CN106336978A - Soft hydrophilic antistatic multifunctional detergent - Google Patents
Soft hydrophilic antistatic multifunctional detergent Download PDFInfo
- Publication number
- CN106336978A CN106336978A CN201610638579.3A CN201610638579A CN106336978A CN 106336978 A CN106336978 A CN 106336978A CN 201610638579 A CN201610638579 A CN 201610638579A CN 106336978 A CN106336978 A CN 106336978A
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- CN
- China
- Prior art keywords
- quaternary ammonium
- ammonium salt
- surfactant
- polysiloxane
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to a soft hydrophilic antistatic multifunctional detergent mainly including an anionic surfactant playing a cleaning effect, polysiloxane quaternary ammonium salt, a filling agent, an anti-reprecipitation agent, a preservative, a whitening agent, an essence, a zwitterionic surfactant and a nonionic surfactant, wherein the polysiloxane quaternary ammonium salt is amide quaternary ammonium salt having both ends with hydroxyls, is named as quaternary ammonium salt-80 in foreign, and the polysiloxane quaternary ammonium salt can be compounded with commonly used anionic surfactants, such as alkyl alcohol sulfate, alkyl alcohol ether sulfate, alkylbenzene sulfonate, and olefin sulfonate. The soft hydrophilic antistatic multifunctional detergent has better flexibility, hydrophilicity and antistatic property, is applied to fabrics and personal hair washing and hair care, and has more obvious effect, is applied to cars, leather and furniture and can play roles in increasing luster and resisting static electricity, can achieve the effect by one step, and avoids the problems of generation of silicon spots, hydrophilia reduction, antistatic property decrease and the like.
Description
Technical field
The invention belongs to detergent Technology field, it is related to a kind of soft hydrophilic anti-static multifunctional detergent.
Background technology
Fabric softener is typically made up of cationic surfactant, such as octadecane dimethyl benzyl ammonium chloride；Double 18
Alkyl dimethyl ammonium chloride etc..The ester group octadecyl ammonium chloride developed in recent years has hydrophilic hydroxyl simultaneously, and can biology drop
Solution, has obtained more and more widely using.In order that the fabrics feel soft after washing is it is necessary to be carried out in two steps, first use cloudy from
Detergent laundering of textile fabrics based on son, then with adding cationic softener (softener) after clear water rinse, makes cation
Type softener is adsorbed onto on fabric, then centrifuge dripping → dry.
For easy operation, washing softness one step is made to complete, people once attempted with cationic surfactant and anion
Detergent adds washing tub together, but because cationic surfactant and anion surfactant interaction generation do not dissolve in
The condensation product of water, is attached on fabric, not only affects outward appearance, medicated clothing does not wash clean, and is not much submissive effect yet.People once used
The polysiloxanes (emulsified silicone oil) of emulsion-type are compounded as submissive detergent with the detergent of anionic, due to silicone oil hydrophobicity
Too strong, being easily deposited on and become silicon speckle it is difficult to remove on fabric, even if there is no obvious silicon speckle, after washing, making fabric hydrophilic
Reduce, and easily stain dust, antistatic behaviour reduces.
Content of the invention
In order to overcome the disadvantages mentioned above of prior art, the present invention provides a kind of soft hydrophilic anti-static multifunctional detergent,
It is shinny and other effects that it can give the excellent soft hydrophilic antistatic of substrate, can settle at one go, it is to avoid silicon speckle, parent simultaneously
The problems such as aqueouss decline, antistatic behaviour reduces.
The technical solution adopted for the present invention to solve the technical problems is: a kind of soft hydrophilic anti-static multifunctional washing
Agent, has mainly included the anion surfactant of cleaning action, polysiloxane quaternary ammonium, filler, anti-has sunk agent, anti-corrosion again
Agent, brightening agent, essence, zwitterionic surfactant and nonionic surfactant, wherein polysiloxane quaternary ammonium are two ends
For hydroxyl acid amide type quaternary ammonium salt, external title quaternary ammonium salt 80, this polysiloxane quaternary ammonium not only can be with conventional anion
Surfactant compatibility, such as alkyl alcohol sulfate；Alkyl alcohol ether sulfate；Alkylbenzenesulfonate；Alkenyl sulphonate, or even can be with
Fatty acid soaps surfactant compatibility, will not produce precipitation when they being mixed by a certain percentage, will not condense, not assemble
Amass on fabric and on substrate body, and clean result does not reduce, this polysiloxane quaternary ammonium is the hydroxyl alkyl in two ends
Amidoquat salt such as laurylamide propyl group -2- hydroxyl dimethyl acetic acid ammonium, molecular formula is:
ch3ch3
? ? ?
c11h23conh(ch2)3n(ch3)2-ch2-ch-ch2o(ch2)3-sio〔si(ch3)2o〕nsi-(ch2)3o
Ac
oh ch3ch3
ch3
??
