CN106346963A - Battery label printing thermal transfer ribbon and preparation method thereof - Google Patents

Battery label printing thermal transfer ribbon and preparation method thereof Download PDF

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Publication number
CN106346963A
CN106346963A CN201610720814.1A CN201610720814A CN106346963A CN 106346963 A CN106346963 A CN 106346963A CN 201610720814 A CN201610720814 A CN 201610720814A CN 106346963 A CN106346963 A CN 106346963A
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Prior art keywords
label printing
battery label
carbon ribbon
layer
thickness
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CN201610720814.1A
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CN106346963B (en
Inventor
李金洞
杜小冬
岳修锋
乔鲜花
杨盼盼
王蓬勃
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Jiaozuo Zhuoli Film Material Co ltd
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Zhuoli Imaging Technology Co ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J31/00—Ink ribbons; Renovating or testing ink ribbons
    • B41J31/05—Ink ribbons having coatings other than impression-material coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09J161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C09J161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
    • C09J193/04—Rosin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Impression-Transfer Materials And Handling Thereof (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention belongs to the technical field of thermoprinting materials, and particularly relates to a battery label printing thermal transfer ribbon and a preparation method thereof. The carbon ribbon comprises a base band, and a back coating, a color layer and an adhesive layer which are respectively arranged on two sides of the base band, wherein the adhesive layer is coated on the surface of the color layer; the adhesive layer is divided into two layers: the upper layer is a catalyst layer, and the components of the catalyst layer comprise 80-90% of rosin modified maleic acid resin and 10-20% of assistant aqueous paraffin slurry in percentage by mass; the lower layer is a main resin layer and is composed of high imino group melamine resin. The battery label printing thermal transfer ribbon provided by the invention has the advantages of high adhesive force, organic solvent wiping resistance, high temperature resistance and the like, and meanwhile, the battery label printing thermal transfer ribbon provided by the invention has a simple and convenient preparation method and is easy to popularize and apply, so that the battery label printing thermal transfer ribbon has good popularization and application values.

Description

A kind of battery label printing carbon ribbon and preparation method thereof
Technical field
The invention belongs to technical field of hot stamping materials is and in particular to a kind of battery label printing carbon ribbon and preparation method thereof.
Background technology
In recent years, new energy technology is promoted and the technology of lithium electricity industry develops, and the volume of production of lithium battery and sales volume also exist Rapidly increase, the label being applied to battery industry is also in increase progressively.Simultaneously with the multiformity of applied environment, lithium battery Manufacturing enterprise also steps up to the performance requirement of battery label, particularly: battery label will have enough resistance to alcohol repellency, wear-resisting Property, and can in high temperature coating process trace not impaired.
Existing battery label majority is still being made using Conventional printing process, and it is little that it cannot realize digital printing etc. The performance such as the requirement of type, especially wearability, heat-resisting quantity cannot preferably meet use demand.Make mark in thermal transfer industry Sign day by day ripe today, prepared using carbon ribbon and meet the label of above-mentioned requirements just there is highly important application value.
Content of the invention
Present invention aim at providing a kind of battery label printing carbon ribbon and preparation method thereof, prepared label product exists Wearability, the resistance to aspect of performance such as alcohol repellency can preferably meet existing use demand.
Details are as follows for the technical solution used in the present invention.
A kind of battery label printing carbon ribbon, the back coating being respectively provided with including base band, base band two sides and color layers and coating The adhesive layer with latency reaction solidification is had to constitute in color layer surface；
Described base thickness is 4.4 ~ 4.6 μm, and back coating thickness is 0.1 ~ 0.2 μm, and color layers thickness is 1 ~ 2 μm, adhesive layer Thickness is 1.0 ~ 1.2 μm, and battery label printing carbon ribbon gross thickness is 6.5 ~ 7.5 μm；
Described base band, is, for example, specifically pet film；
Described back coating and color layers can be prepared from by prior art, also refer to following formula and are prepared from:
Back coating adopts acryl-modified silicone resin resin, and wherein silicone content is 25%；
Color layers adopt vistanex and pigment, auxiliary agent to constitute, by quality ratio, vistanex: pigment: auxiliary agent=4:0.5 ~1.0:0.2~0.5；
Described adhesive layer is divided into two-layer again:
Upper strata (top layer) is catalyst layer, and its thickness is 0.3 ~ 0.5 μm；Its composition is by Abietyl modified maleic acid resin and auxiliary agent water Property paraffin slurry constitute, by percentage to the quality, Abietyl modified maleic acid resin accounts for 70 ~ 90%, auxiliary agent aqueous paraffin slurry accounting 10 ~ 30%；
Lower floor's (adjacent color layers) is main body resin bed, and its thickness is 0.6 ~ 0.8 μm, is made up of high imino group melmac.
