CN106350164A - 一种抗菌型切削油及其制备方法 - Google Patents
一种抗菌型切削油及其制备方法 Download PDFInfo
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- CN106350164A CN106350164A CN201610685416.0A CN201610685416A CN106350164A CN 106350164 A CN106350164 A CN 106350164A CN 201610685416 A CN201610685416 A CN 201610685416A CN 106350164 A CN106350164 A CN 106350164A
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- cutting oil
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- 239000010730 cutting oil Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 239000013556 antirust agent Substances 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 239000002199 base oil Substances 0.000 claims abstract description 6
- 239000007866 anti-wear additive Substances 0.000 claims abstract description 4
- 230000000845 anti-microbial effect Effects 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 15
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 15
- 238000005520 cutting process Methods 0.000 claims description 11
- 241000158728 Meliaceae Species 0.000 claims description 9
- 229910052788 barium Inorganic materials 0.000 claims description 9
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 9
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
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- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 241000282894 Sus scrofa domesticus Species 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 7
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 6
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- LPMBTLLQQJBUOO-KTKRTIGZSA-N (z)-n,n-bis(2-hydroxyethyl)octadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CCO)CCO LPMBTLLQQJBUOO-KTKRTIGZSA-N 0.000 claims description 5
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- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 5
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- 125000005605 benzo group Chemical group 0.000 claims 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims 1
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- 241001465754 Metazoa Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
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- 230000002596 correlated effect Effects 0.000 description 1