-ch2-co-ch2-n-(ch2)3-nhco c11h23
? ?
oh ch3ac
N=10～50 in formula, the middle dimethyl siloxane chain for 10 50 units, because molecular weight is larger, two ends have relatively
Big amide ether type quaternary ammonium group, so good hydrophilic property, completely water-soluble, can be with anionic surfactant compatibility.Hydrophilic anti-
Static behaviour is good.
Described polysiloxane quaternary ammonium, to hold containing hydrogen silicone oil as raw material, is first reacted with (+)-2,3-Epoxy-1-propanol propylene ether, generates end ring
Oxygen silicone oil, then quaternized with the salt open loop of amido propyl dimethyl tertiary amine, generate the quaternized water-soluble silicon oil in end.
Described polysiloxane quaternary ammonium is as shown in the table with various anion surfactant intermiscibilities:
Anionic surfactant concentration this silicon quaternary ammonium salt consumption aqueous solution intermiscibility
Sodium lauryl sulphate 5% 1% is sufficiently stirred for mixing
- sodium olefin sulfonate 5% 1% is sufficiently stirred for mixing
Dodecyl polyoxyethylene sodium sulfate 5% 1% is sufficiently stirred for mixing
Fatty acid mixed potash soap 4% 1% is separately plus 2%cab mixes
Fatty acid mixed soda soap 4% 1% is separately plus 2%cab mixes
Mixed alkyl class sodium sulfonate 4% 1% is separately plus 2%cab mixes.
Described zwitterionic surfactant includes empgen BB；Cocamido propyl betaine or aminoacid system
Row.
The positive effect of the present invention is: has more excellent compliance；Hydrophilic；Antistatic behaviour.Be applied to fabric and
People's hair-washing hair-care, effect becomes apparent from.It is applied to automobile；Leather；Furniture can act the antistatic property that adds lustre to, and can settle at one go, keep away
Exempt to occur silicon speckle, the problems such as hydrophilic declines, antistatic behaviour reduces.
Specific embodiment
With reference to embodiment, the present invention is further described.
A kind of soft hydrophilic anti-static multifunctional detergent, has mainly included the anion surface active of cleaning action
Agent, polysiloxane quaternary ammonium, filler, anti-sink again agent, preservative, brightening agent, essence, zwitterionic surfactant and non-from
Sub- surfactant, wherein polysiloxane quaternary ammonium are two ends is hydroxyl acid amide type quaternary ammonium salt, external title quaternary ammonium salt 80,
This polysiloxane quaternary ammonium not only can be with conventional anion surfactant compatibility, such as alkyl alcohol sulfate；Alkyl ethoxylated sulfur
Hydrochlorate；Alkylbenzenesulfonate；Alkenyl sulphonate, or even they can be pressed certain with fatty acid soaps surfactant compatibility
Precipitation will not be produced during ratio mixing, will not condense, will not accumulate on fabric and on substrate body, and clean result does not drop
Low, this polysiloxane quaternary ammonium is the hydroxyl alkylamide quaternary ammonium salt such as laurylamide propyl group -2- hydroxyl two in two ends
Methyl acetic acid ammonium, molecular formula is:
ch3ch3
? ? ?
c11h23conh(ch2)3n(ch3)2-ch2-ch-ch2o(ch2)3-sio〔si(ch3)2o〕nsi-(ch2)3o
Ac
oh ch3ch3
ch3
??
-ch2-co-ch2-n-(ch2)3-nhco c11h23
? ?
oh ch3ac
N=10～50 in formula, the middle dimethyl siloxane chain for 10 50 units, because molecular weight is larger, two ends have relatively
Big amide ether type quaternary ammonium group, so good hydrophilic property, completely water-soluble, can be with anionic surfactant compatibility.Hydrophilic anti-
Static behaviour is good.
Described polysiloxane quaternary ammonium, to hold containing hydrogen silicone oil as raw material, is first reacted with (+)-2,3-Epoxy-1-propanol propylene ether, generates end ring
Oxygen silicone oil, then quaternized with the salt open loop of amido propyl dimethyl tertiary amine, generate the quaternized water-soluble silicon oil in end.
Described polysiloxane quaternary ammonium is as shown in the table with various anion surfactant intermiscibilities:
Anionic surfactant concentration this silicon quaternary ammonium salt consumption aqueous solution intermiscibility
Sodium lauryl sulphate 5% 1% is sufficiently stirred for mixing
- sodium olefin sulfonate 5% 1% is sufficiently stirred for mixing
Dodecyl polyoxyethylene sodium sulfate 5% 1% is sufficiently stirred for mixing
Fatty acid mixed potash soap 4% 1% is separately plus 2%cab mixes
Fatty acid mixed soda soap 4% 1% is separately plus 2%cab mixes
Mixed alkyl class sodium sulfonate 4% 1% is separately plus 2%cab mixes.
