CN106356206A - Capacitor impregnating liquid and preparation method thereof - Google Patents

Capacitor impregnating liquid and preparation method thereof Download PDF

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Publication number
CN106356206A
CN106356206A CN201610946429.9A CN201610946429A CN106356206A CN 106356206 A CN106356206 A CN 106356206A CN 201610946429 A CN201610946429 A CN 201610946429A CN 106356206 A CN106356206 A CN 106356206A
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Prior art keywords
soybean oil
modified
weight
oil
impregnation liquid
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CN201610946429.9A
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CN106356206B (en
Inventor
胡忠胜
华玲萍
吴良军
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Anhui Feida Electrical Technology Co Ltd
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Anhui Feida Electrical Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G13/00Apparatus specially adapted for manufacturing capacitors; Processes specially adapted for manufacturing capacitors not provided for in groups H01G4/00 - H01G11/00
    • H01G13/04Drying; Impregnating

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Fats And Perfumes (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The invention relates to capacitor impregnating liquid and a preparation method thereof. The capacitor impregnating liquid is prepared from the following raw materials in parts by weight: 68 to 75 parts of tea-seed oil, 22 to 25 parts of modified soybean oil, 1.25 to 1.32 parts of microcrystalline wax, 1 to 1.2 parts of modified diatomite, 0.25 to 0.4 part of modified gypsum powder, 0.78 to 0.9 part of polytetrafluoroethylene and 1.1 to 1.4 parts of polyethylene wax. The capacitor impregnating liquid is prepared by using the tea-seed oil and the modified soybean oil as basic raw materials, adding the ingredients such as the modified diatomite and gypsum and adding the ingredients such as the microcrystalline wax, polytetrafluoroethylene and the polyethylene wax and by proportioning the raw materials, so that the prepared capacitor impregnating liquid adopts raw materials with low cost, free from obvious pollution and stable in performance.