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- 238000009432 framing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
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- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000013460 polyoxometalate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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Abstract
本发明提供一种抗菌型切削油及其制备方法。抗菌型切削油，按质量份计，包括基础油65～75份；表面活性剂15～20份；极压抗磨剂3～6份；防锈剂5～11份；超分子化合物2～6份；所述超分子化合物为水杨醛缩氨基硫脲与金属氧簇合成的具有生物活性的物质。本发明在切削油中加入由水杨醛缩氨基硫脲与金属氧簇合成的超分子化合物，切削油中抗菌防腐败性能大大的得到提高，防止该切削油腐败和变质，本发明的抗菌型切削油具有良好的杀菌和防腐的作用，且对环境无毒害。
Description
技术领域
本发明属于切削油领域，具体涉及一种抗菌型切削油及其制备方法。
背景技术
切削油是由基础油复配不同比例的极压抗磨剂、润滑剂、防锈剂、防霉杀菌剂，催冷剂等添加剂合成，切削油具有极佳的对数控机床本身、刃具、工件和乳化液的彻底保护性能。切削油有超强的润滑极压效果，有效保护刀具并延长其使用寿命，可获得极高的工件精密度和表面光洁度。
切削油具有极佳的对数控机床本身、刃具、工件和乳化液的彻底保护性能。切削油有超强的润滑极压效果，有效保护刀具并延长其使用寿命，可获得极高的工件精密度和表面光洁度。切削油具备好的润滑、冷却、防锈和清洗性能，在加工过程中能满足工艺要求，但是切削油使用的矿物油和防腐剂对环境有巨大的危害，动植物作为基础油会使得切削油容易腐败和发臭。
CN104830486A公开了一种车床用切削油，包括按以下重量份数配比的各组分：石油磺酸钠：8-12份、石油磺酸钡：8-10份、硫化油：7-9份、三乙醇胺：8-12份、油酸：10份、氢氧化钾：10-12份、水：2-3份、环烷酸松香钠皂：15-18份、高速机油：60-70份，该发明能够克服冷却及防锈效果差的缺点，保证产品质量的目的，但该车床用切削油抗菌性能差，容易腐败和变质。
发明内容
有鉴于此，本发明目的之一在于提供一种抗菌型切削油，该抗菌型切削油解决了切削油抗菌性能差和易腐败和变质。
为达此目的，本发明采用以下技术方案：
一种抗菌型切削油，按质量份计，包括以下组分：
所述超分子化合物为水杨醛缩氨基硫脲与金属氧簇合成的具有生物活性的物质。
本发明中的超分子化合物为水杨醛缩氨基硫脲和多金属氧簇(POMs)合成的具有生物活性的三维网状超分子化合物，多金属氧簇是一类骨架结构中富含Mo、W、V、Nb和Ta 5种过渡元素的金属-氧簇合物，POMs在结构化学、分析化学、食品化学、表面科学、医药、电化学、光化学和催化等方面有着广泛的应用，可以为Mo-氧簇合物，其超分子分子式为C8H6N3S(H2Mo2O7)，简称H2L，该超分子化合物具有极强的仿生性能，能够进行DNA切割，引入到切削油中抗菌防腐败性能大大的得到提高，为了防止该切削油腐败和变质，本发明引入了具有极强杀菌性能的超分子化合物，具有良好的杀菌和防腐的作用，且对环境无毒害。
其中，所述基础油选自动物油和/或植物油，优选牛油、猪油、菜籽油或蓖麻油中的一种或至少两种的混合物，进一步优选牛油、猪油、菜籽油和蓖麻油的混合物。
其中，所述表面活性剂选自斯盘-60、吐温-80或OP-10中的一种或至少两种的混合物，优选斯盘-60、吐温-80和OP-10的混合物；
优选地，所述斯盘-60、吐温-80和OP-10的质量比为1:1～3:1.5～3，进一步优选1:1:1.5。
其中，所述极压抗磨剂选自石油磺酸钡、硼酸酯或苯并三氮唑中的一种或至少两种的混合物，优选石油磺酸钡、硼酸酯和苯并三氮唑的混合物。
其中，所述防锈剂选自油酸三乙醇胺、油酸二乙醇胺或石油磺酸钠中的一种或至少两种的混合物，优选油酸三乙醇胺、油酸二乙醇胺和石油磺酸钠的混合物；
优选地，所述油酸三乙醇胺、油酸二乙醇胺和石油磺酸钠的质量比为1:1～2:3～4，进一步优选1:1:3。
其中，所述水杨醛缩氨基硫脲与金属氧簇的质量比为1:4～10。
其中，按质量百分数计，包括以下组分：
其中，按质量百分数计，包括以下组分：
本发明的目的之二在于提供一种上述抗菌型切削油的制备方法，采用该制备方法制备的抗菌型切削油防腐性能强，不易变质。
一种如上述抗菌型切削油的制备方法，包括以下步骤：
(1)按照配方，将基础油加入容器中调匀，加热，加入极压抗磨添加剂、防锈剂和超分子化合物，搅拌，得到混合液；
(2)对所述混合液进行加热，加入表面活性剂，乳化均匀后冷却，得到抗菌型切削油。
其中，所述步骤(1)中加热温度为30～50℃，优选40℃；搅拌时间为2～4h，优选3h；