Described zwitterionic surfactant includes empgen BB；Cocamido propyl betaine or aminoacid system
Row.
Example one. fabric liquid softening detergent
Formula is as follows:
Sodium alkyl benzene sulfonate (30%) 50%
Amphion cab (30%) 17%
Nonionic surfactant apg (100%) 10%
1.2- propylene glycol (100%) 10%
Polysiloxane quaternary ammonium (50%) 6%
Deionized water 7%
Total 100%
Compound method: first weigh up deionized water, then sequentially add sodium alkyl benzene sulfonate, cab, apg, propylene glycol fully stir evenly
Afterwards, add end quaternary ammonium salt polysiloxanes, after stirring, become light yellow clear aqueous solution, solid content is 33% about.
This formula is used for doing washing after being watered, foaming abundancy, and clean ability is strong, and after washing, submissive effect is good, hydrophilic antistatic.
Example two. bubble bright car shampoo
Formula is as follows:
Sodium lauryl sulphate k-12 (85%) 25%
Amphion cab (30%) 17%
Nonionic aeo9(100%) 8.3%
1.2- propylene glycol (100%) 8.2%
Polysiloxane quaternary ammonium (50%) 5%
Deionized water 36.5%
Total 100%
Compound method: first that k-12 is soluble in water, then plus cab, aeo9, after propylene glycol heating for dissolving, add the poly- silicon of end quaternary ammonium salt
Oxygen alkane, stirring, be settled into transparent aqueous solution, solid content is 41%.
This formula can be used for body of a motor car washing, is sprayed onto vehicle body with spraying method, then with, after wet towel scouring, rinsing dry
Only.
Example three. transparent conditioning shampoo shampoo
Formula is as follows:
Aes(72%) 15%
Amphion cab (30%) 23%
6501(100%) 5%
Triethylene glycol butyl ether 3%
Polysiloxane quaternary ammonium (50%) 5%
nacl 2.5%
Appropriate soluble perfume
Citric acid (10%) adjusts ph6.0 in right amount
Deionized water 46%
Compound method: first weigh up deionized water, add cab, stirring and dissolving aes at 70 DEG C, add 6501, three after dissolving is good
Glycol butyl ether, end quaternary ammonium salt polysiloxanes, stirring and dissolving, then plus 6501, nacl, become clear solution, after being cooled to 40 DEG C, add water
Dissolubility essence, with 10% citric acid regulation ph6.0 about.
With the hair washing of this transparent shampoo, no matter hygrometric state, dry state feel be smooth, soft, antistatic, especially dry state is submissive, easily combs
Reason, hair is easily shaped.
The present invention has more excellent compliance；Hydrophilic；Antistatic behaviour.It is applied to fabric and personal hair-washing hair-care, effect
Fruit becomes apparent from.It is applied to automobile；Leather；Furniture can act the antistatic property that adds lustre to, and can settle at one go, it is to avoid silicon speckle, parent
The problems such as aqueouss decline, antistatic behaviour reduces.
Claims (4)
1. a kind of soft hydrophilic anti-static multifunctional detergent, is characterized in that: mainly included the anion table of cleaning action
Face activating agent, polysiloxane quaternary ammonium, filler, anti-agent, preservative, brightening agent, essence, the zwitterionic surfactant of sinking again
And nonionic surfactant, wherein polysiloxane quaternary ammonium be two ends be hydroxyl acid amide type quaternary ammonium salt, abroad claim quaternary ammonium
Salt 80, this polysiloxane quaternary ammonium not only can be with conventional anion surfactant compatibility, such as alkyl alcohol sulfate；Alkyl
Ether alcohol sulfate；Alkylbenzenesulfonate；Alkenyl sulphonate, or even can be with fatty acid soaps surfactant compatibility, that is, them
Precipitation will not be produced when mixing by a certain percentage, will not condense, will not accumulate on fabric and on substrate body, and wash effect
Fruit does not reduce, and this polysiloxane quaternary ammonium is the hydroxyl alkylamide quaternary ammonium salt such as laurylamide propyl group -2- in two ends
Hydroxyl dimethyl acetic acid ammonium, molecular formula is:
ch3ch3
? ? ?
c11h23conh(ch2)3n(ch3)2-ch2-ch-ch2o(ch2)3-sio〔si(ch3)2o〕nsi-(ch2)3o
Ac
oh ch3ch3
ch3
??
-ch2-co-ch2-n-(ch2)3-nhco c11h23
? ?
oh ch3ac
N=10～50 in formula, the middle dimethyl siloxane chain for 10 50 units, because molecular weight is larger, two ends have relatively
Big amide ether type quaternary ammonium group, so good hydrophilic property, completely water-soluble, can be with anionic surfactant compatibility；Hydrophilic anti-
Static behaviour is good.