The preparation method of described battery label printing carbon ribbon, comprises the steps:
(1) first, it is coated with back coating in base band one side surface, standby after drying；
During coating back coating, by quality ratio, can be in solvent: the ratio of back of the body varnish (back coating material)=8:2, by back coating thing It is coated after material dissolved dilution, during drying, drying temperature may be designed as 80 ~ 100 DEG C again；
(2) secondly, another side surface of the base band of coating back coating is coated with color layers in step (1), standby after drying；
During coating color layers, by quality ratio, can be in toluene: the ratio of vistanex=4:1, with toluene by polyolefin tree tree After liposoluble solution, add pigment and auxiliary agent to be ground, be coated again after being ground drying, drying temperature is designed as 80 ~ 100 ℃；
(3) the 3rd, in proportion using organic solvent by after Abietyl modified maleic acid resin and aqueous paraffin wax liquor dissolved dilution, apply Cloth, on the color layers in step (2), makes catalyst layer after drying, standby；Described organic solvent is, for example, specifically second Alcohol；
During organic solvent dissolving material, by quality ratio, ethanol: (Abietyl modified maleic acid resin+wax liquor)=5:1(is with mass ratio Meter, Abietyl modified maleic acid resin: wax liquor=5:1), drying temperature is preferably arranged to 90 ~ 100 DEG C；
(4) the 4th, in proportion using organic solvent by after high imino group melmac dissolved dilution, it is uniformly coated on step (3) catalyst layer surface, is battery label printing carbon ribbon provided herein after drying；
During coating, by quality ratio, organic solvent: high imino group melmac=8:2, described organic solvent is concrete for example For isopropanol.
One of main innovation point of the present invention is to employ the adhesive layer structure with certain latency reaction solidification, In this Rotating fields, because so that the waxiness (aqueous paraffin slurry) in catalyst layer is free in catalyst layer the reason preparation temperature Surface, serves preferably buffer action to Abietyl modified maleic acid resin and high imino group melmac, so that Can preserve for a long time when battery label printing carbon ribbon is below 50 DEG C；And when specifically used, because when thermal transfer operates, temperature is relatively Wax can preferably be melted by high (TRANSIENT HIGH TEMPERATURE is up to 180 DEG C), so that Abietyl modified maleic acid resin and high imino group three Cymel combines and reacts solidification, and then bonds in printing material, thus making it have stronger firmness.
In general, battery label printing carbon ribbon provided by the present invention has high adhesion force, organic solvent-resistant wipes, resistance to The advantages of high temperature, specifically, through conventional taber instrument wear testing, battery label printing carbon ribbon Rubbing number of the present invention reaches More than 200 times (existing tradition carbon ribbon is at 50 times about), resistance to alcohol performance reaches more than 100 times, and (existing tradition carbon ribbon is at 50 times Left and right)；Further application experiment shows, battery label is through, in high temperature (110 ~ 150 DEG C) coating process, adhesive layer is again Solidified, be further ensure that trace is indeformable, not damaged；Simultaneously as battery label provided by the present invention prints carbon Band its preparation method easy it is easy to popularization and application, thus there is preferably application value.
Specific embodiment
With reference to embodiment, technical scheme is described in detail as follows.Before introducing specific embodiment, only In following embodiments, involved partial material situation is briefly described as follows.
