CN106356206B - A kind of capacitor impregnation liquid and preparation method thereof - Google Patents

A kind of capacitor impregnation liquid and preparation method thereof Download PDF

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Publication number
CN106356206B
CN106356206B CN201610946429.9A CN201610946429A CN106356206B CN 106356206 B CN106356206 B CN 106356206B CN 201610946429 A CN201610946429 A CN 201610946429A CN 106356206 B CN106356206 B CN 106356206B
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parts
oil
modified
soybean oil
gypsum
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CN106356206A (en
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胡忠胜
华玲萍
吴良军
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Anhui Feida Electrical Technology Co Ltd
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Anhui Feida Electrical Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G13/00Apparatus specially adapted for manufacturing capacitors; Processes specially adapted for manufacturing capacitors not provided for in groups H01G4/00 - H01G11/00
    • H01G13/04Drying; Impregnating

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
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Abstract

The present invention relates to a kind of capacitor impregnation liquid and preparation method thereof, are made by weight of following raw material:68 75 parts of tea-seed oil, 22 25 parts of modified soybean oil, 1.25 1.32 parts of microwax, 1 1.2 parts of modification infusorial earth, 0.25 0.4 parts of modified landplaster, 0.78 0.9 parts of polytetrafluoroethylene (PTFE), 1.1 1.4 parts of polyethylene wax;Capacitor impregnation liquid provided by the invention is prepared by basic raw material using tea-seed oil, modified soybean oil, add in the ingredients such as modified diatomite, gypsum, and add in the ingredients such as microwax, polytetrafluoroethylene (PTFE), polyethylene wax, by proportioning, and the cost of raw material is lower, without apparent pollution, performance is relatively stablized.