2. soft hydrophilic anti-static multifunctional detergent as claimed in claim 1, is characterized in that: described polysiloxane quaternary ammonium with
End containing hydrogen silicone oil is raw material, first reacts with (+)-2,3-Epoxy-1-propanol propylene ether, generates end epoxy silicon oil, then with amido propyl dimethyl uncle
The salt open loop of amine is quaternized, generates the quaternized water-soluble silicon oil in end.
3. soft hydrophilic anti-static multifunctional detergent as claimed in claim 1, is characterized in that: described polysiloxane quaternary ammonium with
Various anion surfactant intermiscibilities are as shown in the table:
Anionic surfactant concentration this silicon quaternary ammonium salt consumption aqueous solution intermiscibility
Sodium lauryl sulphate 5% 1% is sufficiently stirred for mixing
- sodium olefin sulfonate 5% 1% is sufficiently stirred for mixing
Dodecyl polyoxyethylene sodium sulfate 5% 1% is sufficiently stirred for mixing
Fatty acid mixed potash soap 4% 1% is separately plus 2%cab mixes
Fatty acid mixed soda soap 4% 1% is separately plus 2%cab mixes
Mixed alkyl class sodium sulfonate 4% 1% is separately plus 2%cab mixes.
4. soft hydrophilic anti-static multifunctional detergent as claimed in claim 1, is characterized in that: described amphion surface activity
Agent includes empgen BB；Cocamido propyl betaine or amino acid series.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610638579.3A CN106336978A (en) | 2016-08-08 | 2016-08-08 | Soft hydrophilic antistatic multifunctional detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610638579.3A CN106336978A (en) | 2016-08-08 | 2016-08-08 | Soft hydrophilic antistatic multifunctional detergent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106336978A true CN106336978A (en) | 2017-01-18 |
Family
ID=57824358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610638579.3A Pending CN106336978A (en) | 2016-08-08 | 2016-08-08 | Soft hydrophilic antistatic multifunctional detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106336978A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107558267A (en) * | 2017-09-26 | 2018-01-09 | 广东溢达纺织有限公司 | The dyeing and finishing method and textile product of textile material |
| CN108085194A (en) * | 2017-12-11 | 2018-05-29 | 定远县杰仕达体育用品有限公司 | A kind of surface cleaning agent used after basketball production |
| CN117342956A (en) * | 2023-12-05 | 2024-01-05 | 广州恒广复合材料有限公司 | Preparation method for synthesizing quaternary ammonium salt-80 by utilizing microchannel reactor |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040167056A1 (en) * | 2002-04-10 | 2004-08-26 | Lentsch Steven E. | Fabric treatment compositions and methods for treating fabric in a dryer |
| CN101565896B (en) * | 2008-12-22 | 2011-07-27 | 上海氟聚化学产品有限公司 | Quaternary amino cation modified polysiloxane softening agent and preparation method thereof |
| CN104292467A (en) * | 2013-07-18 | 2015-01-21 | 赢创工业集团股份有限公司 | New amino acid-modified siloxanes, process for preparing them and application |
| CN104419241A (en) * | 2013-09-11 | 2015-03-18 | 赢创工业集团股份有限公司 | Coating composition comprising polysiloxane quats |
-
2016
- 2016-08-08 CN CN201610638579.3A patent/CN106336978A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040167056A1 (en) * | 2002-04-10 | 2004-08-26 | Lentsch Steven E. | Fabric treatment compositions and methods for treating fabric in a dryer |
| CN101565896B (en) * | 2008-12-22 | 2011-07-27 | 上海氟聚化学产品有限公司 | Quaternary amino cation modified polysiloxane softening agent and preparation method thereof |
| CN104292467A (en) * | 2013-07-18 | 2015-01-21 | 赢创工业集团股份有限公司 | New amino acid-modified siloxanes, process for preparing them and application |
| CN104419241A (en) * | 2013-09-11 | 2015-03-18 | 赢创工业集团股份有限公司 | Coating composition comprising polysiloxane quats |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107558267A (en) * | 2017-09-26 | 2018-01-09 | 广东溢达纺织有限公司 | The dyeing and finishing method and textile product of textile material |
| CN107558267B (en) * | 2017-09-26 | 2020-01-31 | 广东溢达纺织有限公司 | Dyeing and finishing method for textile material and textile product |
| CN108085194A (en) * | 2017-12-11 | 2018-05-29 | 定远县杰仕达体育用品有限公司 | A kind of surface cleaning agent used after basketball production |
| CN117342956A (en) * | 2023-12-05 | 2024-01-05 | 广州恒广复合材料有限公司 | Preparation method for synthesizing quaternary ammonium salt-80 by utilizing microchannel reactor |
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