied to external wall external thermal insulation field.
For achieving the above object, the present invention adopts the following technical scheme that with loose type molding styrofoam as substrate, lies against Have on the equipment of evacuation function, by silica aerogel composite slurry uniform fold on substrate, open vacuum pump and apply Plus negative pressure, so that silica aerogel composite slurry is penetrated in the gap between substrate granular polystyrene and be full of, removed with scraper plate Unnecessary silica aerogel composite slurry, through 60 DEG C of maintenances 120 hours or natural curing 42 days, prepared silica aerogel osmosis type A level fireproof heated board.
The silica aerogel osmosis type a level fireproof heated board that the present invention makes, the long 600-1200mm of plate, plate width 300-600mm, Thickness of slab 30-90mm.
The silica aerogel osmosis type a level fireproof heated board of the present invention, using silica aerogel composite slurry and loose type Molding styrofoam makes for primary raw material.Wherein, silica aerogel composite slurry is made up of the raw material of following weight portion:
100 parts of silica aerogel
Portland cement 100-500 part
Polycarboxylate water-reducer 1.0-5.0 part
Water-soluble organic silicon waterproofing agent 1.0-5.0 part
Water 160-240 part.
Wherein, loose type molding styrofoam is not more than 15kg/m for density3Loose type molding styrofoam.
The present invention molds styrofoam as substrate with loose type, with silica aerogel, portland cement, polycarboxylate water-reducer, water Dissolubility waterproofing agent of organosilicon and water mix and blend make silica aerogel composite slurry, make silica aerogel multiple using vacuum pressure Condensation material slurry penetrates in substrate, through removing unnecessary silica aerogel composite slurry, maintenance, prepared silica aerogel infiltration Type a level fireproof heated board, product quality is light, intensity is high, heat conductivity is little, combustibility is a level, and property indices meet existing Row country design standard for energy efficiency of buildings requires the requirement with fire safety rules, can be widely applied to external wall external thermal insulation field.
Brief description
Fig. 1 is the structural representation of the silica aerogel osmosis type a level fireproof heated board of the present invention.
In figure, 1 is silica aerogel osmosis type a level fireproof heated board.
Specific embodiment
Embodiment one
As shown in figure 1, being the structural representation of the silica aerogel osmosis type a level fireproof heated board of the present invention.With loose type molding Styrofoam is substrate, lies against on the equipment with evacuation function, by silica aerogel composite slurry uniform fold in base On plate, open vacuum pump and apply negative pressure, make silica aerogel composite slurry penetrate into the gap between substrate granular polystyrene In and be full of, remove unnecessary silica aerogel composite slurry with scraper plate, through 60 DEG C of maintenances 120 hours or natural curing 42 My god, prepared silica aerogel osmosis type a level fireproof heated board.
The silica aerogel osmosis type a level fireproof heated board of the present invention, using silica aerogel composite slurry and loose type Molding styrofoam makes for primary raw material.Wherein, silica aerogel composite slurry is made up of the raw material of following weight portion:
100 parts of silica aerogel
100 parts of portland cement
1.0 parts of polycarboxylate water-reducer
1.0 parts of water-soluble organic silicon waterproofing agent
160 parts of water.
Wherein, loose type molding styrofoam is density 10kg/m3Loose type molding styrofoam.
The silica aerogel osmosis type a level fireproof heated board of the present invention, a size of 600mm × 300mm × 30mm, with reference to country Relevant criterion carries out technical performance test, and the equal conformance with standard of property indices requires, test result such as table 1.
Table 1
Inspection project Unit Measured data
Apparent density kg/m3 83
Heat conductivity w/(m·k) 0.036
Tensile strength perpendicular to plate face mpa 0.11
Dimensional stability % 0.30
Fracture bend loading n 25
Compression performance mpa 0.11
Vapor transmission coefficient ng/(pa·m·s) 5.0
Water absorption rate (v/v) % 2.9
Combustibility —— A2 level
Embodiment two
As shown in figure 1, being the structural representation of the silica aerogel osmosis type a level fireproof heated board of the present invention.With loose type molding Styrofoam is substrate, lies against on the equipment with evacuation function, by silica aerogel composite slurry uniform fold in base On plate, open vacuum pump and apply negative pressure, make silica aerogel composite slurry penetrate into the gap between substrate granular polystyrene In and be full of, remove unnecessary silica aerogel composite slurry with scraper plate, through 60 DEG C of maintenances 120 hours or natural curing 42 My god, prepared silica aerogel osmosis type a level fireproof heated board.