Material situation:
Pet film, thickness is 4.5 ± 0.2 μm of thin film, and longitudinal tensile strength is not less than 190mpa, DuPont product；
Vistanex, softening point: 85 ~ 90 DEG C, melting viscosity 3000 ~ 3800, Mitsui Chemical Manufacture；
Abietyl modified maleic acid resin, at 95 ~ 115 DEG C, acid number, in 180 ~ 200mg koh/g, is U.S.'s cyanogen specialization work to softening point Company produces；
Aqueous paraffin is starched, and particle diameter is 0.2 ~ 0.6 μm, and solid content 35 ~ 45%, produces for German Bi Ke chemistry (byk)；
High imino group melmac, its primary response group is high imino group, is that Qing Te chemical company of the U.S. produces.
Embodiment 1
The battery label printing carbon ribbon that the present embodiment is provided, is made by the steps and forms:
(1) first, it is coated with back coating in base band one side surface, standby after drying；
During coating back coating, by quality ratio, by solvent: (back coating material, silicone content is 25% acrylic acid to back of the body varnish Modified organic silicone resin)=8:2 ratio, by back coating material dissolution dilute after be coated again, during drying, drying temperature meter For 90 DEG C, back coating thickness is 0.2 μm；
(2) secondly, another side surface of the base band of coating back coating is coated with color layers in step (1), standby after drying；
During coating color layers, by quality ratio, vistanex: pigment: auxiliary agent=4:0.8:0.5；By toluene: vistanex= Vistanex is first dissolved by the ratio of 4:1 with toluene, is subsequently adding pigment and auxiliary agent is ground, enter after being ground again Row coating, during drying, drying temperature is designed as 100 DEG C, and color layers thickness is 1.5 μm；
(3) in proportion using ethanol by after Abietyl modified maleic acid resin and aqueous paraffin wax liquor dissolved dilution, be coated on step (2), on the color layers in, after drying, make catalyst layer, standby；
During organic solvent dissolving material, by quality ratio, ethanol: (Abietyl modified maleic acid resin+wax liquor)=5:1(is with mass ratio Meter, Abietyl modified maleic acid resin: wax liquor=5:1), drying temperature is set to 90 DEG C；Drying rear catalyst thickness degree is 0.45 μ m；
(4) in proportion using organic solvent (isopropanol) by after high imino group melmac dissolved dilution (by quality ratio, Isopropanol: high imino group melmac=8:2), it is uniformly coated on the catalyst layer surface of step (3), after 90 DEG C of drying i.e. For battery label printing carbon ribbon provided herein；Matrix resin thickness degree is 0.7 μm；Prepared carbon ribbon gross thickness is 7.35 μm (4.5 μm of pet thickness).
In the present embodiment, after the completion of carbon ribbon preparation, color layer weight is 25g, and catalyst layer weight is 5g, matrix resin layer Weight is 16g.
With regard to the battery label printing carbon ribbon prepared by the present embodiment, using taber instrument wear testing (method of testing: with rubbing Wipe instrument friction and print specimen page to scanner None- identified, record Rubbing number), its Rubbing number is up to 260 times；Solvent is surveyed Take temperature bright, its Rubbing number is up to 150 times.
Embodiment 2
The battery label printing carbon ribbon that the present embodiment is provided, its preparation method is substantially the same manner as Example 1, but partial parameters are adjusted Whole as follows:
In set-up procedure (1), drying temperature is 90 DEG C, back coating thickness 0.2 m；
In set-up procedure (2), drying temperature is 100 DEG C, and color layers thickness is 1.6 m；
In set-up procedure (3), drying temperature is 90 DEG C, and catalyst layer thickness is 0.3 m；
In set-up procedure (4), drying temperature is 90 DEG C, and matrix resin thickness degree is 0.8 m；
Prepared carbon ribbon gross thickness be 7.3 m about (pet film thickness be 4.4 m).
In the present embodiment, color layer weight be 23g(by quality ratio, vistanex: pigment: auxiliary agent=4:0.5: 0.2)；Catalyst layer weight be 5g(by quality ratio, Abietyl modified maleic acid resin: wax liquor=4:1.5)；Matrix resin layer weight Measure as 18g.