Description

A kind of capacitor impregnation liquid and preparation method thereof
Technical field
The invention belongs to capacitor manufacture field is and in particular to a kind of capacitor impregnation liquid and preparation method thereof.
Background technology
Capacitor impregnant uses primarily as electrolyte, and it needs there is good cryogenic property, antioxygenic property Deng, use the mineral oil component such as Oleum Ricini more present capacitor impregnation liquid, add a small amount of antioxidant to make, but current The combination property of capacitor impregnation liquid is poor, and during use, the mobility of antioxidant and low temperature is bad, and moisture effect is also poor, The performance of capacitor and usage cycles are caused to decline.
Content of the invention
The present invention provides a kind of capacitor impregnation liquid and preparation method thereof, by rational proportioning is carried out to raw material, and Composition in raw material is modified, makes impregnation liquid have good antioxidation and good low temperature flow, can significantly prolong The usage cycles of long capacitor.
The present invention is achieved through the following technical solutions:
A kind of capacitor impregnation liquid, is made up of following raw material by weight: Oleum Camelliae 68-75 part, modified soybean oil 22-25 part, Microwax 1.25-1.32 part, modification infusorial earth 1-1.2 part, modified landplaster 0.25-0.4 part, politef 0.78-0.9 Part, Tissuemat E 1.1-1.4 part;
Described modification infusorial earth uses following methods to prepare:
(1), kieselguhr is pulverized, cross 120 mesh sieves, using drying oven at 225-245 DEG C isothermal holding 45-65min;
(2), oxalic acid solution immersion treatment 12-15h being 2.5% by the kieselguhr use quality fraction that step (1) is handled well, will Kieselguhr after immersion dried 2-3h at 285-300 DEG C, is then lowered the temperature with the speed of 2 DEG C/min, is cooled to 190 DEG C when continue insulation 2-2.5h, then continue to be cooled to room temperature with 3 DEG C/min in dry environment, carry out micronizing, obtain Modification infusorial earth.
Preferably, described modified landplaster uses following methods to prepare:
(1), Gypsum Fibrosum is pulverized, cross 100 mesh sieves, broken Gypsum Fibrosum is used n-butyl alcohol immersion treatment 2- of Gypsum Fibrosum weight 3-5 times 3h, using ultrasonic Treatment in immersion process, isolates Gypsum Fibrosum;
(2), step (1) is processed the Gypsum Fibrosum obtaining to dry, add benzene sulfonyl chloride, the 0.2-0.25% of Gypsum Fibrosum weight 0.5-0.8% Phthalate ester coupling agent, the poly-ferric chloride of 0.1-0.12%, under anaerobic using batch mixer mix and blend, then will mix Mixture after conjunction uses ultrasonic Treatment 12-15min, then carries out drying, micronizing, obtains modified gypsum.
Preferably, described modified soybean oil uses following methods to prepare:
(1), soybean oil is heated to 250-255 DEG C, at this temperature isothermal holding 30-35min, then takes Semen sojae atricolor weight of oil 1- Process 20-25s in oil put into by 1.2% Bufo siccuss grass, pulls residue out;
(2), add the Cupressaceae root of Semen sojae atricolor weight of oil 3.5-4% in the soybean oil handled well to step (1), and continue to be incubated 2- 3min, pulls Cupressaceae root out, removes residue;
(3), the soybean oil obtaining to step (2) continues insulation 5-10min, is then cooled to 100-108 DEG C, adds soybean oil weight The Tonnae Sinensiss natural gum of amount 0.3%, then, is naturally cooling to room temperature, soybean oil is ground, cross 200 mesh sieves;
(4), add in the soybean oil obtaining in step (3) Semen sojae atricolor weight of oil 0.25% silane coupler wd-65,0.3% Chlorinated paraffin, and use ultrasonic Treatment 20-25min, obtain modified soybean oil.
Further, a kind of preparation method of capacitor impregnation liquid, comprises the following steps:
(1), politef, Tissuemat E are carried out respectively micronizing;
(2), Oleum Camelliae, modified soybean oil are mixed in proportion, add microwax, be heated to 102-105 DEG C and stirred Mix so as to be uniformly dispersed;
(3), politef, Tissuemat E and modification infusorial earth, modified landplaster that step (1) is handled well are proportionally added into In the mixture that step (2) obtains, it is heated to 120-125 DEG C in a kettle., with 1000-1100r/min stir process 12- 15min, obtains capacitor impregnation liquid.
Beneficial effects of the present invention: based on the capacitor impregnation liquid that the present invention provides uses Oleum Camelliae, modified soybean oil Prepared by raw material, add the compositions such as modified kieselguhr, Gypsum Fibrosum, and adds microwax, politef, Tissuemat E etc. to become Point, through proportioning, and the cost of raw material is lower, no significantly pollutes, and performance is more stable, the mobility during use and anti- Oxidation susceptibility is excellent, does not have corrosivity, can be prevented effectively from the corrosion occurring in use to pole plate and housing, lifting electricity The usage cycles of container, compared with the impregnation liquid of existing detergent alkylate matrix, use time can extend 25-30%, with Semen Ricini The impregnation liquid of oil base body is compared, and its use time can extend 28-35%, and other experiment detections also demonstrate that, former using the present invention Material, but raw material is modified processing without the method for the present invention, also can substantially reduce the using effect of capacitor, Er Qieben The cost of invention impregnation liquid is lower.
Specific embodiment