The silica aerogel osmosis type a level fireproof heated board of the present invention, using silica aerogel composite slurry and loose type Molding styrofoam makes for primary raw material.Wherein, silica aerogel composite slurry is made up of the raw material of following weight portion:
100 parts of silica aerogel
200 parts of portland cement
2.0 parts of polycarboxylate water-reducer
2.0 parts of water-soluble organic silicon waterproofing agent
180 parts of water.
Wherein, loose type molding styrofoam is density 12kg/m3Loose type molding styrofoam.
The silica aerogel osmosis type a level fireproof heated board of the present invention, a size of 900mm × 500mm × 60mm, with reference to country Relevant criterion carries out technical performance test, and the equal conformance with standard of property indices requires, test result such as table 2.
Table 2
Inspection project Unit Measured data
Apparent density kg/m3 92
Heat conductivity w/(m·k) 0.038
Tensile strength perpendicular to plate face mpa 0.11
Dimensional stability % 0.30
Fracture bend loading n 26
Compression performance mpa 0.12
Vapor transmission coefficient ng/(pa·m·s) 4.5
Water absorption rate (v/v) % 2.8
Combustibility —— A2 level
Embodiment three
As shown in figure 1, being the structural representation of the silica aerogel osmosis type a level fireproof heated board of the present invention.With loose type molding Styrofoam is substrate, lies against on the equipment with evacuation function, by silica aerogel composite slurry uniform fold in base On plate, open vacuum pump and apply negative pressure, make silica aerogel composite slurry penetrate into the gap between substrate granular polystyrene In and be full of, remove unnecessary silica aerogel composite slurry with scraper plate, through 60 DEG C of maintenances 120 hours or natural curing 42 My god, prepared silica aerogel osmosis type a level fireproof heated board.
The silica aerogel osmosis type a level fireproof heated board of the present invention, using silica aerogel composite slurry and loose type Molding styrofoam makes for primary raw material.Wherein, silica aerogel composite slurry is made up of the raw material of following weight portion:
100 parts of silica aerogel
300 parts of portland cement
3.0 parts of polycarboxylate water-reducer
3.0 parts of water-soluble organic silicon waterproofing agent
200 parts of water.
Wherein, loose type molding styrofoam is density 14kg/m3Loose type molding styrofoam.
The silica aerogel osmosis type a level fireproof heated board of the present invention, a size of 1000mm × 600mm × 80mm, with reference to state Family's relevant criterion carries out technical performance test, and the equal conformance with standard of property indices requires, test result such as table 3.
Table 3
Inspection project Unit Measured data
Apparent density kg/m3 101
Heat conductivity w/(m·k) 0.040
Tensile strength perpendicular to plate face mpa 0.12
Dimensional stability % 0.30
Fracture bend loading n 27
Compression performance mpa 0.13
Vapor transmission coefficient ng/(pa·m·s) 4.2
Water absorption rate (v/v) % 2.7
Combustibility —— A2 level
Example IV
As shown in figure 1, being the structural representation of the silica aerogel osmosis type a level fireproof heated board of the present invention.With loose type molding Styrofoam is substrate, lies against on the equipment with evacuation function, by silica aerogel composite slurry uniform fold in base On plate, open vacuum pump and apply negative pressure, make silica aerogel composite slurry penetrate into the gap between substrate granular polystyrene In and be full of, remove unnecessary silica aerogel composite slurry with scraper plate, through 60 DEG C of maintenances 120 hours or natural curing 42 My god, prepared silica aerogel osmosis type a level fireproof heated board.
The silica aerogel osmosis type a level fireproof heated board of the present invention, using silica aerogel composite slurry and loose type Molding styrofoam makes for primary raw material.Wherein, silica aerogel composite slurry is made up of the raw material of following weight portion:
100 parts of silica aerogel
500 parts of portland cement
5.0 parts of polycarboxylate water-reducer
5.0 parts of water-soluble organic silicon waterproofing agent
240 parts of water.
Wherein, loose type molding styrofoam is density 15kg/m3Loose type molding styrofoam.
The silica aerogel osmosis type a level fireproof heated board of the present invention, a size of 1200mm × 600mm × 90mm, with reference to state Family's relevant criterion carries out technical performance test, and the equal conformance with standard of property indices requires, test result such as table 4.
Table 4
Inspection project Unit Measured data
Apparent density kg/m3 109
Heat conductivity w/(m·k) 0.041
Tensile strength perpendicular to plate face mpa 0.13
Dimensional stability % 0.30
Fracture bend loading n 28
Compression performance mpa 0.14
Vapor transmission coefficient ng/(pa·m·s) 4.0
Water absorption rate (v/v) % 2.7
Combustibility —— A2 level