Description

A kind of capacitor impregnation liquid and preparation method thereof
Technical field
The invention belongs to capacitor manufacture fields, and in particular to a kind of capacitor impregnation liquid and preparation method thereof.
Background technology
Capacitor impregnant is used primarily as dielectric, needs have good cryogenic property, antioxygenic property Deng, mostly using mineral oil components such as castor oil, add in a small amount of antioxidant is made present capacitor impregnation liquid, but current The comprehensive performance of capacitor impregnation liquid is poor, and antioxidant and the mobility of low temperature are bad during use, and dampproof effect is also poor, The performance and service life for causing capacitor decline.
The content of the invention
The present invention provides a kind of capacitor impregnation liquid and preparation method thereof, by reasonably being matched to raw material, and Ingredient in raw material is modified, makes maceration extract that there is good anti-oxidant and good low temperature flow, can prolong significantly The service life of long capacitor.
The invention is realized by the following technical scheme:
A kind of capacitor impregnation liquid, is made by weight of following raw material:68-75 parts of tea-seed oil, modified soybean oil 22-25 Part, 1.25-1.32 parts of microwax, 1-1.2 parts of modification infusorial earth, 0.25-0.4 parts of modified landplaster, polytetrafluoroethylene (PTFE) 0.78- 0.9 part, 1.1-1.4 parts of polyethylene wax;
The modification infusorial earth is prepared using following methods:
(1), diatomite crushed, cross 120 mesh sieves, using drying oven at 225-245 DEG C isothermal holding 45-65min;
(2), by step(1)The diatomite use quality fraction handled well is 2.5% oxalic acid solution immersion treatment 12- 15h, by the diatomite after immersion at 285-300 DEG C drying process 2-3h, then cooled down with the speed of 2 DEG C/min, drop Continue to keep the temperature 2-2.5h when temperature is to 190 DEG C, then continue to be cooled to room temperature with 3 DEG C/min in dry environment, carry out Ultramicro-powder It is broken, obtain modification infusorial earth.
Preferably, the modified landplaster is prepared using following methods:
(1), gypsum crushed, cross 100 mesh sieves, by broken gypsum using the n-butanol immersion of 3-5 times of gypsum weight at 2-3h is managed, ultrasonication is used in soaking process, isolates gypsum;
(2), by step(1)Obtained gypsum drying is handled, adds in benzene sulfonyl chloride, the 0.2- of gypsum weight 0.5-0.8% 0.25% phthalate ester coupling agent, the poly-ferric chloride of 0.1-0.12%, are mixed, then using batch mixer under anaerobic By mixed mixture using ultrasonication 12-15min, then dried, ultramicro grinding, obtain modified gypsum.
Preferably, the modified soybean oil is prepared using following methods:
(1), soybean oil is heated to 250-255 DEG C, isothermal holding 30-35min, then takes soybean oil weight at this temperature The toad grass of amount 1-1.2%, which is put into oil, handles 20-25s, pulls residue out;
(2), to step(1)The cypress root of soybean weight of oil 3.5-4% is added in the soybean oil handled well, and continues to keep the temperature 2-3min pulls cypress root out, removes residue;
(3), to step(2)Obtained soybean oil continues to keep the temperature 5-10min, is then cooled to 100-108 DEG C, adds in soybean The Chinese toon natural gum of weight of oil 0.3%, then, is naturally cooling to room temperature, soybean oil is ground, cross 200 mesh sieves;
(4), to step(3)In add in obtained soybean oil soybean weight of oil 0.25% silane coupling agent WD-65, 0.3% chlorinated paraffin, and ultrasonication 20-25min is used, obtain modified soybean oil.
Further, a kind of preparation method of capacitor impregnation liquid, comprises the following steps:
(1), polytetrafluoroethylene (PTFE), polyethylene wax be subjected to ultramicro grinding respectively;
(2), tea-seed oil, modified soybean oil mixed in proportion, add in microwax, be heated to 102-105 DEG C and go forward side by side Row stirring, makes it be uniformly dispersed;
(3), by step(1)Polytetrafluoroethylene (PTFE), polyethylene wax and the modification infusorial earth handled well, modified landplaster are in proportion Add in step(2)In obtained mixture, 120-125 DEG C is heated in a kettle, with 1000-1100r/min stir process 12-15min obtains capacitor impregnation liquid.
Beneficial effects of the present invention:Based on capacitor impregnation liquid provided by the invention is using tea-seed oil, modified soybean oil Raw material prepare, add in the ingredients such as modified diatomite, gypsum, and add in microwax, polytetrafluoroethylene (PTFE), polyethylene wax etc. into Point, by proportioning, and the cost of raw material is lower, and without apparent pollution, performance is relatively stablized, mobility during use and anti- Oxidation susceptibility is excellent, without corrosivity, can effectively avoid the corrosion for occurring to pole plate and housing in use, promote electricity The service life of container, compared with the maceration extract of existing detergent alkylate matrix, usage time can extend 25-30%, with castor-oil plant The maceration extract of oil base body is compared, and usage time can extend 28-35%, other experiment detections also turn out, use the original of the present invention Material, but raw material is modified processing without the method for the present invention, can also substantially reduce the using effect of capacitor, Er Qieben The cost of invention maceration extract is lower.
Specific embodiment
Embodiment 1