Embodiment 1
A kind of capacitor impregnation liquid, is made up of following raw material by weight: 72 parts of Oleum Camelliae, 23 parts of modified soybean oil, microwax 1.28 parts, 1.1 parts of modification infusorial earth, 0.32 part of modified landplaster, 0.8 part of politef, 1.25 parts of Tissuemat E;
Described modification infusorial earth uses following methods to prepare:
(1), kieselguhr is pulverized, cross 120 mesh sieves, using drying oven at 225-245 DEG C isothermal holding 45-65min;
(2), oxalic acid solution immersion treatment 12-15h being 2.5% by the kieselguhr use quality fraction that step (1) is handled well, will Kieselguhr after immersion dried 2-3h at 285-300 DEG C, is then lowered the temperature with the speed of 2 DEG C/min, is cooled to 190 DEG C when continue insulation 2-2.5h, then continue to be cooled to room temperature with 3 DEG C/min in dry environment, carry out micronizing, obtain Modification infusorial earth.
Preferably, described modified landplaster uses following methods to prepare:
(1), Gypsum Fibrosum is pulverized, crosses 100 mesh sieves, broken Gypsum Fibrosum is used n-butyl alcohol immersion treatment 2.5h of 5 times of Gypsum Fibrosum weight, Using ultrasonic Treatment in immersion process, isolate Gypsum Fibrosum;
(2), step (1) is processed the Gypsum Fibrosum obtaining to dry, add benzene sulfonyl chloride, 0.22% phthalate ester of Gypsum Fibrosum weight 0.75% Mixed mixture, under anaerobic using batch mixer mix and blend, is then made by coupling agent, 0.1% poly-ferric chloride Use ultrasonic Treatment 15min, then carry out drying, micronizing, obtain modified gypsum.
Preferably, described modified soybean oil uses following methods to prepare:
(1), soybean oil is heated to 252 DEG C, at this temperature isothermal holding 32min, then takes the toad of Semen sojae atricolor weight of oil 1.2% Process 22s in oil put into by bufonid toad grass, pulls residue out;
(2), add the Cupressaceae root of Semen sojae atricolor weight of oil 3.8% in the soybean oil handled well to step (1), and continue to be incubated 2.5min, Pull Cupressaceae root out, remove residue;
(3), the soybean oil obtaining to step (2) continues insulation 8min, is then cooled to 106 DEG C, adds Semen sojae atricolor weight of oil 0.3% Tonnae Sinensiss natural gum, then, be naturally cooling to room temperature, soybean oil be ground, cross 200 mesh sieves;
(4), add in the soybean oil obtaining in step (3) Semen sojae atricolor weight of oil 0.25% silane coupler wd-65,0.3% Chlorinated paraffin, and use ultrasonic Treatment 23min, obtain modified soybean oil.
Further, a kind of preparation method of capacitor impregnation liquid, comprises the following steps:
(1), politef, Tissuemat E are carried out respectively micronizing;
(2), Oleum Camelliae, modified soybean oil are mixed in proportion, add microwax, be heated to 103 DEG C and be stirred, make It is uniformly dispersed;
(3), politef, Tissuemat E and modification infusorial earth, modified landplaster that step (1) is handled well are proportionally added into In the mixture that step (2) obtains, it is heated to 123 DEG C in a kettle., with 1100r/min stir process 14min, obtain electric capacity Device impregnation liquid.
The electric capacity impregnation liquid performance that the present embodiment is made is as follows:
Dielectric strength 52.4kv/2.5mm, specific insulation is 6.38 × 1012Measure at .m(100 DEG C of ω), capacitor life-span 22.6% can be extended than conventional impregnation liquid.
Embodiment 2
A kind of capacitor impregnation liquid, is made up of following raw material by weight: 70 parts of Oleum Camelliae, 23 parts of modified soybean oil, microwax 1.32 parts, 1.15 parts of modification infusorial earth, 0.36 part of modified landplaster, 0.85 part of politef, 1.25 parts of Tissuemat E;
Described modification infusorial earth uses following methods to prepare:
(1), kieselguhr is pulverized, cross 120 mesh sieves, using drying oven at 230 DEG C isothermal holding 60min;
(2), oxalic acid solution immersion treatment 13h being 2.5% by the kieselguhr use quality fraction that step (1) is handled well, will soak Dried 3h at 290 DEG C of kieselguhr afterwards, is then lowered the temperature with the speed of 2 DEG C/min, is cooled to when 190 DEG C and continues to protect Warm 2.2h, then continues to be cooled to room temperature with 3 DEG C/min in dry environment, carries out micronizing, obtains modification infusorial earth.
The electric capacity impregnation liquid performance that the present embodiment is made is as follows:
Dielectric strength 50.6kv/2.5mm, specific insulation is 5.98 × 1012Measure at .m(100 DEG C of ω), capacitor life-span 19.7% can be extended than conventional impregnation liquid.
Embodiment 3
A kind of capacitor impregnation liquid, is made up of following raw material by weight: 74 parts of Oleum Camelliae, 24 parts of modified soybean oil, microwax 1.28 parts, 1.15 parts of modification infusorial earth, 0.28 part of modified landplaster, 0.8 part of politef, 1.35 parts of Tissuemat E;
Described modification infusorial earth uses following methods to prepare:
(1), kieselguhr is pulverized, cross 120 mesh sieves, using drying oven at 242 DEG C isothermal holding 50min;
(2), oxalic acid solution immersion treatment 13h being 2.5% by the kieselguhr use quality fraction that step (1) is handled well, will soak Dried 2.6h at 292 DEG C of kieselguhr afterwards, is then lowered the temperature with the speed of 2 DEG C/min, is cooled to and continues when 190 DEG C Insulation 2.3h, then continues to be cooled to room temperature with 3 DEG C/min in dry environment, carries out micronizing, obtain modification infusorial earth.