Claims (3)

1. a kind of silica aerogel osmosis type a level fireproof heated board and preparation method thereof it is characterised in that: with loose type mold polyphenyl Plate is substrate, with silica aerogel, portland cement, polycarboxylate water-reducer, water-soluble organic silicon waterproofing agent and water mix and blend system Become silica aerogel composite slurry, so that cement polymer slurry is penetrated in substrate using vacuum pressure, unnecessary through removing Silica aerogel composite slurry, maintenance, prepared silica aerogel osmosis type a level fireproof heated board.
2. a kind of silica aerogel osmosis type a level fireproof heated board according to claim 1 and preparation method thereof, its feature exists In: its silica aerogel composite slurry is made up of the raw material of following weight portion:
100 parts of silica aerogel
Portland cement 100-500 part
Polycarboxylate water-reducer 1.0-5.0 part
Water-soluble organic silicon waterproofing agent 1.0-5.0 part
Water 160-240 part.
3. a kind of silica aerogel osmosis type a level fireproof heated board according to claim 1 and preparation method thereof, its feature exists In: its loose type molding styrofoam is not more than 15kg/m for density3Loose type molding styrofoam.
CN201610844226.9A 2016-09-23 2016-09-23 Silica aerogel penetrating A-class fireproof heat retaining panel and manufacturing method thereof Pending CN106363937A (en)

Priority Applications (1)

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CN201610844226.9A CN106363937A (en) 2016-09-23 2016-09-23 Silica aerogel penetrating A-class fireproof heat retaining panel and manufacturing method thereof

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Application Number Priority Date Filing Date Title
CN201610844226.9A CN106363937A (en) 2016-09-23 2016-09-23 Silica aerogel penetrating A-class fireproof heat retaining panel and manufacturing method thereof

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Publication Number Publication Date
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109370077A (en) * 2018-09-19 2019-02-22 宁夏保利节能科技有限公司 A kind of inorganic slurry and preparation method thereof of thermosetting composite polyphenylene plate
CN109467454A (en) * 2017-09-08 2019-03-15 穆振奎 A kind of compound A grades of fireproof and heat-insulating material of aerosil and its preparation process
CN110344509A (en) * 2019-05-24 2019-10-18 穆振奎 A kind of preparation method of enhanced infiltration fireproof heated board
CN112848020A (en) * 2020-12-31 2021-05-28 富思特新材料科技发展股份有限公司 Method for reinforcing substrate

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104018588A (en) * 2014-06-12 2014-09-03 凯盟节能建材科技江苏有限公司 Negative pressure permeation method for manufacturing inorganic modified polystyrene board
CN105000834A (en) * 2015-07-01 2015-10-28 卓达新材料科技集团有限公司 Hydrophobic silicon oxide aerogel insulation material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104018588A (en) * 2014-06-12 2014-09-03 凯盟节能建材科技江苏有限公司 Negative pressure permeation method for manufacturing inorganic modified polystyrene board
CN105000834A (en) * 2015-07-01 2015-10-28 卓达新材料科技集团有限公司 Hydrophobic silicon oxide aerogel insulation material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109467454A (en) * 2017-09-08 2019-03-15 穆振奎 A kind of compound A grades of fireproof and heat-insulating material of aerosil and its preparation process
CN109370077A (en) * 2018-09-19 2019-02-22 宁夏保利节能科技有限公司 A kind of inorganic slurry and preparation method thereof of thermosetting composite polyphenylene plate
CN110344509A (en) * 2019-05-24 2019-10-18 穆振奎 A kind of preparation method of enhanced infiltration fireproof heated board
CN112848020A (en) * 2020-12-31 2021-05-28 富思特新材料科技发展股份有限公司 Method for reinforcing substrate

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Application publication date: 20170201