优选地，所述步骤(2)中加热温度为50～60℃，优选55℃。
与现有技术相比，本发明的有益效果为：本发明在切削油中加入由水杨醛缩氨基硫脲与金属氧簇合成的超分子化合物，切削油中抗菌防腐败性能大大的得到提高，防止该切削油腐败和变质，本发明的抗菌型切削油具有良好的杀菌和防腐的作用，且对环境无毒害。
具体实施方式
下面通过实施例来进一步说明本发明的技术方案。
实施例1
本实施例中的抗菌型切削油，按质量百分数计，包括以下组分：
上述抗菌型切削油的制备方法，包括以下步骤：
将牛油、猪油、菜籽油和蓖麻油加入容器中调匀，加热至35℃，加入石油磺酸钡、硼酸酯、苯并三氮唑、防锈剂和超分子化合物，搅拌3h，得到混合液；
对所述混合液进行加热，加入表面活性剂，乳化均匀后冷却，得到抗菌型切削油。
实施例2
本实施例中的抗菌型切削油，按质量百分数计，包括以下组分：
上述抗菌型切削油的制备方法，包括以下步骤：
将牛油、猪油、菜籽油和蓖麻油加入容器中调匀，加热至35℃，加入石油磺酸钡、硼酸酯、苯并三氮唑、防锈剂和超分子化合物，搅拌3h，得到混合液；
对所述混合液进行加热，加入表面活性剂，乳化均匀后冷却，得到抗菌型切削油。
实施例3
本实施例中的抗菌型切削油，按质量百分数计，包括以下组分：
上述抗菌型切削油的制备方法，包括以下步骤：
将牛油、猪油、菜籽油和蓖麻油加入容器中调匀，加热至35℃，加入石油磺酸钡、硼酸酯、苯并三氮唑、防锈剂和超分子化合物，搅拌3h，得到混合液；
对所述混合液进行加热，加入表面活性剂，乳化均匀后冷却，得到抗菌型切削油。
实施例4
本实施例中的抗菌型切削油，按质量百分数计，包括以下组分：
上述抗菌型切削油的制备方法，包括以下步骤：
将牛油、猪油、菜籽油和蓖麻油加入容器中调匀，加热至35℃，加入石油磺酸钡、硼酸酯、苯并三氮唑、防锈剂和超分子化合物，搅拌3h，得到混合液；
对所述混合液进行加热，加入表面活性剂，乳化均匀后冷却，得到抗菌型切削油。
测试：将实施例1-4制得的抗菌型切削油进行相关性能测试，结果如下表：
从上表可以看出，实施例1～4中的抗菌型切削油的抗腐蚀和抗菌性能，能够防止抗菌型切削油腐败和变质。
本发明的抗菌型切削油具有良好的耐腐蚀抗菌性能强的作用，在金属切削的过程中能很好的起到润滑、光洁、防锈防腐蚀的作用，该切削油所添加的添加剂也都是绿色环保可生物降解的。
尽管本发明中所涉及的数值范围(尺寸、工艺参数)在上述实施例中未列举出具体数值，但本领域的技术人员完全可以想象到只要落入上述该数值范围内的任何数值均可实施本发明，当然也包括若干项数值范围内具体值的任意组合。此处，出于篇幅的考虑，省略了给出某一项或多项数值范围内具体值的实施例，此不应当视为本发明的技术方案的公开不充分。
申请人声明，本发明通过上述实施例来说明本发明的技术原理。这些描述只是为了解释本发明的原理，而不能以任何方式解释为对本发明保护范围的限制。所属技术领域的技术人员应该明了，对本发明的任何改进，对本发明产品各原料的等效替换及辅助成分的添加、具体方式的选择等，均落在本发明的保护范围和公开范围之内。
Claims (10)
1.一种抗菌型切削油，其特征在于，按质量份计，包括以下组分：
所述超分子化合物为水杨醛缩氨基硫脲与金属氧簇合成的具有生物活性的物质。
2.根据权利要求1所述的抗菌型切削油，其特征在于，所述基础油选自动物油和/或植物油，优选牛油、猪油、菜籽油或蓖麻油中的一种或至少两种的混合物，进一步优选牛油、猪油、菜籽油和蓖麻油的混合物。
3.根据权利要求1所述的抗菌型切削油，其特征在于，所述表面活性剂选自斯盘-60、吐温-80或OP-10中的一种或至少两种的混合物，优选斯盘-60、吐温-80和OP-10的混合物；
优选地，所述斯盘-60、吐温-80和OP-10的质量比为1:1～3:1.5～3，进一步优选1:1:1.5。
4.根据权利要求1所述的抗菌型切削油，其特征在于，所述极压抗磨剂选自石油磺酸钡、硼酸酯或苯并三氮唑中的一种或至少两种的混合物，优选石油磺酸钡、硼酸酯和苯并三氮唑的混合物。
5.根据权利要求1所述的抗菌型切削油，其特征在于，所述防锈剂选自油酸三乙醇胺、油酸二乙醇胺或石油磺酸钠中的一种或至少两种的混合物，优选油酸三乙醇胺、油酸二乙醇胺和石油磺酸钠的混合物；
优选地，所述油酸三乙醇胺、油酸二乙醇胺和石油磺酸钠的质量比为1:1～2:3～4，进一步优选1:1:3。
6.根据权利要求1所述的抗菌型切削油，其特征在于，所述水杨醛缩氨基硫脲与金属氧簇的质量比为1:4～10。
7.根据权利要求1所述的抗菌型切削油，其特征在于，按质量百分数计，包括以下组分：
8.根据权利要求1所述的抗菌型切削油，其特征在于，按质量百分数计，包括以下组分：
9.一种如权利要求1所述抗菌型切削油的制备方法，其特征在于，包括以下步骤：
(1)按照配方，将基础油加入容器中调匀，加热，加入极压抗磨添加剂、防锈剂和超分子化合物，搅拌，得到混合液；
(2)对所述混合液进行加热，加入表面活性剂，乳化均匀后冷却，得到抗菌型切削油。
10.根据权利要求9所述的制备方法，其特征在于，所述步骤(1)中加热温度为30～50℃，优选40℃；搅拌时间为2～4h，优选3h；
优选地，所述步骤(2)中加热温度为50～60℃，优选55℃。
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