A kind of capacitor impregnation liquid, is made by weight of following raw material:It is 72 parts of tea-seed oil, 23 parts of modified soybean oil, micro- Brilliant 1.28 parts of wax, 1.1 parts of modification infusorial earth, 0.32 part of modified landplaster, 0.8 part of polytetrafluoroethylene (PTFE), 1.25 parts of polyethylene wax;
The modification infusorial earth is prepared using following methods:
(1), diatomite crushed, cross 120 mesh sieves, using drying oven at 225-245 DEG C isothermal holding 45-65min;
(2), by step(1)The diatomite use quality fraction handled well is 2.5% oxalic acid solution immersion treatment 12- 15h, by the diatomite after immersion at 285-300 DEG C drying process 2-3h, then cooled down with the speed of 2 DEG C/min, drop Continue to keep the temperature 2-2.5h when temperature is to 190 DEG C, then continue to be cooled to room temperature with 3 DEG C/min in dry environment, carry out Ultramicro-powder It is broken, obtain modification infusorial earth.
Preferably, the modified landplaster is prepared using following methods:
(1), gypsum crushed, cross 100 mesh sieves, broken gypsum used to the n-butanol immersion treatment of 5 times of gypsum weight 2.5h using ultrasonication in soaking process, isolates gypsum;
(2), by step(1)Obtained gypsum drying is handled, adds in benzene sulfonyl chloride, 0.22% phthalein of gypsum weight 0.75% Acid esters coupling agent, 0.1% poly-ferric chloride, are mixed under anaerobic using batch mixer, then by mixed mixing Object uses ultrasonication 15min, is then dried, ultramicro grinding, obtains modified gypsum.
Preferably, the modified soybean oil is prepared using following methods:
(1), soybean oil is heated to 252 DEG C, isothermal holding 32min, then takes soybean weight of oil 1.2% at this temperature Toad grass be put into oil and handle 22s, pull residue out;
(2), to step(1)The cypress root of soybean weight of oil 3.8% is added in the soybean oil handled well, and continues to keep the temperature 2.5min pulls cypress root out, removes residue;
(3), to step(2)Obtained soybean oil continues to keep the temperature 8min, is then cooled to 106 DEG C, adds in soybean weight of oil 0.3% Chinese toon natural gum, then, is naturally cooling to room temperature, soybean oil is ground, cross 200 mesh sieves;
(4), to step(3)In add in obtained soybean oil soybean weight of oil 0.25% silane coupling agent WD-65, 0.3% chlorinated paraffin, and ultrasonication 23min is used, obtain modified soybean oil.
Further, a kind of preparation method of capacitor impregnation liquid, comprises the following steps:
(1), polytetrafluoroethylene (PTFE), polyethylene wax be subjected to ultramicro grinding respectively;
(2), tea-seed oil, modified soybean oil mixed in proportion, add in microwax, be heated to 103 DEG C and stirred It mixes, it is made to be uniformly dispersed;
(3), by step(1)Polytetrafluoroethylene (PTFE), polyethylene wax and the modification infusorial earth handled well, modified landplaster are in proportion Add in step(2)In obtained mixture, 123 DEG C are heated in a kettle, with 1100r/min stir process 14min, are obtained Capacitor impregnation liquid.
Capacitance maceration extract performance is as follows made of the present embodiment:
Dielectric strength 52.4kV/2.5mm, volume resistivity are 6.38 × 1012Ω.m(It is measured at 100 DEG C), the capacitor longevity Life can also extend 22.6% than conventional maceration extract.
Embodiment 2
A kind of capacitor impregnation liquid, is made by weight of following raw material:It is 70 parts of tea-seed oil, 23 parts of modified soybean oil, micro- Brilliant 1.32 parts of wax, 1.15 parts of modification infusorial earth, 0.36 part of modified landplaster, 0.85 part of polytetrafluoroethylene (PTFE), 1.25 parts of polyethylene wax;
The modification infusorial earth is prepared using following methods:
(1), diatomite crushed, cross 120 mesh sieves, using drying oven at 230 DEG C isothermal holding 60min;
(2), by step(1)The diatomite use quality fraction handled well is 2.5% oxalic acid solution immersion treatment 13h, will Diatomite after the immersion drying process 3h at 290 DEG C, is then cooled down with the speed of 2 DEG C/min, when being cooled to 190 DEG C after Continue insurance temperature 2.2h, then continues to be cooled to room temperature with 3 DEG C/min in dry environment, carries out ultramicro grinding, obtain modified diatom Soil.
Capacitance maceration extract performance is as follows made of the present embodiment:
Dielectric strength 50.6kV/2.5mm, volume resistivity are 5.98 × 1012Ω.m(It is measured at 100 DEG C), the capacitor longevity Life can also extend 19.7% than conventional maceration extract.
Embodiment 3
A kind of capacitor impregnation liquid, is made by weight of following raw material:It is 74 parts of tea-seed oil, 24 parts of modified soybean oil, micro- Brilliant 1.28 parts of wax, 1.15 parts of modification infusorial earth, 0.28 part of modified landplaster, 0.8 part of polytetrafluoroethylene (PTFE), 1.35 parts of polyethylene wax;
The modification infusorial earth is prepared using following methods:
(1), diatomite crushed, cross 120 mesh sieves, using drying oven at 242 DEG C isothermal holding 50min;
(2), by step(1)The diatomite use quality fraction handled well is 2.5% oxalic acid solution immersion treatment 13h, will Diatomite after the immersion drying process 2.6h at 292 DEG C, is then cooled down with the speed of 2 DEG C/min, when being cooled to 190 DEG C Continue to keep the temperature 2.3h, then continue to be cooled to room temperature with 3 DEG C/min in dry environment, carry out ultramicro grinding, obtain modified silicon Diatomaceous earth.