Prepared battery label printing carbon ribbon, conventional taber instrument wear testing, its Rubbing number reaches 200 times；Solvent The test of taber instrument shows, its Rubbing number reaches 105 times.
Embodiment 3
The battery label printing carbon ribbon that the present embodiment is provided, its preparation method is substantially the same manner as Example 1, but partial parameters are adjusted Whole as follows:
In set-up procedure (1), drying temperature is 90 DEG C, back coating thickness 0.2 m；
In set-up procedure (2), drying temperature is 100 DEG C, and color layers thickness is 1.0 m；
In set-up procedure (3), drying temperature is 90 DEG C, and catalyst layer thickness is 0.5 m；
In set-up procedure (4), drying temperature is 90 DEG C, and matrix resin thickness degree is 0.6 m；
Prepared battery label printing carbon ribbon thickness is 4.5 μm of 6.8 m(pet thickness).
In the present embodiment, color layer weight be 19g(by quality ratio, vistanex: pigment: auxiliary agent=4:0.7: 0.25), catalyst layer weight be 6g(by quality ratio, Abietyl modified maleic acid resin: wax liquor=5:1.5)；Matrix resin layer weight Measure as 15g.
Prepared battery label printing carbon ribbon, conventional taber instrument wear testing, its Rubbing number reaches 150 times；Solvent The test of taber instrument shows, its Rubbing number reaches 95 times.
Embodiment 4
The battery label printing carbon ribbon that the present embodiment is provided, its preparation method is substantially the same manner as Example 1, but partial parameters are adjusted Whole as follows:
In set-up procedure (1), drying temperature is 90 DEG C, back coating thickness 0.2 m；
In set-up procedure (2), drying temperature is 100 DEG C, and color layers thickness is 1.3 m；
In set-up procedure (3), drying temperature is 90 DEG C, and catalyst layer thickness is 0.4 m；
In set-up procedure (4), drying temperature is 90 DEG C, and matrix resin thickness degree is 0.7 m；
Prepared battery label printing carbon ribbon thickness is 4.5 μm of 7.1 m(pet thickness).
In the present embodiment, color layer weight be 19g(by quality ratio, vistanex: pigment: auxiliary agent=4:1:0.5)； Catalyst layer weight be 6g(by quality ratio, Abietyl modified maleic acid resin: wax liquor=5:1.5)；Matrix resin layer weight is 15g.
Prepared battery label printing carbon ribbon, conventional taber instrument wear testing, its Rubbing number reaches 190 times；Solvent The test of taber instrument shows, its Rubbing number reaches 115 times.
Embodiment 5
The battery label printing carbon ribbon that the present embodiment is provided, its preparation method is substantially the same manner as Example 1, but partial parameters are adjusted Whole as follows:
In set-up procedure (1), drying temperature is 90 DEG C, back coating thickness 0.2 m；
In set-up procedure (2), drying temperature is 100 DEG C, and color layers thickness is 1.4 m；
In set-up procedure (3), drying temperature is 90 DEG C, and catalyst layer thickness is 0.4 m；
In set-up procedure (4), drying temperature is 90 DEG C, and matrix resin thickness degree is 0.6 m；
Prepared battery label printing carbon ribbon thickness is 4.5 μm of 7.1 m(pet thickness).
In the present embodiment, color layer weight be 19g(by quality ratio, vistanex: pigment: auxiliary agent=4:0.8: 0.2)；Catalyst layer weight be 6g(by quality ratio, Abietyl modified maleic acid resin: wax liquor=5:1)；Matrix resin layer weight For 15g.
Prepared battery label printing carbon ribbon, conventional taber instrument wear testing, its Rubbing number reaches 150 times；Solvent The test of taber instrument shows, its Rubbing number reaches 95 times.
It should be noted that above-described embodiment is only presently preferred embodiments of the present invention, the not exhaustion of technical scheme, upper On the basis of stating embodiment, part Experiment parameter (such as material proportion, drying temperature etc.) is suitably adjusted and can be obtained this Whole technical schemes of invention, repeat no more.