Claims (4)

1. a kind of capacitor impregnation liquid is it is characterised in that be made up of following raw material by weight: Oleum Camelliae 68-75 part, modification are big Oleum Glycines 22-25 part, microwax 1.25-1.32 part, modification infusorial earth 1-1.2 part, modified landplaster 0.25-0.4 part, polytetrafluoroethyl-ne Alkene 0.78-0.9 part, Tissuemat E 1.1-1.4 part;
Described modification infusorial earth uses following methods to prepare:
(1), kieselguhr is pulverized, cross 120 mesh sieves, using drying oven at 225-245 DEG C isothermal holding 45-65min;
(2), oxalic acid solution immersion treatment 12-15h being 2.5% by the kieselguhr use quality fraction that step (1) is handled well, will Kieselguhr after immersion dried 2-3h at 285-300 DEG C, is then lowered the temperature with the speed of 2 DEG C/min, is cooled to 190 DEG C when continue insulation 2-2.5h, then continue to be cooled to room temperature with 3 DEG C/min in dry environment, carry out micronizing, obtain Modification infusorial earth.
2. a kind of capacitor impregnation liquid according to claim 1 is it is characterised in that described modified landplaster is using with lower section Prepared by method:
(1), Gypsum Fibrosum is pulverized, cross 100 mesh sieves, broken Gypsum Fibrosum is used n-butyl alcohol immersion treatment 2- of Gypsum Fibrosum weight 3-5 times 3h, using ultrasonic Treatment in immersion process, isolates Gypsum Fibrosum;
(2), step (1) is processed the Gypsum Fibrosum obtaining to dry, add benzene sulfonyl chloride, the 0.2-0.25% of Gypsum Fibrosum weight 0.5-0.8% Phthalate ester coupling agent, the poly-ferric chloride of 0.1-0.12%, under anaerobic using batch mixer mix and blend, then will mix Mixture after conjunction uses ultrasonic Treatment 12-15min, then carries out drying, micronizing, obtains modified gypsum.
3. a kind of capacitor impregnation liquid according to claim 1 and 2 it is characterised in that: described modified soybean oil using with Lower section method preparation:
(1), soybean oil is heated to 250-255 DEG C, at this temperature isothermal holding 30-35min, then takes Semen sojae atricolor weight of oil 1- Process 20-25s in oil put into by 1.2% Bufo siccuss grass, pulls residue out;
(2), add the Cupressaceae root of Semen sojae atricolor weight of oil 3.5-4% in the soybean oil handled well to step (1), and continue to be incubated 2- 3min, pulls Cupressaceae root out, removes residue;
(3), the soybean oil obtaining to step (2) continues insulation 5-10min, is then cooled to 100-108 DEG C, adds soybean oil weight The Tonnae Sinensiss natural gum of amount 0.3%, then, is naturally cooling to room temperature, soybean oil is ground, cross 200 mesh sieves;
(4), add in the soybean oil obtaining in step (3) Semen sojae atricolor weight of oil 0.25% silane coupler wd-65,0.3% Chlorinated paraffin, and use ultrasonic Treatment 20-25min, obtain modified soybean oil.
4. a kind of preparation method of the capacitor impregnation liquid described in claim 3 is it is characterised in that comprise the following steps:
(1), politef, Tissuemat E are carried out respectively micronizing;
(2), Oleum Camelliae, modified soybean oil are mixed in proportion, add microwax, be heated to 102-105 DEG C and stirred Mix so as to be uniformly dispersed;
(3), politef, Tissuemat E and modification infusorial earth, modified landplaster that step (1) is handled well are proportionally added into In the mixture that step (2) obtains, it is heated to 120-125 DEG C in a kettle., with 1000-1100r/min stir process 12- 15min, obtains capacitor impregnation liquid.
CN201610946429.9A 2016-10-26 2016-10-26 A kind of capacitor impregnation liquid and preparation method thereof Active CN106356206B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107705984A (en) * 2017-11-18 2018-02-16 陈馨雅 A kind of capacitor impregnation liquid containing tea-seed oil
CN108899203A (en) * 2018-07-12 2018-11-27 合肥连森裕腾新材料科技开发有限公司 A kind of high efficient microelectronic device maceration extract

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62179710A (en) * 1986-02-03 1987-08-06 日本石油化学株式会社 Oil impregnated capacitor with excellent low temperature characteristics
CN1139697A (en) * 1995-05-19 1997-01-08 埃勒夫阿托化学有限公司 Crosslinkable Dielectric Composition
CN201387811Y (en) * 2009-04-15 2010-01-20 宁波碧彩实业有限公司 Anti-explosion and flame-proof high-voltage capacitor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62179710A (en) * 1986-02-03 1987-08-06 日本石油化学株式会社 Oil impregnated capacitor with excellent low temperature characteristics
CN1139697A (en) * 1995-05-19 1997-01-08 埃勒夫阿托化学有限公司 Crosslinkable Dielectric Composition
CN201387811Y (en) * 2009-04-15 2010-01-20 宁波碧彩实业有限公司 Anti-explosion and flame-proof high-voltage capacitor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107705984A (en) * 2017-11-18 2018-02-16 陈馨雅 A kind of capacitor impregnation liquid containing tea-seed oil
CN108899203A (en) * 2018-07-12 2018-11-27 合肥连森裕腾新材料科技开发有限公司 A kind of high efficient microelectronic device maceration extract

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Denomination of invention: A capacitor impregnating solution and its preparation method

Effective date of registration: 20230221

Granted publication date: 20180601

Pledgee: Ningguo SME financing Company limited by guarantee

Pledgor: ANHUI FEIDA ELECTRICAL TECHNOLOGY Co.,Ltd.

Registration number: Y2023980033056