Claims (4)

1. a kind of capacitor impregnation liquid, which is characterized in that be made by weight of following raw material:68-75 parts of tea-seed oil is modified greatly 22-25 parts of soya-bean oil, 1.25-1.32 parts of microwax, 1-1.2 parts of modification infusorial earth, 0.25-0.4 parts of modified landplaster, polytetrafluoroethyl-ne 0.78-0.9 parts of alkene, 1.1-1.4 parts of polyethylene wax;
The modification infusorial earth is prepared using following methods:
(1), diatomite crushed, cross 120 mesh sieves, using drying oven at 225-245 DEG C isothermal holding 45-65min;
(2), by step(1)The diatomite use quality fraction handled well is 2.5% oxalic acid solution immersion treatment 12-15h, will Diatomite after the immersion drying process 2-3h at 285-300 DEG C, is then cooled down with the speed of 2 DEG C/min, is cooled to 190 DEG C when continue to keep the temperature 2-2.5h, then continue to be cooled to room temperature with 3 DEG C/min in dry environment, carry out ultramicro grinding, obtain Modification infusorial earth.
2. a kind of capacitor impregnation liquid according to claim 1, which is characterized in that the modified landplaster use is with lower section It is prepared by method:
(1), gypsum crushed, cross 100 mesh sieves, broken gypsum used to the n-butanol immersion treatment 2- of 3-5 times of gypsum weight 3h using ultrasonication in soaking process, isolates gypsum;
(2), by step(1)Obtained gypsum drying is handled, adds in benzene sulfonyl chloride, the 0.2-0.25% of gypsum weight 0.5-0.8% Phthalate ester coupling agent, the poly-ferric chloride of 0.1-0.12%, be mixed under anaerobic using batch mixer, then will be mixed Then mixture after conjunction is dried, ultramicro grinding using ultrasonication 12-15min, is obtained modified gypsum.
3. a kind of capacitor impregnation liquid according to claim 1 or 2, it is characterised in that:The modified soybean oil use with It is prepared by lower section method:
(1), soybean oil is heated to 250-255 DEG C, isothermal holding 30-35min, then takes soybean weight of oil 1- at this temperature 1.2% toad grass, which is put into oil, handles 20-25s, pulls residue out;
(2), to step(1)The cypress root of soybean weight of oil 3.5-4% is added in the soybean oil handled well, and continues to keep the temperature 2- 3min pulls cypress root out, removes residue;
(3), to step(2)Obtained soybean oil continues to keep the temperature 5-10min, is then cooled to 100-108 DEG C, adds in soybean oil weight The Chinese toon natural gum of amount 0.3%, then, is naturally cooling to room temperature, soybean oil is ground, cross 200 mesh sieves;
(4), to step(3)In add in obtained soybean oil soybean weight of oil 0.25% silane coupling agent WD-65,0.3% Chlorinated paraffin, and ultrasonication 20-25min is used, obtain modified soybean oil.
4. the preparation method of the capacitor impregnation liquid described in a kind of claim 3, which is characterized in that comprise the following steps:
(1), polytetrafluoroethylene (PTFE), polyethylene wax be subjected to ultramicro grinding respectively;
(2), tea-seed oil, modified soybean oil mixed in proportion, add in microwax, be heated to 102-105 DEG C and stirred It mixes, it is made to be uniformly dispersed;
(3), by step(1)Polytetrafluoroethylene (PTFE), polyethylene wax and modification infusorial earth, the modified landplaster handled well are proportionally added into Step(2)In obtained mixture, 120-125 DEG C is heated in a kettle, with 1000-1100r/min stir process 12- 15min obtains capacitor impregnation liquid.
CN201610946429.9A 2016-10-26 2016-10-26 A kind of capacitor impregnation liquid and preparation method thereof Active CN106356206B (en)

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Publication number Priority date Publication date Assignee Title
CN107705984A (en) * 2017-11-18 2018-02-16 陈馨雅 A kind of capacitor impregnation liquid containing tea-seed oil
CN108899203A (en) * 2018-07-12 2018-11-27 合肥连森裕腾新材料科技开发有限公司 A kind of high efficient microelectronic device maceration extract

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1139697A (en) * 1995-05-19 1997-01-08 埃勒夫阿托化学有限公司 Crossable dielectric combination
CN201387811Y (en) * 2009-04-15 2010-01-20 宁波碧彩实业有限公司 Anti-explosion and flame-proof high-voltage capacitor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0616460B2 (en) * 1986-02-03 1994-03-02 日本石油化学株式会社 Oil-impregnated capacitor with excellent low-temperature characteristics

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1139697A (en) * 1995-05-19 1997-01-08 埃勒夫阿托化学有限公司 Crossable dielectric combination
CN201387811Y (en) * 2009-04-15 2010-01-20 宁波碧彩实业有限公司 Anti-explosion and flame-proof high-voltage capacitor

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Denomination of invention: A capacitor impregnating solution and its preparation method

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