Claims (9)

1. a kind of battery label printing carbon ribbon is it is characterised in that include back coating and the color that base band, base band two sides are respectively provided with Layer, wherein color layer surface is coated with adhesive layer；
Described base thickness is 4.4 ~ 4.6 μm, and back coating thickness is 0.1 ~ 0.2 μm, and color layers thickness is 1 ~ 2 μm, adhesive layer Thickness is 1.0 ~ 1.2 μm, and battery label printing carbon ribbon gross thickness is 6.5 ~ 7.5 μm；
Described adhesive layer is divided into two-layer:
Upper strata is catalyst layer, and its thickness is 0.3 ~ 0.5 μm；Its composition is by Abietyl modified maleic acid resin and auxiliary agent aqueous paraffin Slurry is constituted, and by percentage to the quality, Abietyl modified maleic acid resin accounts for 70 ~ 90%, and auxiliary agent aqueous paraffin starches accounting 10 ~ 30%；
Lower floor is main body resin bed, and its thickness is 0.6 ~ 0.8 μm, is made up of high imino group melmac.
2. battery label printing carbon ribbon as claimed in claim 1 is it is characterised in that described base band is pet film.
3. battery label printing carbon ribbon as claimed in claim 1 is it is characterised in that described back coating is using acrylic acid modified organic Silicones, wherein silicone content are 25%；
Described color layers adopt vistanex and pigment, auxiliary agent to constitute, by percentage to the quality, vistanex: pigment: help Agent=4:0.5 ~ 1.0:0.2 ~ 0.5.
4. battery label printing carbon ribbon as claimed in claim 1 is it is characterised in that in catalyst layer, by quality ratio, Colophonium changes Property maleic acid resin: auxiliary agent aqueous paraffin slurry=5:1,4:1.5 or 4:1.5.
5. the preparation method of battery label printing carbon ribbon described in any one of claim 1 ~ 4 is it is characterised in that include following walking Rapid:
(1) first, it is coated with back coating in base band one side surface, standby after drying；
(2) secondly, another side surface of the base band of coating back coating is coated with color layers in step (1), standby after drying；
(3) the 3rd, in proportion using organic solvent by after Abietyl modified maleic acid resin and aqueous paraffin wax liquor dissolved dilution, apply Cloth, on the color layers in step (2), makes catalyst layer after drying, standby；
(4) the 4th, in proportion using organic solvent by after high imino group melmac dissolved dilution, it is uniformly coated on step (3) catalyst layer surface, dries.
6. the preparation method of battery label printing carbon ribbon described in claim 5 is it is characterised in that in step (1), be coated with back coating When, by quality ratio, in solvent: the ratio of resin=8:2, it is coated after back coating resin dissolved dilution again, during drying, Drying temperature is designed as 80 ~ 100 DEG C.
7. the preparation method of battery label printing carbon ribbon described in claim 5 is it is characterised in that in step (2), be coated with color layers When, by quality ratio, in toluene: the ratio of vistanex=4:1, with toluene by after the dissolving of polyolefin tree resin, add pigment It is ground with auxiliary agent, be coated after being ground drying, drying temperature is designed as 80 ~ 100 DEG C again.
8. the preparation method of battery label printing carbon ribbon described in claim 5 is it is characterised in that in step (3), described organic molten Agent is ethanol；During dissolving material, by quality ratio, ethanol: (Abietyl modified maleic acid resin+wax liquor)=5:1, drying temperature sets It is set to 90 ~ 100 DEG C.
9. the preparation method of battery label printing carbon ribbon described in claim 5 is it is characterised in that in step (4), described organic molten Agent is isopropanol, during coating, by quality ratio, organic solvent: high imino group melmac=8:2.
CN201610720814.1A 2016-08-25 2016-08-25 Battery label printing thermal transfer ribbon and preparation method thereof Active CN106346963B (en)

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Publication number Priority date Publication date Assignee Title
CN110869999A (en) * 2017-07-14 2020-03-06 伊利诺斯工具制品有限公司 Color-changing heat transfer label
CN107471840A (en) * 2017-08-24 2017-12-15 河南卓立膜材料股份有限公司 A kind of water-based mixed base carbon ribbon special TTO and preparation method thereof

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